Thermodynamics and an introduction to thermostatistics:
Gespeichert in:
| Vorheriger Titel: | Callen, Herbert B. Thermodynamics |
|---|---|
| 1. Verfasser: | |
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
New York ; Chichester ; Brisbane ; Toronto ; Singapore
John Wiley & sons
[1985]
|
| Ausgabe: | Second edition |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Hier auch später erschienene, unveränderte Nachdrucke |
| Beschreibung: | xvi, 493 Seiten Illustrationen, Diagramme |
| ISBN: | 0471862568 9780471862567 |
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| 245 | 1 | 0 | |a Thermodynamics and an introduction to thermostatistics |c Herbert B. Callen, University of Pennsylvania |
| 250 | |a Second edition | ||
| 264 | 1 | |a New York ; Chichester ; Brisbane ; Toronto ; Singapore |b John Wiley & sons |c [1985] | |
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Datensatz im Suchindex
| _version_ | 1805073296370171904 |
|---|---|
| adam_text |
THERMODYNAMICS AND AN INTRODUCTION TO THERMOSTATISTICS SECOND EDITION
HERBERT B. CALLEN UNIVERSITY OF PENNSYLVANIA JOHN WILEY & SONS NEW YORK
CHICHESTER BRISBANE TORONTO SINGAPORE CONTENTS PARTI GENERAL PRINCIPLES
OF CLASSICAL THERMODYNAMICS L INTRODUCTION THE NATURE OF THERMODYNAMICS
AND THE BASIS OF THERMOSTATISTICS 2 1 THE PROBLEM AND THE POSTULATES 5
1.1 THE TEMPORAL NATURE OF MACROSCOPIC MEASUREMENTS 5 1.2 THE SPATIAL
NATURE OF MACROSCOPIC MEASUREMENTS 6 1.3 THE COMPOSITION OF
THERMODYNAMIC SYSTEMS 9 1.4 THE INTERNAL ENERGY 11 1.5 THERMODYNAMIC
EQUILIBRIUM 13 1.6 WALLS AND CONSTRAINTS 15 1.7 MEASURABILITY OF THE
ENERGY 16 1.8 QUANTITATIVE DEFINITION OF HEAT*UNITS 18 1.9 THE BASIC
PROBLEM OF THERMODYNAMICS 25 1.10 THE ENTROPY MAXIMUM POSTULATES 27 2
THE CONDITIONS OF EQUILIBRIUM 35 2.1 INTENSIVE PARAMETERS 35 2.2
EQUATIONS OF STATE 37 2.3 ENTROPIC INTENSIVE PARAMETERS 40 2.4 THERMAL
EQUILIBRIUM*TEMPERATURE 43 2.5 AGREEMENT WITH INTUITIVE CONCEPT OF
TEMPERATURE 45 2.6 TEMPERATURE UNITS 46 2.7 MECHANICAL EQUILIBRIUM 49
2.8 EQUILIBRIUM WITH RESPECT TO MATTER FLOW 54 2.9 CHEMICAL EQUILIBRIUM
56 XI XII CONTENTS 3 SOME FORMAL RELATIONSHIPS, AND SAMPLE SYSTEMS 59
3.1 THE EULER EQUATION 59 3.2 THE GIBBS-DUHEM RELATION 60 3.3 SUMMARY OF
FORMAL STRUCTURE 63 3.4 THE SIMPLE IDEAL GAS AND MULTICOMPONENT SIMPLE
IDEAL GASES 66 3.5 THE "IDEAL VAN DER WAALS FLUID" 74 3.6
ELECTROMAGNETIC RADIATION 78 3.7 THE "RUBBER BAND" 80 3.8
UNCONSTRAINABLE VARIABLES; MAGNETIC SYSTEMS 81 3.9 MOLAR HEAT CAPACITY
AND OTHER DERIVATIVES 84 4 REVERSIBLE PROCESSES AND THE MAXIMUM WORK
THEOREM 91 4.1 POSSIBLE AND IMPOSSIBLE PROCESSES 91 4.2 QUASI-STATIC AND
REVERSIBLE PROCESSES 95 4.3 RELAXATION TIMES AND IRREVERSIBILITY 99 4.4
HEAT FLOW: COUPLED SYSTEMS AND REVERSAL OF PROCESSES 101 4.5 THE MAXIMUM
WORK THEOREM 103 4.6 COEFFICIENTS OF ENGINE, REFRIGERATOR, AND HEAT PUMP
PERFORMANCE 113 4.7 THE CARNOT CYCLE 118 4.8 MEASURABILITY OF THE
TEMPERATURE AND OF THE ENTROPY 123 4.9 OTHER CRITERIA OF ENGINE
PERFORMANCE; POWER OUTPUT AND "ENDOREVERSIBLE ENGINES" 125 4.10 OTHER
CYCLIC PROCESSES 128 5 ALTERNATIVE FORMULATIONS AND LEGENDRE
