Theoretical foundations of electron spin resonance:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
New York [u.a.]
Acad. Press
1978
|
| Schriftenreihe: | Physical chemistry
37 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XIII, 399 S. graph. Darst. |
| ISBN: | 0123263506 |
Internformat
MARC
| LEADER | 00000nam a2200000 cb4500 | ||
|---|---|---|---|
| 001 | BV002252689 | ||
| 003 | DE-604 | ||
| 005 | 20220505 | ||
| 007 | t | ||
| 008 | 890928s1978 d||| |||| 00||| eng d | ||
| 020 | |a 0123263506 |9 0-12-326350-6 | ||
| 035 | |a (OCoLC)3540653 | ||
| 035 | |a (DE-599)BVBBV002252689 | ||
| 040 | |a DE-604 |b ger |e rakddb | ||
| 041 | 0 | |a eng | |
| 049 | |a DE-91 |a DE-355 |a DE-706 |a DE-83 |a DE-188 |a DE-19 | ||
| 050 | 0 | |a QC763 | |
| 082 | 0 | |a 538/.3 | |
| 084 | |a UM 3700 |0 (DE-625)145893: |2 rvk | ||
| 084 | |a UP 8200 |0 (DE-625)146449: |2 rvk | ||
| 084 | |a VE 8600 |0 (DE-625)147149:253 |2 rvk | ||
| 084 | |a VG 9700 |0 (DE-625)147242:253 |2 rvk | ||
| 084 | |a CHE 248f |2 stub | ||
| 100 | 1 | |a Harriman, John E. |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Theoretical foundations of electron spin resonance |c John E. Harriman |
| 264 | 1 | |a New York [u.a.] |b Acad. Press |c 1978 | |
| 300 | |a XIII, 399 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 1 | |a Physical chemistry |v 37 | |
| 650 | 7 | |a Elektron paramagnetische resonantie |2 gtt | |
| 650 | 7 | |a Elektronspinresonantie |2 gtt | |
| 650 | 4 | |a Spectroscopie de résonance paramagnétique électronique | |
| 650 | 4 | |a Electron paramagnetic resonance spectroscopy | |
| 650 | 0 | 7 | |a Elektronenspinresonanzspektroskopie |0 (DE-588)4151888-3 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Elektronenspinresonanz |0 (DE-588)4132116-9 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Theorie |0 (DE-588)4059787-8 |2 gnd |9 rswk-swf |
| 689 | 0 | 0 | |a Elektronenspinresonanz |0 (DE-588)4132116-9 |D s |
| 689 | 0 | |5 DE-604 | |
| 689 | 1 | 0 | |a Elektronenspinresonanzspektroskopie |0 (DE-588)4151888-3 |D s |
| 689 | 1 | |5 DE-604 | |
| 689 | 2 | 0 | |a Elektronenspinresonanzspektroskopie |0 (DE-588)4151888-3 |D s |
| 689 | 2 | 1 | |a Theorie |0 (DE-588)4059787-8 |D s |
| 689 | 2 | |5 DE-604 | |
| 830 | 0 | |a Physical chemistry |v 37 |w (DE-604)BV001888852 |9 37 | |
| 856 | 4 | 2 | |m HBZ Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001480261&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 999 | |a oai:aleph.bib-bvb.de:BVB01-001480261 | ||
Datensatz im Suchindex
| _version_ | 1804116709008736256 |
|---|---|
| adam_text | Titel: Theoretical foundations of electron spin resonance
Autor: Harriman, John E.
