Lasers and chemical change:
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
Berlin [u.a.]
Springer
1981
|
| Schriftenreihe: | Springer series in chemical physics
10 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XII, 497 S. graph. Darst. |
| ISBN: | 3540103791 0387103791 |
Internformat
MARC
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| 245 | 1 | 0 | |a Lasers and chemical change |c A. Ben-Shaul ... |
| 264 | 1 | |a Berlin [u.a.] |b Springer |c 1981 | |
| 300 | |a XII, 497 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
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| 490 | 1 | |a Springer series in chemical physics |v 10 | |
| 650 | 4 | |a Lasers chimiques | |
| 650 | 4 | |a Lasers en chimie | |
| 650 | 4 | |a Photochimie | |
| 650 | 4 | |a Spectroscopie moléculaire | |
| 650 | 4 | |a Structure moléculaire | |
| 650 | 4 | |a Chemical lasers | |
| 650 | 4 | |a Lasers in chemistry | |
| 650 | 4 | |a Molecular spectroscopy | |
| 650 | 4 | |a Molecular structure | |
| 650 | 4 | |a Photochemistry | |
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| 999 | |a oai:aleph.bib-bvb.de:BVB01-001490038 | ||
Datensatz im Suchindex
| _version_ | 1804116725283684352 |
|---|---|
| adam_text | A Ben-Shaul Y Haas KX Kompa
R,D Levine
Lasers and
Chemical Change
With 245 Figures
Springer-Verlag Berlin Heidelberg New York 1981
Contents
1 Lasers and Chemical Change 1
1 1 Light Amplification and Population Inversion in Chemical
Processes 3
1 2 Molecular Rate Processes 13
1 3 Photoselective Chemistry 21
131 The Discrete Spectrum 22
132 The Quasicontinuum 29
133 Radiationless Transitions 37
134 Dissociative Continuum 40
135 Ionization 42
1 4 The Road Ahead 43
2 Disequilibrium 45
2 1 Specificity and Selectivity of Chemical Reactions 45
211 Overview: Microscopic Disequilibrium 45
212 The Detailed Rate Constant 49
213 Detailed Balance 51
214 Energy Disposal and Energy Consumption 53
215 The Reaction Probability Matrix 55
216 Measures of Specificity and Selectivity 58
217 The Maximum Entropy Formalism 62
2 2 Surprisal Analysis 65
221 The Prior Distribution 65
222 The Surprisal 68
223 Vibrational Surprisal 70
224 The Rotational State Distribution 74
225 Electronic Excitation 79
226 Polyatomic Molecules 80
227 Surprisal Analysis and Collision Dynamics 83
228 On the Role of Reagent Translation 87
2 3 Molecular Reaction Dynamics 89
231 Computational Studies 89
232 Potential Energy Surface(s) 92
233 Bond-Tightening Models 94
234 Kinematic Models of Collision Dynamics 97
235 Unimolecular Processes - The RRK Approach 99
236 Unimolecular Processes - Selectivity and Specificity 106
237 Preparing the Initial State 109
2 4 State-to-State Processes 113
241 The Prior Detailed Rate Constant 113
242 The Exponential Gap Representation 119
243 Reactive Collisions 122
244 The Adiabaticity Parameter 124
245 Polyatomic Molecules 129
246 Temperature Dependence 131
247 Electronic Energy Transfer 134
248A Laser Bridge for the Exponential Gap 139
249 Intramolecular Electronic to Vibrational Energy Tansfer:
Radiationless Transitions 141
2 5 Macroscopic Disequilibrium 144
251 The Master Equation: Relaxation of Harmonic Oscillators 144
252 Rotational Relaxation 150
253 Separation of Time Scales 152
254 Vibrational Anharmonicity and V-V Up-Pumping 154
255 Intermode V-V Transfer 159
256 From Macroscopic Relaxation to Microscopic Information 163
257 Thermodynamics of Molecular Disequilibrium 168
258 Laser Thermodynamics 172
Appendices •
2 A The Prior Distribution 177
2 B Practical Surprisal Analysis 185
2 C Statistical Models, Prior Distributions, and Collision
Dynamics 187
2 D Derivation of the Treanor Distribution 190
3 Photons, Molecules, and Lasers 192
3 1 Interaction of Molecules with Radiation 192
311 The Golden Rule 193
312 The Line Shape Function 201
313 Coherent Interaction 205
3 2 Essential Physics of Lasers 209
321 The Gain Coefficient 209
322 Laser Oscillators 211
323 Laser Radiation and Modes 216
324 The Laser Rate Equations 225
3 3 Survey of Atomic and Molecular Spectroscopy 232
331 Atomic Spectra 232
332 Molecular Spectra 235
333 Electronic Spectra of Diatomic Molecules 238
334 Infrared Spectra of Diatomic Molecules 242
335 Energy Levels of Polyatomic Molecules 246
336 Infrared Spectra of Polyatomic Molecules 257
337 The Near Ultraviolet Spectrum of Carbonyl Compounds 261
3 4 Laser Sources 266
341 Laser Specifications 267
342 Exciplex Lasers 272
343 Dye Lasers 278
344 C02 Lasers 284
4 Chemical Lasers 289
4 1 Survey of Chemical Lasers 289
4 2 Lasing Conditions in Chemical Lasers 295