TRANSFORMATIONS 131 5.1 THE ENERGY MINIMUM PRINCIPLE 131 5.2 LEGENDRE
TRANSFORMATIONS 137 5.3 THERMODYNAMIC POTENTIALS 146 5.4 GENERALIZED
MASSIEU FUNCTIONS 151 6 THE EXTREMUM PRINCIPLE IN THE LEGENDRE
TRANSFORMED REPRESENTATIONS 153 6.1 THE MINIMUM PRINCIPLES FOR THE
POTENTIALS 153 6.2 THE HELMHOLTZ POTENTIAL 157 6.3 THE ENTHALPY; THE
JOULE-THOMSON OR "THROTTLING" PROCESS 160 6.4 THE GIBBS POTENTIAL;
CHEMICAL REACTIONS 167 6.5 OTHER POTENTIALS 172 6.6 COMPILATIONS OF
EMPIRICAL DATA; THE ENTHALPY OF FORMATION 173 6.7 THE MAXIMUM PRINCIPLES
FOR THE MASSIEU FUNCTIONS 179 CONTENTS XIH 7 MAXWELL RELATIONS 7.1 THE
MAXWELL RELATIONS 7.2 A THERMODYNAMIC MNEMONIC DIAGRAM 7.3 A PROCEDURE
FOR THE REDUCTION OF DERIVATIVES IN SINGLE-COMPONENT SYSTEMS 7.4 SOME
SIMPLE APPLICATIONS 7.5 GENERALIZATIONS: MAGNETIC SYSTEMS 8 STABILITY OF
THERMODYNAMIC SYSTEMS 8.1 INTRINSIC STABILITY OF THERMODYNAMIC SYSTEMS
8.2 STABILITY CONDITIONS FOR THERMODYNAMICS POTENTIALS 8.3 PHYSICAL
CONSEQUENCES OF STABILITY 8.4 LE CHATELIER'S PRINCIPLE; THE QUALITATIVE
EFFECT OF FLUCTUATIONS 8.5 THE LE CHATELIER-BRAUN PRINCIPLE 9
FIRST-ORDER PHASE TRANSITIONS 9.1 FIRST-ORDER PHASE TRANSITIONS IN
SINGLE-COMPONENT SYSTEMS 9.2 THE DISCONTINUITY IN THE ENTROPY-LATENT
HEAT 9.3 THE SLOPE OF COEXISTENCE CURVES; THE CLAPEYRON EQUATION 9.4
UNSTABLE ISOTHERMS AND FIRST-ORDER PHASE TRANSITIONS 9.5 GENERAL
ATTRIBUTES OF FIRST-ORDER PHASE TRANSITIONS 9.6 FIRST-ORDER PHASE
TRANSITIONS IN MULTICOMPONENT SYSTEMS*GIBBS PHASE RULE 9.7 PHASE
DIAGRAMS FOR BINARY SYSTEMS 10 CRITICAL PHENOMENA 10.1 THERMODYNAMICS IN
THE NEIGHBORHOOD OF THE CRITICAL POINT 10.2 DIVERGENCE AND STABILITY
10.3 ORDER PARAMETERS AND CRITICAL EXPONENTS 10.4 CLASSICAL THEORY IN
THE CRITICAL REGION; LANDAU THEORY 10.5 ROOTS OF THE CRITICAL POINT
PROBLEM 10.6 SCALING AND UNIVERSALITY 11 THE NERNST POSTULATE 11.1
NERNST'S POSTULATE, AND THE PRINCIPLE OF THOMSEN AND BERTHOLOT 11.2 HEAT
CAPACITIES AND OTHER DERIVATIVES AT LOW TEMPERATURES 11.3 THE
"UNATTAINABILITY" OF ZERO TEMPERATURE 12 SUMMARY OF PRINCIPLES FOR
GENERAL SYSTEMS 12.1 GENERAL SYSTEMS 12.2 THE POSTULATES 181 181 183 186
190 199 203 203 207 209 210 212 215 215 222 228 233 243 245 248 255 255
261 263 265 270 272 277 277 280 281 283 283 283 XIV CONTENTS 12.3 THE
INTENSIVE PARAMETERS 284 12.4 LEGENDRE TRANSFORMS 285 12.5 MAXWELL
RELATIONS 285 12.6 STABILITY AND PHASE TRANSITIONS 286 12.7 CRITICAL
PHENOMENA 287 12.8 PROPERTIES AT ZERO TEMPERATURE 287 13 PROPERTIES OF
MATERIALS 289 13.1 THE GENERAL IDEAL GAS 289 13.2 CHEMICAL REACTIONS IN
IDEAL GASES 292 13.3 SMALL DEVIATIONS FROM "IDEALITY"*THE VIRIAL
EXPANSION 297 13.4 THE "LAW OF CORRESPONDING STATES" FOR GASES 299 13.5
DILUTE SOLUTIONS: OSMOTIC PRESSURE AND VAPOR PRESSURE 302 13.6 SOLID
SYSTEMS 305 14 IRREVERSIBLE THERMODYNAMICS 307 14.1 GENERAL REMARKS 307
14.2 AFFINITIES AND FLUXES 308 14.3 PURELY-RESISTIVE AND LINEAR SYSTEMS
312 14.4 THE THEORETICAL BASIS OF THE ONSAGER RECIPROCITY 314 14.5
THERMOELECTRIC EFFECTS 316 14.6 THE CONDUCTIVITIES 319 14.7 THE SEEBECK
EFFECT AND THE THERMOELECTRIC POWER 320 14.8 THE PELTIER EFFECT 323 14.9