Jahr: 1978
CONTENTS
Preface ix
ÄCKNOWLEDGMENTS Jciii
Chapter 0. REVIEW OF ELEMENTARY ELECTRON SPIN RESONANCE
Systems Studied by Electron Spin Resonance 1
The Basic Electron Spin Resonance Experiment 2
Belaxation and Lineshape 4
The Spin Hamiltonian 6
The Electronic Zeeman Interaction 7
Magnetic Hyperfine Interactions 9
Equivalent Nuclei and Intensity Patterns 10
Other Interactions 13
Chapter I. THE ORIGIN OF MAGNETIC ENERGY LEVELS
1. The Dirac Electron 15
Origin of the Dirac Equation 15
Some Properties of the Dirac Equation and Dirac Operators 18
Solutions of the Dirac Equation 20
Perturbations of the Dirac Hydrogen Atom 32
Other Calculations with Four-Component Functions 35
Summary of Section 1 36
2. The Relationship between Relativistic and
, Nonrelativistic Theories 37
i Characteristics of and Criteria for Transformations 38
The Foldy—Wouthuysen Transformation 40
Foldy-Wouthuysen Transformation with Electric Fields Present 45
I Partitioning of the Dirac Equation 47
f Discussion of Terms Occurring in the Hamiltonian 55
j Hydrogenic Ion Results 65
Summary of Section 2 67
i v
vj CONTENTS
3. Radiative Corrections
Quantum Electrodynamics
Anomalous Magnetic Moment
Modification of the Dirac Equation 72
Reduction to Nonrelativistic Form
Summary of Section 3
4. Relativistic Many-Electron Theories 76
The Bethe-Salpeter Equation 76
The Breit Equation 78
Reduction to Nonrelativistic Form 82
Other Methods 86
Discussion of Results 8o
Extension to Many Electrons ^
Summary of Section 4 89
5. Effects of Nuclear Structure 90
Nuclear Size 90
Nuclear Moments 90
Summary of Section 5 97
6. The Separation of Nuclear and Electronic Motions 98
Center of Mass in Relativistic Quantum Mechanies 98
Nonrelativistic, One-Electron Atoms 98
Effeet on Relativistic Corrections for One-Electron Atoms 99
Otter Systems 101
Summary of Section 6 108
Chapter II. THE DESCRIPTION OF MAGNETIC ENERGY LEVELS
7. The Spin Hamiltonian as a Summary of Experimental Data 111
Isotropie Spin Hamiltonian for S= j 112
Nearly Degenerate Electronic States 130
Nonisotropic Spin Hamiltonians 135
Powder Spectra 15g
Summary of Section 7 162
8. The Relationship of the Spin Hamiltonian to Calculated
Energy Levels 164
Partitioning Treatment 164
Spin Hamiltonian j^Y
States with Additkmal Degeneracies 180
Summary of Section 8 Ig7
CONTENTS VÜ
9. Perturbation Expressions for Spin Hamiltonian Parameters 189
Form of the Spin Hamiltonian 189
Spin Hamiltonian Parameters 191
Orientation Dependence of Spin Hamiltonian Parameters 205
Summary of Section 9 207
10. Summarizing Calculated Data in Terms of Density
Matrix Components 208
Spin Components of Reduced Density Matriees 208
Relationship to Spin Hamiltonian Parameters 213
Summary of Section 10 219
Chapter III. CALCULATTONS
11. Wave Functions for Open-Shell Systems 221
Spin Couplings and Antisymmetry 222
Spin Eigenfunctions 223
The Interaction of Space and Spin via Permutational Symmetry 238
Comparison of Functions of Different Types 240
Other Methods of Calculation 267
An Kxample: Lithium Atom 271
Summary of Section 11 276
12. Evaluation of Spin Hamiltonian Parameters 277
Operators Involved 277
Basis Functions 279
Integrals 283
Summary of Section 12 301
13. Semiempirical Methods 302
Atomic Orbital Spin Density 302
All-Valence-Electron Semiempirical Methods 303
Pi-Electron Methods 304
Simple Valence Bond Treatments 321
Summary of Section 13 324
j
; 14. External Perturbations 326
I
Static and Dynamic Effects 326
Nature of the Interaction 326
Perturbation Treatments 327
Semiempirical Methods 327
Summary of Section 14 328
VÜi CONTENTS
APPENDICES
Appendix A Classical Mechanics and Fields including
Relativistic Forms; Units 329
Classical Mechanics of Particles 329
Electromagnetic Fields and Potentials 330
Charged Particles in Fields 331
Four-Vectors and Lorentz Transformations 332
Units 336
Appendix B Gauge Transforraations in Nonrelativistic
Quantum Mechanics 343
Appendix C Rotations, Tensors, Angular Momentum, and
Related Topics 346
Angular Momentum Operators 346
Angular Momentum Eigenfunctions 347
Matrices of Angular Momentum Operators 348
Coupling of Angular Momenta 349
Time Reversal, Complex Conjugation, and Kramers Conjugation 353
Rotations 355
Tensors and Tensor Operators 361
Appendix D Reduced Density Matrices 365
Appendix E Some UsefuI Operator Identities and Matrix
Relationships 370
Inverse of Operator Sum 370
Exponential Operators 370
Eigenvalues and Eigenvectors of a Complex Hermitian Matrix 372
Diagonalization and Inversion of 2 X 2 Matriees 373
Commutators of Spin-Dependent Operators with . / - 375
Appendix F Summary of Terms in the Hamiltonian 378
