Colloidal systems and interfaces:
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
New York u.a.
Wiley
1988
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XVIII, 422 S. Ill. |
| ISBN: | 0471828483 |
Internformat
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IMAGE 1
COLLOIDAL SYSTEMS
AND INTERFACES
SYDNEY ROSS DEPARTMENT OF CHEMISTRY RENSSELAER POLYTECHNIC INSTITUTE
TROY, NEW YORK *. '; IAN DOUGLAS MORRISON WEBSTER RESEARCH CENTER XEROX
CORPORATION WEBSTER, NEW YORK
WILEY
A WILEY-INTERSCIENCE PUBLICATION JOHN WILEY & SONS NEW YORK * CHICHESTER
* BRISBANE * TORONTO * SINGAPORE
IMAGE 2
CONTENTS
INTRODUCTION PARTICULATE PROPERTIES 2 INTERFACIAL PROPERTIES 2 STABILITY
OF DISPERSED-PHASE SYSTEMS DEFINITIONS AND GLOSSARY OF TERMS 3
PART I. PARTICULATES
CHAPTER I.A. OPTICAL PROPERTIES-LIGHT SCATTERING 9
CHAPTER I.B. KINETIC PROPERTIES-RHEOLOGY 14
1. CLASSIFICATION OF FLOW 14. A. NEWTONIAN FLOW 14
B. PLASTIC FLOW 17
C. SHEAR THINNING 19 *
D. DILATANCY 20
E. THIXOTROPY 20
F. UNITS AND DIMENSIONS 21 2. INSTRUMENTS TO MEASURE VISCOSITY 21 A.
CAPILLARY VISCOSIMETERS 21 B. COAXIAL CYLINDRICAL RHEOMETERS 23
C. CONE-AND-PLATE RHEOMETERS 23 D. VISCOELASTOMETERS 25
XI
IMAGE 3
XLL CONTENTS
CHAPTER I.C. STATISTICAL PROPERTIES
1. BROWNIAN MOTION 26 2. COLLIGATIVE PROPERTIES 27 3. FRACTALS 27
CHAPTER I.D. SIZE AND SURFACE AREA
1. PARTICLE-SIZING TECHNIQUES FOR COARSE PARTICLES (2/IM AND ABOVE) 33
A. OPTICAL MICROSCOPE 33 B. SIEVES 34
C. ELUTRIATORS, IMPACTORS, AND CYCLONES 36 D. HEGMAN FINENESS-OF-GRIND
GAUGE 37 E. DIFFRACTION 38
2. PARTICLE-SIZING TECHNIQUES FOR FINE PARTICLES (0.5-2/IM) 39 A.
SEDIMENTATION 39
B. INDIVIDUAL PARTICLE SENSORS 41 C. MERCURY POROSIMETRY 43 3.
PARTICLE-SIZING TECHNIQUES FOR ULTRAFINE PARTICLES ( 0.5//M) 43
A. TRANSMISSION AND ELECTRON MICROSCOPES 43 B. TURBIDITY 44
C. LASER LIGHT SCATTERING 45 D. QUASI-ELASTIC LIGHT SCATTERING 46 E.
CENTRIFUGATION 47
F. HYDRODYNAMIC CHROMATOGRAPHY 48 G. SEDIMENTATION FIELD-FLOW
FRACTIONATION 49 4. SURFACE AREA BY ADSORPTION 50 A. PHYSICAL ADSORPTION
50
B. ADSORPTION FROM SOLUTION 53
26
31
56 CHAPTER I.E. PROCESSING METHODS FOR MAKING EMULSIONS AND SUSPENSIONS
1. HIGH-SHEAR MILLS 59
2. IMPACT MILLS 60
3. CHEMICAL PROCESSING AIDS 63 "REFERENCES FOR PART I 64
PART II. INTERFACES
CHAPTER II.A. CAPILLARITY OF PURE LIQUIDS 1. MOLECULAR THEORY OF SURFACE
TENSION 2. MOLECULAR THEORY OF INTERFACIAL TENSION
69
69 73
IMAGE 4