THE THOMSEN EFFECT 324 PART II STATISTICAL MECHANICS 15 STATISTICAL
MECHANICS IN THE ENTROPY REPRESENTATION: THE MICROCANONICAL FORMALISM
329 15.1 PHYSICAL SIGNIFICANCE OF THE ENTROPY FOR CLOSED SYSTEMS 329
15.2 THE EINSTEIN MODEL OF A CRYSTALLINE SOLID 333 15.3 THE TWO-STATE
SYSTEM 337 15.4 A POLYMER MODEL*THE RUBBER BAND REVISITED 339 15.5
COUNTING TECHNIQUES AND THEIR CIRCUMVENTION; HIGH DIMENSIONALITY 343 16
THE CANONICAL FORMALISM; STATISTICAL MECHANICS IN HELMHOLTZ
REPRESENTATION 349 16.1 THE PROBABILITY DISTRIBUTION 349 16.2 ADDITIVE
ENERGIES AND FACTORIZABILITY OF THE PARTITION SUM 353 CONTENTS XV 16.3
INTERNAL MODES IN A GAS 16.4 PROBABILITIES IN FACTORIZABLE SYSTEMS 16.5
STATISTICAL MECHANICS OF SMALL SYSTEMS: ENSEMBLES 16.6 DENSITY OF STATES
AND DENSITY-OF-ORBITAL STATES 16.7 THE DEBYE MODEL OF NON-METALLIC
CRYSTALS 16.8 ELECTROMAGNETIC RADIATION 16.9 THE CLASSICAL DENSITY OF
STATES 16.10 THE CLASSICAL IDEAL GAS 16.11 HIGH TEMPERATURE
PROPERTIES*THE EQUIPARTITION THEOREM 17 ENTROPY AND DISORDER;
GENERALIZED CANONICAL FORMULATIONS 17.1 ENTROPY AS A MEASURE OF DISORDER
17.2 DISTRIBUTIONS OF MAXIMAL DISORDER 17.3 THE GRAND CANONICAL
FORMALISM 18 QUANTUM FLUIDS 18.1 QUANTUM PARTICLES; A "FERMION PRE-GAS
MODEL" 18.2 THE IDEAL FERMI FLUID 18.3 THE CLASSICAL LIMIT AND THE
QUANTUM CRITERIA 18.4 THE STRONG QUANTUM REGIME; ELECTRONS IN A METAL
18.5 THE IDEAL BOSE FLUID 18.6 NON-CONSERVED IDEAL BOSE FLUIDS;
ELECTROMAGNETIC RADIATION REVISITED 18.7 BOSE CONDENSATION 19
FLUCTUATIONS 19.1 THE PROBABILITY DISTRIBUTION OF FLUCTUATIONS 19.2
MOMENTS AND THE ENERGY FLUCTUATIONS 19.3 GENERAL MOMENTS AND CORRELATION
MOMENTS 20 VARIATIONAL PROPERTIES, PERTURBATION EXPANSIONS, AND MEAN
FIELD THEORY 20.1 THE BOGOLIUBOV VARIATIONAL THEOREM 20.2 MEAN FIELD
THEORY 20.3 MEAN FIELD THEORY IN GENERALIZED REPRESENTATION; THE BINARY
ALLOY 355 358 360 362 364 368 370 372 375 379 379 382 385 393 393 399
402 405 410 412 413 423 423 424 426 433 433 440 449 PART III FOUNDATIONS
21 POSTLUDE: SYMMETRY AND THE CONCEPTUAL FOUNDATIONS OF THERMOSTATISTICS
21.1 STATISTICS 455 455 XVI CONTENTS 21.2 SYMMETRY 458 21.3 NOETHER'S
THEOREM 460 21.4 ENERGY, MOMENTUM AND ANGULAR MOMENTUM; THE GENERALIZED
"FIRST LAW" OF THERMODYNAMICS 461 21.5 BROKEN SYMMETRY AND GOLDSTONE'S
THEOREM 462 21.6 OTHER BROKEN SYMMETRY COORDINATES*ELECTRIC AND MAGNETIC
MOMENTS 465 21.7 MOLE NUMBERS AND GAUGE SYMMETRY 466 21.8 TIME REVERSAL,
THE EQUAL PROBABILITY OF MICROSTATES, AND THE ENTROPY PRINCIPLE 467 21.9
SYMMETRY AND COMPLETENESS 469 APPENDIX A SOME RELATIONS INVOLVING
PARTIAL DERIVATIVES A.I PARTIAL DERIVATIVES A.2 TAYLOR'S EXPANSION A. 3
DIFFERENTIALS A.4 COMPOSITE FUNCTIONS A.5 IMPLICIT FUNCTIONS APPENDIX B
MAGNETIC SYSTEMS GENERAL REFERENCES INDEX 473 473 474 475 475 476 479
485 487 |
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| id | DE-604.BV000980012 |
| illustrated | Illustrated |
| indexdate | 2024-07-20T05:07:21Z |
| institution | BVB |
| isbn | 0471862568 9780471862567 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-000594857 |
| oclc_num | 299636254 |
