Geochemistry in mineral exploration:
Gespeichert in:
| Vorheriger Titel: | Hawkes, Herbert E. Geochemistry in mineral exploration |
|---|---|
| Hauptverfasser: | , , |
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
London [u.a.]
Acad. Press
1979
|
| Ausgabe: | 2. ed. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XVII, 657 S. graph. Darst., Kt. |
| ISBN: | 0125962509 0125962525 |
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| 100 | 1 | |a Rose, Arthur W. |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Geochemistry in mineral exploration |c Arthur W. Rose ; Herbert E. Hawkes ; John S. Webb |
| 250 | |a 2. ed. | ||
| 264 | 1 | |a London [u.a.] |b Acad. Press |c 1979 | |
| 300 | |a XVII, 657 S. |b graph. Darst., Kt. | ||
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Datensatz im Suchindex
| _version_ | 1804116639215517696 |
|---|---|
| adam_text | Contents
PREFACE
Chapter 1
INTRODUCTION
I. Geochemistry in Mineral Exploration ..... 2
II. Scales and Sampling Media in Geochemical Exploration . . 2
A. Reconnaissance surveys ....... 2
B. Detailed surveys........ 4
III. History........... 5
IV. Present Status......... 6
V. Literature.......... 9
VI. Related Fields of Applied Geochemistry . . . . . 11
Chapter 2
BASIC PRINCIPLES
I. The Geochemical Environment ...... 13
II. Geochemical Dispersion ....... 16
III. Geochemical Mobility........ 18
IV. Geochemical Reactions ........ 18
A. Dispersion of elements under deep-seated conditions . . 20
B. Mobility under surficial conditions ..... 23
V. Association of Elements........ 25
VI. Patterns of Geochemical Distribution ..... 28
A. Normal background values ...... 30
B. Statistical distribution of background values ... 32
C. The geochemical anomaly...... 34
VII. Principles of Interpretation ....... 35
vii
viii Contents
Chapter 3
PRINCIPLES OF TRACE ANALYSIS
I. Mode of Occurrence of Trace Elements in Solids ... 44
A. Stability of important minerals..... 46
II. Preparation of Samples ........ 46
III. Decomposition of Samples ....... 49
A. Volatilization ........ 51
B. Fusion.......... 51
C. Vigorous acid attack....... 51
D. Attack by weak aqueous extractants .... 52
E. Oxidation - reduction agents...... 53
IV. Separation.......... 53
A. Separation in liquid phase...... 53
B. Separation in solid phase....... 54
V. Estimation.......... 54
A: Colorimetry ......... 54
B. Emission spectrometry and spectrography .... 56
C. Atomic absorption ........ 57
D. X-ray fluorescence spectrometry ..... 58
E. Fluorimetry ......... 58
F. Radiometric methods ....... 58
G. Electroanalytical methods ...... 59
H. Chromatographic methods ...... 59
I. Mass spectrometry ........ 60
J. Other methods........ 60
K. Units for reporting chemical analyses .... 61
VI. Reliability of Geochemical Analyses ..... 61
A. Precision ......... 62
B. Accuracy ......... 65
C. Routine checks of precision and accuracy .... 66
VII. Analytical Procedures ........ 66
VHI. Selected References on Techniques of Chemical Analysis . . 70
Chapter 4
PATTERNS OF DEEP-SEATED ORIGIN—ORE TYPES,
GEOCHEMICAL PROVINCES, AND PRODUCTIVE PLUTONS
I. Classification of Mineral Deposits ...... 72
A. Ore-forming processes ....... 72
B. Geochemical recognition of ore types .... 72
II. Productive Environments of Deep-seated Origin ... 77
HI. Geochemical and Metallogenic Provinces ..... 78
Contents ix
IV. Processes Forming Productive Plutons ..... 84
V. Ores Related to Productive Plutons...... 87
A. Pegmatites......... 87
B. Magmatic copper-nickel sulfides..... 88
C. Ores associated with granitic rocks ..... 89
D. Hydrothermal tin deposits ...... 90
E. Molybdenum, tungsten, and gold deposits ... 93
F. Base-metal sulfide deposits ...... 93
G. Porphyry-copper deposits ...... 94
H. Volcanogenic massive sulfides ...... 95
Chapter 5
EPIGENETIC ANOMALIES IN BEDROCK
I. Formation of Diffusion Aureoles ...... 98
II. Formation of Leakage Anomalies...... 101
III. Zoning in Epigenetic Orebodies and Aureoles . . . . 104
IV. Examples of Diffusion Aureoles . . . . . . 107
