The solid-state chemistry of binary metal hydrides:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
New York
Benjamin
1965
|
| Schriftenreihe: | The physical inorganic chemistry series.
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XI,139 S.m.Abb. |
Internformat
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Datensatz im Suchindex
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|---|---|
| adam_text | (THE SOLID-STATE CHEMISTRY
OF BINARY METAL HYDRIDES
GEORGE G LIBOWITZ
Kennecott Copper Corporation Ledgemont Laboratory
WABENJAMIN,INC
1965 New York Amsterdam
amp;
Contents
Editors Foreword v
Preface vii
Chapter 1 CLASSIFICATION AND CHEMICAL
BONDING OF HYDRIDES 1
1-1 Introduction 1
1-2 The Saline Hydrides 2
1-3 The Metallic Hydrides 3
1-4 The Covalent Metal Hydrides 9
1-5 Deuterides and Tri tides 10
References 10
Chapter 2 PREPARATION AND CHEMICAL
PROPERTIES 12
2-1 Direct Combination of the Elements 12
2-2 Electrochemical Preparation 16
2-3 Other Methods of Preparation 17-
N ix
X—CONTENTS
2-4 Chemical Properties 18
References 21
Chapter 3 CRYSTAL STRUCTURES AND PHASE
RELATIONSHIPS 23
3-1 X-Ray and Neutron Diffraction 23
3-2 Structures of Alkali Metal Hydrides 29
3-3 Structures of Alkaline Earth Hydrides 29
3-4 Phases and Structures of the Titanium Subgroup
Metallic Hydrides 31
3-5 Phases and Structures of the Vanadium Subgroup
Metallic Hydrides 34
3-6 Structures of the Chromium Hydrides 36
3-7 Structures of Palladium and Nickel Hydrides 36
3-8 Phases and Structures of the Rare Earth Hydrides 38
3-9 Phases and Structures of the Actinide Hydrides 41
3-10 Relation between Metal and Hydride Structures 44
3-11 Structures of Covalent Hydrides 47
References 48
Chapter 4 THERMODYNAMICS OF METAL HYDRIDES 50
4-1 Introduction 50
4-2 Pressure-Composition Isotherms 50
4-3 Standard Enthalpies, Entropies, and Free Energies
of Formation * 53
4-4 Dissociation Pressure of Deuterides 56
4-5 Partial Molal Quantities 58
4-6 Thermodynamic Properties of Saline Hydrides 63
4-7 Thermodynamic Properties of Titanium, Zirconium,
and Hafnium Hydrides 66
4-8 Thermodynamic Properties of Vanadium Subgroup
Transition Metal Hydrides 72
4-9 Thermodynamic Properties of Palladium Hydride 77
4-10 Thermodynamic Properties of the Rare Earth
Hydrides 78
4-11 Thermodynamic Properties of the Actinide Hydrides 81
4-12 Thermodynamic Properties of Covalent Hydrides 82
4-13 Hysteresis in Pressure-Composition Isotherms 82
4-14 Lattice Energies of Hydrides 85
References 88
CONTENTS—xi
Chapter 5 ELECTRICAL AND MAGNETIC PROPERTIES 88
5-1 Electrochemistry of Hydrides 91
5-2 Electrical Properties of Saline Hydrides 93
5-3 Electrical Properties of Metallic Hydrides 94
5-4 Electrical Properties of Rare Earth Hydrides 97
5-5 Magnetic Susceptibilities of Hydrides 103
5-6 Magnetic Properties of the Rare Earth Hydrides 105
5-7 Nuclear Magnetic Resonance in Hydrides 107
References 112
Chapter 6 NONSTOICHIOMETRY AND LATTICE
DEFECTS IN METAL HYDRIDES 114
6-1 Introduction 114
6-2 Small Deviations from Stoichiometry 115
6-3 Large Deviations from Stoichiometry 119
6-4 Color Centers in Saline Hydrides 122
6-5 Diffusion of Hydrogen in Hydrides 123
References 126
Author Index 129
Subject Index 133
|
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| indexdate | 2024-07-09T15:37:36Z |
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| language | English |
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| physical | XI,139 S.m.Abb. |
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| publishDate | 1965 |
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| series2 | The physical inorganic chemistry series. |
| spelling | Libowitz, George G. Verfasser aut The solid-state chemistry of binary metal hydrides New York Benjamin 1965 XI,139 S.m.Abb. txt rdacontent n rdamedia nc rdacarrier The physical inorganic chemistry series. Estados Da Materia (Quimica) larpcal Hydrides Metallhydride (DE-588)4169593-8 gnd rswk-swf Festkörperchemie (DE-588)4129288-1 gnd rswk-swf Hydride (DE-588)4160888-4 gnd rswk-swf Metallhydride (DE-588)4169593-8 s DE-604 Festkörperchemie (DE-588)4129288-1 s Hydride (DE-588)4160888-4 s HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001265115&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Libowitz, George G. The solid-state chemistry of binary metal hydrides Estados Da Materia (Quimica) larpcal Hydrides Metallhydride (DE-588)4169593-8 gnd Festkörperchemie (DE-588)4129288-1 gnd Hydride (DE-588)4160888-4 gnd |
| subject_GND | (DE-588)4169593-8 (DE-588)4129288-1 (DE-588)4160888-4 |
| title | The solid-state chemistry of binary metal hydrides |
| title_auth | The solid-state chemistry of binary metal hydrides |
| title_exact_search | The solid-state chemistry of binary metal hydrides |
| title_full | The solid-state chemistry of binary metal hydrides |
| title_fullStr | The solid-state chemistry of binary metal hydrides |
| title_full_unstemmed | The solid-state chemistry of binary metal hydrides |
| title_short | The solid-state chemistry of binary metal hydrides |
| title_sort | the solid state chemistry of binary metal hydrides |
| topic | Estados Da Materia (Quimica) larpcal Hydrides Metallhydride (DE-588)4169593-8 gnd Festkörperchemie (DE-588)4129288-1 gnd Hydride (DE-588)4160888-4 gnd |
| topic_facet | Estados Da Materia (Quimica) Hydrides Metallhydride Festkörperchemie Hydride |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001265115&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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