REFERENCES 387
Index 395
|
| any_adam_object | 1 |
| author | Harriman, John E. |
| author_facet | Harriman, John E. |
| author_role | aut |
| author_sort | Harriman, John E. |
| author_variant | j e h je jeh |
| building | Verbundindex |
| bvnumber | BV002252689 |
| callnumber-first | Q - Science |
| callnumber-label | QC763 |
| callnumber-raw | QC763 |
| callnumber-search | QC763 |
| callnumber-sort | QC 3763 |
| callnumber-subject | QC - Physics |
| classification_rvk | UM 3700 UP 8200 VE 8600 VG 9700 |
| classification_tum | CHE 248f |
| ctrlnum | (OCoLC)3540653 (DE-599)BVBBV002252689 |
| dewey-full | 538/.3 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 538 - Magnetism |
| dewey-raw | 538/.3 |
| dewey-search | 538/.3 |
| dewey-sort | 3538 13 |
| dewey-tens | 530 - Physics |
| discipline | Chemie / Pharmazie Physik Chemie |
| format | Book |
| fullrecord | <?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>02158nam a2200541 cb4500</leader><controlfield tag="001">BV002252689</controlfield><controlfield tag="003">DE-604</controlfield><controlfield tag="005">20220505 </controlfield><controlfield tag="007">t</controlfield><controlfield tag="008">890928s1978 d||| |||| 00||| eng d</controlfield><datafield tag="020" ind1=" " ind2=" "><subfield code="a">0123263506</subfield><subfield code="9">0-12-326350-6</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(OCoLC)3540653</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)BVBBV002252689</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-604</subfield><subfield code="b">ger</subfield><subfield code="e">rakddb</subfield></datafield><datafield tag="041" ind1="0" ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="049" ind1=" " ind2=" "><subfield code="a">DE-91</subfield><subfield code="a">DE-355</subfield><subfield code="a">DE-706</subfield><subfield code="a">DE-83</subfield><subfield code="a">DE-188</subfield><subfield code="a">DE-19</subfield></datafield><datafield tag="050" ind1=" " ind2="0"><subfield code="a">QC763</subfield></datafield><datafield tag="082" ind1="0" ind2=" "><subfield code="a">538/.3</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">UM 3700</subfield><subfield code="0">(DE-625)145893:</subfield><subfield code="2">rvk</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">UP 8200</subfield><subfield code="0">(DE-625)146449:</subfield><subfield code="2">rvk</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">VE 8600</subfield><subfield code="0">(DE-625)147149:253</subfield><subfield code="2">rvk</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">VG 9700</subfield><subfield code="0">(DE-625)147242:253</subfield><subfield code="2">rvk</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">CHE 248f</subfield><subfield code="2">stub</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Harriman, John E.</subfield><subfield code="e">Verfasser</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Theoretical foundations of electron spin resonance</subfield><subfield code="c">John E. Harriman</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="a">New York [u.a.]</subfield><subfield code="b">Acad. Press</subfield><subfield code="c">1978</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">XIII, 399 S.</subfield><subfield code="b">graph. Darst.</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="490" ind1="1" ind2=" "><subfield code="a">Physical chemistry</subfield><subfield code="v">37</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Elektron paramagnetische resonantie</subfield><subfield code="2">gtt</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Elektronspinresonantie</subfield><subfield code="2">gtt</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Spectroscopie de résonance paramagnétique électronique</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Electron paramagnetic resonance spectroscopy</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Elektronenspinresonanzspektroskopie</subfield><subfield code="0">(DE-588)4151888-3</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Elektronenspinresonanz</subfield><subfield code="0">(DE-588)4132116-9</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Theorie</subfield><subfield code="0">(DE-588)4059787-8</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="689" ind1="0" ind2="0"><subfield code="a">Elektronenspinresonanz</subfield><subfield code="0">(DE-588)4132116-9</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="0" ind2=" "><subfield code="5">DE-604</subfield></datafield><datafield tag="689" ind1="1" ind2="0"><subfield