Photophysics of aromatic molecules:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
London u.a.
Wiley
1970
|
| Schriftenreihe: | Wiley monographs in chemical physics
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XIII, 704 S. graph. Darst. |
| ISBN: | 0471074209 |
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Datensatz im Suchindex
| _version_ | 1804116367307177984 |
|---|---|
| adam_text | PHOTOPHYSICS OF AROMATIC MOLECULES JOHN B. BIRKS READER IN PHYSICS,
UNIVERSITY OF MANCHESTER WILEY - INTERSCIENCE A DIVISION OF JOHN WILEY &
SONS LTD LONDON NEW YORK SYDNEY TORONTO ITFFISKFTI I CONTENTS 1.
EXCITED STATES OF AROMATIC MOLECULES 1.1 ELECTRONIC STRUCTURE . 1.2
MOLECULAR STRUCTURE . 1.3 THE PFEO MODEL. . . 1.4 SELECTION RULES 1.5
OTHER THEORETICAL MODEIS TABLES 1.1-1.3 ! . 1.6 REFERENCES . . . . 2.
PHOTOPHYSICAL PROCESSES 2.1 INTRODUCTION . . . . .; . , ;, ? , ; 29
2.2 UNIMOLECULAR PROCESSES 30 2.3 BIPHOTONIC PROCESSES . : . . . . . .
32 2.4 BIMOLECULAR PROCESSES . . . . . . . 3 4 2.5 RATE PARAMETERS . ;
! ; ; ! :I . . . . 36 TABLES 2.1-2.5 . V : J : . : . . . 3 8 2.6
REFERENCES . . . I . . . . . 43 3. ABSORPTION 3.1 VIBRONICSTATES . : T
V. R. . , . . . . 44 3.2 HOT BANDS . . . . . . ; . . 46 3.3 THE
EXTINCTION COEFFICIENT . . . . . . 4 6 * ,3.4 THE BORN-OPPENHEIMER
APPROXIMATION . . *- 4 - ^ 47 3.5 THE EINSTEIN COEFFICIENTS . . .: . .
**,.; 48 3.6 TRANSITION MOMENTS . . .;;;. ;. :.; . 50 3.7 OSCILLATOR
STRENGTHS . W-WRI RU U L.-I :*** * . V . 51 3.8 THE FRANCK-CONDON
PRINCIPLE . J . . I * . 52 3.9 ABSORPTION SPECTRA . . . . * . . 54 IX 1
3 4 8 10 11 28 CONTENTS 3.10 FLASH PHOTOLYSIS AND S!*S P ABSORPTION 3.11
MULTIPHOTONIC ABSORPTION . TABLES 3.1-3.7 . . . 3.12 REFERENCES 58 62 70
82 4. FLUORESCENCE 4.1 THE FLUORESCENCE SPECTRUM 4.2 THE MIRROR SYMMETRY
RELATION 4.3 THE RADIATIVE LIFETIME . 4.4 THE FLUORESCENCE PARAMETERS .
4.5 COMPETING BIMOLECULAR PROCESSES 4.6 DETERMINATION OF FLUORESCENCE
LIFETIMES . :VI;TT.VH **** 4.7 DETERMINATION OF FLUORESCENCE SPECTRA
AND QUANTUM YIELDS 4.8 EXPERIMENTAL TESTS OF THE RADIATIVE LIFETIME
RELATIONS . 4.9 FLUORESCENCE LIFETIMES AND QUANTUM EFFICIENCIES . 4.10
FLUORESCENCE SPECTRA . .... * * * 4.11 SCINTILLATOR SOLUTES . . ,.
.:... . 4.12 INFLUENCE OF ENVIRONMENT ON FLUORESCENCE AND ABSORPTION
SPECTRA . . . . TABLES 4.1-4.9 , 4.13 REFERENCES . . . . 5.
RADIATIONLESS TRANSITIONS 5.1 SINGLET-SINGLET INTERNAL CONVERSION 5.2
INTERSYSTEM CROSSING 5.3 TRIPLET-TRIPLET INTERNAL CONVERSION 5.4
INTERNAL QUENCHING OF FLUORESCENCE 5.5 T, * S 0 INTERSYSTEM CROSSING .
5.6 THE THEORY OF RADIATIONLESS TRANSITIONS 5.7 TI - S 0 INTERSYSTEM
CROSSING: FRANCK-CONDON FACTORS 5.8 THE ISOTOPE RULE 5.9 T, *S 0
INTERSYSTEM CROSSING: COMPARISON OF THEORY EXPERIMENT 5.10 ENERGY GAPS .
