UV-visible photocatalysis for clean energy production and pollution remediation: materials, reaction mechanisms, and applications
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| Format: | Book |
| Language: | English |
| Published: |
Weinheim, Germany
Wiley-VCH
[2023]
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| Subjects: | |
| Online Access: | http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-35050-6/ Inhaltsverzeichnis Inhaltsverzeichnis |
| Physical Description: | xxxv, 340 Seiten Illustrationen, Diagramme |
| ISBN: | 9783527350506 3527350500 |
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MARC
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| 245 | 1 | 0 | |a UV-visible photocatalysis for clean energy production and pollution remediation |b materials, reaction mechanisms, and applications |c edited by Xinchen Wang, Masakazu Anpo, and Xianzhi Fu ; with a foreword by Professor Detlef Bahnemann |
| 264 | 1 | |a Weinheim, Germany |b Wiley-VCH |c [2023] | |
| 264 | 4 | |c © 2023 | |
| 300 | |a xxxv, 340 Seiten |b Illustrationen, Diagramme | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
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| 650 | 0 | 7 | |a Schadstoffverringerung |0 (DE-588)4194323-5 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Fotokatalyse |0 (DE-588)4193873-2 |2 gnd |9 rswk-swf |
| 653 | |a Catalysis | ||
| 653 | |a Chemie | ||
| 653 | |a Chemistry | ||
| 653 | |a Energie | ||
| 653 | |a Energy | ||
| 653 | |a Environmental Chemistry | ||
| 653 | |a Environmental Science | ||
| 653 | |a Environmental Studies | ||
| 653 | |a Katalyse | ||
| 653 | |a Photokatalyse | ||
| 653 | |a Solar Energy & Photovoltaics | ||
| 653 | |a Solarenergie | ||
| 653 | |a Solarenergie u. Photovoltaik | ||
| 653 | |a Umweltchemie | ||
| 653 | |a Umweltforschung | ||
| 653 | |a Umweltwissenschaften | ||
| 653 | |a CH20: Umweltchemie | ||
| 653 | |a CH40: Katalyse | ||
| 653 | |a EG34: Solarenergie u. Photovoltaik | ||
| 653 | |a EN60: Umweltwissenschaften | ||
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| 700 | 1 | |a Fu, Xianzhi |0 (DE-588)1217442480 |4 edt | |
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Record in the Search Index
| _version_ | 1814162805751808000 |
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| adam_text |
CONTENTS
UV-VISIBLE
PHOTOCATALYSIS
FOR
CLEAN
ENERGY
PRODUCTION
AND
POLLUTION
REMEDIATION:
MATERIALS,
REACTION
MECHANISMS,
AND
APPLICATIONS
-
A
PREFACE
XV
LIST
OF
CONTRIBUTORS
XIX
1
INTRODUCTION
1
XINCHEN
WANG,
MASAKAZU
ANPO,
AND
XIANZHI
FU
1.1
CHALLENGES
AND
OBJECTIVES
IN
THE
USE
OF
SOLAR
ENERGY
1
1.2
BRIEF
HISTORY
OF
THE
PROGRESS
IN
PHOTOCATALYSTS
AND
PHOTOCATALYTIC
REACTIONS
2
1.3
BRIEF
INTRODUCTION
OF
THE
CHAPTERS
4
1.4
CONCLUSION
AND
PERSPECTIVES
6
REFERENCES
6
PART
I
FUNDAMENTALS
OF
PHOTOCATALYSIS
9
2
VISIBLE-LIGHT
ACTIVE
PHOTOCATALYSTS
IN
POLLUTANT
DEGRADATION/
CONVERSION
WITH
SIMULTANEOUS
HYDROGEN
PRODUCTION
11
AMENE
NASERI,
MORASAE
SAMADI,
AND
ALIREZA
Z,
MOSHFEGH
2.1
INTRODUCTION
11
2.2
PRINCIPLES
OF
SIMULTANEOUS
PHOTOCATALYSIS
13
2.2.1
DUAL-FUNCTIONAL
VS.
