Physical chemistry:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
New York u.a.
McGraw-Hill
1988
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| Ausgabe: | 3. ed. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XVII, 920 S. graph. Darst. |
| ISBN: | 0070374740 |
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| 245 | 1 | 0 | |a Physical chemistry |c Ira N. Levine |
| 250 | |a 3. ed. | ||
| 264 | 1 | |a New York u.a. |b McGraw-Hill |c 1988 | |
| 300 | |a XVII, 920 S. |b graph. Darst. | ||
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Datensatz im Suchindex
| _version_ | 1804116673917091840 |
|---|---|
| adam_text | THIRD EDITION
DH YSIC A
CHEMISTRY
RA N LEVINE
Chemistry Department
Brooklyn College
City University of New York
Brooklyn, New York
McGRAW-HILL BOOK COMPANY
New York St Louis San Francisco Auckland Bogota Caracas Colorado Springs
Hamburg Lisbon London Madrid Mexico Milan Montreal New Delhi
Oklahoma City Panama Paris San Juan Sao Paulo Singapore Sydney
Tokyo Toronto
CONTENTS
Preface xv
THERMODYNAMICS
1 1 Physical Chemistry
1 2 Thermodynamics
1 3 Temperature
1 4 The Mole
1 5 Ideai Gases
1 6 Differential Calculus
1 7 Equations of State
1 8 Integral Calculus
1 9 Study Suggestions
1 10 Summary
THE FIRST LAW OF THERMODYNAMICS
2:1 Classical Mechanics
2 2 P-KWork
2 3 Heat
2 4 The First Law of Thermodynamics
2 5 Enthalpy
2 6 Heat Capacities
2 7 The Joule and Joule-Thomson Experiments
2 8 Perfect Gases and the First Law
2 9 Calculation of First-Law Quantities
2 10 State Functions and Line Integrals
2 11 The Molecular Nature of Internal Energy
2 12 Problem Solving
2 13 Summary
CON1ENTS
, THE SECOND LAW OF THERMODYNAMICS 76
3 1 The Second Law of Thermodynamics 76
3 2 Heat Engines 78
3 3 Entropy 83
3 4 Calculation of Entropy Changes 86
3 5 Entropy, Reversibility, and Irreversibility 91
3 6 The Thermodynamic Temperature Scale 94
3 7 What Is Entropy? 96
3 8 Entropy, Time, and Cosmology 101
3 9 Summary 103
MATERIAL EQUILIBRIUM 107
4 1 Material Equilibrium 107
4 2 • Thermodynamic Properties of Nonequilibrium Systems 108
4 3 Entropy and Equilibrium 109
4 4 The Gibbs and Helmholtz Functions 111
4 5 Thermodynamic Relations for a System in Equilibrium 115
4 6 Calculation of Changes in State Functions 124
4 7 Chemical Potentials 126
4 8 Phase Equilibrium 131
4 9 Reaction Equilibrium 133
4 10 Entropy and Life 136
4 11 Summary 137
STANDARD THERMODYNAMIC FUNCTIONS OF REACTION 141
5 1 Standard States 141
5 2 Standard Enthalpy of Reaction 142
5:3 Standard Enthalpy of Formation 143
5 4 Determination of Standard Enthalpies of Formation and Reaction 145
5 5 Temperature Dependence of Reaction Heats 151
5 6 Conventional Entropies and the Third Law 153
5 7 Standard Gibbs Energy of Reaction 158
5 8 Thermodynamics Tables 160
5 9 Estimation of Thermodynamic Properties 162
5 10 The Unattainability of Absolute Zero 165
5 11 Summary - 165
REACTION EQUILIBRIUM IN IDEAL GAS MIXTURES 170
6 1 Chemical Potentials in an Ideal Gas Mixture 170
6 2 Ideal-Gas Reaction Equilibrium 172
6 3 Temperature Dependence of the Equilibrium Constant
6 4 Ideal-Gas Equilibrium Calculations
