Rare-earth elements: solid state materials: chemical, optical and magnetic properties
Gespeichert in:
| 1. Verfasser: | |
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| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Berlin ; Boston
De Gruyter
[2024]
|
| Schriftenreihe: | De Gruyter Graduate
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| Schlagworte: | |
| Online-Zugang: | https://www.degruyter.com/isbn/9783110680812 Inhaltsverzeichnis |
| Beschreibung: | XII, 261 Seiten Illustrationen, Diagramme |
| ISBN: | 9783110680812 |
Internformat
MARC
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| 100 | 1 | |a Höppe, Henning A. |d 1972- |e Verfasser |0 (DE-588)133060926 |4 aut | |
| 245 | 1 | 0 | |a Rare-earth elements |b solid state materials: chemical, optical and magnetic properties |c Henning Höppe |
| 264 | 1 | |a Berlin ; Boston |b De Gruyter |c [2024] | |
| 264 | 4 | |c © 2024 | |
| 300 | |a XII, 261 Seiten |b Illustrationen, Diagramme | ||
| 336 | |b txt |2 rdacontent | ||
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| 338 | |b nc |2 rdacarrier | ||
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| 650 | 0 | 7 | |a Magnetische Eigenschaft |0 (DE-588)4129002-1 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Optische Eigenschaft |0 (DE-588)4123887-4 |2 gnd |9 rswk-swf |
| 653 | |a Seltenerdmetalle | ||
| 653 | |a Seltenerdverbindungen | ||
| 653 | |a Seltenerdchemie | ||
| 653 | |a Lanthanoide | ||
| 653 | |a optische Eigenschaften | ||
| 653 | |a magnetische Eigenschaften | ||
| 653 | |a Rare-Earth Elements | ||
| 653 | |a Rare-Earth Chemistry | ||
| 653 | |a Lanthanoids | ||
| 653 | |a Rare-Earth compounds | ||
| 653 | |a Optical properties | ||
| 653 | |a Magnetic properties | ||
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Datensatz im Suchindex
| _version_ | 1807953322569629696 |
|---|---|
| adam_text |
CONTENTS
ABBREVIATIONS
-
V
PREFACE
-
VII
1
THE
RARE-EARTH
ELEMENTS
-
1
1.1
AN
INTRODUCTION
-
1
1.2
A
SHORT
HISTORY
OF
DISCOVERY
-
3
PARTL:
GENERAL
ASPECTS
OF
RARE-EARTH
ELEMENTS
2
BASIC
ASPECTS
AND
GENERAL
PROPERTIES
-
11
2.1
THE
RARE-EARTH
ELEMENTS
IN
THE
PERIODIC
TABLE
-
11
2.2
ELECTRONIC
CONFIGURATION
-
16
3
GENERAL
TRENDS
OF
PHYSICAL
AND
CHEMICAL
BEHAVIOR
-
17
3.1
ATOMIC,
IONIC
AND
VAN
DER
WAALS
RADII
-
17
3.2
DENSITIES,
MELTING
AND
BOILING
POINTS
-
18
3.3
CRYSTAL
STRUCTURES
OF
THE
ELEMENTS
-
19
3.4
ON
CERIUM
-
A
SHORT
STORY
-
21
3.5
IONIZATION
BEHAVIOR
AND
CHEMICAL
HARDNESS
-
24
3.6
OXIDATION
STATES
-
COLORS
IN
AN
AQUEOUS
SOLUTION
-
26
3.7
GENERAL
REACTIVITY
-
28
3.8
SOLUTION
CHEMISTRY
-
29
3.8.1
REDUCTION
POTENTIALS
-
29
3.8.2
ACID-BASE
CHEMISTRY
AND
SIMPLE
COMPLEXES
-
31
4
NATURAL
RESOURCES
-
36
4.1
GENERAL
ASPECTS
-
36
4.2
ORES
AND
MINERALS
-
38
5
PRODUCTION
-
42
5.1
CONCENTRATION
OF
RARE-EARTH
MINERALS
-
42
5.2
SEPARATION
AND
PURIFICATION
OF
THE
ELEMENTS
-
43
5.2.1
SOLVENT-SOLVENT
EXTRACTION
-
45
5.2.2
FURTHER
SEPARATION
APPROACHES
-
47
5.2.3
SCANDIUM
-
48
5.3
OBTAINING
THE
ELEMENTS
-
49
X
----
CONTENTS
6
BASIC
COMPOUND
CLASSES
-
50
6.1
HYDROGEN
COMPOUNDS
-
50
6.1.1
STRUCTURES
AND
BONDING
OF
RH
2
AND
RH
3
-
51
6.1.2
HYDROGEN
STORAGE-LANI,
-
54
6.2
BINARY
HALIDES
AND
HALIDE
OXIDES
-
56
6.2.1
TRIHALIDES
RX3
-
57
6.2.2
TETRAFLUORIDES
RF
4
-
61
6.2.3
REDUCED
HALIDES
-
62
6.2.4
HALIDE
OXIDES
-
66
6.3
OXIDES
-
70
6.3.1
THE
SESQUIOXIDES
R
2
0
3
AND
MIXED
III/IV-OXIDES
-
70
6.3.2
SYNTHESES
AND
STRUCTURES
OF
THE
DIOXIDES
AND
INTERMEDIATE
OXIDES
-
72
6.3.3
A
CLOSER
LOOK
ON
CEO
2
-
74
6.3.4
THE
MONOXIDES
AND
EU
3
O
4
-
76
6.3.5
THE
SUPERCONDUCTING
OXIDES
LA
2
.