CONVENTIONAL
PHOTOCATALYSTS
13
2.2.2
REACTION
EFFICIENCY
EVALUATION
15
2.3
COOPERATION
PHOTOCATALYSTS
FOR
ORGANIC
POLLUTANT
DEGRADATION/CONVERSION
AND
H
2
FUEL
PRODUCTION
16
2.3.1
PHOTOCATALYST
DESIGN
16
2.3.2
ORGANIC
SUBSTRATE
TYPE
19
2.3.3
REACTION
CONDITIONS
21
2.4
CONCLUSIONS
23
ACKNOWLEDGMENT
24
REFERENCES
24
VI
CONTENTS
3
SELECTIVE
OXIDATION
OF
ALCOHOLS
USING
CARBON
NITRIDE
PHOTOCATALYSTS
27
OLEKSANDR
SAVATEEV
3.1
3.2
3.3
3.4
3.4.1
3.4.2
3.4.3
3.4.4
INTRODUCTION
27
HEPTAZINE-BASED
GRAPHITIC
CARBON
NITRIDES
28
MECHANISM
OF
ALCOHOLS
OXIDATION
BY
CARBON
NITRIDES
29
IMPROVING
SELECTIVITY
OF
ALCOHOLS
OXIDATION
32
OPTIMIZING
REACTION
TIME
AND
CONVERSION
OF
ALCOHOL
32
SUBSTITUTING
02
BY
OTHER
OXIDANTS
35
COMBINING
CARBON
NITRIDE
PHOTOCATALYST
WITH
H
2
EVOLVING
CATALYST
36
EMPLOYING
PHOTO-CHARGEABLE
IONIC
CARBON
NITRIDES
UNDER
ANAEROBIC
CONDITIONS
36
3.5
CONCLUSION
38
REFERENCES
38
4
APPLICATION
OF
S-SCHEME
HETEROJUNCTION
PHOTOCATALYST
41
CHUANBIAO
BIE
AND
JIAGUO
YU
4.1
4.2
4.3
4.4
4.5
4.6
4.7
4.8
INTRODUCTION
41
HYDROGEN
EVOLUTION
44
CARBON
DIOXIDE
REDUCTION
46
POLLUTANT
DEGRADATION
48
HYDROGEN
PEROXIDE
PRODUCTION
50
DISINFECTION
AND
STERILIZATION
52
ORGANIC
SYNTHESIS
54
CONCLUSION
AND
OUTLOOK
55
REFERENCES
56
5
THE
ROLE
OF
THE
DEFECTS
ON
THE
PHOTOCATALYTIC
REACTIONS
ON
ZNO
59
ZHONGMING
WANG,
WENXIN
DAI,
AND
XIANZHI
FU
5.1
5.2
5.2.1
5.2.2
5.2.3
5.3
INTRODUCTION
59
TYPES
OF
SURFACE
DEFECTS
AND
THEIR
ELECTRICAL
STRUCTURE
60
OXYGEN
VACANCIES
60
ZINC
VACANCIES
60
INTERSTITIAL
OXYGEN
AND
ZINC
61
CONTROLLABLE
PREPARATION
AND
CHARACTERIZATION
OF
SURFACE
VACANCY
DEFECTS
62
5.3.1
5.3.1.1
5.3.1.2
5.3.1.3
CONTROLLABLE
PREPARATION
OF
SURFACE
VACANCY
DEFECTS
62
FORMATION
OF
VACANCY
DEFECTS
VIA
ANNEALING
AT
DIFFERENT
CONDITIONS
62
FORMATION
OF
VACANCY
DEFECTS
VIA
METAL
AND
NONMETAL
DOPING
63
FORMATION
OF
ZNO
WITH
VACANCY
DEFECTS
VIA
HIGH-ENERGY
ELECTRONS
AND
LIGHT
IRRADIATION
64
5.3.2
5.3.2.1
5.3.2.2
CHARACTERIZATION
OF
SURFACE
VACANCY
DEFECTS
64
RAMAN
SPECTROSCOPY
64
X-RAY
PHOTOELECTRON
(XPS)
SPECTROSCOPY
64
CONTENTS
VII
5.3.23
53.2.4
5.4
5.4.1
5.4.2
ELECTRON
PARAMAGNETIC
RESONANCE
(EPR)
SPECTROSCOPY
65
PHOTOLUMINESCENCE
(PL)
SPECTRA
66
MECHANISM
OF
SURFACE
DEFECTS
ON
PHOTOCATALYTIC