V. Examples of Leakage Anomalies and Zoning .... 109
A. Polymetallic vein and replacement deposits . . . 109
B. Porphyry-copper and molybdenum deposits . . . 114
C. Epithermal deposits of Au-Ag-As-Sb-Hg . . . 118
D. Volcanogenic massive-sulfide deposits . . . . 119
E. Mississippi-valley type lead-zinc deposits . . . . 120
F. Leakage anomalies in specific types of material . . 121
VI. Geochemical Rock Surveys ....... 121
A. Orientation surveys . . . . . . . 122
B. Collection and processing of samples .... 124
C. Preparation of maps and handling of data . . . 125
D. Interpretation of data . . . . . . . 126
Chapter 6
WEATHERING
I. Nature of Weathering........ 128
n. Weathering Processes........ 129
A. Physical weathering . . . . . . . 130
B. Chemical weathering . . . . . . . 131
C. Biologic agents in weathering . . . . . . 133
III. Factors Affecting Weathering Processes..... 134
A. Resistance of minerals in weathering . . . . 134
B. Permeability......... 136
Contents
C. Climate .....
D. Relief and drainage ....
IV. Products of Weathering ....
A. Residual primary minerals from the parent rock
B. Secondary minerals ....
C. Soluble products.....
D. Residual structures and textures
V. Selected References on Weathering .
Chapter 7
SOIL FORMATION
I. Soil Profile Development......
n. Factors Affecting Soil Formation.....
A. Parent material .......
B. Climate........
C. Biologic activity .......
D. Relief.........
E. Time.........
HI. Classification of Soils .......
A. The Soil Taxonomy system .....
B. Old classification of soils .....
IV. Soils of Humid Regions.......
A. Podzolic and related soils of temperate forested regions
B. Tropical soils.......
C. Intrazonal hydromorphic soils.....
V. Soils of Subhumid and Arid Regions ....
A. Grassland soils .......
B. Desert soils........
C. Soils of arctic areas......
D. Intrazonal saline and alkali soils ....
VI. Mountain Soils........
VII. Selected References on Soil Formation ....
Chapter 8
CHEMICAL EQUILIBRIA IN THE SURFICIAL ENVIRONMENT
I. Composition of Natural Waters ......
II. Eh-pH Relationships........
A. Hydrogen-ion concentration ......
B. Oxidation-reduction potential .....
C. Eh-pH diagrams ........
Contents xi
D. Forms of sulfur and carbon in solution . . . . 188
III. Formation of Complexes....... 191
IV. Solubility of Minerals........ 192
V. Adsorption and Ion Exchange on Colloidal Particles . . . 195
A. Ion exchange in clay minerals ...... 196
B. Adsorption on surfaces....... 197
VI. Organic Matter......... 206
A. Simple organic compounds...... 206
B. Humic substances ........ 208
VII. Electrochemical Dispersion . . . . . . . 212
VIII. Selected References on Chemical Equilibria in the Surficial Environ-
ment ........... 214
Chapter 9
MECHANICAL AND BIOLOGICAL DISPERSION IN THE
SURFICIAL ENVIRONMENT
I. Mechanical Factors ........ 216
A. Simple gravity movement ...... 216
B. Dispersion in ground water...... 220
C. Mechanics of dispersion in surface water .... 224
D. Dispersion by glaciers . . . . . . .231
E. Dispersion by wind action ...... 235
F. Dispersion by animal activity...... 235
G. Dispersion in permafrost areas..... 236
II. Biological Factors ......... 236
A. The effect of vegetation ....... 236
B. The effect of microorganisms ...... 238
III. The Influence of Environment on Dispersion .... 238
A. Climate......... 238
B. Relief.......... 239
C. Rock types......... 239
D. Life processes ........ 240
E. Time.......... 240
IV. Selected References on Dispersion in the Surficial Environment . 241
Chapter 10
SURFICIAL DISPERSION PATTERNS
I. Classification of Surficial Dispersion Patterns .... 242
II. Syngenetic Patterns........244
A. Clastic patterns........244
ii Contents
B. Hydromorphic patterns....... 245
C Biogenic patterns ........ 245
HI. Epigenetic Patterns........ 245
A. Hydromorphic patterns....... 245
B. Biogenic patterns . . . . ... . . 246
IV. Partition of Dispersed Constituents Between Liquid and Solid
Media........... 246
A. Liquid media ........ 246
B. Solid media......... 248
V. Extractability of Metal from Clastic Samples .... 249
