Ceramic science for materials technologists:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Glasgow [u.a.]
Hill
1983
|
| Ausgabe: | 1. publ. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Literaturangaben |
| Beschreibung: | X, 357 S. Ill., graph. Darst. |
| ISBN: | 0412003511 0249441632 |
Internformat
MARC
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| 100 | 1 | |a MacColm, Ian J. |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Ceramic science for materials technologists |c I. J. McColm |
| 250 | |a 1. publ. | ||
| 264 | 1 | |a Glasgow [u.a.] |b Hill |c 1983 | |
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Datensatz im Suchindex
| _version_ | 1804115405173686273 |
|---|---|
| adam_text | Ceramic Science
for Materials Technologists
I J McColm, B Sc, D Phil
Senior Lecturer in Industrial Technology
University of Bradford
Leonard Hill
Distributed in the USA by
Chapman and Hall
New York
Contents
1 Traditional ceramics 1
1 1 Introduction 1
1 2 Study area defined 2
1 3 Role of heat—heat work 3
1 4 Translucency 4
1 5 Silicates - 6
151 Silicates and aluminosilicates containing isolated anion groups 9
152 Chain silicates 19
153 Sheet silicates 25
154 Framework silicates 33
155 Sodium silicates 42
156 Cements 44
157 Thermal transformations of ceramic raw materials—topotaxy 51
158 Phosphate-bonded refractories 58
References and further reading 61
2 Special light ceramics for modern applications 63
2 1 Analysis of a strength equation 63
211 Surface energy 63
212 Origin of Young s modulus 66
2 2 The covalent bond model 68
221 Nature of the problem 68
222 Matter waves 70
223 The wave nature of the atom 71
224 Atomic orbitals and their specification 72
225 Atom groundstates, aufbau principle and the periodic table 76
226 Valence bond description of covalent bonding 77
227 Molecular orbital theory of covalent bonding 82
2 3 Identification of potential high-strength materials 88
2 4 Boron 88
241 Structure and bonding 89
2 5 Carbon and graphite 91
251 Structure and bonding 93
252 Carbon fibres for engineering use 95
253 Graphite reactivity 96
2 6 Silicon 97
261 Preparation and structure 97
262 Hole conductivity 98
263 p-n junctions 99
vii
Vlll CONTENTS
2 7 Boron carbide 100
271 Structure 100
2 8 Boron nitride 101
281 Preparation and properties of pyrolytic boron nitride 101
2 9 Boric oxide 103
2 10 Silicon carbide 104
2 10 1 Structure 105
2 10 2 Oxidation 106
2 11 Silicon nitride 107
2 11 1 Structure 107
2 11 2 Properties and fabrication 108
2 11 3 a-Silicon nitride and silicon oxynitride 110
2 11 4 Fabrication with silicon nitride 111
2 11 5 Densification aids in Si3N4 sintering 112
2 12 Sialons 114
2 12 1 Representation of the Si-Al-O-N system 115
2 12 2 Si-AI-O-N phase relationships 117
2 12 3 Sialon preparation 120
2 12 4 Metal-sialons 120
2 12 5 Nitrogen glasses 122
2 13 Realization of high strength and the development of toughness through fibre-
composites 123
2 13 1 Composite elastic properties 125
2 13 2 Composite strength 126
2 13 3 Specific strength and specific stiffness 129
2 13 4 Composite toughness 130
References and further reading 131
3 Glass 132
3 1 Introduction 132
311 Definition 134
312 Viscosity 138
3 2 Structural models for glass 142
321 Zachariasen random network 143
322 Porai-Koshits crystallite model 147
323 Discrete-ion concept 148
324 Five-fold symmetry model 150
325 Goodman s strained mixed cluster model 151
3 3 Predictions of glass formation 152
331 Bond strength and type 153
332 Coordination environment 153
333 Strained mixed cluster model 153
334 Kinetics and concept of free volume 153
335 Cooling rate 156
3 4 Mechanical properties 158
341 Group 1: flawless glass 159
342 Group 2: flaws exist—how do they propagate? 160
343 Characterization of Griffith flaws 162
344 Fracture mechanics 165
345 Plastic flow in glass 167
346 Group 3: flaw generation hypotheses 169
347 Crack propagation and static fatigue 172
348 Methods of glass strengthening 178
349 Load-duration analysis for glass design 181
3 5 Glass/metal and glass/ceramic bonding 184
351 Technical procedures 184
352 Theories of adherence 187
353 The glass/metal interface 192
CONTENTS IX
3 6 Durability 194
361 General observations 195
362 Mechanisms and rate laws 197
363 Methods of corrosion protection 201
