Carbene chemistry:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
New York [u.a.]
Acad. Press
1971
|
| Ausgabe: | 2. ed. |
| Schriftenreihe: | Organic chemistry
1 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XI, 615 S. |
Internformat
MARC
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| 100 | 1 | |a Kirmse, Wolfgang |d 1930- |e Verfasser |0 (DE-588)127192697 |4 aut | |
| 245 | 1 | 0 | |a Carbene chemistry |c by Wolfgang Kirmse |
| 250 | |a 2. ed. | ||
| 264 | 1 | |a New York [u.a.] |b Acad. Press |c 1971 | |
| 300 | |a XI, 615 S. | ||
| 336 | |b txt |2 rdacontent | ||
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| 338 | |b nc |2 rdacarrier | ||
| 490 | 1 | |a Organic chemistry |v 1 | |
| 650 | 0 | 7 | |a Carbene |0 (DE-588)4147281-0 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Carbenoide |0 (DE-588)4147285-8 |2 gnd |9 rswk-swf |
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Datensatz im Suchindex
| _version_ | 1804116381998776320 |
|---|---|
| adam_text | Titel: Carbene chemistry
Autor: Kirmse, Wolfgang
Jahr: 1971
CONTENTS
Preface
to
Second
Edition.
.
.
.
.
.
ix
Preface
to
First
Edition
.
.
?
.
?
.
xi
PART
I
Methylene
Transfer
Reactions
CHAPTER
1
Introduction
I.
Examples
of
Methylene
Transfer
...
1
II.
Mechanisms
of
Methylene
Transfer
.
.
3
III.
Carbenes
and
Carbenoids
....
5
Review
Literature
on
Carbenes
...
7
CHAPTER
2
Photochemical
and
Thermal
Methylene
Transfer
Reactions
I.
Photolysis
of
Ketene.....9
II.
Photolysis
of
Alkyl-
and
Arylketenes
.
.
14
III.
Photolysis
of
Carbon
Suboxide
.
.16
IV.
Photolysis
of
Diazo
Compounds
.
.18
V.
Pyrolysis
of
Diazo
Compounds
.
.24
VI.
Bamford-Stevens
Reaction
.
.
.
.29
VII.
Decomposition
of
Diazirines
.
.
.34
VIII.
Decomposition
of
Cyclopropanes
.
.
.37
IX.
Photolysis
of
Oxiranes.....41
X.
Pyrolysis
of
7-Norbornadienone
Ketals
.
44
XI.
Rearrangement
of
Carbonyl
Compounds
.
47
XII.
Decomposition
of
Polyhalomethanes
.51
XIII.
Decomposition
of
Alkanes
.
.
.
.56
XIV.
Reactions
of
Atomic
Carbon
.
.
.
.58
XV.
Decomposition
of
Olefins
.
.62
XVI.
Desulfurization
and
Deoxygenation
Reactions
65
XVII.
Decomposition
of
Ylides.....68
References
.
.....75
CHAPTER
3
Organometallic
Methylene
Transfer
Agents
I.
Catalytic
Decomposition
of
Diazoalkanes
.
85
II.
Simmons-Smith
Reaction
.
.
.
.92
III.
Organolithium
Reagents
.
.
.96
IV.
Organomercury
Reagents
.
.
.
.110
V.
Organosilicon
and
Organotin
Reagents
.
114
VI.
Carbene
Complexes
of
the
Transition
Metals
.
116
References
.
123
v
vi
CHAPTER
4
PART
II
CHAPTER
5
CHAPTER
6
CHAPTER
7
CHAPTER
8
CONTENTS
Base-Induced
a-Elimination
I.
Basic
Hydrolysis
of
Haloforms
.
.129
II.
Trihalomethides
in
Aprotic
Media
.
.
.136
III.
«-Elimination
at
Methylene
Halides
.
.141
IV.
Dehydrohalogenation
of
Benzylic
Halides
.
143
V.
Solvolysis
of
Propargyl
and
Allenyl
Halides
.
144
VI.
cc-Elimination
at
Alkyl
Halides
.
.
.148
VII.
Deprotonation
of
Carbonium
Ions
.
.
.150
References.......154
Structure
and
Reactivity
of
Carbenes
and
Carbenoids
The
Structural
Theory
of
Carbenes
James
F.
Harrison
I.
An
Approach
to
the
Electronic
Structure
of
Carbenes......
II.
The
Electronic
Structure
of
CH
2
III.
Use
of
Extended
Huckel
Theory
in
the
Elucidation
of
Carbene
Structure
.
IV.
Halocarbenes
.
....
V.
Charge
Distribution
....
VI.
Conclusions
.
.
....
References
.
.
....
The
Spectra
of
Carbenes
I.
Electronic
and
Vibration-Rotation
Spectroscopy
......
II.
Electron
Spin
Resonance
(ESR)
Spectroscopy
References......
Reactions
with
Carbon-Hydrogen
Bonds
I.
Insertion
and
Abstraction
Mechanisms
II.
Stereochemistry.....
III.
Selectivity......
IV.
Intramolecular
Insertion
References......
Addition
to
Alkenes
I.
Stereospecificity.....
II.
Stereoselectivity
.....
III.
Reactivity......
IV.
Synthesis
of
Cyclopropanes
V.
Addition
Accompanied
by
Rearrangement
VI.
Intramolecular
Addition
References......
.
159
.
171
.
178
.
186
.
188
.
191
.
192
.
195
.
200
.
206
.
209
.
220
.
222
.
236
.
261
.
267
.
288
.
296
.
302
.