6 5 Shifts in Ideal-Gas Reaction Equilibria
6 6 Summary
CONTENTS
ONE-COMPONENT PHASE EQUILIBRIUM
7 1 The Phase Rule
7 2 One-Component Phase Equilibrium
7 3 the Clapeyron Equation
7 4 Solid-Solid Phase Transitions
7 5 Higher-Order Phase Transitions
7 6 Summary
REAL GASES
8 1 Compression Factors
8 2 Real-Gas Equations of State
8 3 Condensation
8 4 Critical Data and Equations of State
8 5 The Law of Corresponding States
8 6 Differences between Real-Gas and Ideal-Gas Thermodynamic
Properties
8 7 Taylor Series
8 8 Summary
SOLUTIONS
9 1 Solution Composition
9 2 Partial Molar Quantities
9 3 Determination of Partial Molar Quantities
9 4 Ideal Solutions
9 5 Thermodynamic Properties of Ideal Solutions
9 6 Ideally Dilute Solutions
9 7 Thermodynamic Properties of Ideally Dilute Solutions
9 8 Summary
NONIDEAL SOLUTIONS 260
10*1 Activities and Activity Coefficients 260
10 2 Determination of Activities and Activity Coefficients 264
10 3 Activity Coefficients on the Molality and Molar Concentration Scales 271
10 4 Solutions of Electrolytes 272
10 5 Determination of Electrolyte Activity Coefficients 278
10 6 The Debye-Hiickel Theory of Electrolyte Solutions 280
10 7 Ionic Association 284
10 8 Standard-State Thermodynamic Properties of Solution Components 285
10 9 Nonideal Gas Mixtures 289
10 10 Summary 292
REACTION EQUILIBRIUM IN NONIDEAL SYSTEMS 297
11 1 The Equilibrium Constant 297
11 2 Reaction Equilibrium in Nonelectrolyte Solutions 298
11 3 Reaction Equilibrium in Electrolyte Solutions 299
11 4 Reaction Equilibria Involving Pure Solids or Pure Liquids 304
11 5 Reaction Equilibrium in Nonideal Gas Mixtures 307
11 6 Temperature and Pressure Dependences of the Equilibrium Constant 307
11 7 Summary of Standard States 309
i18 Coupled Reactions 310
11 9 Gibbs Energy Change for a Reaction 311
11 10 Summary 312
MULTICOMPONENT PHASE EQUILIBRIUM 316
12 1 Colligative Properties 316
12 2 Vapor-Pressure Lowering 316
12 3 Freezing-Point Depression and Boiling-Point Elevation 317
12 4 Osmotic Pressure 321
12 5 Two-Component Phase Diagrams 327
12 6 Two-Component Liquid-Vapor Equilibrium 327
12 7 Two-Component Liquid-Liquid Equilibrium 334
12 8 Two-Component Solid-Liquid Equilibrium 336
12 9 Structure of Phase Diagrams 345
12 10 Solubility 346
12 11 Three-Component Systems 349
12 12 Summary 351
SURFACE CHEMISTRY 357
13 1 The Interphase Region 357
13 2 Curved Interfaces 361
13 3 Thermodynamics of Surfaces • 364
13 4 Surface Films on Liquids 369
13 5 Adsorption of Gases on Solids 371
13 6 Colloids 376
13 7 Summary 379
ELECTROCHEMICAL SYSTEMS-
14 1 Electrostatics
14 2 Electrochemical Systems
14 3 Thermodynamics of Electrochemical Systems
14 4 Galvanic Cells
14 5 Types of Reversible Electrodes
14 6 Thermodynamics of Galvanic Cells
14 7 Standard Electrode Potentials
14 8 Classification of Galvanic Cells
14 9 Liquid-Junction Potentials
14 10 Applications of EMF Measurements
14 11 Batteries
14 12 Ion-Selective Membrane Electrodes
14 13 Membrane Equilibrium
14 14 The Electrical Double Layer
14 15 Dipole Moments and Polarization
14 16 Bioelectrochemistry
14 17 Summary
CONTENTS
KINETIC-MOLECULAR THEORY OF GASES
