Electronic transitions in organometalloids:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
New York
Acad.Pr.
1969
|
| Schriftenreihe: | Organometallic chemistry.
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XII, 297 S. Ill., Tab. |
Internformat
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Datensatz im Suchindex
| _version_ | 1804116370011455488 |
|---|---|
| adam_text | Electronic Transitions
iln Organometalloids
!3jRIANGRAMSEY
DEPARTMENT OF CHEMISTRY
THE UNIVERSITY OF AKRON
]! J
XKRON, OHIO
ACADEMIC PRESS New York and London
Contents
Foreword vii
Preface ix
I INTRODUCTION TO ELECTRONIC TRANSITIONS
A Molecular Orbital Transition Energies •* 1
B Intensities 6
;Cj Charge Transfer Stales 7
I)! Solvent Effects on Spectra 9
References 11
1L ORGANOMETALLIC DERIVATIVES OF GROUPS I AND II
j Organometallic Derivatives of Group /
A General Comments on Structure 12
B Spectra of Simple Alkyllithiums 13
C Spectra of Conjugated Alkvl Derivatives 14
; D: Spectra of Metal Adducts of Aromatic Hydrocarbons 20
E Alkali Metals a Bonded to sp2 Carbon 20
Organometallic Derivatives of Group II
Text 23
i , References 24
III ORGANOMETALLIC DERIVATIVES OF GROUP III
A General Comments 26
B Alkylboranes 27
j C i Aryl-, Vinyl-, and Alkynylborancs 30
D Conjugated Heterocyclic Boranes 46
E Triarylborane Anion Radicals and Dianions 55
F Tetravalcnt Boron Organometallic Compounds 56
G Substituted Boron Hydrides 60
5 XI
Xll Contents
H Carboranes 61
References 62
IV ORGANOMETALLIC DERIVATIVES OF GROUP IV
A The Role of d Orbitals 65
B Alkyl and Aryl Noncatenated Organometallic Compounds 70
C Alkenyl and Alkynyl Organometallic Compounds 84
D The RjM—C(X)R and R3M(CH2)„C(XJR Chromophores 94
E Metal Esters and Azides 105
F /V-Ketimine- and Azoorganometallic Compounds 109
G The Metal-Metal Bond Chrcmophore 113
H Substituted Metal-Metal Chromophores 126
References 130
V ORGANOMETALLIC DERIVATIVES OF GROUP V AND TELLURIUM
Organometallic Derivatives of Group V
A Alkyl Derivatives 135
B Alkenyl and Alkynyl Derivatives 138
C Heterocyclic Organometallic Compounds 142
D Phosphoranes (Ylides) 143
E The RjP—N=Y Chromophores * 149
F Aryl Derivatives 160
G Aryl Tetracoordinate Metalloids 173
H Miscellaneous Metalloids 181
Organometallic Derivatives of Tellurium
Text 182
References 184
App en dixA ELECTRONIC TRANSITIONS OF GROUP IA ORGANO
METALLIC COMPOUNDS 187
A ppend ix B ELECTRONIC TRANSITIONS OF ORGANOBORON
COMPOUNDS 197
A ppend ix C ELECTRONIC TRANSITIONS OF GROUP IVA ORGANO-
METALLOIDS 221
Ap p en d ix D ELECTRONIC TRANSITIONS OF GROUP VA ORGANO-
METALLOIDS 240
ADDENDUM
Text 262
References 277
Author Index 279
Subject Index 293
|
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| illustrated | Illustrated |
| indexdate | 2024-07-09T15:37:25Z |
| institution | BVB |
| language | English |
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| physical | XII, 297 S. Ill., Tab. |
| psigel | TUB-nveb |
| publishDate | 1969 |
| publishDateSearch | 1969 |
| publishDateSort | 1969 |
| publisher | Acad.Pr. |
| record_format | marc |
| series2 | Organometallic chemistry. |
| spelling | Ramsey, Brian G. Verfasser aut Electronic transitions in organometalloids New York Acad.Pr. 1969 XII, 297 S. Ill., Tab. txt rdacontent n rdamedia nc rdacarrier Organometallic chemistry. Composés organométalliques - Spectre Elektronenoverdracht gtt Organometaalverbindingen gtt Organometallic compounds Spectra Metallorganische Verbindungen (DE-588)4038906-6 gnd rswk-swf Elektronenübergang (DE-588)4290574-6 gnd rswk-swf Metallorganische Verbindungen (DE-588)4038906-6 s Elektronenübergang (DE-588)4290574-6 s DE-604 HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001258270&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Ramsey, Brian G. Electronic transitions in organometalloids Composés organométalliques - Spectre Elektronenoverdracht gtt Organometaalverbindingen gtt Organometallic compounds Spectra Metallorganische Verbindungen (DE-588)4038906-6 gnd Elektronenübergang (DE-588)4290574-6 gnd |
| subject_GND | (DE-588)4038906-6 (DE-588)4290574-6 |
| title | Electronic transitions in organometalloids |
| title_auth | Electronic transitions in organometalloids |
| title_exact_search | Electronic transitions in organometalloids |
| title_full | Electronic transitions in organometalloids |
| title_fullStr | Electronic transitions in organometalloids |
| title_full_unstemmed | Electronic transitions in organometalloids |
| title_short | Electronic transitions in organometalloids |
| title_sort | electronic transitions in organometalloids |
| topic | Composés organométalliques - Spectre Elektronenoverdracht gtt Organometaalverbindingen gtt Organometallic compounds Spectra Metallorganische Verbindungen (DE-588)4038906-6 gnd Elektronenübergang (DE-588)4290574-6 gnd |
| topic_facet | Composés organométalliques - Spectre Elektronenoverdracht Organometaalverbindingen Organometallic compounds Spectra Metallorganische Verbindungen Elektronenübergang |
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