Modern methods for the separation of rarer metal ions:
Gespeichert in:
1. Verfasser: | |
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Format: | Buch |
Sprache: | English |
Veröffentlicht: |
Oxford
Pergamon Press
1969
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Schlagworte: | |
Online-Zugang: | Inhaltsverzeichnis |
Beschreibung: | 620 S. graph. Darst. |
Internformat
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245 | 1 | 0 | |a Modern methods for the separation of rarer metal ions |c Johann Korkisch |
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adam_text | Titel: Modern methods for the separation of rarer metal ions
Autor: Korkisch, Johann
Jahr: 1969
CONTENTS
PAGE
Preface x
Acknowledgements xii
1. Separation Techniques 1
1.1. Ion Exchange 1
1.1.1. Ion Exchange Resins 1
1.1.2. Ion Exchange Selectivities 5
1.1.3. Ion Exchange Separations 9
1.1.4. Inorganic Ion Exchangers 10
1.2. Chromatography 11
1.2.1. Partition Chromatography 12
1.2.2. Paper Chromatography 12
1.2.3. Electrochromatography 14
1.2.4. Partition Chromatography on Thin Layers 16
1.2.5. Reversed-phase Partition Chromatography 17
1.2.6. Gas Chromatography 19
1.3. Liquid-Liquid Extraction 20
1.3.1. The Extraction Process 20
1.3.2. Types of Solute 22
1.3.3. Applications 23
1.4. Distillation 24
1.5. Coprecipitation 25
1.6. Selected Bibliography 26
2. AcnNiDE Elements
2.1. Separation on Cation Exchangers 28
2.2. Separation on Anion Exchangers 29
2.2.1. Separation as Anionic Sulphate Complexes ( Sulphate Method ) 53
2.2.2. Separation as Anionic Chloride Complexes ( Chloride Method ) 53
2.2.3. Separation as Anionic Nitrate Complexes ( Nitrate Method ) 62
2.2.4. Separation as Anionic Complexes with Various Other Complex-
ing Agents 77
2.3. Other Chromatographic Methods 97
2.3.1. Separation on Cellulose Columns 113
2.3.2. Separation by Paper Chromatography, Paper 113
Electrophoresis and on the Ring-Oven 115
2.3.3. Separation by Partition Chromatography on Silica Gel 121
2.3.4. Separation by Reversed-phase Partition Chromatography 123
2.4. Extraction Methods 131
2.4.1. Extraction with Ethers 131
2.4.2. Extraction with Ketones 136
2.4.3. Extraction with Ethyl Acetate 142
2.4.4. Extraction with Organic Phosphorus Compounds 144
2.4.5. Extraction with Chelating Agents 159
2.5. Separation by Coprecipitation 185
yi CONTENTS
PAGE
3. Rare Earth Elements 197
3.1. Separation on Cation Exchangers 197
3.1.1. Hydrochloric Acid Media 198
3.1.2. Sulphuric Acid Media 200
3.1.3. Nitric Acid Media 201
3.1.4. Other Media 201
3.1.5. Media containing Organic Complexing Agents 201
3.2. Separation on Anion Exchangers 214
3.3. Other Chromatographic Methods 223
3.3.1. Separation by Partition Chromatography 223
3.3.2. Separation by Reversed-phase Partition Chromatography 227
3.4. Extraction Methods 233
3.4.1. Extraction with Ethers, Ketones and Alcohols 233
3.4.2. Extraction with Organic Phosphorus Compounds 235
3.4.3. Extraction with Chelating Agents 241
3.5. Separation by Coprecipitation 250
4. Lithium 256
4.1. Separation on Cation Exchangers 256
4.2. Separation on Anion Exchangers 260
4.3. Other Chromatographic Methods 261
4.4. Extraction Methods 262
5. Rubidium, Caesium and Francium 266
5.1. Separation on Cation Exchangers 266
5.1.1. Separation on Cation Exchange Resins 266
5.1.2. Separation on Inorganic Cation Exchangers 271
5.2. Separation on Anion Exchangers 281
5.3. Other Chromatographic Methods 282
5.4. Extraction Methods 288
5.5. Separation by Coprecipitation 291
