Electrochemistry of solids: an introduction ; with 23 tables
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Berlin [u.a.]
Springer
1982
|
| Schriftenreihe: | Inorganic chemistry concepts
7 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XII, 240 S. graph. Darst. |
| ISBN: | 3540111166 0387111166 |
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Datensatz im Suchindex
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|---|---|
| adam_text | HANS RICKERT ELECTROCHEMISTRY OF SOLIDS AN INTRODUCTION WITH 95 FIGURES
AND 23 TABLES SPRINGER-VERLAG BERLIN HEIDELBERG NEW YORK 1982 CONTENTS
LIST OF SYMBOLS XI 1 INTRODUCTION 1 1.1 REFERENCES 7 3 2 DISORDER IN
SOLIDS 6 2.1 GENERAL CONSIDERATIONS REGARDING LATTICE DEFECTS AND THEIR
SIGNIFICANCE 6 2.2 POINT DEFECTS 7 2.3 DISORDER EQUILIBRIA 13 2.4 THE
CHEMICAL POTENTIALS OF DEFECTS 16 2.5 INTERNAL DISORDER EQUILIBRIA 22
2.6 KINETIC DERIVATION OF DISORDER EQUILIBRIA 31 2.7 DISORDER EQUILIBRIA
INVOLVING NEIGHBOURING PHASES. 32 2.8 DISORDER EQUILIBRIA INVOLVING
SURFACES 36 2.9 REFERENCES 38 3 EXAMPLES OF DISORDER IN SOLIDS 41 3.1
DISORDER IN DOPED ZIRCONIUM DIOXIDE AND THORIUM DIOXIDE 42 3.2 DISORDER
IN ZNO, CU 2 0 AND CUO 44 3.3 STRUCTURAL DISORDER 46 3.4 REFERENCES 49 4
THERMODYNAMIC QUANTITIES OL QUASI-FREE ELECTRONS AND ELECTRON DEFECTS IN
SEMICONDUCTORS 51 4.1 GENERAL CONSIDERATIONS 51 4.2 ELECTROCHEMICAL
POTENTIAL Y) E OF ELECTRONS 52 4.3 THE FERMI DISTRIBUTION FUNCTION F(S)
52 4.4 THE DENSITY OF STATES D(S) 55 4.5 RELATION BETWEEN THE
CONCENTRATION OF ELECTRONS OR ELECTRON DEFECTS AND THEIR ELECTROCHEMICAL
POTENTIAL 57 4.6 CHEMICAL POTENTIAL OF ELECTRONS AND STANDARD STATES 59
VIII CONTENTS 4.7 THE ACTIVITY COEFFICIENT OF ELECTRONS AND ELECTRON
DEFECTS IN THE CASE OF DEGENERACY 61 4.8 THE PHASE BOUNDARY
SOLID/VACUUM. THE WORK FUNCTION W 62 4.9 THE VOLTA POTENTIAL OR CONTACT
POTENTIAL 63 4.10 THE PHASE BOUNDARY SOLID I/SOLID II. THE GALVANI
VOLTAGE 64 4.11 REFERENCES 65 5 AN EXAMPLE OF ELECTRONIC DISORDER.
ELECTRONS AND ELECTRON DEFECTS IN A-AG 2 S 66 5.1 DISORDER IN 2 S AND
COULOMETRIC TITRATION CURVE 66 5.2 QUANTITATIVE EVALUATION OF
COULOMETRIC TITRATION CURVES OF 2 S 69 5.3 ENTROPY AND ENTHALPY OF THE
ELECTRONS IN AG 2 S . . 74 5.4 REFERENCES 78 6 MOBILITY, DIFFUSION AND
PARTIAL CONDUCTIVITY OF IONS AND ELECTRONS 79 6.1 PHENOMENOLOGICAL
TREATMENT OF TRANSPORT PROCESSES 79 6.1.1 DIFFUSION EQUATIONS 79 6.1.2
THE MECHANICAL MOBILITY B M 81 6.1.3 THE NERNST-EINSTEIN EQUATION 82
6.1.4 THE COMPONENT DIFFUSION COEFFICIENT D K 83 6.1.5 RELATIONSHIP
BETWEEN D AND D K 83 6.1.6 RELATIONSHIP BETWEEN THE COMPONENT DIFFUSION
COEF- FICIENT D K AND THE TRACER DIFFUSION COEFFICIENT D TR . 84 6.1.7
PARTICLE FLUX IN AN ELECTRICAL FIELD 84 6.1.8 PARTICLE FLUX IN THE
PRESENCE OF A CONCENTRATION OR ACTIVITY GRADIENT AND AN ELECTRICAL FIELD
86 6.1.9 DESCRIPTION OF PARTICLE FLUXES USING THE GENERAL TRANSPORT
EQUATIONS OF IRREVERSIBLE THERMODYNAMICS. . . 87 CHEMICAL DIFFUSION 89
STATISTICAL TREATMENT OF TRANSPORT QUANTITIES . . . 90 EXPERIMENTAL
DETERMINATION OF PARTIAL CONDUCTIVITIES 96 TRANSFERENCE MEASUREMENTS 97
MEASUREMENTS OF TRANSFERENCE NUMBERS BY MEANS OF EMF MEASUREMENTS USING