REACTION
BEHAVIOR
66
ROLES
OF
DEFECTS
IN
GAS
ADSORPTION
66
DEFECTS
FUNCTION
AS
A
DOUBLE-EDGED
SWORD
IN
REGULATING
PHOTOCATALYTIC
PERFORMANCE
69
5.4.3
5.43.1
5.43.2
DEFECT
ENGINEERING
REGULATES
PHOTOCORROSION
OF
ZNO
70
RELATIONSHIP
BETWEEN
DEFECTS
AND
PHOTOCORROSION
70
CONSTRUCTING
AN
ELECTRON
CHANNEL
THROUGH
ELECTRON
TRANSFER
UPON
THE
ADSORPTION
OF
MOLECULES
AND
ITS
ROLE
IN INHIBITING
PHOTOCORROSION
OF
ZNO
70
5.5
CONCLUSIONS
AND
PROSPECTS
72
REFERENCES
73
PART
II
PHOTOCATALYTIC
SPLITTING
OF
WATER
TO
PRODUCE
HYDROGEN
77
6
STRATEGIES
FOR
PROMOTING
OVERALL
WATER
SPLITTING
WITH
PARTICULATE
PHOTOCATALYSTS
VIA
SINGLE-STEP
VISIBLE-LIGHT
PHOTOEXCITATION
79
JIADONG
XIAO,
XIAOPING
TAO,
AND
KAZUNARI
DOMEN
6.1
6.2
INTRODUCTION
79
SRTIO,:AL/RH/CR,O,/COOOH:
A
MODEL
PARTICULATE
OWS
PHOTOCATALYST
81
6.3
CURRENT
STRATEGIES
PROMOTING
OWS
WITH
VISIBLE-LIGHT-ACTIVATED
PARTICULATE
PHOTOCATALYSTS
82
6.3.1
63.1.1
63.1.2
6.3.2
6.3.3
6.4
DEFECT
CONTROL
OF
THE
SEMICONDUCTOR
MATERIAL
83
NEW
PRECURSOR
DESIGNS
83
ALIOVALENT
DOPING
84
DUAL-COCATALYST
LOADING
86
SURFACE
NANOLAYER
COATING
88
CONCLUDING
REMARKS
89
ACKNOWLEDGMENTS
89
REFERENCES
90
7
INTEGRATION
OF
REDOX
COCATALYSTS
FOR
PHOTOCATALYTIC
HYDROGEN
EVOLUTION
93
MUHAMMAD
TAYYAB,
YUJIE
LIU,
ZEHONG
XU,
SUMMAN
AMAN,
WENHUI
YUE,
RANA
M.
IRFAN,
LIANG
ZHOU,
AND
J
INLONG
ZHANG
7.1
7.2
7.2.1
INTRODUCTION
93
FUNDAMENTALS
OF
DUAL
COCATALYSTS
95
CLASSIFICATION
OF
COCATALYSTS
ON
THE
BASIS
OF
THE
FUNCTIONAL
MECHANISM
95
7.2.2
THE
ADVANTAGES
OF
THE
DESIGN
OF
DUAL
COCATALYSTS
96
VIII
CONTENTS
7.2.3
7.2.4
7.3
THE
EFFECT
OF
REDOX
COCATALYST
PARAMETERS
ON
PHOTOCATALYSIS
96
DESIGN
PRINCIPLES
OF
DUAL
COCATALYSTS
97
RECENT
ADVANCES
IN
THE
CONFIGURATION
OF
DUAL
REDOX
COCATALYSTS/PHOTOCATALYST
98
7.3.1
7.3.2
7.3.2.1
7.3.2.2
7.3.2.3
7.3.2.4
7.4
7.5
RANDOM
DISTRIBUTION
98
SPATIALLY
SEPARATED
DISTRIBUTION
99
TIP/SIDE
DISTRIBUTION
99
YORK-SHELL
DISTRIBUTION
101
FACET-DEPENDENT
DISTRIBUTION
102
CENTER/EDGE
DISTRIBUTION
103
MAJOR
TYPES
OF
PHOTOCATALYTIC
WATER
SPLITTING
103
CONCLUSIONS
105
REFERENCES
105
8
POLYMERIC
CARBON
NITRIDE-BASED
MATERIALS
IN
AQUEOUS
SUSPENSIONS
FOR
WATER
PHOTO-SPLITTING
AND
PHOTO-REFORMING
OF
BIOMASS
AQUEOUS
SOLUTIONS
TO
GENERATE
H2
109
E.I.