. . ; . -F I 5.11 S! * S 0 INTERNAL CONVERSION * V ;. V .; . 5.12 S 2
*S! INTERNAL CONVERSION . . ;. . **;;.-.?, 5.13 DUAL LUMINESCENCES . .
. . ** ( . 5.14 INTERNAL CONVERSION IN BENZENE AND ITS DERIVATIVES
TABLES 5.1-5.10 . . . ;. 5.15 REFERENCES . . . . . . ; ^ WITH CONTENTS
XI 6. THE TRIPLET STATE 6.1 TRIPLET AND PHOSPHORESCENCE PARAMETERS . .
**-.-* . 193 6.2 THE DETERMINATIONOF TRIPLET QUANTUM YIELDS . . . 195
6.3 TRIPLET QUANTUMYIELDS . .., , . . ,..,..* . 200 6.4
SPECTROPHOSPHORIMETRY . . . . . .201 I 6.5 THE DETERMINATION OF
PHOSPHORESCENCE QUANTUM EFFICIENCIES 206 6.6 PHOSPHORESCENCE LIFETIMES,
QUANTUM EFFICIENCIES AND SPECTRA 207 6.7 THEHEAVYATOMEIFECT 208 6.8
SINGLET-TRIPLET ABSORPTION 211 6.9 TRIPLET-TRIPLET ABSORPTION _..,* . .
. . . 218 6.10 TRIPLET ENERGY LEYELS . 222 6.11 ASSIGNMENT OF THE
ELECTRONIC STATES OF THE POLYACENES . 224 6.12 SPIN-ORBIT INTERACTION .
. . . . . . 226 6.13 SINGLET-TRIPLET INTERSYSTEM CROSSING 229 6.14
TRIPLET-TRIPLET INTERNAL CONVERSION AND FLUORESCENCE . 235 6.15
PHOTO-IONIZATION . . , . . - . . . . 237 6.16 VAPOURSOF BENZENE AND ITS
DERIVATIVES . . . . 240 6.17 THE TRIPLET STATE OFBENZENE . . . V . 248
TABLES 6.1-6.23 . . . ; . ,. : . . 251 6.18 REFERENCES . . ^T , . . . .
. 297 7. EXCIMERS 7.1 EXCIMER FLUORESCENCE . . . . * * * 301 7.2
PHOTOSTATIONARY REACTION KINETICS . . , . .... . 302 7.3 TRANSIENT
REACTION KINETICS .. . . . 304 7.4 DETERMINATIONOF RATE PARAMETERS . . .
. . 305 7.5 HIGHTEMPERATUREBEHAVIOUR . ,. . 309 7.6 FREQUENCY FACTORS
AND ACTIVATION ENERGIES . . .311 Y , 7.7 DIFFUSION-CONTROLLED PROCESSES
...,,.-.* 312 7.8 EXCIMER FLUORESCENCE IN SOLUTION 316 7.9 EXCIMER
FLUORESCENCE OFCRYSTALS . . . . . 317 7.10 PHOTODIMER AND EXCIMER
FORMATION. . . . 319 7.11 SANDWICH DIMERS . . . . . . -., . 322 7.12
INTRAMOLECULAR EXCIMER FLUORESCENCE . . . . . 323 7.13 THE EXCIMER
POTENTIAL ENERGY DIAGRAM , . . . . 325 R; 7.14 THEORYOF EXCIMER STATES .
. . . . . 327 .: 7.15 DETERMINATION OF EXCIMER INTERACTION POTENTIAL . .
331 7.16 PHOTOPHYSICAL PROCESSES IN EXCIMERS . .... ; . 335 ;-;. 7.17
EXCIMER FORMATION PROCESSES . . . *. . . 339 7.18 EXCIMER
PHOSPHORESCENCE . .! . . . . 343 TABLES 7.1-7.11 . . . . . . : . 349
7.19 REFERENCES . 370 XII CONTENTS 8. DELAYED LUMINESCENCE 8.1 TYPESOF
DELAYED LUMINESCENCE . . : : . -. 8.2 E-TYPE DELAYED FLUORESCENCE ; ^
; : ; ;_ ^, 8.3 FLUORESCENCE OF MIXED MOLECULAR SPECIES . . 8.4
TRIPLET-TRIPLET INTERACTION IN CONCENTRATED FLUID SOLUTIONS 8.5
TRIPLET-TRIPLET INTERACTION IN DILUTE FLUID SOLUTIONS . 8.6 P-TYPE
DELAYED FLUORESCENCE IN FLUID SOLUTIONS . 8.7 P-TYPE DELAYED
FLUORESCENCE IN RIGID SOLUTIONS . F ;; 8.8 MECHANISM OF TRIPLET-TRIPLET
INTERACTION . . ; 8.9 THE DETERMINATION OF TOTAL TRIPLET QUANTUM YIELDS
* : V ! 8.10 RECOMBINATIONLUMINESCENCE. . . : :** * ; - TABLE8.1 .