15 1 Kinetic-Molecular Theory of Gases
15 2 Pressure of an Ideal Gas
15 3 Temperature
15 4 Distribution of Molecular Speeds in an Ideal Gas
15 5 Applications of the Maxwell Distribution
15 6 Collisions with a Wall and Effusion
15 7 Molecular Collisions and Mean Free Path
15 8the Barometric Formula
15 9 The Boltzmann Distribution Law
15 10 Heat Capacities of Ideal Polyatomic Gases
15 11 Summary
TRANSPORT PROCESSES
16 1 Kinetics
16 2 Thermal Conductivity
16 3 Viscosity
16 4 Diffusion and Sedimentation
16 5 Electrical Conductivity
16 6 Electrical Conductivity of Electrolyte Solutions
16 7 Summary
CONTENTS
t REACTION KINETICS 512
17 1 Reaction Kinetics 512
17 2 Measurement of Reaction Rates 516
17 3 Integration of Rate Laws 518
17 4 Determination of the Rate Law 524
17 5 Rate Laws and Equilibrium Constants for Elementary Reactions 528
17 6 Reaction Mechanisms 530
17 7 Temperature Dependence of Rate Constants 537
17 8 Relation between Rate Constants and Equilibrium Constants
for Complex Reactions 542
17 9 The Rate Law in Nonideal Systems 543
17 10 Unimolecular Reactions 544
17 11 Trimolecular Reactions 546
17 12 Chain Reactions and Free-Radical Polymerizations 547
17 13 Fast Reactions 553
17 14 Reactions in Liquid Solutions 556
17 15 Catalysis 561
17 16 Enzyme Catalysis 563
17 17 Heterogeneous Catalysis 566
17 18 Nuclear Decay 571
17 19 Summary 572
QUANTUM MECHANICS 581
18 1 Blackbody Radiation and Energy Quantization 581
18 2 The Photoelectric Effect and Photons 584
18 3 The Bohr Theory of the Hydrogen Atom 586
18 4 The de Broglie Hypothesis 587
18 5 The Uncertainty Principle 589
18 6 Quantum Mechanics 590
18 7 The Time-Independent Schrodinger Equation 595
18 8 The Particle in a One-Dimensional Box 597
18 9 The Particle in a Three-Dimensional Box 602
18 10 Degeneracy 603
18 11 Operators 604
18 12 The One-Dimensional Harmonic Oscillator 608
18 13 Two-Particle Problems 610
18 14 The Two-Particle Rigid Rotor 612
18 15 Approximation Methods 613
18 16 Summary 615
ATOMIC STRUCTURE 620
19 1 Units 620
19 2 Historical Background 621
19 3 The Hydrogen Atom 622
19 4 Electron Spin 632
19 5 The Helium Atom and the Pauli Principle 633
19 6 Many-Electron Atoms and the Periodic Table 640
19 7 Hartree-Fock and Configuration-Interaction Wave Functions 646
19 8 Summary 648
MOLECULAR ELECTRONIC STRUCTURE 652
20 1 Chemical Bonds 652
20 2 The Born-Oppenheimer Approximation 656
20 3 The Hydrogen Molecule Ion 660
20 4 The Simple MO Method for Diatomic Molecules 666
20 5 SCF, Hartree-Fock, and CI Wave Functions 672
20 6 The MO Treatment of Polyatomic Molecules 673
20 7 Calculation of Molecular Properties 683
20 8 The VSEPR Method 686
20 9 Semiempiricar Methods 688
20 10 The Valence-Bond Method 693
20 11 Future Prospects 694
20 12 Summary 695
SPECTROSCOPY AND PHOTOCHEMISTRY 699
21 1 Electromagnetic Radiation 699
21 2 Spectroscopy 702
21 3 Rotation and Vibration of Diatomic Molecules 707
21 4 Rotational and Vibrational Spectra of Diatomic Molecules 713
21 5 Molecular Symmetry 719
21 6 Rotation of Polyatomic Molecules 721
21 7 Microwave Spectroscopy 723
21 8 Vibration of Polyatomic Molecules 726
21 9 Infrared Spectroscopy 728