GALVANIC CELLS 98 DETERMINATION OF PARTIAL CONDUCTIVITIES BY MEANS OF
STATIONARY POLARIZATION MEASUREMENTS 101 ALTERNATING CURRENT
MEASUREMENTS. COMPLEX IMPEDANCE DIAGRAMS 110 REFERENCES 116 6.1.10 6.2
6.3 6.3.1 6.3.2 6.3.3 6.4 6.5 CONTENTS IX 7 SOLID IONIC CONDUCTORS,
SOLID ELECTROLYTES AND SOLID-SOLUTION ELECTRODES 118 7.1 SOLID IONIC
CONDUCTORS, SOLID ELECTROLYTES 118 7.1.1 OXYGEN ION CONDUCTORS 118 7.1.2
SODIUM ION CONDUCTORS 121 7.1.3 SILVER ION CONDUCTORS 122 7.1.4 COPPER
ION CONDUCTORS 123 7.1.5 LITHIUM ION CONDUCTORS 124 7.1.6 FLUORINE ION
CONDUCTORS 125 7.2 SOLID-SOLUTION ELECTRODES 126 7.3 REFERENCES 127 8
GALVANIC CELLS WITH SOLID ELECTROLYTES FOR THERMODYNAMIC INVESTIGATIONS
129 8.1 DETERMINATION OF GIBBS REAETION ENERGIES . . . . 129 8.2
DETERMINATION OF CHEMICAL POTENTIALS, THERMODYNAMIC ACTIVITIES OR
PARTIAL PRESSURES . .138 8.2.1 GALVANIC CELLS OF THE FIRST KIND 139
8.2.2 GALVANIC CELLS OF THE SECOND KIND 145 8.3 DETERMINATION OF AS AND
AH FROM THE TEMPERATURE-DEPENDENCE OF THE ELECTROMOTIVE FORCE OF
GALVANIC CELLS 147 8.4 REFERENCES /. 148 9 TECHNICAL APPLICATIONS OF
SOLID ELECTROLYTES * SOLID-STATE IONICS 149 9.1 SENSORS 149 9.2 FUEL
CELLS AND ELECTROLYZERS 150 9.3 BATTERIES WITH SOLID ELECTROLYTES. THE
SODIUM-SULFUR BATTERY 152 9.4 CHEMOTRONIC BUILDING UNITS 153 9.4.1
COULOMETERS AND TIME SWITCHES 154 9.4.2 ANALOG MEMORIES 154 9.4.3
CAPACITORS CONTAINING SOLID ELECTROLYTES 155 9.5 REFERENCES 155 10
SOLID-STATE REACTIONS 157 10.1 THEORY OF THE FORMATION OF TARNISHING
LAYERS ON METAL SURFAEES 157 10.1.1 RATE LAWS DESCRIBING THE FORMATION
OF TARNISHING LAYERS 158 10.1.2 CALCULATION OF THE PARABOLIC RATE LAW
CONSTANT USING THE METHOD OF C. WAGNER 160 10.2 EXAMPLES OF THE
FORMATION OF TARNISHING LAYERS ON METALS AND OTHER SOLID-STATE REACTIONS
163 10.2.1 OXIDATIONOF COPPER TO CU 2 OAT 1000 C 163 X CONTENTS 10.2.2
OXIDATIONOF ZINC AT 400C 164 10.2.3 REACTION OF SILVER WITH LIQUID
SULFUR AT 400 C . . 165 10.2.4 FORMATION OF DOUBLE SALTS AND DOUBLE
OXIDES VIA SOLID-STATE REACTIONS 166 10.3 REFERENCES 167 11 CTALVANIE
CELLS WITH SOLID ELECTROLYTES FOR KINETIC INVESTIGATIONS 168 11.1
ELECTROCHEMICAL MEASUREMENTS OF OXYGEN DIFFUSION IN METALS AT HIGHER
TEMPERATURES USING ZIRCONIUM DIOXIDE AS SOLID ELECTROLYTE 168 11.1.1 THE
PIINCIPLE OF ELECTROCHEMICAL MEASUREMENTS OF OXYGEN DIFFUSION IN METALS
168 11.1.2 THE POTENTIOSTATIC METHOD 170 11.1.2.1 THE LINEAR GEOMETRY
171 11.1.2.2 THE CYLINDRICAL GEOMETRY 173 11.1.3 THE GALVANOSTATIC
METHOD 176 11.2 ELECTROCHEMICAL INVESTIGATIONS ON THE FORMATION OF
NICKEL SULFIDE IN THE SOLID-STATE AT HIGHER TEMPERATURES 180 11.2.1
POTENTIOSTATIC MEASUREMENTS 182 11.2.2 GALVANOSTATIC MEASUREMENTS 183
11.3 ELECTROCHEMICAL INVESTIGATIONS OF THE TRANSFER OF SILVER, SILVER
IONS AND ELECTRONS ACROSS THE PHASE BOUNDARY SOLID SILVER/SOLID SILVER
SULFIDE 185 11.3.1 SIMPLIFIED EXPERIMENTAL ARRANGEMENT 185 11.3.2
EXTENDED EXPERIMENTAL ARRANGEMENT 186 11.3.3 RESULTS AND DISCUSSION OF
POLARIZATION MEASUREMENTS AT THE PHASE BOUNDARY AG(S)/AG 2 S(S). 188
11.4 ELECTROCHEMICAL STUDIES OF EVAPORATION AND CONDENSATION 190 11.5 AN