VI. Contrast.......... 250
VII. Form of Surficial Patterns....... 252
A. Clastic patterns........ 252
B. Hydromorphic patterns....... 254
C. Biogenic patterns........ 256
Anomalies Not Related to Mineral Deposits .... 256
A. High-background source rocks ..... 257
B. Contamination........ 258
C. Sampling errors........ 259
D. Analytical errors ........ 260
IX. Suppression of Significant Anomalies ..... 260
Chapter 11
ANOMALIES IN RESIDUAL OVERBURDEN
I. Anomalies in Gossans and Leached Outcrops of Ore . . 261
II. Syngenetic Anomalies in Residual Soil ..... 266
A. Mode of occurrence ....... 266
B. Form and magnitude of the anomaly .... 269
C. Homogeneity ........ 278
D. Variations with depth and soil type..... 281
III. Hydromorphic Anomalies in Residual Soil .... 285
IV. Anomalies Not Related to Mineral Deposits .... 285
Chapter 12
ANOMALIES IN TRANSPORTED OVERBURDEN
I. Common Features of Anomalies in Transported Overburden . 288
A. Syngenetic anomalies ....... 289
B. Epigenetic anomalies ....... 289
C. Anomalies not related to mineral deposits . . . 290
n. Glacial Overburden ........ 290
A. Syngenetic (clastic) anomalies...... 291
Contents xiii
B. Hydromorphic anomalies ...... 300
C. Biogenic anomalies ....... 304
D. Superjacent anomalies of complex origin . . . 305
E. Schematic models of dispersion in glaciated areas . . 306
III. Organic Deposits ......... 306
IV. Colluvium and Alluvium . . . . . . . 311
A. Syngenetic anomalies . . . . . . . 313
B. Epigenetic anomalies ....... 314
V. Other Types of Transported Overburden .... 317
Chapter 13
GEOCHEMICAL SOIL SURVEYS
I. Orientation Surveys ........ 320
A. Residual soil ........ 321
B. Transported overburden ...... 325
C. Contamination ........ 325
D. Choice of procedures ....... 328
II. Field Operations......... 329
A. Sampling pattern ........ 329
B. Sampling procedure....... 333
C. Locating and identifying samples..... 336
D. Sample preparation and analysis ..... 337
E. Preparation of geochemical maps ..... 339
III. Interpretation of Data ........ 341
A. Estimation of background and threshold values . . . 341
B. Recognition of non-significant anomalies .... 342
C. Distinction between lateral and superjacent anomalies . . 344
D. Appraisal of anomalies ....... 345
IV. General Procedure for Follow-up...... 346
Chapter 14
ANOMALIES IN NATURAL WATERS
I. Mode of Occurrence of Elements ...... 348
II. Factors Affecting Composition of Natural Waters . . . 351
A. Composition of rain water . . . . . . 351
B. Reaction with soil and rock ...... 352
C. Regional and climatic factors ...... 354
D. Age of ground water ....... 355
E. Oxidation-reduction ....... 355
F. Adsorption ......... 355
xiv Contents
G. Mixing of waters........ 358
H. Background content of natural waters .... 358
III. Persistence of Anomalies ....... 358
A. Contrast at source ........ 358
B. Decay by dilution........ 361
C. Decay at precipitation barriers ..... 363
D. Re-solution at precipitation barriers ..... 368
IV. Time Variations......... 368
V. Ground-water Anomalies....... 373
VI. Stream-water Anomalies........ 377
VII. Lake-water Anomalies........ 380
VIII. Anomalies Not Related to Mineral Deposits .... 381
Chapter 15
ANOMALIES IN DRAINAGE SEDIMENTS
I. Spring and Seepage Areas...... 383
II. Active Stream Sediments ...... 392
A. Mode of occurrence ...... 392
B. Contrast........ 394
C. Decay patterns ....... 399
D. Anomaly enhancement ...... 406
E. Effect of precipitation barriers .... 411
F. Lateral homogeneity ...... 413
G. Vertical homogeneity ...... 415
H. Time variations ....... 415
III. Flood-plain Sediments....... 416
IV. Lake Sediments........ 419
A. Mode of occurrence ...... 420
B. Homogeneity and contrast..... 421
C. Decay patterns ....... 424
V. Drainage Anomalies Not Related to Mineral Deposits 426
VI. Marine Sediments........ 427
Chapter 16
GEOCHEMICAL DRAINAGE SURVEYS
Orientation Surveys........ 431
A. Water.......... 432
B. Drainage sediment........ 433
C. Contamination ........ 434
Contents xv