* -** I L: ---P -1- 0 ; ^»AE»; 8.11 REFERENCES . . . . ; ! . . *
V^ 9. MOLECULAR COMPLEXES AND EXCIPLEXES 9.1 DONOR-ACCEPTORCOMPLEXES . .
N. . 9.2 CHARGE-TRANSFER ABSORPTION . ; :. 9.3 KINETICSOF DA COMPLEXES
.; . * 9.4 CONTACT CT ABSORPTION. . . . 5.5 LUMINESCENCE OF DA COMPLEXES
9.6 EXCIPLEXES . . . . . 9.7 MIXED EXCIMERS . .. . 9.8 FLUORESCENCE OF
EXCIPLEXES .) 9.9 IMPURITY QUENCHING OF FLUORESCENCE. 9.10 PHOTOCHEMICAL
QUENCHING OF FLUORESCENCE 9.11 KINETICSOF IMPURITY QUENCHING . . 9.12
IMPURITY QUENCHING OF TRIPLET STATES I TABLES 9.1-9.27 V V . I ; 9.13
REFERENCES . . . . . . 372 373 375 378 384 385 389 391 394 397 400
401 403 406 410 412 415 420 421 425 433 439 441 447 452 489 10.
INTERACTIONS WITH OXYGEN AND NITRIC OXIDE 10.1 OXYGEN AND NITRIC OXIDE
10.2 CONTACT CT ABSORPTION . 10.3 ENHANCED S 0 -T! ABSORPTION 10.4
QUENCHING BY OXYGEN . 10.5 PHOTOPEROXIDATION STUDIES 10.6 QUENCHING BY
NITRIC OXIDE 10.7 STATIC QUENCHING . ; 10.8 KINETICS OF FLUORESCENCE
QUENCHING BY OXYGEN 10.9 COLLISIONALANDEXCHANGEQUENCHING .. ^ TABLES
10.1-10.3 . 10.10 REFERENCES 492 493 494 496 502 504 506 508 510 514 517
CONTENTS . XIII 11. ENERGY MIGRATION AND TRANSFER 11.1 MIGRATION AND
TRANSFER PROCESSES . . . . 11.2 RADIATIVE MIGRATION AND TRANSFER . . . .
11.3 EXCITON STATES IN CRYSTALS 11.4 SINGLET EXCITON MIGRATION AND
TRANSFER IN CRYSTALS 11.5 TRIPLET-TRIPLET ENERGY TRANSFER IN SOLUTION
11.6 TRIPLET EXCITON MIGRATION AND TRANSFER IN MIXED CRYSTALS 11.7
TRIPLET-TRIPLET INTERACTIONS IN MIXED CRYSTALS 11.8 TRIPLET EXCITONS IN
PURE CRYSTALS . . . . 11.9 SINGLET-SINGLET ENERGY TRANSFER IN SOLUTION .
11.10 INFLUENCEOFDIFFUSIONON ENERGY TRANSFER . 11.11 EXCITATION
MIGRATION AND TRANSFER IN AROMATIC LIQUID SOLU- TIONS . . 11.12 OTHER
INTERMOLECULAR TRANSFER PROCESSES . 11.13 INTRAMOLECULAR ENERGY TRANSFER
. . . . 11.14 PHOTOCHEMISTRY AND PHOTOBIOLOGY . . . . TABLES 11.1-11.18
. . . 11.15 REFERENCES . . 518 521 523 528 537 544 550 559 567 576 580
590 594 599 601 619 12. POSTSCRIPT 625 TABLES 12.1-12.2 . . . . . . .