CONTENTS XLLL
3. DISPERSION FORCE CONTRIBUTIONS TO INTERFACIAL TENSION 74 4. ACID-BASE
CONTRIBUTIONS TO INTERFACIAL TENSION 78
5. THERMODYNAMICS OF SURFACES AND INTERFACES 81 A. COALESCENCE, OF
DROPLETS 83 B. SPREADING OF ONE LIQUID ON ANOTHER 84 C. ENCAPSULATION OF
ONE LIQUID BY ANOTHER 84 D. WORKS OF ADHESION AND COHESION 86
E. FREE ENERGY OF EMERSION 87 6. THERMODYNAMICS OF LIQUIDS IN CONTACT
WITH SOLIDS 87
7. DEGREES OF LIQUID-SOLID INTERACTION 91 8. DISPERSION ENERGIES OF
SOLID SUBSTRATES 92 9. FLOATING PARTICLES 98 10. INITIAL AND FINAL
SPREADING COEFFICIENTS 99 11. DETERMINATION OF SPREADING PRESSURE BY
ADSORPTION
TECHNIQUES 103 12. DYNAMICS OF INITIAL SPREADING 104 13. THERMODYNAMICS
OF CURVED INTERFACES 105 14. SESSILE AND PENDENT DROPS 107
15. THE KELVIN EQUATION 109 16. CAPILLARY FLOW AND MARANGONI FLOW 110
17. METHODS TO MEASURE SURFACE AND INTERFACIAL TENSION 113
A. CAPILLARY HEIGHT 113 B. DROP WEIGHT 114 C. WHILHELMY PLATE 114 D. THE
DU NOIIY RING 114
E. SESSILE AND PENDENT DROP 115 F. MAXIMUM PULL ON A ROD 116 G. MAXIMUM
BUBBLE PRESSURE 117 H. SPINNING DROP 118
I. VIBRATING JET 118 18. METHODS TO MEASURE CONTACT ANGLE 118 A.
GONIOMETER * 119 B. INTERFACIAL MENISCUS 119
C. FIBER BALANCE 119 D. THE BARTELL CELL 121 E. THE WASHBURN EQUATION
121 19. CONTACT ANGLES ON IRREGULAR SURFACES 122 20. THE JAMIN EFFECT
125
IMAGE 5
XIV CONTENTS
CHAPTER N.B. THE RELATION OF CAPILLARITY TO PHASE DIAGRAMS
1. INTRODUCTION 126
2. REGULAR SOLUTION THEORY 128
CHAPTER II.C. SURFACE-ACTIVE SOLUTES
1. INTRODUCTION 132
2. RANGE OF SOLUTES FROM LIPOPHILIC TO HYDROPHILIC 133 3. TYPES:
ANIONIC, CATIONIC, AND NONIONIC
CHAPTER II.D. PHYSICAL PROPERTIES OF INSOLUBLE MONOLAYERS
1. OBSERVATIONS 139
2. VISCOELASTICITY OF INSOLUBLE MONOLAYERS 3. BUILT-UP" FILMS:
LANGMUIR-BLODGETT FILMS
126
132
135
145 146
139
CHAPTER II.E. AQUEOUS SOLUTIONS OF SURFACE-ACTIVE SOLUTES
1. ADSORPTION 148
2. LUNDELIUS' RULE AND THE FERGUSON EFFECT 149 3. MICELLIZATION AND
SOLUBILIZATION 151 A. SPONTANEOUS ASSOCIATION 151 B. METHODS TO
DETERMINE CRITICAL MICELLE
CONCENTRATION 152 C. EQUILIBRIUM OR PHASE SEPARATION? 154 D. EFFECTS OF
VARYING MOLECULAR STRUCTURE 156 E. SOLUBILIZATION BY MICELLES
(MICROEMULSIONS) 161 4. THE KRAFFT POINT 164 5. DYNAMIC SURFACE TENSIONS
165 6. ELASTICITY OF SURFACE FILMS 167
7. ULTRALOW DYNAMIC SURFACE TENSION 170 8. THEORIES OF RATE OF BUBBLE
RISE IN VISCOUS MEDIA 170