II. Choice of Material to be Sampled...... 435
A. Water.......... 435
B. Seepage soils......... 435
C. Stream sediments........ 437
D. Heavy minerals........ 438
E. Organic sediment........ 439
F. Lake sediment and water...... 439
III. Sample Layout ......... 440
A. Ground-water patterns ....... 441
B. Drainage channel patterns ...... 442
IV. Collection and Processing of Samples..... 444
A. Water.......... 445
B. Stream and seepage sediment...... 447
C. Lake sediment........ 449
D. Heavy minerals........ 450
V. Preparation of Maps........ 450
VI. Interpretation of Data........ 453
VII. Follow-up Techniques........ 454
Chapter 17
VEGETATION
I Uptake of Mineral Matter by Plants..... 457
A. Plant nutrition........ 457
B. Availability of elements in soil ..... 458
C. Reactions in the root tips of plants ..... 458
D. Movement and storage within plants .... 463
II. Biogeochemical Anomalies ....... 464
A. Variation between plant species..... 464
B. Variation between plant parts...... 464
C. Depth of root penetration...... 466
D. Variation with other factors...... 467
E. Contrast......... 468
F. Homogeneity ........ 470
G. Form of anomalies ....... 470
III. Biogeochemical Surveying Techniques . . . . .471
A. Orientation survey . ¦ . . . . . 473
B. Choice of sampling medium ...... 473
C. Collecting and processing of samples .... 474
D. Choice of analytical method ...... 474
E. Interpretation of data ....... 475
F. Advantages and disadvantages of biogeochemical surveys . 475
IV. Geobotanical Indicators....... 476
xvi Contents
A. Indicators of ground water...... 478
B. Indicators of saline deposits...... 479
C. Indicators of hydrocarbons...... 479
D. Indicators of rock types....... 481
E. Indicators of ore........ 481
V. Geobotanical Surveying Techniques ...... 484
VI. Remote Sensing of Geobotanical Anomalies .... 485
Chapter 18
VOLATILES AND AIRBORNE PARTICULATES
I. Properties of Gases and Aerosols ...... 490
II. Units of Measurement . . . . . . . .491
III. Source of Naturally Occurring Gases ..... 492
A. Atmospheric gases....... 492
B. Deep-seated gases ........ 494
C. Radiogenic gases........ 495
D. Biogenic gases........ 495
E. Gases generated in sulfide deposits..... 495
F. Atmospheric particulates...... 497
IV. Reactivity of Gases........ 498
V. Movement of Gases ........ 500
A. Diffusion......... 500
B. Water transport........ 502
C. Transfer between water and vapor phases .... 503
D. Vapor transport........ 504
E. Relative effects of infiltration versus diffusion . . . 505
VI. Geochemical Behavior of Selected Gases .... 506
VII. Applications of Vapor Geochemistry..... 511
A. Exploration for sulfide deposits . . . . . 511
B. Exploration for uranium . . . . . . 512
C. Exploration for petroleum ...... 513
D. Location of buried faults...... 514
E. Forecasting of earthquakes...... 514
F. Forecasting of volcanic eruptions ..... 514
G. Location of geothermal areas ...... 514
VIII. Vapor Survey Techniques....... 514
A. Soil air.......... 516
B. Water.......... 516
C. Gas traps......... 517
D. Atmospheric air ........ 517
Contents xvii
Chapter 19
COMPUTERIZED DATA-HANDLING AND
STATISTICAL INTERPRETATION
I. Data-handling by Computer ....... 520
A. Recording of data ........ 520
B. Production of tables, histograms, and summaries . . 521
C. Computer-generated maps . . . . . . 521
D. Contouring of concentrations ...... 523
E. Moving averages and trend surfaces ..... 523
II. Multivariate Statistical Methods...... 525
A. Regression analysis ....... 525
B. Discriminant analysis ....... 527
C. Factor analysis . . . . . . . .531
D. Cluster analysis ........ 533
Chapter 20
GEOCHEMICAL METHODS IN MINERAL EXPLORATION
I. Optimization of Exploration ....... 535
II. Planning of Exploration ........ 536
A. Selection of professional leadership ..... 536
B. Selection of areas ........ 538
C. The exploration sequence ...... 538
III. Choice of Exploration Methods...... 540
A. Target size......... 543
B. Property control........ 544
C. Reliability of method....... 544
D. Cost.......... 544
E. Value of expected ore....... 545