6. Beryllium 292
6.1. Separation on Cation Exchangers 292
6.2. Separation on Anion Exchangers 295
6.3. Other Chromatographic Methods 298
6.4. Extraction Methods 300
6.5. Separation by Coprecipitation 304
7. Radium 306
7.1. Separation on Ion Exchangers 306
7.2. Other Chromatographic Methods 308
7.3. Extraction Methods 309
7.4. Separation by Coprecipitation 309
CONTENTS VU
PAOE
8. Gallium, Indium and Thallium 311
8.1. Separation on Cation Exchangers 311
8.2. Separation on Anion Exchangers 315
8.3. Other Chromatographic Methods 320
8.4. Extraction Methods 323
8.5. Separation by Coprecipitation 340
9. Germanium 345
9.1. Separation on Cation Exchangers 345
9.2. Separation on Anion Exchangers 346
9.3. Other Chromatographic Methods 347
9.4. Extraction Methods 349
9.5. Distillation Methods 352
9.6. Separation by Coprecipitation 355
10. Selenium, Tellurium and Polonium 357
10.1. Separation on Cation Exchangers 357
10.2. Separation on Anion Exchangers 360
10.3. Other Chromatographic Methods 362
10.4. Extraction Methods 365
10.5. Distillation Methods 370
10.6. Separation by Coprecipitation 372
11. Silver 375
11.1. Separation on Cation Exchangers 375
11.2. Separation on Anion Exchangers 377
11.3. Other Chromatographic Methods 378
11.4. Extraction Methods 382
11.5. Separation by Coprecipitation 386
12. Gold 388
12.1. Separation on Cation Exchangers 388
12.2. Separation on Anion Exchangers 389
12.3. Other Chromatographic Methods 391
12.4. Extraction Methods 393
12.4.1. Extraction of Tetrachloroaurate 394
12.4.2. Extraction of Tetrabromoaurate 395
12.4.3. Miscellaneous Methods for the Extraction of Gold 396
12.5. Separation by Coprecipitation 398
13. Titanium 4°°
13.1. Separation on Cation Exchangers 400
13.2. Separation on Anion Exchangers 403
13.3. Other Chromatographic Methods 4O7
Viii CONTENTS
PAGE
13.4. Extraction Methods 409
13.4.1. Extraction of Titanium Thiocyanate 410
13.4.2. Extraction of Titanium Cupferrate 411
13.4.3. Extraction with Miscellaneous Reagents 411
13.5. Separation by Coprecipitation 414
14. Zirconium and Hafnium 415
14.1. Separation on Cation Exchangers 415
14.2. Separation on Anion Exchangers 419
14.3. Other Chromatographic Methods 424
14.4. Extraction Methods 428
14.5. Separation by Coprecipitation 434
15. Vanadium 435
15.1. Separation on Cation Exchangers 435
15.2. Separation on Anion Exchangers 439
15.3. Other Chromatographic Methods 442
15.4. Extraction Methods 444
15.5. Separation by Coprecipitation 453
16. Niobium and Tantalum 455
16.1. Separation on Cation Exchangers 455
16.2. Separation on Anion Exchangers 456
16.3. Other Chromatographic Methods 460
16.4. Extraction Methods 464
16.5. Separation by Coprecipitation 475
17. Molybdenum and Tungsten 476
17.1. Separation on Cation Exchangers 476
17.2. Separation on Anion Exchangers 479
17.3. Other Chromatographic Methods 482
17.4. Extraction Methods 486
17.4.1. Extraction of Halide Complexes 486
17.4.2. Extraction of Thiocyanate Complexes 488
17.4.3. Extraction of Dithiol Complexes 491
MA A. Extraction of Benzoin cc-Oxime (BO) Complexes 493
17.4.5. Extraction of Oxine Complexes 494
17.4.6. Extraction of Cupferron Complexes 495
17.4.7. Extraction of Acetylacetone Complexes 496
17.4.8. Extraction with Alkylphosphates 497
17.4.9. Extraction with 2-Thenoyltrifluoroacetone (TTA) 497
17.4.10. Extraction with Miscellaneous Reagents 498
17.5. Separation by Coprecipitation 502
18. Technetium and Rhenium 504
18.1. Separation on Cation Exchangers 504