21 10 Raman Spectroscopy 731
21 11 Electronic Spectroscopy 733
21 12 Nuclear-Magnetic-Resonance Spectroscopy 736
21 13 Electron-Spin-Resonance Spectroscopy 747
21 14 Optical Rotatory Dispersion and Circular Dichroism 748
21 15 Photoelectron Spectroscopy 750
21 16 Photochemistry 751
21 17 Summary 756
STATISTICAL MECHANICS 762
22 1 Statistical Mechanics 762
22 2 The Canonical Ensemble 764
22 3 Canonical Partition Function for a System of
Noninteracting Particles 773
CONTENTS
t 22 4 Canonical Partition Function of a Pure Ideal Gas 777
22 5 The Boltzmann Distribution Law for Noninteracting Molecules 779
22 6 Statistical Thermodynamics of Ideal Diatomic and Monatomic Gases 783
22 7 Statistical Thermodynamics of Ideal Polyatomic Gases 793
22 8 Ideal-Gas Thermodynamic Properties and Equilibrium Constants 796
22 9 Entropy and the Third Law of Thermodynamics 800
22 10 Intermolecular Forces 803
22 11 Statistical Mechanics of Fluids 809
22 12 Summary 813
THEORIES OF REACTION RATES „ 819
23 1 Hard-Sphere Collision Theory of Gas-Phase Reactions 819
23 2 Potential-Energy Surfaces 822
23 3 Molecular Reaction Dynamics 830
23 4 Activated-Complex Theory for Ideal-Gas Reactions 834
23 5 Thermodynamic Formulation of ACT 844
23 6 Unimolecular Reactions 846
23 7 Trimolecular Reactions 848
23 8 Reactions in Solution 849
23 9 Summary 853
SOLIDS AND LIQUIDS 856
24 1 Solids and Liquids 856
24 2 Polymers 857
24 3 Chemical Bonding in Solids 858
24 4 Cohesive Energies of Solids 859
24 5 Theoretical Calculation of Cohesive Energies 861
24 6 Interatomic Distances in Crystals 863
24 7 Crystal Structures 865
24 8 Examples of Crystal Structures 870
24 9 Determination of Crystal Structures 874
24 10 Determination of Surface Structures 879
24 11 Band Theory of Solids 881
, 24 12 Statistical Mechanics of Crystals 883
24 13 Defects in Solids 889
24 14 Liquids 889
24 15 Summary 893
Bibliography 896
Appendix 899
* Answers to Selected Problems 901
Index 905
|
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| spelling | Levine, Ira N. 1937- Verfasser (DE-588)13821204X aut Physical chemistry Ira N. Levine 3. ed. New York u.a. McGraw-Hill 1988 XVII, 920 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Chimie physique et théorique ram Chemistry, Physical and theoretical Physikalische Chemie (DE-588)4045959-7 gnd rswk-swf (DE-588)4151278-9 Einführung gnd-content Physikalische Chemie (DE-588)4045959-7 s DE-604 HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001457696&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
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| title | Physical chemistry |
| title_auth | Physical chemistry |
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| title_full | Physical chemistry Ira N. Levine |
| title_fullStr | Physical chemistry Ira N. Levine |
| title_full_unstemmed | Physical chemistry Ira N. Levine |
| title_short | Physical chemistry |
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| topic | Chimie physique et théorique ram Chemistry, Physical and theoretical Physikalische Chemie (DE-588)4045959-7 gnd |
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