code="a">Elektronenspinresonanzspektroskopie</subfield><subfield code="0">(DE-588)4151888-3</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="1" ind2=" "><subfield code="5">DE-604</subfield></datafield><datafield tag="689" ind1="2" ind2="0"><subfield code="a">Elektronenspinresonanzspektroskopie</subfield><subfield code="0">(DE-588)4151888-3</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="2" ind2="1"><subfield code="a">Theorie</subfield><subfield code="0">(DE-588)4059787-8</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="2" ind2=" "><subfield code="5">DE-604</subfield></datafield><datafield tag="830" ind1=" " ind2="0"><subfield code="a">Physical chemistry</subfield><subfield code="v">37</subfield><subfield code="w">(DE-604)BV001888852</subfield><subfield code="9">37</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="m">HBZ Datenaustausch</subfield><subfield code="q">application/pdf</subfield><subfield code="u">http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001480261&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA</subfield><subfield code="3">Inhaltsverzeichnis</subfield></datafield><datafield tag="999" ind1=" " ind2=" "><subfield code="a">oai:aleph.bib-bvb.de:BVB01-001480261</subfield></datafield></record></collection> |
| id | DE-604.BV002252689 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T15:42:49Z |
| institution | BVB |
| isbn | 0123263506 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-001480261 |
| oclc_num | 3540653 |
| open_access_boolean | |
| owner | DE-91 DE-BY-TUM DE-355 DE-BY-UBR DE-706 DE-83 DE-188 DE-19 DE-BY-UBM |
| owner_facet | DE-91 DE-BY-TUM DE-355 DE-BY-UBR DE-706 DE-83 DE-188 DE-19 DE-BY-UBM |
| physical | XIII, 399 S. graph. Darst. |
| publishDate | 1978 |
| publishDateSearch | 1978 |
| publishDateSort | 1978 |
| publisher | Acad. Press |
| record_format | marc |
| series | Physical chemistry |
| series2 | Physical chemistry |
| spelling | Harriman, John E. Verfasser aut Theoretical foundations of electron spin resonance John E. Harriman New York [u.a.] Acad. Press 1978 XIII, 399 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Physical chemistry 37 Elektron paramagnetische resonantie gtt Elektronspinresonantie gtt Spectroscopie de résonance paramagnétique électronique Electron paramagnetic resonance spectroscopy Elektronenspinresonanzspektroskopie (DE-588)4151888-3 gnd rswk-swf Elektronenspinresonanz (DE-588)4132116-9 gnd rswk-swf Theorie (DE-588)4059787-8 gnd rswk-swf Elektronenspinresonanz (DE-588)4132116-9 s DE-604 Elektronenspinresonanzspektroskopie (DE-588)4151888-3 s Theorie (DE-588)4059787-8 s Physical chemistry 37 (DE-604)BV001888852 37 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001480261&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Harriman, John E. Theoretical foundations of electron spin resonance Physical chemistry Elektron paramagnetische resonantie gtt Elektronspinresonantie gtt Spectroscopie de résonance paramagnétique électronique Electron paramagnetic resonance spectroscopy Elektronenspinresonanzspektroskopie (DE-588)4151888-3 gnd Elektronenspinresonanz (DE-588)4132116-9 gnd Theorie (DE-588)4059787-8 gnd |
| subject_GND | (DE-588)4151888-3 (DE-588)4132116-9 (DE-588)4059787-8 |
| title | Theoretical foundations of electron spin resonance |
| title_auth | Theoretical foundations of electron spin resonance |
| title_exact_search | Theoretical foundations of electron spin resonance |
| title_full | Theoretical foundations of electron spin resonance John E. Harriman |
| title_fullStr | Theoretical foundations of electron spin resonance John E. Harriman |
| title_full_unstemmed | Theoretical foundations of electron spin resonance John E. Harriman |
| title_short | Theoretical foundations of electron spin resonance |
| title_sort | theoretical foundations of electron spin resonance |
| topic | Elektron paramagnetische resonantie gtt Elektronspinresonantie gtt Spectroscopie de résonance paramagnétique électronique Electron paramagnetic resonance spectroscopy Elektronenspinresonanzspektroskopie (DE-588)4151888-3 gnd Elektronenspinresonanz (DE-588)4132116-9 gnd Theorie (DE-588)4059787-8 gnd |
| topic_facet | Elektron paramagnetische resonantie Elektronspinresonantie Spectroscopie de résonance paramagnétique électronique Electron paramagnetic resonance spectroscopy Elektronenspinresonanzspektroskopie Elektronenspinresonanz Theorie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001480261&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV001888852 |
| work_keys_str_mv | AT harrimanjohne theoreticalfoundationsofelectronspinresonance |