A. RISE IN PURE LIQUIDS-HADAMARD REGIME 171 B. EFFECT OF SURFACE-ACTIVE
SOLUTES-STOKES REGIME 171 9. PHASE BEHAVIOR OF SURFACE-ACTIVE SOLUTES
173
148
CHAPTER II.F. SURFACE ACTIVITY IN NONAQUEOUS MEDIA 178
IMAGE 6
CONTENTS XV
CHAPTER II.G. THERMODYNAMICS OF ADSORPTION FROM SOLUTION
1. THE GIBBS ADSORPTION ISOTHERM 180 A. TWO-COMPONENT SYSTEMS 182 B.
THREE-COMPONENT SYSTEMS 184 2. THE SURFACE TENSION ISOTHERM 187
3. ADSORPTION ISOTHERM: LANGMUIR 188 4. EQUATION OF STATE: FRUMKIN 189
5. STANDARD-STATE FREE ENERGIES 190 6. TRAUBE'S RULE 193
REFERENCES FOR PART II
180
195
PART III. STABILITY OF DISPERSIONS
CHAPTER 111.A. FORCES OF ATTRACTION 205
1. FORCESOFATTRACTIONBETWEENMOLECUL.ES 205 2. FORCES OF ATTRACTION
BETWEEN PARTICLES 209 A. MOLECULAR APPROACH-HAMAKER THEORY 210 B. MOLAR
APPROACH-LIFSHITZ THEORY 216 3. OTHER METHODS TO OBTAIN HAMAKER
CONSTANTS 223
A. DIRECT MEASUREMENTS OF FORCES OF ATTRACTION 223
B. INDIRECT MEASUREMENTS OF THE FORCES OF ATTRACTION 224
4. VALUES OF HAMAKER CONSTANTS FOR SOME COMMON MATERIALS 227
CHAPTER 111.B. FORCES OF REPULSION 229
1. ELECTROSTATIC REPULSION 229 A. ORIGIN OF CHARGE IN AQUEOUS SYSTEMS
229 B. GOUY-CHAPMAN THEORY 232 C. STERN THEORY 236
2. ANALYSIS OF INTERACTING PLANAR DOUBLE LAYERS 238 A. THE LANGMUIR
APPROXIMATION . 239 B. THE DEBYE-HIICKEL APPROXIMATION 242 3. ANALYSIS
OF INTERACTING SPHERICAL DOUBLE
LAYERS 243
A. THE DERJAGUIN "APPROXIMATION 244 B. THE DEBYE-HUCKEL APPROXIMATION
245 C. CONSTANT SURFACE CHARGE DENSITY 246
IMAGE 7
XVI CONTENTS
CHAPTER III.C. STABILITY OF SYSTEMS 247
1. ELECTROCRATIC AND LYOCRATIC DISPERSIONS 247 2. ELECTROSTATIC
REPULSION VERSUS DISPERSION FORCE ATTRACTION 248 A. DLVO THEORY: TWO
FLAT PLATES 248
B. DLVO THEORY: TWO EQUAL SPHERES OF RADIUS A 249
3. APPLICATIONS OF DLVO THEORY TO DISPERSIONS 249 4. COLLOID STABILITY
AND COMPLEX ION CHEMISTRY 252
CHAPTER 111.D. KINETICS OF COAGULATION 255
REFERENCES FOR PART III 260
PART IV. DISPERSED-PHASE SYSTEMS
CHAPTER IV.A. EMULSIONS 267
1. DEFINITIONS AND GLOSSARY OF TERMS 267 2. DETERMINATION OF EMULSION
TYPE 268 3. COALESCENCE OF EMULSION DROPLETS 268 4. BANCROFT'S RULE 269
5. AMPHIPATHIC PARTICLES AS EMULSION STABILIZERS 271 6. THE HLB SCALE
273
7. THE PHASE-INVERSION TEMPERATURE 276 8. MECHANICAL PROPERTIES OF THE
INTERFACE 277 9. VARIATION WITH CONCENTRATION OF INTERNAL PHASE 279
A. RHEOLOGY OF EMULSIONS 281 B. ELECTRICAL CONDUCTIVITY OF EMULSIONS 283
10. MEASUREMENT OF EMULSION STABILITY 285 11. MAKING EMULSIONS 286 0 A.
