Solubility of gases and liquids: A graphic approach. Data, causes, prediction
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
New York (u.a.)
Plenum Pr.
1976
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| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | X, 275 S. Ill. u. graph. Darst. |
Internformat
MARC
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Datensatz im Suchindex
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|---|---|
| adam_text | SOLUBILITY OF
GASES AND LIQUIDS
A Graphic Approach
Data — Causes — Prediction
W Gerrard
The Polytechnic of North London
London, England
PLENUM PRESS • NEW YORK AND LONDON
Contents
1 The Solubility of Gases in Liquids 1
1 1 Rationalization of Data 1
1 2 Measurement of Gas Solubility 3
1 3 The Bubbler-Tube and Manometer Techniques for the Determina
tion of the Solubilities of Gases in the Upper Half of the bp Range 3
2 Presentation of Solubility Data on the Reference-Line
Diagram 9
2 1 TheConceptof the Reference Line, the R-Line 9
2 2 Solubilities of Hydrocarbon Gases 11
2 3 The Basis of the Explanations of the Essential Patterns of Data 25
3 Henry s Law and Raoult s Law 29
3 1 Henry s Law 29
3 2 Raoult s Law 36
4 Hildebrand s Solubility Parameters 55
4 1 Intermolecular Forces 55
4 2 The Solubility Parameter 55
4 3 Force Constants 56
5 The Hydrogen-Bonding Structure of Water 59
5 1 The Essential Pattern 59
5 2 The Situation about 1974 60
5 3 Significance of the Solubility of Hydrocarbon Gases in Water 61
vii
viii Contents
5 4 Hydrophobic Interactions 63
5 5 Solubility of Certain Gases in Watei and the Influence of the bp/1 *
atm Factor 64
5 6 Other Aspects of Water Structure 74
6 Sources and Form of Data 77
6 1 Review by Markham and Kobe (1941) on The Solubility of Gases
in Liquids 77
6 2 Review by Battino and Clever (1966) on The Solubility of Gases
in Liquids 79
6 3 Papers by Hildebrand and Colleagues 80
6 4 Papers by Clever and Battino 80
6 5 Data Reference Books 81
7 Data for the Noble Gases and Other Gases in the Lower
Half of the Boiling Point Range 83
7 1 References 83
7 2 The Noble Gases Helium to Radon 83
7 3 Hydrogen, Nitrogen, Oxygen, Carbon Monoxide 86
7 4 The Three Factors 87
7 5 Narcotic Effect of Xenon 87
7 6 Argon in Dioxane and Water Mixtures 88
7 7 Other Items 88
8 Carbon Dioxide, Nitrous Oxide, Hydrogen Sulfide,
Chlorine, Sulfur Dioxide, and Carbonyl Chloride 89
8 1 Carbon Dioxide and Nitrous Oxide 89
8 2 Hydrogen Sulfide, bp-61 °C 94
8 3 Chlorine 97
8 4 Sulfur Dioxide, bp — 10°C/1 atm 103
8 5 Carbonyl Chloride, bp 8 2°C/1 atm 113
9 Hydrogen Halides HC1, HBr, HI 115
9 1 Acid-Base Function 115
9 2 Solubility of Hydrogen Halides in Nonaqueous Liquids 120
9 3 Aspect of Electrolytic Conductance 149
9 4 Nitrile-Hydrogen Halide Systems 153
9 5 Solubility in Water 157
Contents X
10 Ammonia and the Three^Methylamines 161
10 1 Ammonia 161
10 2 Methylamines : • • • 166
10 3 Appreciation of the Essential Pattern of Data 184
10 4 Recent Studies on the Interaction of Aliphatic Amines with Water
Structure 184
11 Dimethyl Ether 187
12 Halogenoalkanes 191
12 1 Chloromethane, Chloroethane, and Bromomethane and Non
aqueous Liquids S 191
12 2 Solubility in Water 202
13 Hydrocarbon Gases 205
13 1 Saturated Hydrocarbons 205
13 2 Unsaturated Hydrocarbons 208
13 3 Selective Absorption of Gaseous Hydrocarbons 209
13 4 Solubility in Alcohols 216
13 5 Solubility in Water 217
13 6 Other Examples 218
14 Examples of Certain Other Gases 223
14 1 List of Formulas and bp °C/1 atm 223
14 2 R-Lines 223
14 3 Data for Certain Gases Containing Fluorine 226