X
BA
X
CUO
4
AND
YBA2CU307X
-
77
6.4
BORIDES,
CARBIDES,
NITRIDES
AND
SULFIDES
-
78
6.4.1
BORIDES
-
78
6.4.2
CARBIDES
AND
NITRIDES
-
80
6.4.3
SULFIDES
-
82
6.5
SILICATES
AND
SELECTED
SILICATE-ANALOGOUS
COMPOUNDS
-
83
6.5.1
COORDINATION
STRENGTH
-
83
6.5.2
SILICATES
-
84
6.5.3
ALUMINATES
-
86
6.5.4
NITRIDOSILICATES,
NITRIDOALUMINATES
AND
OXONITRIDOSILICATES
-
88
6.5.5
PHOSPHATES
-
90
6.5.6
BOROPHOSPHATES,
BOROSULFATES
AND
FLUOROOXOBORATES
-
91
PART
II:
PROPERTIES
AND
APPLICATIONS
7
TRANSITIONS
-
97
7.1
TRANSITION
PROBABILITY
-
97
7.2
CONFIGURATION,
TERMS
AND
LEVELS
-
97
7.3
ELECTRIC
AND
MAGNETIC
DIPOLE
TRANSITIONS
-
100
7.4
SPIN
SELECTION
RULE
-
102
7.5
JABLONSKI
DIAGRAMS
-
103
7.6
ENERGY
TRANSFER
MECHANISMS
-
105
7.6.1
FRET
MECHANISM
-
106
7.6.2
DEXTER
MECHANISM
-
106
7.7
FURTHER
PARAMETERS
-
107
7.7.1
BANDWIDTH
OF
A
TRANSITION
-
107
7.7.2
THERMAL
QUENCHING
AND
CONCENTRATION
QUENCHING
-
108
CONTENTS
-
XI
7.7.3
7.7.4
7.8
8
8.1
8.2
8.2.1
8.2.2
8.2.3
8.3
8.4
8.4.1
8.4.2
8.4.3
8.4.4
8.4.5
8.4.6
8.4.7
8.4.8
8.4.9
8.4.10
8.4.11
8.5
8.5.1
8.5.2
8.6
8.7
9
9.1
9.2
9.2.1
9.2.2
9.2.3
9.3
9.3.1
9.3.2
9.4
9.5
9.6
COLOR
COORDINATES
-
109
COLOR
TEMPERATURE
-
110
TRANSITIONS
WITHIN
A
4F
CONFIGURATION
-
JUDD-OFELT
THEORY
-
111
OPTICAL
PROPERTIES
-
117
NEPHELAUXETIC
EFFECT
-
117
CHARGE-TRANSFER
TRANSITIONS
-
119
GENERAL
ASPECTS
-
119
VIEW
ON
RARE-EARTH
IONS
-
120
OPTICAL
ELECTRONEGATIVITY
-
122
THE
CHEMICAL
SHIFT
MODEL
-
123
EMITTERS
WEAKLY
INTERACTING
WITH
LIGANDS
-
126
GADOLINIUM
-
ONLY
PARTIALLY
INNOCENT
-
127
TERBIUM
-
BRIGHT
GREEN
OR
ALSO
BLUE?