321
.
328
.
343
CONTENTS
Vll
CHAPTER
9
Addition
to
Alkynes
I.
Formation
of
Cyclopropenes
II.
Formation
of
Bicyclobutanes
.
363
.
369
CHAPTER
10
CHAPTER
11
CHAPTER
12
CHAPTER
13
III.
Reactions
with
Enynes.....370
IV.
Addition
Accompanied
by
Rearrangement
.
371
V.
“
1,3-Dipolar
Additions”
of
Carbonylcarbenes
375
VI.
Thermal
Reactions
of
Dialkyl
Acetylene
dicarboxylates
....
376
References.......378
Addition
to
Arenes
I.
Aromatic
Carbocyclic
Compounds
.
.381
II.
Aromatic
Heterocyclic
Compounds
.
396
III.
Intramolecular
Reactions
.
.
.401
References
.......403
Reactions
Involving
Hetero
Atoms
I.
Silanes
and
Germanes.....407
II.
Nitrogen
Compounds
.....409
III.
Organophosphorus
Compounds
.
.
.
420
IV.
Oxygen
Compounds.....
422
V.
Organosulfur
Compounds
....
437
VI.
Organic
Halides......
442
VII.
Organometallic
Compounds
....
447
References.......449
Rearrangements
I.
1,2
Shifts
in
Alkylcarbenes
....
457
II.
Cyclopropylidene-Allene
Rearrangement
.
462
III.
Rearrangement
and
Fragmentation
of
Cyclopropylcarbenes.....467
IV.
Cyclobutylidene-Methylenecyclopropane
Rearrangement
......
473
V.
Wolff
Rearrangement
of
Diazo
Ketones
.
475
VI.
Rearrangement
of
Arylcarbenes
.
.
493
References.......
497
Silicon,
Germanium,
and
Tin
Structural
Analogs
of
Carbenes
Peter
P.
Gaspar
and
B.
Jerosch
Herold
I.
Introduction.......504
II.
Silicon
Dichloride,
:SiCl
2
....
506
III.
Silicon
Dibromide
and
Diiodide,
SiBr
2
and
Sil
2
.
511
IV.
Chlorosilyene
and
Bromosilyene,
HSiCl
and
HSiBr........512
vin
CONTENTS
Author
Index
Subject
Index
V.
Silicon
Difluoride,
SiF
2
513
VI.
Silylene,
SiH
2
......
517
VII.
Silicon
Atoms,
Si.....
527
Vili.
Alkyl-
and
Arylsilylenes,
RSiH
and
RR Si
528
IX.
Silicon
Monoxide
and
Silicon
Monosulfide,
SiO
and
SiS......
536
X.
Germanium
Atoms,
Ge
536
XI.
Germylene,
GeH
2
.....
537
XII.
Dialkyl
and
Diaryl
Germylenes,
R
2
Ge
.
540
XIII.
Germanium
Dihalides,
GeX
2
.
541
XIV.
Germanium
Monoxide
and
Monosulfide,
GeO
and
GeS......
544
XV.
Divalent
Tin
Compounds
544
XVI.
Conclusion......
544
References......
546
551
598
|
| any_adam_object | 1 |
| author | Kirmse, Wolfgang 1930- |
| author_GND | (DE-588)127192697 |
| author_facet | Kirmse, Wolfgang 1930- |
| author_role | aut |
| author_sort | Kirmse, Wolfgang 1930- |
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| dewey-full | 547.412 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 547 - Organic chemistry |
| dewey-raw | 547.412 |
| dewey-search | 547.412 |
| dewey-sort | 3547.412 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| edition | 2. ed. |
| format | Book |
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| id | DE-604.BV001941600 |
| illustrated | Not Illustrated |
| indexdate | 2024-07-09T15:37:37Z |
| institution | BVB |
| language | English |
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| physical | XI, 615 S. |
| psigel | TUB-nvmb |
| publishDate | 1971 |
| publishDateSearch | 1971 |
| publishDateSort | 1971 |
| publisher | Acad. Press |
| record_format | marc |
| series | Organic chemistry |
| series2 | Organic chemistry |
| spelling | Kirmse, Wolfgang 1930- Verfasser (DE-588)127192697 aut Carbene chemistry by Wolfgang Kirmse 2. ed. New York [u.a.] Acad. Press 1971 XI, 615 S. txt rdacontent n rdamedia nc rdacarrier Organic chemistry 1 Carbene (DE-588)4147281-0 gnd rswk-swf Carbenoide (DE-588)4147285-8 gnd rswk-swf Carbenoide (DE-588)4147285-8 s DE-604 Carbene (DE-588)4147281-0 s Organic chemistry 1 (DE-604)BV000005319 1 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001265505&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Kirmse, Wolfgang 1930- Carbene chemistry Organic chemistry Carbene (DE-588)4147281-0 gnd Carbenoide (DE-588)4147285-8 gnd |
| subject_GND | (DE-588)4147281-0 (DE-588)4147285-8 |
| title | Carbene chemistry |
| title_auth | Carbene chemistry |
| title_exact_search | Carbene chemistry |
| title_full | Carbene chemistry by Wolfgang Kirmse |
| title_fullStr | Carbene chemistry by Wolfgang Kirmse |
| title_full_unstemmed | Carbene chemistry by Wolfgang Kirmse |
| title_short | Carbene chemistry |
| title_sort | carbene chemistry |
| topic | Carbene (DE-588)4147281-0 gnd Carbenoide (DE-588)4147285-8 gnd |
| topic_facet | Carbene Carbenoide |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001265505&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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