THE METHOD OF PHASE INVERSION 286
B. PHASE-INVERSION TEMPERATURE (PIT) METHOD 287
C. CONDENSATION METHODS 287 D. INTERMITTENT MILLING 287 E. ELECTRIC
EMULSIFICATION 287 F. SPECIAL METHODS 288
IMAGE 8
CONTENTS XVII
12. BREAKING EMULSIONS 288 A. MECHANICAL DEMULSIFICATION 288 B. THERMAL
DEMULSIFICATION 289 C. CHEMICAL DEMULSIFICATION 289 13. MICROEMULSIONS
AND MINIEMULSIONS 290 14. EMULSION POLYMERIZATION 293
CHAPTER IV.B. FOAMS * 294
1. PROPERTIES OF FOAMS 294 2. GEOMETRY OF BUBBLES AND FOAMS 295 3.
EQUATION OF STATE OF FOAM 296 4. THEORIES OF FOAM STABILITY 298
A. THERMODYNAMIC STABILITY 298 B. MARANGONI-GIBBS-RAYLEIGH THEORY 300.
C. THE MARANGONI EFFECT 300 D. STRESSES ON FOAMS 301
E. ELASTICITY OF LAMELLAE 302 F. ENHANCED VISCOSITY OR RIGIDITY 304 G.
BLACK FILMS 307 H. INFLUENCE OF LIQUID-CRYSTAL PHASES 307
I. MUTUAL REPULSION OF OVERLAPPING DOUBLE LAYERS 310 J. EFFECT OF
DISPERSED PARTICLES ON FOAM STABILITY 310 K. FOAMINESS AND PHASE
DIAGRAMS 311
1. SUMMARY OF FOAM STABILIZATION 314 5. MECHANISMS OF ANTIFOAMING ACTION
314 A. IMPAIRMENT OF FOAM STABILITY 314 B. SURFACE AND INTERFACIAL
TENSION RELATIONS 315
C. FOAM INHIBITION-AQUEOUS SYSTEMS 317 D. COMPOUNDED FOAM INHIBITORS 318
E. SILICONE FOAM INHIBITORS 319 F. HYDROPHOBIC PARTICLES 320 6. METHODS
OF MEASURING FOAM PROPERTIES 322
A. STABILITY 322
B. SURFACE RHEOLOGY 325 O
CHAPTER IV.C. SUSPENSIONS 327
1. ADSORPTION FROM SOLUTION BY SOLIDS 327
A. ACIDIC OR BASIC CHARACTER OF SOLID SUBSTRATES 328 B. NONAQUEOUS MEDIA
330 C. AQUEOUS MEDIA 332 D. RATES OF ADSORPTION ON SOLID SURFACES 333
IMAGE 9
XVIH CONTENTS
2. SOLUTION ADSORPTION ISOTHERM 334
3. ADSORPTION OF DYES 338 4. EXPERIMENTAL TECHNIQUES FOR SUSPENSIONS 339
A. FLOCCULATED AND DEFLOCCULATED SUSPENSIONS 339
B. SEDIMENTATION RATES AND VOLUMES 340 C. ADSORPTION AT THE SOLID-LIQUID
INTERFACE D. SURFACE TENSION TITRATIONS 343 E. RHEOLOGY 344
F. ELECTRICAL PROPERTIES IN AQUEOUS MEDIA G. ELECTRICAL PROPERTIES IN
NONAQUEOUS MEDIA 350 5. POLYMER STABILIZATION OF SUSPENSIONS 354 6.
ELECTRIC EFFECTS IN DRY SUSPENSIONS 360
7. FLOCCULATION OF SUSPENSIONS 363 8. NUCLEATION AND CRYSTAL GROWTH 364
9. MODEL COLLOIDAL SYSTEMS 366 A. PARTICLES OF UNIFORM SIZE 367
B. SURFACES OF UNIFORM COMPOSITION 370 10. SOME SPECIAL DISPERSIONS 372
342
346
APPENDIX A. APPENDIX A
APPENDIX C.
APPENDIX D.
APPENDIX E.
APPENDIX F.
APPENDIX G.
APPENDIX H.
APPENDIX J.
APPENDIX K.