-
130
EUROPIUM
-
SOMETIMES
HYPERSENSITIVE
-
134
SAMARIUM
AND
BURNING
HOLES
-
140
DYSPROSIUM
-
AS
LONG-LASTING
AS
POSSIBLE
-
142
HOLMIUM-A
CHAMELEON
-
145
ERBIUM-PUTTING
PHOTONS
TOGETHER
-
147
NEODYMIUM
-
A
PERFECT
MATCH
FOR
STIMULATED
EMISSION
-
150
PRASEODYMIUM-OCCASIONALLY
A
KNIFE
FOR
PHOTONS
-
153
THULIUM
-
NORMALLY
BLUE
-
155
YTTERBIUM
-
SOLAR
CELLS
ARE
PLEASED
-
156
EMITTERS
STRONGLY
INTERACTING
WITH
LIGANDS
(5D-4F
TRANSITIONS)
-
158
TRIVALENT
CERIUM
-
THE
MOST
EFFICIENT
LN
3+
-
159
DIVALENT
EUROPIUM-A
TRUE
CHAMELEON
-
164
ON
WHITE
LEDS-A
SHORT
STORY
-
167
FURTHER
DIVALENT
RARE-EARTH
IONS
-
171
MAGNETISM
-
174
BASIC
PRINCIPLES
-
174
PARAMAGNETISM
-
177
INNER
TRANSITION
METALS
-
178
VAN
VLECK
PARAMAGNETISM
-
180
OUTER
TRANSITION
METALS
-
182
MAGNETIC
ORDERING
-
183
FERROMAGNETISM
AND
ANTIFERROMAGNETISM
-
184
MAGNETISM
OF
METALLIC
4F
SYSTEMS
-
187
MAGNETIC
BEHAVIOR
OF
THE
LANTHANIDE
METALS
-
189
THE
EUROPIUM
CHALCOGENIDES,
ANTIFERROMAGNETISM
AND
FERRIMAGNETISM
-
192
RARE-EARTH
FERROMAGNETS
-
OFTEN
REALLY
HARD
AND
PERMANENT
-
195
XII
-
CONTENTS
9.6.1
SMCO
5
-
197
9.6.2
SM
2
CO
17
-
199
9.6.3
SM
2
FE
17
N
3
-
199
9.6.4
ND
2
FE
14
B
-----
200
9.7
MAGNETOCALORIC
MATERIALS
-
201
9.7.1
GD
5
(SI
2
GE
2
)
-----
203
9.7.2
EU
2
IN
-
204
EPILOGUE
-
205
A
IONIC
RADII
-
207
B
PHYSICAL
PROPERTIES
-
209
C
CHEMICAL
SHIFT
MODEL
PARAMETERS
-
211
D
STRUCTURE
TYPES
DERIVED
FROM
CLOSE
PACKINGS
-
213
E
EXEMPLARY
CALCULATION
OF
THE
TRANSITION
INTEGRAL
'
S
BEHAVIOR
-
217
F
EXCERPTS
OF
MAPLE
CALCULATIONS
-
219
F.1
COORDINATION
AND
MAPLE
OF
LAH
3
AND
GDH
3
-
219
F.2
COORDINATIONS
IN
EUBR
2
-
226
F.3
COORDINATIONS
IN
B
TYPE
SM
2
O
3
-
228
GENERAL
INDEX
-
231
FORMULA
INDEX
-
237
BIBLIOGRAPHY
-
241 |
| adam_txt | |
| any_adam_object | 1 |
| any_adam_object_boolean | |
| author | Höppe, Henning A. 1972- |
| author_GND | (DE-588)133060926 |
| author_facet | Höppe, Henning A. 1972- |
| author_role | aut |
| author_sort | Höppe, Henning A. 1972- |
| author_variant | h a h ha hah |
| building | Verbundindex |
| bvnumber | BV049575787 |
| classification_rvk | VE 9300 VH 8045.0 UN 4045 |
| ctrlnum | (OCoLC)1429563083 (DE-599)DNB1306695031 |
| discipline | Chemie / Pharmazie Physik |
| discipline_str_mv | Chemie / Pharmazie Physik |
| format | Book |
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| id | DE-604.BV049575787 |
| illustrated | Illustrated |
| index_date | 2024-07-03T23:31:20Z |
| indexdate | 2024-08-21T00:04:06Z |
| institution | BVB |
| institution_GND | (DE-588)10095502-2 |
| isbn | 9783110680812 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-034920852 |
| oclc_num | 1429563083 |
| open_access_boolean | |
| owner | DE-384 DE-1102 DE-11 DE-19 DE-BY-UBM |
| owner_facet | DE-384 DE-1102 DE-11 DE-19 DE-BY-UBM |
| physical | XII, 261 Seiten Illustrationen, Diagramme |
| publishDate | 2024 |
| publishDateSearch | 2024 |
| publishDateSort | 2024 |
| publisher | De Gruyter |
| record_format | marc |
| series2 | De Gruyter Graduate |
