Molecular spectroscopy with neutrons:
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Cambridge, Mass. [u.a.]
M.I.T. Press
1968
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XVII, 226 S. graph. Darst. |
Internformat
MARC
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Datensatz im Suchindex
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|---|---|
| adam_text | Molecular Spectroscopy
With Neutrons
Henri Boutin
Sidney Yip
t
THE MIT PRESS
Massachusetts Institute of Technology
Cambridge, Massachusetts, and London, England
Contents
Preface ix
Acknowledgments xiii
Part I Introduction
1 General Remarks 1
I
Part II Theory
2 Basic Principles 13
2 1 Coherent and Incoherent Scattering Laws 14
2 2 Cross Sections of Idealized Systems _ 3
2 3 The Space-Time Representation 26
2 4 Gaussian Approximation and the Generalized
Frequency Distribution 30
2 5 Comparison with Infrared Absorption 37
3 Methods of Spectral Analysis 42
3 1 The Lattice Approach 44
3 2 The Molecular Approach 53
3 3 Comparison and Correlation with Infrared
Spectra 66
xv
XVi CONTENTS
Part III Experimental Studies
4 Polymeric Compounds
I Polyethylene and Related Molecules
4 1 Polyethylene 77
4 2 Polypropylene 84
4 3 Polyacrylonitrile 89
4 4 Polyoxymethylene 92
4 5o Nylon-6 94
5 Polymeric Compounds
II Polyglycine and Related Molecules
5 1 Polyglycine 97
5 2 Calculation of Thermodynamic Quantities 105
5 3 Torsions around the C-N Bond 106
6 Hydrogen-Bond Vibrations
6 1 KHF2, KH2F3,HF,, andHCl 110
6 2 HCr02 116
6 3 KH2P04 (Potassium Dihydrogen Phosphate) 116
6 4 Other Ferroelectrics 120
7 Alkaline Earth and Alkali Hydroxides
7 1 Interpretation of Spectroscopic Data 123
7 2 Comparison of Spectroscopic Data for Various
1 Hydroxides 127
8 Dynamics of Molecular Torsion and
Rotation
8 1 Total-Cross-Section Measurements 130
8 2 Differential-Cross-Section Measurements 130
8 3 Ammonium Salts 132
8 4 Methyl Groups 138
8 5 Phenomenological Treatment of Hindered
Rotations 140
9 Ice, Water, Aqueous Solutions, and
Salt Hydrates
9 1 Ice 143
9 2 Liquid Water 153
9 3 Molecular Motion-- in Aqueous Solutions 156
CONTENTS xvii
9 4 Molecular Motions of H20 Molecules in Salt
Hydrates 162
9 5 Study of Diffusive Motions 166
10 Studies Related to the Adsorption of
Hydrogenous Molecules on Surfaces 171
10 1 General 171
10 2 Water Adsorbed on Oxide Powders 17 !
10 3 Diffusive Motions 182
10 4 Role of Water in Biological Systems 18 5
10 5 Study of Hydrogenous Molecules in Zeolite and
Molecular Sieves 184
10 6 Study of Clathrate Hydrates 187
11 Molecular Systems of Special Interest 192
11 1 Acetamide and Related Compounds 19 !
11 2 Hexamine 195
11 3 Hydrides 197
11 4 Ring Compounds 200
12 Experimental Considerations 205
12 1 Chopper Time-of-Flight Spectrometer 205
12 2 Other Experimental Techniques 207
Appendices
A Derivation of Double Differential
Scattering Cross Section
B Scattering by an Oscillator
Index 221
|
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| discipline | Chemie / Pharmazie Physik |
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| language | English |
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| spelling | Boutin, Henri Verfasser aut Molecular spectroscopy with neutrons Henri Boutin ; Sidney Yip Cambridge, Mass. [u.a.] M.I.T. Press 1968 XVII, 226 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Neutron (DE-588)4041964-2 gnd rswk-swf Neutronenstreuung (DE-588)4041980-0 gnd rswk-swf Molekül (DE-588)4039972-2 gnd rswk-swf Chemie (DE-588)4009816-3 gnd rswk-swf Molekülspektroskopie (DE-588)4128850-6 gnd rswk-swf Neutronenstreuung (DE-588)4041980-0 s Molekülspektroskopie (DE-588)4128850-6 s DE-604 Molekül (DE-588)4039972-2 s Neutron (DE-588)4041964-2 s Chemie (DE-588)4009816-3 s Yip, Sidney Verfasser aut HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001256938&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Boutin, Henri Yip, Sidney Molecular spectroscopy with neutrons Neutron (DE-588)4041964-2 gnd Neutronenstreuung (DE-588)4041980-0 gnd Molekül (DE-588)4039972-2 gnd Chemie (DE-588)4009816-3 gnd Molekülspektroskopie (DE-588)4128850-6 gnd |
| subject_GND | (DE-588)4041964-2 (DE-588)4041980-0 (DE-588)4039972-2 (DE-588)4009816-3 (DE-588)4128850-6 |
| title | Molecular spectroscopy with neutrons |
| title_auth | Molecular spectroscopy with neutrons |
| title_exact_search | Molecular spectroscopy with neutrons |
| title_full | Molecular spectroscopy with neutrons Henri Boutin ; Sidney Yip |
| title_fullStr | Molecular spectroscopy with neutrons Henri Boutin ; Sidney Yip |
| title_full_unstemmed | Molecular spectroscopy with neutrons Henri Boutin ; Sidney Yip |
| title_short | Molecular spectroscopy with neutrons |
| title_sort | molecular spectroscopy with neutrons |
| topic | Neutron (DE-588)4041964-2 gnd Neutronenstreuung (DE-588)4041980-0 gnd Molekül (DE-588)4039972-2 gnd Chemie (DE-588)4009816-3 gnd Molekülspektroskopie (DE-588)4128850-6 gnd |
| topic_facet | Neutron Neutronenstreuung Molekül Chemie Molekülspektroskopie |
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