Conformation of biological molecules: New results from NMR
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Berlin
Springer
1982
|
| Schriftenreihe: | NMR.
20. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | VIII, 216 S. Ill., graph. Darst. |
| ISBN: | 354010769X 038710769X |
Internformat
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| 245 | 1 | 0 | |a Conformation of biological molecules |b New results from NMR |
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| 650 | 2 | |a Structures macromoléculaires | |
| 650 | 4 | |a Biomolecules | |
| 650 | 4 | |a Conformational analysis | |
| 650 | 4 | |a Macromolecular Substances | |
| 650 | 4 | |a Magnetic Resonance Spectroscopy |x methods | |
| 650 | 4 | |a Molecular Biology | |
| 650 | 4 | |a Molecular Conformation | |
| 650 | 4 | |a Nuclear magnetic resonance spectroscopy | |
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Datensatz im Suchindex
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| adam_text | G. GOVIL R.V. HOSUR CONFORMATION OF BIOLOGICAL MOLECULES NEW RESULTS
FROM NMR WITH 92 FIGURES SPRINGER-VERLAG BERLIN HEIDELBERG NEWYORK1982
CONTENTS 1 GENERAL THEORY 1 1.1 INTRODUCTION 1 1.2 WHAT IS CONFORMATION?
2 1.3 CONFORMATIONAL THEORY 4 1.4 STRUCTURE OF LONG-CHAIN POLYMERS 8 1.5
PROBLEMS IN NMR STUDIES OF BIOLOGICAL MOLECULES 9 1.5.1 ! H-NMR 9 1.5.2
2 H-NMR 11 1.5.3 C-NMR 12 1.5.4 15 N-NMR 14 1.5.5 31 P-NMR 15 1.5.6
OTHER NUCLEI 16 2 NMR TECHNIQUES IN CONFORMATIONAL STUDIES 18 2.1
COUPLING CONSTANTS 18 2.2 CHEMICAL SHIFTS OF HYDROGEN-BONDED PROTONS 22
2.3 MAGNETIC ANISOTROPY OF CHEMICAL BONDS OR GROUPS 23 2.4 13 C CHEMICAL
SHIFTS 25 2.5 31 P CHEMICAL SHIFTS 26 2.6 RELAXATION TIMES (TJ AND T 2 )
26 2.7 NUCLEAR OVERHAUSER EFFECT 29 2.8 PARAMAGNETIC REAGENTS 30 2.9 USE
OF LIQUID CRYSTALS AS SOLVENTS 35 2.10 DEUTERIUM QUADRUPOLE COUPLING
CONSTANTS 36 2.11 SOLVENT ACCESSIBILITY 36 2.12 FROM NMR PARAMETERS TO
SPATIAL STRUCTURES 37 3 NUCLEOSIDES, NUCLEOTIDES AND NUCLEIC ACIDS 39
3.1 DESCRIPTION OF NUCLEOTIDE STRUCTURES 39 3.2 GLYCOSIDIC BOND
ROTATIONS 43 3.3 SUGAR RING CONFORMATION: PSEUDOROTATION 46 3.4 BACKBONE
ANGLES 51 3.4.1 TORSION ANGLES 51 3.4.2 ANGLES 53 3.4.3 ANGLES ^ 55
3.4.4 TORSION ANGLES CO , CO 55 3.5 NMR STUDIES ON NUCLEOSIDES 58 VI
CONTENTS 3.6 SMALL NUCLEOTIDES 58 3.6.1 2 -, 3 - AND 5 -MONONUCLEOTIDES
61 3.6.2 CYCLIC NUCLEOTIDES 61 3.6.3 PYRIDINE NUCLEOSIDES AND
NUCLEOTIDES 62 3.6.4 5 -DI- AND TRIPHOSPHATES 62 3.7 DINUCLEOSIDE
PHOSPHATES AND SHORT SEGMENTS OF NUCLEIC ACIDS 63 3.8 RANDOM-COIL
POLYNUCLEOTIDES 66 3.8.1 OLIGO- AND POLYRIBONUCLEOTIDES 67 3.8.2
DEOXYRIBONUCLEOTIDES 70 3.9 HELICAL POLYNUCLEOTIDES 70 3.10 T-RNA 74
3.11 DRUG-NUCLEIC ACID INTERACTIONS 79 4 AMINO ACIDS, PEPTIDES AND
PROTEINS 81 4.1 DESCRIPTION OF THE STRUCTURE OF PEPTIDE UNITS 81 4.2
THEORETICAL CONSIDERATIONS. THE , TY MAPS 87 4.3 NMR TECHNIQUES IN THE
STUDY OF PEPTIDE CONFORMATIONS 92 4.3.1 CIS-TRANS ISOMERIZATION(ANGLE
CO) 92 4.3.2 AN D I// ANGLES 94 4.3.3 SIDE-CHAIN CONFORMATIONS 96 4.3.4
DETECTIONOFN-H-0=CHYDROGEN BONDS 97 4.3.5 MOLECULAR SYMMETRY 99 4.3.6
CONFORMATIONAL MOBUEITY 99 4.3.7 *H AND 13 C CHEMICAL SHIFTS 100 4.4
