The chemistry of beryllium:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Amsterdam
Elsevier
1964
|
| Schriftenreihe: | Topics in inorganic and general chemistry
1 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | IX, 151 S. Ill. |
Internformat
MARC
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| 245 | 1 | 0 | |a The chemistry of beryllium |c by D. A. Everest |
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| 300 | |a IX, 151 S. |b Ill. | ||
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Datensatz im Suchindex
| _version_ | 1804116737303511040 |
|---|---|
| adam_text | THE CHEMISTRY OF
BERYLLIUM
BY
D A EVEREST, PH D,FRIC,AMIMM
The National Chemical Laboratory,
Teddington (Great Britain)
ELSEVIER PUBLISHING COMPANY
AMSTERDAM/LONDON/NEW YORK
Contents
Preface v
Chapter 1 Introduction to Beryllium Chemistry
1 History 1
2 General chemical character of beryllium 2
3 Valency and charge state of beryllium 3
4 Beryllium of charge number one 6
References 6
Chapter 2 Solution Chemistry of the Simple Be2+ Ion
1 General considerations 7
2 Solution chemistry of the hydrated Be2+ ion in weakly acidic
media 8
3 Beryllium hydroxide 12
4 Acidic reactions of beryllium hydroxide 14
5 Interactions of beryllium cations with ion-exchange resins and
solvents 16
6 Beryllium in liquid ammonia 19
References 21
Chapter 3 Simple Oxosalts of Beryllium
1 Beryllium carbonates 23
2 Beryllium sulphate 25
3 Beryllium selenate 27
4 Beryllium nitrate 28
5 Beryllium phosphates 29
6 Beryllium arsenates 30
7 Beryllium oxalate 30
8 Normal beryllium salts of carboxylic acids 32
9 Beryllium perchlorate 33
10 Beryllium azide 33
11 Beryllium iodate and periodate 33
12 Beryllium sulphonates 33
13 Beryllium silicates 34
14 Beryllium cyanide 35
References 35
VIII CONTENTS
Chapter 4 The Beryllium Halides
1 Preparation of beryllium fluoride 38
2 Properties of beryllium fluoride 39
3 Aqueous solutions of beryllium fluoride 42
4 Fluoroberyllates prepared from aqueous solution 43
5 Anhydrous beryllium fluoride systems 45
6 Beryllium fluoride glasses 48
7 Miscellaneous reactions of beryllium fluoride 49
8 Preparation of beryllium chloride 50
9 Properties of beryllium chloride 50
10 Aqueous solutions of beryllium chloride 52
11 Anhydrous beryllium chloride systems 53
12 Beryllium chloride complexes with neutral ligands 54
13 Miscellaneous reactions of beryllium chloride 56
14 Preparation and properties of beryllium bromide 57
15 Reactions of beryllium bromide 57
16 Preparation and properties of beryllium iodide 58
17 Reactions of beryllium iodide 59
References 59
Chapter 5 Complex Beryllium Compounds
1 Factors governing the stability of beryllium complexes 64
2 Beryllium complexes with l ,3-diketones 67
3 Beryllium complexes with hydroxy acids 69
4 Beryllium oxide carboxylates (basic carboxylates) 71
5 Beryllium co-ordin ition polymers 76
6 Beryllium-phthalocyanine complexes 78
References 79
Chapter 6 Simple Binary Compounds of Beryllium
1 Beryllium hydride 82
2 Beryllium borides 84
3 Beryllium carbide 84
4 Beryllium nitride 85
5 Beryllium oxide 86
6 Beryllium sulphide 88
7 Beryllium selenide and telluride 88
8 Beryllides 88
References 89
Chapter 7 Organo-beryllium Compounds
1 Dimethylberyllium 91
2 Diethylberyllium 95
3 Di-«opropylberyll;um 96
4 Di-te/7 -butylbery!iium 97
5 Diphenylberyllium 97
CONTENTSIX
6 Dicyclopentadienylberyllium 98
7 Catalytic reactions 98
8 Beryllium compounds of the spiran type 99
9 Beryllium alcoholates and phenolates 99
References 100
Chapter 8 The Extractive Metallurgy of Beryllium
1 Beryllium ores 102
2 Extraction of beryllium from beryl 104
3 Copaux fluorosilicate process 104
4 Sulphate routes for recovery of beryllium from beryl 109
5 Chlorination methods 113
6 Preparation of metallic beryllium 113
7 Magnesium reduction of beryllium fluoride 114
8 Electrolysis of beryllium chloride 115
References 116
Chapter 9 The Analytical Chemistry of Beryllium
1 Introduction 117
2 Breakdown of beryllium-containing samples 117
3 Quantitative procedures for beryllium determination 118
4 Newer methods for beryllium separation 123
5 Radiochemical separation procedures 125
6 Radiometric methods of beryllium analysis 126
7 Spectrometric methods 129
8 Polarographic methods 130
References 131
Chapter 10 The Beryllium Health Hazard and its Control
1 An outline of the occurrence and nature of beryllium disease 133
2 Health control in a beryllium laboratory 135
3 Maximum permissible concentrations 138
References 140
Chapter 11 Nuclear Properties and Reactions of Beryllium 141
References 145
Subject Index 146
|
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| spelling | Everest, David Anthony Verfasser aut The chemistry of beryllium by D. A. Everest Amsterdam Elsevier 1964 IX, 151 S. Ill. txt rdacontent n rdamedia nc rdacarrier Topics in inorganic and general chemistry 1 Metais E Seus Compostos (Quimica) larpcal Beryllium Beryllium (DE-588)4144824-8 gnd rswk-swf Beryllium (DE-588)4144824-8 s DE-604 Topics in inorganic and general chemistry 1 (DE-604)BV001888756 1 HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001497405&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Everest, David Anthony The chemistry of beryllium Topics in inorganic and general chemistry Metais E Seus Compostos (Quimica) larpcal Beryllium Beryllium (DE-588)4144824-8 gnd |
| subject_GND | (DE-588)4144824-8 |
| title | The chemistry of beryllium |
| title_auth | The chemistry of beryllium |
| title_exact_search | The chemistry of beryllium |
| title_full | The chemistry of beryllium by D. A. Everest |
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| title_full_unstemmed | The chemistry of beryllium by D. A. Everest |
| title_short | The chemistry of beryllium |
| title_sort | the chemistry of beryllium |
| topic | Metais E Seus Compostos (Quimica) larpcal Beryllium Beryllium (DE-588)4144824-8 gnd |
| topic_facet | Metais E Seus Compostos (Quimica) Beryllium |
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