| spelling | Höppe, Henning A. 1972- Verfasser (DE-588)133060926 aut Rare-earth elements solid state materials: chemical, optical and magnetic properties Henning Höppe Berlin ; Boston De Gruyter [2024] © 2024 XII, 261 Seiten Illustrationen, Diagramme txt rdacontent n rdamedia nc rdacarrier De Gruyter Graduate Seltenerdmetall (DE-588)4132099-2 gnd rswk-swf Chemische Eigenschaft (DE-588)4371174-1 gnd rswk-swf Festkörperchemie (DE-588)4129288-1 gnd rswk-swf Magnetische Eigenschaft (DE-588)4129002-1 gnd rswk-swf Optische Eigenschaft (DE-588)4123887-4 gnd rswk-swf Seltenerdmetalle Seltenerdverbindungen Seltenerdchemie Lanthanoide optische Eigenschaften magnetische Eigenschaften Rare-Earth Elements Rare-Earth Chemistry Lanthanoids Rare-Earth compounds Optical properties Magnetic properties Seltenerdmetall (DE-588)4132099-2 s Chemische Eigenschaft (DE-588)4371174-1 s Optische Eigenschaft (DE-588)4123887-4 s Magnetische Eigenschaft (DE-588)4129002-1 s Festkörperchemie (DE-588)4129288-1 s DE-604 Walter de Gruyter GmbH & Co. KG (DE-588)10095502-2 pbl Erscheint auch als Online-Ausgabe, EPUB 978-3-11-068088-1 Erscheint auch als Online-Ausgabe, PDF 978-3-11-068082-9 X:MVB https://www.degruyter.com/isbn/9783110680812 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=034920852&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p vlb 20231020 DE-101 https://d-nb.info/provenance/plan#vlb |
| spellingShingle | Höppe, Henning A. 1972- Rare-earth elements solid state materials: chemical, optical and magnetic properties Seltenerdmetall (DE-588)4132099-2 gnd Chemische Eigenschaft (DE-588)4371174-1 gnd Festkörperchemie (DE-588)4129288-1 gnd Magnetische Eigenschaft (DE-588)4129002-1 gnd Optische Eigenschaft (DE-588)4123887-4 gnd |
| subject_GND | (DE-588)4132099-2 (DE-588)4371174-1 (DE-588)4129288-1 (DE-588)4129002-1 (DE-588)4123887-4 |
| title | Rare-earth elements solid state materials: chemical, optical and magnetic properties |
| title_auth | Rare-earth elements solid state materials: chemical, optical and magnetic properties |
| title_exact_search | Rare-earth elements solid state materials: chemical, optical and magnetic properties |
| title_exact_search_txtP | Rare-earth elements solid state materials: chemical, optical and magnetic properties |
| title_full | Rare-earth elements solid state materials: chemical, optical and magnetic properties Henning Höppe |
| title_fullStr | Rare-earth elements solid state materials: chemical, optical and magnetic properties Henning Höppe |
| title_full_unstemmed | Rare-earth elements solid state materials: chemical, optical and magnetic properties Henning Höppe |
| title_short | Rare-earth elements |
| title_sort | rare earth elements solid state materials chemical optical and magnetic properties |
| title_sub | solid state materials: chemical, optical and magnetic properties |
| topic | Seltenerdmetall (DE-588)4132099-2 gnd Chemische Eigenschaft (DE-588)4371174-1 gnd Festkörperchemie (DE-588)4129288-1 gnd Magnetische Eigenschaft (DE-588)4129002-1 gnd Optische Eigenschaft (DE-588)4123887-4 gnd |
| topic_facet | Seltenerdmetall Chemische Eigenschaft Festkörperchemie Magnetische Eigenschaft Optische Eigenschaft |
| url | https://www.degruyter.com/isbn/9783110680812 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=034920852&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT hoppehenninga rareearthelementssolidstatematerialschemicalopticalandmagneticproperties AT walterdegruytergmbhcokg rareearthelementssolidstatematerialschemicalopticalandmagneticproperties |