CONFORMATIONS OF AMINO ACIDS 101 4.5 LINEAR PEPTIDES 102 4.5.1
DIPEPTIDES 105 4.5.2 TRIPEPTIDES 106 4.5.3 TETRAPEPTIDES 107 4.5.4
PENTAPEPTIDES 108 4.5.5 HEXAPEPTIDES 108 4.5.6 LARGER PEPTIDES. PEPTIDE
HORMONES 108 4.5.6.1 ANGIOTENSIN 108 4.5.6.2 LEUTEINIZING
HORMONE-RELEASING HORMONE (LRF) 109 4.5.6.3 PEPTIDES CONTAINING
A-AMINOBUTYRIC ACID (AA,) 109 4.5.6.4 HUMAN PARATHYROID HORMONE (PTH)
110 4.5.6.5 INSULIN 110 4.6 CYCLIC PEPTIDES 110 4.6.1 DIPEPTIDES 110
4.6.2 TRIPEPTIDES 115 4.6.3 TETRAPEPTIDES 116 4.6.4 PENTAPEPTIDES 116
4.6.5 HEXAPEPTIDES 117 4.6.6 LARGER CYCLIC PEPTIDES, PEPTIDE HORMONES
AND ANTIBIOTICS 119 4.6.6.1 OXYTOCIN AND VASOPRESSIN 119 CONTENTS VII
4.6.6.2 GRAMICIDIN S 121 4.6.6.3 VALINOMYCIN 122 4.7 HOMOPOLYMERIC
PEPTIDES. HELIX-COIL TRANSITION 124 4.8 CHARACTERIZATION OF PROTEIN
STRUCTURES BY NMR 128 4.8.1 SPATIAL ARRANGEMENT OF ATOMS IN THE
MOLECULES 129 4.8.2 PROTEIN MOBILITY 130 4.8.3 ENZYME * SUBSTRATE
BINDING 130 4.8.4 THERMODYNAMIC PARAMETERS 130 4.8.5 CONFORMATION OF
SPECIFIC PROTEINS 133 4.8.5.1 LYSOZYME 133 4.8.5.2 BASIC PANCREATIC
TRYPSIN INHIBITOR (BPTI) 134 4.8.5.3 DIHYDROFOLATE REDUCTASE 136 4.8.5.4
ANTIBODY COMBINING SITE 137 4.8.5.5 MYELIN BASIC PROTEIN (MBP) 137
4.8.5.6 CALCIUM-BINDING PROTEINS 137 4.8.5.7 ELASTIN AND TROPOELASTIN
137 4.8.5.8 RIBONUCLEASE 138 4.8.5.9 HEMOPROTEINS AND HEMOENZYMES 138
4.8.5.10 COLLAGEN 140 4.8.5.11 A-CHYMOTRYPSIN 140 4.9 PROTEIN-NUCLEIC
ACID INTERACTION 141 4.9.1 SPECIFICITY 141 4.9.2 NATURE OF
INTERMOLECULAR FORCES 142 4.9.3 APPLICATIONS 143 5 POLYSACCHARIDES 144
5.1 STRUCTURES OF POLYSACCHARIDES AND CARBOHYDRATES 144 5.2
CONFORMATIONS OF MONOSACCHARIDES 144 5.3 CONFORMATIONS OF
POLYSACCHARIDES 148 5.4 GLYCOPROTEINS AND PEPTIDE-CARBOHYDRATE
INTERACTIONS 152 6 LIPIDS AND MOLECULAR ORGANIZATION IN MEMBRANES 155
6.1 BIOMEMBRANES 155 6.2 GENERAL PROPERTIES OF PHOSPHOLIPIDS 157 6.3
CONFORMATIONS OF PHOSPHOLIPIDS 157 6.3.1 CONFORMATIONS OF THE GLYCEROL
MOIETY 158 6.3.2 CONFORMATIONS IN THE A-CHAINS 160 6.3.3 CONFORMATIONS
IN THE SS AND Y CHAINS 161 6.4 MEMBRANE ORGANIZATION AND FLUIDITY 163
6.4.1 FLUIDITY 163 6.4.1.1 ROTATIONAL MOTIONS 164 6.4.1.2 LATERAL
DIFFUSION ON THE SURFACE OF THE MEMBRANE 165 6.4.1.3 FLIP-FLOP MOTIONS
165 VIII CONTENTS 6.4.2 DETERMINATION OF ORGANIZATION 165 6.4.2.1 31
P-NMR 166 6.4.2.2 2 H-NMR 167 6.4.2.3 OTHER STUDIES 170 6.5
LIPID-PROTEIN AND LIPID-CHOLESTEROL INTERACTIONS 172 7 ACKNOWLEDGEMENTS
174 8 REFERENCES 175 9 APPENDIX 200 10 SUBJECT INDEX 213
|
| any_adam_object | 1 |
| author | Govil, Girjesh Hosur, Ramakrishna V. |
| author_facet | Govil, Girjesh Hosur, Ramakrishna V. |
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| dewey-tens | 570 - Biology 530 - Physics |
| discipline | Chemie / Pharmazie Physik Biologie Chemie |
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| illustrated | Illustrated |
| indexdate | 2024-07-09T15:23:06Z |
| institution | BVB |
| isbn | 354010769X 038710769X |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-000635138 |
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| physical | VIII, 216 S. Ill., graph. Darst. |
| publishDate | 1982 |
