The chemistry of niobium and tantalum:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Amsterdam [u.a.]
Elsevier
1967
|
| Schriftenreihe: | Topics in inorganic and general chemistry
10 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | VIII, 243 S. |
Internformat
MARC
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| 100 | 1 | |a Fairbrother, Fred |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a The chemistry of niobium and tantalum |c F. Fairbrother |
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| 650 | 7 | |a Metais E Seus Compostos (Quimica) |2 larpcal | |
| 650 | 7 | |a Niobium |2 gtt | |
| 650 | 7 | |a Quimica Inorganica |2 larpcal | |
| 650 | 7 | |a Tantalium |2 gtt | |
| 650 | 4 | |a Niobium | |
| 650 | 4 | |a Tantalum | |
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Datensatz im Suchindex
| _version_ | 1804116737306656768 |
|---|---|
| adam_text | THE CHEMISTRY OF
NIOBIUM AND TANTALUM
BY
F FAIRBROTHER, D Sc ,FRIC
Professor Emeritus,
University of Manchester (Great Britain)
ELSEVIER PUBLISHING COMPANY
AMSTERDAM/LONDON/NEWYORK
Contents
Preface , v
Introduction 1
Chapter ] Separation and Extraction Metallurgy 7
a Separation of the metals 7
b Extraction of the metals 10
References 14
Chapter 2 Physical Properties of the Metals 16
References 18
Chapter 3 Oxygen Compounds 20
a Anhydrous oxides 20
b Hydrous oxides 33
c Niobates and tantalates 36
(i) Water-soluble niobates, 36 - (ii) Water-soluble tantalates, 40 - (iii) An
hydrous niobates and tantalates (mixed oxides), 41 - (iv) Niobium and
tantalum bronzes, 47
d Hydrous oxide complexes 47
(i) a-Hydroxy-acid complexes, 47 - (ii) Di-ol complexes, 51 - (iii) Inorganic-
acid complexes, 53 - (iv) Amine complexes, 54 - (v j Water-insoluble com
plexes, 56
e Tropolone complexes 56
f Alkoxides and related compounds 58
g Nitrato and phosphato compounds 62
(i) Nitrates, 62 - (ii) Phosphates, 63
h Antimony-oxygen compounds 65
i Sulphato complexes 65
j Peroxo compounds 67
References 68
Chapter 4 Halogen Compounds 74
A Pentahalides and Their Derivatives
1 Pentafluorides 74
a Preparation 74
b Physical properties 76
c Chemical properties 78
(i) Reactions with non-ionic ligands, 78 - (ii) Reactions with ionic ligands,
80 - (iii) Niobium (V) and tantalum (V) oxide fluorides, 85
2 Pentachlorides 86
a Preparation 86
(i) From the metals, 86 - (ii) From the anhydrous or liydrous pentoxides, 86
b Physical properties 88
c Chemical properties 94
(i) Simple adducts, 94 - (ii) Chlorine-elimination reactions, 98 - (iii) Reduc
tion reactions, 100 - (iv) Reactions with anionic ligands, 100 - (v) Niobium
(V) and tantalum (V) oxide chlorides, 101
CONTENTS VII
3 Pentabromides 108
a Preparation 108
(i) From the anhydrous pentoxides, 108 - (ii) From the metals, 109
b Physical properties 110
c Chemical properties Ill
(i) Simple adducts, 111 - (ii) Bromine-elimination reactions, 112 - (iii)
Reduction reactions,~113 - (iv) Niobium (V) and tantalum (V) oxide bro
mides, 113
4 Pentaiodides 115
a Preparation 115
b Physical properties 116
c Chemical properties 117
(i) Niobium (V) and tantalum (V) iodides, 117 - (ii) Niubium (V) and
tantalum (V) oxide iodides, 118
B Sub-Halides and Their Derivatives
1 Tetrahalide s - 120
a Tetrafluorides 120
b Tetrachlorides 122
M(IV) oxide chlorides, 128
c Tetrabromides 129
d Tetraiodides 130
M(IV) oxide iodides, 132
2 Trihalide phases 133
a Trifluorides 133
(i) Niobium trifluoride, 133 - (ii) Tantalum trifluoride, 134
b Trichlorides 134
(i) Niobium trichloride, 134- (ii) Nb-;C18 136 - (iii) Tantalum trichlo
ride, 137
c Tribromides 138
(i) Niobium tribromide, 138 - (ii)Nb3Brg, 138 - (iii) Tantalum tribromide,
d Triiodides 140
(i) Niobium triiodide, 140 - (ii) Nb3I8, 141 - (iii) Tantalum triiodide, 141
3 Polynuclear halides containing M, clusters 142
a Fluorides 142
b Chlorides 144
(i) Anhydrous phases, 144 - (ii) Hydrated salts, 145