GARCIA-LOPEZ,
G.
MARCI,
AND
L.
PALMISANO
8.1
8.2
8.3
INTRODUCTION
109
G-C
3
N
4
-BASED
PHOTOCATALYSTS
FOR
H2
PRODUCTION
112
CONCLUSIONS
116
REFERENCES
116
9
ORGANIC
SUPRAMOLECULAR
MATERIALS
FOR
PHOTOCATALYTIC
SPLITTING
OF
WATER
TO
PRODUCE
HYDROGEN
119
XIANJIE
CHEN
AND
YONGFA
ZHU
9.1
9.2
9.2.1
9.2.2
INTRODUCTION
119
ORGANIC
SUPRAMOLECULAR
PHOTOCATALYSTS
FOR
WATER
SPLITTING
121
PDI-BASED
SUPRAMOLECULAR
PHOTOCATALYSTS
FOR
HYDROGEN
PRODUCTION
123
PORPHYRIN-BASED
SUPRAMOLECULAR
PHOTOCATALYSTS
FOR
HYDROGEN
PRODUCTION
127
9.3
CONCLUSION
AND
PERSPECTIVES
133
REFERENCES
134
10
VISIBLE
LIGHT-RESPONSIVE
TIO,
THIN-FILM
PHOTOCATALYSTS
FOR
THE
SEPARATE
EVOLUTION
OF
H
2
AND
02
FROM
WATER
137
ASWOTHY
RAJAN,
BERNAURDSHAW
NEPPOLIAN,
AND
MASAKAZU
ANPO
10.1
10.1.1
10.1.2
INTRODUCTION
137
FABRICATION
OF
VISIBLE
LIGHT-RESPONSIVE
TIO
2
THIN
FILMS
138
CHARACTERISTICS
OF
THE
VISIBLE
LIGHT-RESPONSIVE
TIO
2
THIN
FILMS
FABRICATED
BY
RF-MS
DEPOSITION
METHOD
138
CONTENTS
IX
10.1.2.1
EFFECT
OF
THE
DISTANCE
BETWEEN
THE
TARGET
AND
SUBSTRATE
(DR-S)
AND
SUBSTRATE
TEMPERATURE
(TS)
139
10.1.2.2
10.1.2.3
10.2
EFFECT
OF
THE
PRESSURE
OF
SPUTTERING
AR
GAS
141
EFFECT
OF
SURFACE
TREATMENTS
ON
THE
TIO,
THIN
FILMS
142
PHOTOELECTROCHEMICAL
PROPERTIES
OF
TIO
2
THIN
FILMS
FABRICATED
BY
RF-MS
METHOD
144
10.2.1
SETUP
THE
REACTOR
FOR
SEPARATE
EVOLUTION
OF
H2
AND
O
2
IN THE
PHOTOCATALYTIC
SPLITTING
OF
H,O
144
10.3
SEPARATE
EVOLUTION
OF
PURE
H2
AND
O
2
USING
A
VISIBLE
LIGHT-RESPONSIVE
TIO,
THIN-FILM
PHOTOCATALYST
FABRICATED
BY RF-MS
DEPOSITION
METHOD
AND
THE
FACTORS
AFFECTING
THE
EFFICIENCY
145
10.4
TOWARD
GREENER
PATHWAY:
INTEGRATION
OF
THE
REACTION
SYSTEM
OF
THE
PHOTOCATALYTIC
SPLITTING
OF
WATER
WITH
AN
ARTIFICIAL
PLANT
FACTORY
149
10.5
CONCLUSION
AND
PERSPECTIVE
150
REFERENCES
151
11
DEVELOPMENT
OF
HIGHLY
EFFICIENT
CDS-BASED
PHOTOCATALYSTS
FOR
HYDROGEN
PRODUCTION:
STRUCTURAL
MODIFICATION,
DURABILITY,
AND
MECHANISM
153
WEI
LI
AND
CHUANYI
WANG
11.1
11.2
11.2.1
11.2.2
11.2.3
11.2.4
11.3
INTRODUCTION
153
CDS-BASED
PHOTOCATALYSIS
154
CONSTRUCTION
OF
P-N
TYPE
BI,O,/CDS
HETEROSTRUCTURE
154