REFERENCES FOR PART IV
BIBLIOGRAPHY APPENDICES PHYSICAL CONSTANTS UNITS MATHEMATICAL FORMULAS
USED IN TEXT ELECTROSTATIC AND INDUCTION CONTRIBUTIONS TO INTERMOLECULAR
POTENTIAL ENERGIES
ELECTRIC PROPERTIES OF REPRESENTATIVE MOLECULES LIFETIMES OF
CONTRIBUTORS TO COLLOID AND INTERFACE SCIENCE KENDALL AWARDEES
ELECTROSTATIC UNITS MANUFACTURERS OF INSTRUMENTS MANUFACTURERS OF
PROCESSING EQUIPMENT
INDEX
374 385 391 393
394 395
396 397 398 402 404
405 411 415 |
| any_adam_object | 1 |
| author | Ross, Sydney Morrison, Ian D. |
| author_facet | Ross, Sydney Morrison, Ian D. |
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| author_variant | s r sr i d m id idm |
| building | Verbundindex |
| bvnumber | BV000860469 |
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| discipline | Chemie / Pharmazie |
| format | Book |
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| id | DE-604.BV000860469 |
| illustrated | Illustrated |
| indexdate | 2024-12-18T01:00:24Z |
| institution | BVB |
| isbn | 0471828483 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-000540250 |
| oclc_num | 260136248 |
| open_access_boolean | |
| owner | DE-12 DE-19 DE-BY-UBM DE-703 DE-355 DE-BY-UBR DE-20 DE-83 DE-11 DE-188 |
| owner_facet | DE-12 DE-19 DE-BY-UBM DE-703 DE-355 DE-BY-UBR DE-20 DE-83 DE-11 DE-188 |
| physical | XVIII, 422 S. Ill. |
| publishDate | 1988 |
| publishDateSearch | 1988 |
| publishDateSort | 1988 |
| publisher | Wiley |
| record_format | marc |
| spelling | Ross, Sydney Verfasser aut Colloidal systems and interfaces Sydney Ross ; Ian Douglas Morrison New York u.a. Wiley 1988 XVIII, 422 S. Ill. txt rdacontent n rdamedia nc rdacarrier Emulsion (DE-588)4014626-1 gnd rswk-swf Grenzflächenaktiver Stoff (DE-588)4158138-6 gnd rswk-swf Kolloidchemie (DE-588)4134420-0 gnd rswk-swf Grenzfläche (DE-588)4021991-4 gnd rswk-swf Dispersion (DE-588)4012484-8 gnd rswk-swf Oberflächenchemie (DE-588)4126166-5 gnd rswk-swf Kolloid (DE-588)4164695-2 gnd rswk-swf Kolloid (DE-588)4164695-2 s Grenzfläche (DE-588)4021991-4 s DE-604 Oberflächenchemie (DE-588)4126166-5 s Dispersion (DE-588)4012484-8 s Grenzflächenaktiver Stoff (DE-588)4158138-6 s Emulsion (DE-588)4014626-1 s Kolloidchemie (DE-588)4134420-0 s Morrison, Ian D. Verfasser aut HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=000540250&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Ross, Sydney Morrison, Ian D. Colloidal systems and interfaces Emulsion (DE-588)4014626-1 gnd Grenzflächenaktiver Stoff (DE-588)4158138-6 gnd Kolloidchemie (DE-588)4134420-0 gnd Grenzfläche (DE-588)4021991-4 gnd Dispersion (DE-588)4012484-8 gnd Oberflächenchemie (DE-588)4126166-5 gnd Kolloid (DE-588)4164695-2 gnd |
| subject_GND | (DE-588)4014626-1 (DE-588)4158138-6 (DE-588)4134420-0 (DE-588)4021991-4 (DE-588)4012484-8 (DE-588)4126166-5 (DE-588)4164695-2 |
| title | Colloidal systems and interfaces |
| title_auth | Colloidal systems and interfaces |
| title_exact_search | Colloidal systems and interfaces |
| title_full | Colloidal systems and interfaces Sydney Ross ; Ian Douglas Morrison |
| title_fullStr | Colloidal systems and interfaces Sydney Ross ; Ian Douglas Morrison |
| title_full_unstemmed | Colloidal systems and interfaces Sydney Ross ; Ian Douglas Morrison |
| title_short | Colloidal systems and interfaces |
| title_sort | colloidal systems and interfaces |
| topic | Emulsion (DE-588)4014626-1 gnd Grenzflächenaktiver Stoff (DE-588)4158138-6 gnd Kolloidchemie (DE-588)4134420-0 gnd Grenzfläche (DE-588)4021991-4 gnd Dispersion (DE-588)4012484-8 gnd Oberflächenchemie (DE-588)4126166-5 gnd Kolloid (DE-588)4164695-2 gnd |
| topic_facet | Emulsion Grenzflächenaktiver Stoff Kolloidchemie Grenzfläche Dispersion Oberflächenchemie Kolloid |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=000540250&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT rosssydney colloidalsystemsandinterfaces AT morrisoniand colloidalsystemsandinterfaces |