18.2. Separation on Anion Exchangers 504
CONTENTS IX
PAGE
18.3. Other Chromatographic Methods 509
18.4. Extraction Methods 511
18.4.1. Extraction with Tetraphenylarsonium Chloride (TPAC) 511
18.4.2. Extraction with Cyclic Organic Bases and Ketones 512
18.4.3. Extraction of Thiocyanate Complexes 513
18.4.4. Extraction with Miscellaneous Reagents 515
18.5. Separation by Distillation and Sublimation 519
18.6. Separation by Coprecipitation 521
19. Platinum Metals 524
19.1. Separation on Cation Exchangers 524
19.2. Separation on Anion Exchangers 526
19.3. Other Chromatographic Methods 530
19.4. Extraction Methods 533
19.4.1. Extraction with Ethers, Ketones and Esters 533
19.4.2. Extraction with Tri-n-butylphosphate (TBP) 534
19.4.3. Extraction with Chloroform and Carbon Tetrachloride 535
19.4.4. Extraction with Pyridine 536
19.4.5. Extraction with Chelating Agents 537
19.5. Distillation Methods 546
19.6. Separation by Coprecipitation 551
Author Index 555
Subject Index
|
any_adam_object | 1 |
author | Korkisch, Johann |
author_facet | Korkisch, Johann |
author_role | aut |
author_sort | Korkisch, Johann |
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dewey-search | 546.3 544/.1 |
dewey-sort | 3546.3 |
dewey-tens | 540 - Chemistry and allied sciences |
discipline | Chemie / Pharmazie Chemie |
format | Book |
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spelling | Korkisch, Johann Verfasser aut Modern methods for the separation of rarer metal ions Johann Korkisch Oxford Pergamon Press 1969 620 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Ionen gtt Ionenuitwisseling gtt Lanthaniden gtt Metalen gtt Scheidingstechnieken gtt Metal ions Separation (Technology) Seltenerdmetall (DE-588)4132099-2 gnd rswk-swf Trennverfahren (DE-588)4078395-9 gnd rswk-swf Seltenerdmetall (DE-588)4132099-2 s Trennverfahren (DE-588)4078395-9 s DE-604 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001341818&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
spellingShingle | Korkisch, Johann Modern methods for the separation of rarer metal ions Ionen gtt Ionenuitwisseling gtt Lanthaniden gtt Metalen gtt Scheidingstechnieken gtt Metal ions Separation (Technology) Seltenerdmetall (DE-588)4132099-2 gnd Trennverfahren (DE-588)4078395-9 gnd |
subject_GND | (DE-588)4132099-2 (DE-588)4078395-9 |
title | Modern methods for the separation of rarer metal ions |
title_auth | Modern methods for the separation of rarer metal ions |
title_exact_search | Modern methods for the separation of rarer metal ions |
title_full | Modern methods for the separation of rarer metal ions Johann Korkisch |
title_fullStr | Modern methods for the separation of rarer metal ions Johann Korkisch |
title_full_unstemmed | Modern methods for the separation of rarer metal ions Johann Korkisch |
title_short | Modern methods for the separation of rarer metal ions |
title_sort | modern methods for the separation of rarer metal ions |
topic | Ionen gtt Ionenuitwisseling gtt Lanthaniden gtt Metalen gtt Scheidingstechnieken gtt Metal ions Separation (Technology) Seltenerdmetall (DE-588)4132099-2 gnd Trennverfahren (DE-588)4078395-9 gnd |
topic_facet | Ionen Ionenuitwisseling Lanthaniden Metalen Scheidingstechnieken Metal ions Separation (Technology) Seltenerdmetall Trennverfahren |
url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001341818&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
work_keys_str_mv | AT korkischjohann modernmethodsfortheseparationofrarermetalions |