F. Comparison of programs....... 545
G. The role of geochemistry in an exploration system . . 545
IV. Organization and Operations ....... 546
A. Field operations ........ 546
B. Laboratory......... 547
C. Supervision ......... 548
APPENDIX. Geochemical Characteristics of the Elements ... 549
REFERENCES.......... 583
SUBJECT INDEX.......... 637
|
| any_adam_object | 1 |
| author | Rose, Arthur W. Hawkes, Herbert Edwin 1872- Webb, John S. |
| author_GND | (DE-588)116550538 |
| author_facet | Rose, Arthur W. Hawkes, Herbert Edwin 1872- Webb, John S. |
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| dewey-full | 622/.1 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 622 - Mining and related operations |
| dewey-raw | 622/.1 |
| dewey-search | 622/.1 |
| dewey-sort | 3622 11 |
| dewey-tens | 620 - Engineering and allied operations |
| discipline | Geologie / Paläontologie Bergbau / Hüttenwesen Geographie |
| edition | 2. ed. |
| format | Book |
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| id | DE-604.BV002183480 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T15:41:42Z |
| institution | BVB |
| isbn | 0125962509 0125962525 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-001434184 |
| oclc_num | 5976769 |
| open_access_boolean | |
| owner | DE-91 DE-BY-TUM DE-29 DE-634 DE-83 DE-188 DE-19 DE-BY-UBM DE-12 DE-703 |
| owner_facet | DE-91 DE-BY-TUM DE-29 DE-634 DE-83 DE-188 DE-19 DE-BY-UBM DE-12 DE-703 |
| physical | XVII, 657 S. graph. Darst., Kt. |
| psigel | TUB-nveb |
| publishDate | 1979 |
| publishDateSearch | 1979 |
| publishDateSort | 1979 |
| publisher | Acad. Press |
| record_format | marc |
| spelling | Rose, Arthur W. Verfasser aut Geochemistry in mineral exploration Arthur W. Rose ; Herbert E. Hawkes ; John S. Webb 2. ed. London [u.a.] Acad. Press 1979 XVII, 657 S. graph. Darst., Kt. txt rdacontent n rdamedia nc rdacarrier Prospection géochimique Prospection géochimique ram Geochemical prospecting Geochemie (DE-588)4020198-3 gnd rswk-swf Prospektion (DE-588)4047505-0 gnd rswk-swf Bohrung (DE-588)4146246-4 gnd rswk-swf Geochemie (DE-588)4020198-3 s Prospektion (DE-588)4047505-0 s Bohrung (DE-588)4146246-4 s DE-604 Hawkes, Herbert Edwin 1872- Verfasser (DE-588)116550538 aut Webb, John S. Verfasser aut Früher u.d.T. Hawkes, Herbert E. Geochemistry in mineral exploration (DE-604)BV007715471 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001434184&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Rose, Arthur W. Hawkes, Herbert Edwin 1872- Webb, John S. Geochemistry in mineral exploration Prospection géochimique Prospection géochimique ram Geochemical prospecting Geochemie (DE-588)4020198-3 gnd Prospektion (DE-588)4047505-0 gnd Bohrung (DE-588)4146246-4 gnd |
| subject_GND | (DE-588)4020198-3 (DE-588)4047505-0 (DE-588)4146246-4 |
| title | Geochemistry in mineral exploration |
| title_auth | Geochemistry in mineral exploration |
| title_exact_search | Geochemistry in mineral exploration |
| title_full | Geochemistry in mineral exploration Arthur W. Rose ; Herbert E. Hawkes ; John S. Webb |
| title_fullStr | Geochemistry in mineral exploration Arthur W. Rose ; Herbert E. Hawkes ; John S. Webb |
| title_full_unstemmed | Geochemistry in mineral exploration Arthur W. Rose ; Herbert E. Hawkes ; John S. Webb |
| title_old | Hawkes, Herbert E. Geochemistry in mineral exploration |
| title_short | Geochemistry in mineral exploration |
| title_sort | geochemistry in mineral exploration |
| topic | Prospection géochimique Prospection géochimique ram Geochemical prospecting Geochemie (DE-588)4020198-3 gnd Prospektion (DE-588)4047505-0 gnd Bohrung (DE-588)4146246-4 gnd |
| topic_facet | Prospection géochimique Geochemical prospecting Geochemie Prospektion Bohrung |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001434184&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT rosearthurw geochemistryinmineralexploration AT hawkesherbertedwin geochemistryinmineralexploration AT webbjohns geochemistryinmineralexploration |