c Bromides 148
(i) Anhydrous phases, 148 - (ii) Hydrated salts, 149
d Iodides 150
References 152
Chapter 5 Hydrogen Systems 159
a General 159
b Niobium dihydride 164
c Molecular hydrides 165
References 166
Chapter 6 Carbon, Silicon and Boron Systems 167
a Carbon systems 167
(i) Carbides, 167 - (ii) Organometallic compounds, 171 - (iii) Cyanogen
compounds, 174
b Silicon systems 174
c Boron systems 179
References 184
VIII CONTENTS
Chapter 7 Nitrogen, Phosphorus, Arsenic, Antimony and Bismuth Systems 187
a Nitrogen systems 187
(i) The niobium-nitrogen system, 187 - (ii) Carbonitrides, 192 - (iii) Oxo-
nitrides, 192 - (iv) The tantalum-nitrogen system, 192 - (v) Tantalum oxide
nitride, 196- (vi) Molecular metal-nitrogen compounds, 196
b Phosphorus systems 197
c Arsenic systems 200
d Antimony systems 202
e Bismuth systems 205
References 205
Chapter 8 Sulphur, Selenium and Tellurium Systems 207
a Sulphur systems 207
(i) The niobium-sulphur system, 207 - (ii) The tantalum-sulphur system,
208 - (iii) Molecular metal-sulphur systems, 211
b Selenium and tellurium systems 212
(i) The niobium-selenium system, 213 - (ii) The niobium-tellurium system,
216 - (iii) The tantalum-selenium system, 217 - (iv) The tantalum-tellurium
system, 219
References 220
Chapter 9 Analytical Chemistry 222
a General 222
b Dissolution of the sample 224
c Separation from other metals 226
d Gravimetric methods 227
e Chromatographic separation 228
f Solvent extraction 229
g Colorimetric methods 229
h Radiochemical methods 231
References 232
Subject Index
a Niobium 235
b Tantalum 239
|
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| spelling | Fairbrother, Fred Verfasser aut The chemistry of niobium and tantalum F. Fairbrother Amsterdam [u.a.] Elsevier 1967 VIII, 243 S. txt rdacontent n rdamedia nc rdacarrier Topics in inorganic and general chemistry 10 Chemie gtt Metais E Seus Compostos (Quimica) larpcal Niobium gtt Quimica Inorganica larpcal Tantalium gtt Niobium Tantalum Niobverbindungen (DE-588)4280031-6 gnd rswk-swf Tantalverbindungen (DE-588)4184437-3 gnd rswk-swf Tantal (DE-588)4059023-9 gnd rswk-swf Niob (DE-588)4042362-1 gnd rswk-swf Tantalverbindungen (DE-588)4184437-3 s DE-604 Tantal (DE-588)4059023-9 s Niobverbindungen (DE-588)4280031-6 s Niob (DE-588)4042362-1 s Topics in inorganic and general chemistry 10 (DE-604)BV001888756 10 HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001497407&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Fairbrother, Fred The chemistry of niobium and tantalum Topics in inorganic and general chemistry Chemie gtt Metais E Seus Compostos (Quimica) larpcal Niobium gtt Quimica Inorganica larpcal Tantalium gtt Niobium Tantalum Niobverbindungen (DE-588)4280031-6 gnd Tantalverbindungen (DE-588)4184437-3 gnd Tantal (DE-588)4059023-9 gnd Niob (DE-588)4042362-1 gnd |
| subject_GND | (DE-588)4280031-6 (DE-588)4184437-3 (DE-588)4059023-9 (DE-588)4042362-1 |
| title | The chemistry of niobium and tantalum |
| title_auth | The chemistry of niobium and tantalum |
| title_exact_search | The chemistry of niobium and tantalum |
| title_full | The chemistry of niobium and tantalum F. Fairbrother |
| title_fullStr | The chemistry of niobium and tantalum F. Fairbrother |
| title_full_unstemmed | The chemistry of niobium and tantalum F. Fairbrother |
| title_short | The chemistry of niobium and tantalum |
| title_sort | the chemistry of niobium and tantalum |
| topic | Chemie gtt Metais E Seus Compostos (Quimica) larpcal Niobium gtt Quimica Inorganica larpcal Tantalium gtt Niobium Tantalum Niobverbindungen (DE-588)4280031-6 gnd Tantalverbindungen (DE-588)4184437-3 gnd Tantal (DE-588)4059023-9 gnd Niob (DE-588)4042362-1 gnd |
| topic_facet | Chemie Metais E Seus Compostos (Quimica) Niobium Quimica Inorganica Tantalium Tantalum Niobverbindungen Tantalverbindungen Tantal Niob |
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