4 3 Operation 304
431 Flash Photolysis: The Iodine Laser as a Model Case 305
432 Hydrogen Halide Chemical Lasers 314
433 The Chemical CO Laser 324
4 4 Chemical Laser Kinetics 326
441 The Rate Equations 327
442 Rotational Equilibrium 334
XII
t
443 Rotational Nonequilibrium 337
444 cw Chemical Lasers 340
4 5 Some Applications of Chemical Lasers 347
451 Total Rate Constants, Kinetic Isotope Effects 348
452 Vibrational Population Ratios from Threshold
Time Measurements 352
453 Gain Probing 354
454 Energy Transfer Measurements: An Example 357
455 An Industrial Diagnostic Application 358
5 Laser Chemistry 360
5 1 The Laser Evolution 361
5 2 Bimolecular Reactions 363
521 Molecular Beam Studies 365
522 Reactions in the Bulk 371
5 3 Electronic Excitation of Polyatomic Molecules 380
531 Direct Photodissociation: The A State of ICN 380
532 Photopredissociation: Formaldehyde 385
533 Excitation of Bound Electronic States: Biacetyl and
Glyoxal 391
5 4 MuKiphoton Activation and Fragmentation 398
541 The Nature of Multiphoton Excitation 401
542 The Rate Equation Approach 410
543 Nondissociative Reactions Induced by Multiphoton
Absorption 427
544 Multiphoton Ionization (MPI) 430
5 5 The Compleat Laser Chemist 434
551 Preparing the Sample 435
552 Excitation and Probing Techniques 438
553 Laser-Oriented Absorption Measurements 446
5 6 From the Laboratory to Large-Scale Laser Chemistry 452
561 Practical Photoselective Chemistry 454
562 State Selective Chemistry 457
5 7 Synergism 459
References 461
Author Index 477
Subject Index 485
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| id | DE-604.BV002267606 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T15:43:04Z |
| institution | BVB |
| isbn | 3540103791 0387103791 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-001490038 |
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| physical | XII, 497 S. graph. Darst. |
| publishDate | 1981 |
| publishDateSearch | 1981 |
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| series | Springer series in chemical physics |
| series2 | Springer series in chemical physics |
| spelling | Lasers and chemical change A. Ben-Shaul ... Berlin [u.a.] Springer 1981 XII, 497 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Springer series in chemical physics 10 Lasers chimiques Lasers en chimie Photochimie Spectroscopie moléculaire Structure moléculaire Chemical lasers Lasers in chemistry Molecular spectroscopy Molecular structure Photochemistry Nichtgleichgewicht (DE-588)4171730-2 gnd rswk-swf Laserchemie (DE-588)4034613-4 gnd rswk-swf Chemischer Laser (DE-588)4135482-5 gnd rswk-swf Chemischer Laser (DE-588)4135482-5 s DE-604 Laserchemie (DE-588)4034613-4 s Nichtgleichgewicht (DE-588)4171730-2 s Ben-Shaul, Avinoam Sonstige oth Springer series in chemical physics 10 (DE-604)BV000000670 10 HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001490038&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Lasers and chemical change Springer series in chemical physics Lasers chimiques Lasers en chimie Photochimie Spectroscopie moléculaire Structure moléculaire Chemical lasers Lasers in chemistry Molecular spectroscopy Molecular structure Photochemistry Nichtgleichgewicht (DE-588)4171730-2 gnd Laserchemie (DE-588)4034613-4 gnd Chemischer Laser (DE-588)4135482-5 gnd |
| subject_GND | (DE-588)4171730-2 (DE-588)4034613-4 (DE-588)4135482-5 |
| title | Lasers and chemical change |
| title_auth | Lasers and chemical change |
| title_exact_search | Lasers and chemical change |
| title_full | Lasers and chemical change A. Ben-Shaul ... |
| title_fullStr | Lasers and chemical change A. Ben-Shaul ... |
| title_full_unstemmed | Lasers and chemical change A. Ben-Shaul ... |
| title_short | Lasers and chemical change |
| title_sort | lasers and chemical change |
| topic | Lasers chimiques Lasers en chimie Photochimie Spectroscopie moléculaire Structure moléculaire Chemical lasers Lasers in chemistry Molecular spectroscopy Molecular structure Photochemistry Nichtgleichgewicht (DE-588)4171730-2 gnd Laserchemie (DE-588)4034613-4 gnd Chemischer Laser (DE-588)4135482-5 gnd |
| topic_facet | Lasers chimiques Lasers en chimie Photochimie Spectroscopie moléculaire Structure moléculaire Chemical lasers Lasers in chemistry Molecular spectroscopy Molecular structure Photochemistry Nichtgleichgewicht Laserchemie Chemischer Laser |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001490038&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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