References and further reading 202
4 Glass-ceramics 204
4 1 Introduction 204
4 2 Technical processes 206
4 3 Nucleation 207
431 Homogeneous nucleation 207
432 Heterogeneous nucleation 210
433 Nucleant characteristics 212
4 4 Liquid phase separation in glass-forming systems 213
441 Occurrence of the spinodal region 215
4 5 Crystal growth 220
451 Screw dislocation mechanism for crystal growth 222
452 Spherulitic and dendritic crystal growth 223
4 6 Glass ceramics arising from control of process variables 224
461 Lithia-silica (Li2O-SiO2) system 224
462 Li2O-AI2O3-SiO2 system 225
463 MgO-Al2O3-SiO2 system 226
464 Na2O-Al2O3-SiO2 system 227
465 Tetrasilicic-mica machinable ceramics 227
4 7 Role of a residual glass phase 229
471 Strength 230
472 Control of fracture toughness and thermal shock resistance 230
473 Creep resistance 231
474 Optical transparency 232
4 8 Summary 233
References and further reading 233
5 Refractory oxide ceramics 235
5 1 Introduction 235
5 2 Prediction of environmental stability 238
5 3 The ionic bond 239
531 Production of isolated cations 239
532 Production of isolated anions 244
533 Coulombic attraction 245
534 Lattice energies 247
535 Kapustinskii equation 249
536 Polarization 253
537 Geometrical aspects of ionic bonds 254
5 4 Alumina, A12O3 257
541 Sources 257
542 Manufacture 257
543 Structure 260
544 a-Alumina 261
545 The ruby laser—a new use for an old material 267
546 l-Alumina 268
547 y-Alumina 272
5 5 Zirconia, ZrO2 272
551 Sources and manufacture 272
552 Bonding and structure 274
553 Mechanical properties 275
554 Problem of the monoclinic/tetragonal phase transition 275
555 Stabilized zirconia 278
556 Ceramic steel: a use for the zirconia phase change 282
CONTENTS
5 6 Magnesia, MgO 284
561 Sources and manufacture 284
562 Structure and strength 286
563 Role of impurities in magnesia 288
5 7 Urania, UO2 292
571 Source and preparation 293
572 Structure 293
573 Strength • 293
5 8 Titania, TiO2 295
581 Manufacture 295
582 Structure 296
583 Bonding 298
584 Mechanical properties 299
5 9 Spinels 299
591 Structure - 300
592 Factors determining degree of inversion 302
593 Preparation and reactivity 305
5 10 ABO3-type oxides 306
5 10 1 Structures 306
5 10 2 Properties 307
5 11 Ferrites 308
References and further reading 309
6 3 Silicides 344
References and further reading 345
Index 347
6 Special ceramics—refractory hard metals
6 1 Interstitial carbides and nitrides of classes 1 and 2
Preparation
Compositions and non-stoichiometry
Properties and uses
Uses of cemented hard-metals
Bonding
6 2 Borides
Structures
Non-stoichiometry
Bonding and valency
Preparation
Properties
Uses
|
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| discipline | Werkstoffwissenschaften |
| edition | 1. publ. |
| format | Book |
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| indexdate | 2024-07-09T15:22:05Z |
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| isbn | 0412003511 0249441632 |
| language | English |
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| spelling | MacColm, Ian J. Verfasser aut Ceramic science for materials technologists I. J. McColm 1. publ. Glasgow [u.a.] Hill 1983 X, 357 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Literaturangaben Keramischer Werkstoff (DE-588)4030282-9 gnd rswk-swf Keramischer Werkstoff (DE-588)4030282-9 s DE-604 HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=000594491&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | MacColm, Ian J. Ceramic science for materials technologists Keramischer Werkstoff (DE-588)4030282-9 gnd |
| subject_GND | (DE-588)4030282-9 |
| title | Ceramic science for materials technologists |
| title_auth | Ceramic science for materials technologists |
| title_exact_search | Ceramic science for materials technologists |
| title_full | Ceramic science for materials technologists I. J. McColm |
| title_fullStr | Ceramic science for materials technologists I. J. McColm |
| title_full_unstemmed | Ceramic science for materials technologists I. J. McColm |
| title_short | Ceramic science for materials technologists |
| title_sort | ceramic science for materials technologists |
| topic | Keramischer Werkstoff (DE-588)4030282-9 gnd |
| topic_facet | Keramischer Werkstoff |
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