Interactions in electrolyte solutions: metal complex and ion-pair formation in solution
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Amsterdam
Elsevier
1966
|
| Schriftenreihe: | Topics in inorganic and general chemistry
8 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | X, 214 S. Ill., graph. Darst. |
Internformat
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Datensatz im Suchindex
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|---|---|
| adam_text | INTERACTIONS IN
ELECTROLYTE SOLUTIONS
(Metal Complex and Ion-Pair Formation in Solution)
BY
GEORGE H NANCOLLAS
Professor of Chemistry,
State University of New York at Buffalo,
Buffalo, NY,USA
Formerly Department of Chemistry,
The University, Glasgow, W 2, Scotland
•
ELSEVIER PUBLISHING COMPANY
AMSTERDAM / LONDON / NEW YORK
Contents
Preface v
List of Main Symbols ec
Chapter 1 Introduction 1
The structure of water 2
Polarisation in a dielectric 7
Ions in solution , 8
Ionic theories 11
Ion association 15
Dielectric saturation and ion-pair formation 19
References 22
Chapter 2 Experimental Methods: Determination of association constants 24
General considerations 24
Conductance method 26
Potentiometric measurements 33
Solubility measurements 37
Spectrophotometry 41
Polarography 45
Ion-exchange method 49
Reaction kinetics 52
Solvent extraction 53
Nuclear magnetic resonance spectroscopy 54
Raman spectra 57
Freezing-point measurements 58
Viscosity measurements 59
Determination of the heats of association 60
References 68
Chapter 3 The Association Constant 73
Constant ionic medium 74
Thermodynamic constants 77
Computation of association constants 85
Method of continuous variations 90
References 92
VIII CONTENTS
Chapter 4 Relationships Involving the Association Constant 94
Ion-pairs and complexes 94
Nature of the metal ion 102
Free-energy changes 103
References 115
Chapter 5 Thermodynamic Properties 117
Ion hydration 118
Free-energy changes 118
Enthalpy of hydration 120
Entropy of hydration 125
Ion association 129
Enthalpy changes 129
Entropy changes 133
Halide complexes 140
Polyamine complexes 144
Carboxylic and amino acid complexes 151
Aminopolycarboxylate complexes 153
References 162
Chapter 6 Mechanism of Complex Formation and Structure of the
Complex 165
Kinetics and mechanism of metal complex formation 165
Structure of the complex 172
References 175
Appendix 177
Table A-l Thermodynamic functions for ion association reactions 179
Table A-2 Thermodynamic properties 181
Table A-3 Halide complexes 182
Table A-4 Thermodynamic functions for metal(II)-amine
complexes 183
Table A-5 Thermodynamic functions for metal complexes with
carboxylic and amino acids 185
Table A-6 Thermodynamic functions for 1:1 metal complexes
with aminopolycarboxylate ions 188
Table A-7 Thermodynamic functions for 1:1 complexes of
rare-earth metal ions 191
Author Index 193
Subject Index 199
|
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| series2 | Topics in inorganic and general chemistry |
| spelling | Nancollas, George H. Verfasser aut Interactions in electrolyte solutions metal complex and ion-pair formation in solution George Nancollas Amsterdam Elsevier 1966 X, 214 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Topics in inorganic and general chemistry 8 Electrolyte solutions Elektrolyt (DE-588)4151826-3 gnd rswk-swf Elektrolytlösung (DE-588)4133913-7 gnd rswk-swf Ionenpaar (DE-588)4162328-9 gnd rswk-swf Komplexbildungsreaktion (DE-588)4164887-0 gnd rswk-swf Elektrolytlösung (DE-588)4133913-7 s Komplexbildungsreaktion (DE-588)4164887-0 s DE-604 Ionenpaar (DE-588)4162328-9 s Elektrolyt (DE-588)4151826-3 s Topics in inorganic and general chemistry 8 (DE-604)BV001888756 8 HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001496750&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Nancollas, George H. Interactions in electrolyte solutions metal complex and ion-pair formation in solution Topics in inorganic and general chemistry Electrolyte solutions Elektrolyt (DE-588)4151826-3 gnd Elektrolytlösung (DE-588)4133913-7 gnd Ionenpaar (DE-588)4162328-9 gnd Komplexbildungsreaktion (DE-588)4164887-0 gnd |
| subject_GND | (DE-588)4151826-3 (DE-588)4133913-7 (DE-588)4162328-9 (DE-588)4164887-0 |
| title | Interactions in electrolyte solutions metal complex and ion-pair formation in solution |
| title_auth | Interactions in electrolyte solutions metal complex and ion-pair formation in solution |
| title_exact_search | Interactions in electrolyte solutions metal complex and ion-pair formation in solution |
| title_full | Interactions in electrolyte solutions metal complex and ion-pair formation in solution George Nancollas |
| title_fullStr | Interactions in electrolyte solutions metal complex and ion-pair formation in solution George Nancollas |
| title_full_unstemmed | Interactions in electrolyte solutions metal complex and ion-pair formation in solution George Nancollas |
| title_short | Interactions in electrolyte solutions |
| title_sort | interactions in electrolyte solutions metal complex and ion pair formation in solution |
| title_sub | metal complex and ion-pair formation in solution |
| topic | Electrolyte solutions Elektrolyt (DE-588)4151826-3 gnd Elektrolytlösung (DE-588)4133913-7 gnd Ionenpaar (DE-588)4162328-9 gnd Komplexbildungsreaktion (DE-588)4164887-0 gnd |
| topic_facet | Electrolyte solutions Elektrolyt Elektrolytlösung Ionenpaar Komplexbildungsreaktion |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001496750&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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