Chemical reactor theory: an introd.
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | Undetermined |
| Veröffentlicht: |
Cambridge
Univ. Pr.
1971
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| Ausgabe: | 2. ed. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | IX, 224 S. Ill., graph. Darst. |
| ISBN: | 0521079713 |
Internformat
MARC
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| 245 | 1 | 0 | |a Chemical reactor theory |b an introd. |c by K. G. Denbigh and J. C. R. Turner |
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Datensatz im Suchindex
| _version_ | 1804116733111304192 |
|---|---|
| adam_text | CHEMICAL
REACTOR THEORY
AN INTRODUCTION
BY
K G DENBIGH, F R S
Principal of Queen Elizabeth College,
University of London
A N D
JCR TURNER
Lecturer in Chemical Engineering,
University of Cambridge
SECOND EDITION
§ 03
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uili
i;
I f
uili
i; P
CAMBRIDGE
AT THE UNIVERSITY PRESS
CONTENTS
Preface page ix
Chapter 1 Introduction: Reactor Types
11 The nature of the problem 1
1-2 Criteria of choice 1
1-3 Batchwise and continuous reaction 2
1-4 The tubular reactor 3
1-5 The continuous stirred tank reactor (C STR)8
1-6 The fluidized-bed reactor 11
1-7 Other types of reactor 12
1-8 The steady state 13
1-9 Transient behaviour 14
1-10 Factors affecting performance 14
References ( 15
Chapter 2 Chemical Kinetics
21 Introduction 16
2-2 The material balance equation 16
2-3 The rate equation 17
2-4 Reaction order and velocity constants 19
2-5 Thermodynamic restrictions on rate equations 21
2-6 Parallel and consecutive reactions 26
2-7 Rate-limiting steps 30
Symbols 33
References 33
Chapter 3 Tubular Reactors
3-1 The plug flow assumption (P FA) 34
3-2 Elementary design method 34
3-3 Acetaldehyde decomposition exampie 37
[ v ]
vi Contents
3-4 Residence-time, space-time, space-velocity page 39
3-5 Deviations from the plug-flow assumption 44
3-6 Transverse temperature gradients: a general discussion 45
3- 7 Transverse temperature gradients: Baron s method 48
3-8 Pressure drop 52
3-9 Summary , 52
Appendix I Isothermal reaction with plug flow 54
Appendix II Adiabatic reaction with plug flow 56
Symbols 58
References 58
Chapter 4 Continuous1 Stirred Tank Reactors
4-1 The perfect mixing assumption 60
4-2 Calculation of reactor volume 63
4-3 Stirred tanks in series 67
4-4 f Autocatalytic reactions 69
4-5 Summary 71
Symbols 73
References 73
Chapter 5 Residence-Time Distributions, Mixing and Dispersion
5-1 The residence-time distribution as a factor in reactor 74
performance
5-2 Residence-time functions, and relations between them 75
5-3 Residence-time in a chain of stirred tanks 77
5-4 Residence-time distributions for composite systems 81
5-5 The determination of residence-time distributions 82
5-6 The measurement of residence-time functions in industry 86
5-7 The effect of a spread of residence-times on reactor yield 87
5-8 Segregation and limits of reactor yield 89
5-9 Residence-times and dispersion in flow through pipes 90
5-10 Dispersion in flow through packed beds 96
References 100
Contents vii
Chapter 6 Chemical Factors Affecting the Choice of Reactor
6-1 Factors affecting choice page 102
6-2 Yield and conversion 103
6-3 Selectivity and reactivity 106
6-4 Consecutive or degradation reactions 107
6-5 Polymerization reactions 111
6-6 Crystallization 117
6-7 Parallel reactions 118
6-8 Parallel-consecutive reactions, coupled reactions 121
6-9 Instantaneous and overall reaction yields 123
6-10 Combination of CSTR and tubular reactor 129
6-11 Removal of product Recirculation 130
Symbols 132
References 132
Chapter 7 Some Mass-Transfer Factors Affecting Reactor
Performance
7-1 The importance of mass-transfer in chemical reaction 134
7-2 Heterogeneous catalysis 135
7-3 Mass-transfer between packing and fluid 137
7-4 Diffusion within catalyst particles 139
7-5 Catalyst effectiveness 140
7-6 Effectiveness factors 143
7-7 Fluid-solid reactions Shrinking particle case 146
7-8 Ash-coated particles 148
7-9 Fluid-fluid reactions Trickle-bed reactors 151
710 Bubble-cloud reactors, fermenters 154
7-11 The physics of fluidized beds 155
7-12 Fluidized-bed reactors 157
Symbols 160
References 161
viii Contents
Chapter 8 The Thermal Characteristics of Reactors
8-1 Introduction
8-2 Well-mixed systems with steady feed
8-3 Tubular reactors
8-4 The diffusion-controlled regime
8-5 The propagation of reaction zones
8-6 Thermal effects in catalyst particles
Symbols
References
Chapter 9 Reactor Stability and Optimization
91 Introduction
9-2 The stability of exothermic reactions
9-3 Limit cycles and oscillating reactions
9-4 Parametric sensitivity
(
9-5 Optimization—simplified objective functions
9-6 Output and yield problems
9-7 The reversible exothermic reaction
9-8 Conclusion
Symbols
References
Index
page 164
|
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| spelling | Denbigh, Kenneth George Verfasser aut Chemical reactor theory an introd. by K. G. Denbigh and J. C. R. Turner 2. ed. Cambridge Univ. Pr. 1971 IX, 224 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Chemischer Reaktor (DE-588)4121085-2 gnd rswk-swf Chemischer Reaktor (DE-588)4121085-2 s DE-604 Turner, James Charles Robin Verfasser aut HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001494800&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Denbigh, Kenneth George Turner, James Charles Robin Chemical reactor theory an introd. Chemischer Reaktor (DE-588)4121085-2 gnd |
| subject_GND | (DE-588)4121085-2 |
| title | Chemical reactor theory an introd. |
| title_auth | Chemical reactor theory an introd. |
| title_exact_search | Chemical reactor theory an introd. |
| title_full | Chemical reactor theory an introd. by K. G. Denbigh and J. C. R. Turner |
| title_fullStr | Chemical reactor theory an introd. by K. G. Denbigh and J. C. R. Turner |
| title_full_unstemmed | Chemical reactor theory an introd. by K. G. Denbigh and J. C. R. Turner |
| title_short | Chemical reactor theory |
| title_sort | chemical reactor theory an introd |
| title_sub | an introd. |
| topic | Chemischer Reaktor (DE-588)4121085-2 gnd |
| topic_facet | Chemischer Reaktor |
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