.637 REFERENCES . . . . . . . 639 TABLE INDEX OF COMPOUNDS . . .641
TABLE INDEX OF PROCESSES AND PARAMETERS 660 AUTHOR INDEX . 669 SUBJECT
INDEX . .681
|
| any_adam_object | 1 |
| author | Birks, John B. |
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| callnumber-search | QC463.H9 |
| callnumber-sort | QC 3463 H9 |
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| ctrlnum | (OCoLC)94058 (DE-599)BVBBV001928242 |
| dewey-full | 547/.6 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 547 - Organic chemistry |
| dewey-raw | 547/.6 |
| dewey-search | 547/.6 |
| dewey-sort | 3547 16 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Chemie |
| format | Book |
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| id | DE-604.BV001928242 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T15:37:23Z |
| institution | BVB |
| isbn | 0471074209 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-001256666 |
| oclc_num | 94058 |
| open_access_boolean | |
| owner | DE-91 DE-BY-TUM DE-91G DE-BY-TUM DE-703 DE-355 DE-BY-UBR DE-29T DE-83 DE-188 |
| owner_facet | DE-91 DE-BY-TUM DE-91G DE-BY-TUM DE-703 DE-355 DE-BY-UBR DE-29T DE-83 DE-188 |
| physical | XIII, 704 S. graph. Darst. |
| psigel | TUB-nveb |
| publishDate | 1970 |
| publishDateSearch | 1970 |
| publishDateSort | 1970 |
| publisher | Wiley |
| record_format | marc |
| series2 | Wiley monographs in chemical physics |
| spelling | Birks, John B. Verfasser aut Photophysics of aromatic molecules John B. Birks London u.a. Wiley 1970 XIII, 704 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Wiley monographs in chemical physics Composés aromatiques - Spectre Excitons, Théorie des Théorie quantique Quantentheorie Aromatic compounds Spectra Chemistry, Physical Exciton theory Quantum theory Absorption (DE-588)4000245-7 gnd rswk-swf Spektrum (DE-588)4056139-2 gnd rswk-swf Fotochemie (DE-588)4045873-8 gnd rswk-swf Aromaten (DE-588)4143049-9 gnd rswk-swf Fotophysik (DE-588)4193388-6 gnd rswk-swf Energietransfer Mikrophysik (DE-588)4152234-5 gnd rswk-swf Fluoreszenz (DE-588)4154818-8 gnd rswk-swf Aromatische Verbindungen (DE-588)4129374-5 gnd rswk-swf Aromatische Verbindungen (DE-588)4129374-5 s Spektrum (DE-588)4056139-2 s DE-604 Aromaten (DE-588)4143049-9 s Fotochemie (DE-588)4045873-8 s Fotophysik (DE-588)4193388-6 s Fluoreszenz (DE-588)4154818-8 s 1\p DE-604 Energietransfer Mikrophysik (DE-588)4152234-5 s 2\p DE-604 Absorption (DE-588)4000245-7 s 3\p DE-604 GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001256666&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 3\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Birks, John B. Photophysics of aromatic molecules Composés aromatiques - Spectre Excitons, Théorie des Théorie quantique Quantentheorie Aromatic compounds Spectra Chemistry, Physical Exciton theory Quantum theory Absorption (DE-588)4000245-7 gnd Spektrum (DE-588)4056139-2 gnd Fotochemie (DE-588)4045873-8 gnd Aromaten (DE-588)4143049-9 gnd Fotophysik (DE-588)4193388-6 gnd Energietransfer Mikrophysik (DE-588)4152234-5 gnd Fluoreszenz (DE-588)4154818-8 gnd Aromatische Verbindungen (DE-588)4129374-5 gnd |
| subject_GND | (DE-588)4000245-7 (DE-588)4056139-2 (DE-588)4045873-8 (DE-588)4143049-9 (DE-588)4193388-6 (DE-588)4152234-5 (DE-588)4154818-8 (DE-588)4129374-5 |
| title | Photophysics of aromatic molecules |
| title_auth | Photophysics of aromatic molecules |
| title_exact_search | Photophysics of aromatic molecules |
| title_full | Photophysics of aromatic molecules John B. Birks |
| title_fullStr | Photophysics of aromatic molecules John B. Birks |
| title_full_unstemmed | Photophysics of aromatic molecules John B. Birks |
| title_short | Photophysics of aromatic molecules |
| title_sort | photophysics of aromatic molecules |
| topic | Composés aromatiques - Spectre Excitons, Théorie des Théorie quantique Quantentheorie Aromatic compounds Spectra Chemistry, Physical Exciton theory Quantum theory Absorption (DE-588)4000245-7 gnd Spektrum (DE-588)4056139-2 gnd Fotochemie (DE-588)4045873-8 gnd Aromaten (DE-588)4143049-9 gnd Fotophysik (DE-588)4193388-6 gnd Energietransfer Mikrophysik (DE-588)4152234-5 gnd Fluoreszenz (DE-588)4154818-8 gnd Aromatische Verbindungen (DE-588)4129374-5 gnd |
| topic_facet | Composés aromatiques - Spectre Excitons, Théorie des Théorie quantique Quantentheorie Aromatic compounds Spectra Chemistry, Physical Exciton theory Quantum theory Absorption Spektrum Fotochemie Aromaten Fotophysik Energietransfer Mikrophysik Fluoreszenz Aromatische Verbindungen |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001256666&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT birksjohnb photophysicsofaromaticmolecules |