| publishDateSearch | 1982 |
| publishDateSort | 1982 |
| publisher | Springer |
| record_format | marc |
| series | NMR. |
| series2 | NMR. |
| spelling | Govil, Girjesh Verfasser aut Conformation of biological molecules New results from NMR Berlin Springer 1982 VIII, 216 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier NMR. 20. Biologie moléculaire Conformation moléculaire Spectroscopie résonance magnétique nucléaire Structures macromoléculaires Biomolecules Conformational analysis Macromolecular Substances Magnetic Resonance Spectroscopy methods Molecular Biology Molecular Conformation Nuclear magnetic resonance spectroscopy Konformation (DE-588)4164965-5 gnd rswk-swf Biomolekül (DE-588)4135124-1 gnd rswk-swf NMR-Spektroskopie (DE-588)4075421-2 gnd rswk-swf Biomolekül (DE-588)4135124-1 s NMR-Spektroskopie (DE-588)4075421-2 s DE-604 Konformation (DE-588)4164965-5 s Hosur, Ramakrishna V. Verfasser aut NMR. 20. (DE-604)BV002321940 20. GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=000635138&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Govil, Girjesh Hosur, Ramakrishna V. Conformation of biological molecules New results from NMR NMR. Biologie moléculaire Conformation moléculaire Spectroscopie résonance magnétique nucléaire Structures macromoléculaires Biomolecules Conformational analysis Macromolecular Substances Magnetic Resonance Spectroscopy methods Molecular Biology Molecular Conformation Nuclear magnetic resonance spectroscopy Konformation (DE-588)4164965-5 gnd Biomolekül (DE-588)4135124-1 gnd NMR-Spektroskopie (DE-588)4075421-2 gnd |
| subject_GND | (DE-588)4164965-5 (DE-588)4135124-1 (DE-588)4075421-2 |
| title | Conformation of biological molecules New results from NMR |
| title_auth | Conformation of biological molecules New results from NMR |
| title_exact_search | Conformation of biological molecules New results from NMR |
| title_full | Conformation of biological molecules New results from NMR |
| title_fullStr | Conformation of biological molecules New results from NMR |
| title_full_unstemmed | Conformation of biological molecules New results from NMR |
| title_short | Conformation of biological molecules |
| title_sort | conformation of biological molecules new results from nmr |
| title_sub | New results from NMR |
| topic | Biologie moléculaire Conformation moléculaire Spectroscopie résonance magnétique nucléaire Structures macromoléculaires Biomolecules Conformational analysis Macromolecular Substances Magnetic Resonance Spectroscopy methods Molecular Biology Molecular Conformation Nuclear magnetic resonance spectroscopy Konformation (DE-588)4164965-5 gnd Biomolekül (DE-588)4135124-1 gnd NMR-Spektroskopie (DE-588)4075421-2 gnd |
| topic_facet | Biologie moléculaire Conformation moléculaire Spectroscopie résonance magnétique nucléaire Structures macromoléculaires Biomolecules Conformational analysis Macromolecular Substances Magnetic Resonance Spectroscopy methods Molecular Biology Molecular Conformation Nuclear magnetic resonance spectroscopy Konformation Biomolekül NMR-Spektroskopie |
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