ELECTROCHEMICAL KNUDSEN CELL FOR THE INVESTIGATION OF THE THERMODYNAMIES
OF GASES . . .196 11.6 ELECTROCHEMICAL MEASUREMENTS OF THE CHEMICAL
DIFFUSION COEFFICIENT OF WUESTITE AND SILVER SULFIDE. . 203 11.7
REFERENCES 214 12 NON-ISOTHERMAL SYSTEMS. SORET EFFECT, TRANSPORT
PROCESSES, AND THERMOPOWERS 216 12.1 BASIC EQUATIONS OF IRREVERSIBLE
THERMODYNAMIES . . 217 12.2 THE SORET EFFECT 219 12.3 STATIONARY
TRANSPORT PROCESSES IN SOLIDS SUBJECTED TO A TEMPERATURE GRADIENT 221
12.4 THERMOELECTRIC POWERS 224 12.5 REFERENCES 233 AUTHOR INDEX SUBJECT
INDEX 235 237
|
| any_adam_object | 1 |
| author | Rickert, Hans |
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| discipline | Chemie / Pharmazie Physik Chemie |
| format | Book |
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| id | DE-604.BV002269706 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T15:43:06Z |
| institution | BVB |
| isbn | 3540111166 0387111166 |
| language | English |
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| physical | XII, 240 S. graph. Darst. |
| publishDate | 1982 |
| publishDateSearch | 1982 |
| publishDateSort | 1982 |
| publisher | Springer |
| record_format | marc |
| series | Inorganic chemistry concepts |
| series2 | Inorganic chemistry concepts |
| spelling | Rickert, Hans Verfasser aut Einführung in die Elektrochemie fester Stoffe Electrochemistry of solids an introduction ; with 23 tables Berlin [u.a.] Springer 1982 XII, 240 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Inorganic chemistry concepts 7 Festkörper (DE-588)4016918-2 gnd rswk-swf Festkörperchemie (DE-588)4129288-1 gnd rswk-swf Elektrochemie (DE-588)4014241-3 gnd rswk-swf Elektrochemie (DE-588)4014241-3 s Festkörper (DE-588)4016918-2 s DE-604 Festkörperchemie (DE-588)4129288-1 s 1\p DE-604 Inorganic chemistry concepts 7 (DE-604)BV001891846 7 GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001491322&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Rickert, Hans Electrochemistry of solids an introduction ; with 23 tables Inorganic chemistry concepts Festkörper (DE-588)4016918-2 gnd Festkörperchemie (DE-588)4129288-1 gnd Elektrochemie (DE-588)4014241-3 gnd |
| subject_GND | (DE-588)4016918-2 (DE-588)4129288-1 (DE-588)4014241-3 |
| title | Electrochemistry of solids an introduction ; with 23 tables |
| title_alt | Einführung in die Elektrochemie fester Stoffe |
| title_auth | Electrochemistry of solids an introduction ; with 23 tables |
| title_exact_search | Electrochemistry of solids an introduction ; with 23 tables |
| title_full | Electrochemistry of solids an introduction ; with 23 tables |
| title_fullStr | Electrochemistry of solids an introduction ; with 23 tables |
| title_full_unstemmed | Electrochemistry of solids an introduction ; with 23 tables |
| title_short | Electrochemistry of solids |
| title_sort | electrochemistry of solids an introduction with 23 tables |
| title_sub | an introduction ; with 23 tables |
| topic | Festkörper (DE-588)4016918-2 gnd Festkörperchemie (DE-588)4129288-1 gnd Elektrochemie (DE-588)4014241-3 gnd |
| topic_facet | Festkörper Festkörperchemie Elektrochemie |
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