14 4 Other R-Line Examples 228
15 Effect of Temperature 231
15 1 Earlier Aspects 231
15 2 Lannung s Data 232
15 3 Data by Gerrard and Colleagues 232
16 Prediction 235
16 1 Approach to the Problem 235
16 2 Lachowicz s Review 236
16 3 Other Papers 236
x Contents
16 4 New Data on Propene and the Four Butenes 240
16 5 TheR-Line Approach to the Acetylene Systems 244
16 6 The Carbon Dioxide Systems 246
16 7 Solubility of Methane, Hydrogen, and Nitrogen in Liquids at High
Pressures 251
16 8 Solubility of Gases in Nitrate Melts 254
16 9 Solubility of Noble Gases in Molten Fluorides 257
17 Textbook Statements 259
17 1 Introduction 259
17 2 Illustrative Examples of Textbook Statements 259
References 263
Index 273
|
| any_adam_object | 1 |
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| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| format | Book |
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| indexdate | 2024-07-09T15:38:09Z |
| institution | BVB |
| language | English |
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| publishDate | 1976 |
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| publisher | Plenum Pr. |
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| spelling | Gerrard, William Verfasser aut Solubility of gases and liquids A graphic approach. Data, causes, prediction New York (u.a.) Plenum Pr. 1976 X, 275 S. Ill. u. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Gassen gtt Gaz Hydrofobe stoffen gtt Liquides Oplosbaarheid gtt Solubilité Vloeistoffen gtt Water gtt Waterstofbruggen gtt Gases Liquids Solubility Flüssigkeit (DE-588)4017621-6 gnd rswk-swf Gas (DE-588)4019320-2 gnd rswk-swf Löslichkeit (DE-588)4114435-1 gnd rswk-swf Flüssigkeit (DE-588)4017621-6 s Löslichkeit (DE-588)4114435-1 s DE-604 Gas (DE-588)4019320-2 s HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001286031&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Gerrard, William Solubility of gases and liquids A graphic approach. Data, causes, prediction Gassen gtt Gaz Hydrofobe stoffen gtt Liquides Oplosbaarheid gtt Solubilité Vloeistoffen gtt Water gtt Waterstofbruggen gtt Gases Liquids Solubility Flüssigkeit (DE-588)4017621-6 gnd Gas (DE-588)4019320-2 gnd Löslichkeit (DE-588)4114435-1 gnd |
| subject_GND | (DE-588)4017621-6 (DE-588)4019320-2 (DE-588)4114435-1 |
| title | Solubility of gases and liquids A graphic approach. Data, causes, prediction |
| title_auth | Solubility of gases and liquids A graphic approach. Data, causes, prediction |
| title_exact_search | Solubility of gases and liquids A graphic approach. Data, causes, prediction |
| title_full | Solubility of gases and liquids A graphic approach. Data, causes, prediction |
| title_fullStr | Solubility of gases and liquids A graphic approach. Data, causes, prediction |
| title_full_unstemmed | Solubility of gases and liquids A graphic approach. Data, causes, prediction |
| title_short | Solubility of gases and liquids |
| title_sort | solubility of gases and liquids a graphic approach data causes prediction |
| title_sub | A graphic approach. Data, causes, prediction |
| topic | Gassen gtt Gaz Hydrofobe stoffen gtt Liquides Oplosbaarheid gtt Solubilité Vloeistoffen gtt Water gtt Waterstofbruggen gtt Gases Liquids Solubility Flüssigkeit (DE-588)4017621-6 gnd Gas (DE-588)4019320-2 gnd Löslichkeit (DE-588)4114435-1 gnd |
| topic_facet | Gassen Gaz Hydrofobe stoffen Liquides Oplosbaarheid Solubilité Vloeistoffen Water Waterstofbruggen Gases Liquids Solubility Flüssigkeit Gas Löslichkeit |
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