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| physical | xvi, 493 Seiten Illustrationen, Diagramme |
| publishDate | 1985 |
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| publisher | John Wiley & sons |
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| spelling | Callen, Herbert B. Verfasser (DE-588)1013343026 aut Thermodynamics and an introduction to thermostatistics Herbert B. Callen, University of Pennsylvania Second edition New York ; Chichester ; Brisbane ; Toronto ; Singapore John Wiley & sons [1985] xvi, 493 Seiten Illustrationen, Diagramme txt rdacontent n rdamedia nc rdacarrier Hier auch später erschienene, unveränderte Nachdrucke Mecánica estadística Mécanique statistique Termodinánica Thermodynamique Statistik Statistical mechanics Statistics Thermodynamics Statistische Mechanik (DE-588)4056999-8 gnd rswk-swf Thermodynamik (DE-588)4059827-5 gnd rswk-swf Statistische Thermodynamik (DE-588)4126251-7 gnd rswk-swf Statistische Mechanik (DE-588)4056999-8 s DE-604 Thermodynamik (DE-588)4059827-5 s Statistische Thermodynamik (DE-588)4126251-7 s Früher u.d.T. Callen, Herbert B. Thermodynamics HEBIS Datenaustausch Darmstadt application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=000594857&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Callen, Herbert B. Thermodynamics and an introduction to thermostatistics Mecánica estadística Mécanique statistique Termodinánica Thermodynamique Statistik Statistical mechanics Statistics Thermodynamics Statistische Mechanik (DE-588)4056999-8 gnd Thermodynamik (DE-588)4059827-5 gnd Statistische Thermodynamik (DE-588)4126251-7 gnd |
| subject_GND | (DE-588)4056999-8 (DE-588)4059827-5 (DE-588)4126251-7 |
| title | Thermodynamics and an introduction to thermostatistics |
| title_auth | Thermodynamics and an introduction to thermostatistics |
| title_exact_search | Thermodynamics and an introduction to thermostatistics |
| title_full | Thermodynamics and an introduction to thermostatistics Herbert B. Callen, University of Pennsylvania |
| title_fullStr | Thermodynamics and an introduction to thermostatistics Herbert B. Callen, University of Pennsylvania |
| title_full_unstemmed | Thermodynamics and an introduction to thermostatistics Herbert B. Callen, University of Pennsylvania |
| title_old | Callen, Herbert B. Thermodynamics |
| title_short | Thermodynamics and an introduction to thermostatistics |
| title_sort | thermodynamics and an introduction to thermostatistics |
| topic | Mecánica estadística Mécanique statistique Termodinánica Thermodynamique Statistik Statistical mechanics Statistics Thermodynamics Statistische Mechanik (DE-588)4056999-8 gnd Thermodynamik (DE-588)4059827-5 gnd Statistische Thermodynamik (DE-588)4126251-7 gnd |
| topic_facet | Mecánica estadística Mécanique statistique Termodinánica Thermodynamique Statistik Statistical mechanics Statistics Thermodynamics Statistische Mechanik Thermodynamik Statistische Thermodynamik |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=000594857&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT callenherbertb thermodynamicsandanintroductiontothermostatistics |