CONSTRUCTION
OF
CDS@H-BN
HETEROSTRUCTURE
ON
RGO
NANOSHEETS
156
N-DOPED
CDS
NANOCATALYST
158
PD
SINGLE-ATOM
DECORATED
CDS
NANOCATALYST
163
SUMMARY
AND
PROSPECT
167
REFERENCES
167
12
THEORETICAL
STUDIES
ON
PHOTOCATALYTIC
H2
PRODUCTION
FROM
H
2
O
171
KANGKANG
LIAN,
ZHONGHUI
WANG,
AND
SEN
LIN
12.1
12.2
12.2.1
12.2.2
12.3
12.3.1
12.3.2
12.4
INTRODUCTION
171
3D
PHOTOCATALYSTS
172
BAND
STRUCTURE
ENGINEERING
172
CARRIER
SEPARATION
174
2D
PHOTOCATALYSTS
177
BAND
STRUCTURE
ENGINEERING
177
CARRIER
SEPARATION
181
SUMMARY
AND
PERSPECTIVES
183
ACKNOWLEDGMENTS
184
REFERENCES
184
CONTENTS
PART
III
PHOTOCATALYTIC
REDUCTION
OF
CO2
AND
FIXATION
OF
N2
187
13
PROGRESS
IN
DEVELOPMENT
OF
COCATALYSTS
FOR
THE
PHOTOCATALYTIC
CONVERSION
OF
CO2
USING
H2O
AS
AN
ELECTRON
DONOR
189
XUANWEN
XU,
TSUNEHIRO
TANAKA,
AND
KENTARO
TERAMURA
13.1
13.1.1
13.1.2
13.2
BACKGROUND
189
PHOTOCATALYSIS
189
PHOTOCATALYTIC
CONVERSION
OF
CO
2
USING
H,O
AS
AN
ELECTRON
DONOR
189
COCATALYSTS
MATTER:
HIGHLY
SELECTIVE
PHOTOCATALYTIC
CONVERSION
OF
CO
2
USING
H2O
AS
THE
ELECTRON
DONOR
191
13.2.1
13.2.1.1
13.2.1.2
13.2.2
METAL
COCATALYSTS
191
COMPARISON
OF
PT,
PD,
AU,
CU,
ZN,
AND
AG
191
AG
NANOPARTICLES
191
FACTORS
INFLUENCING
THE
PERFORMANCE
OF
AG
NANOPARTICLES
AS
COCATALYSTS
192
13.2.2.1
13.2.2.2
13.2.2.3
13.2.3
13.3
13.4
ADDITIVES
192
PHOTOCATALYST
SURFACE
PROPERTIES
192
SIZES,
LOCATION,
AND
MORPHOLOGIES
OF
AG
NANOPARTICLES
193
DUAL
COCATALYSTS
BASED
ON
AG
NANOPARTICLES
193
NONMETAL
COCATALYSTS
194
CONCLUSION
AND
PERSPECTIVES
194
REFERENCES
195
14
PREPARATION,
CHARACTERIZATION,
AND
PHOTOCATALYSTS
'
APPLICATION
OF
SILICAS/SILICATES
WITH
NANOSPACES
CONTAINING
SINGLE-SITE
TI-OXO
SPECIES
199
MASASHI
MORITA
AND
MAKOTO
OGAWA
14.1
14.2
INTRODUCTION
199
MATERIALS
VARIATION
OF
SINGLE-SITE
TI-OXO
SPECIES
IN
NANOSPACE
MATERIALS
200
14.2.1
14.2.2
14.2.3
14.2.4
14.3
14.3.1
14.3.2
14.4
CHARACTERIZATION
OF
TI-OXO
SPECIES
200
TI-CONTAINING
ZEOLITES
AND
MESOPOROUS
SILICAS/SILICATES
200
MOLECULAR
CLUSTER
OF
TI
SINGLE-SITE
IN
SILICA-BASED
MATERIALS
204
OTHER
TI-CONTAINING
NANOSPACE
MATERIALS
205
APPLICATIONS
207
PHOTOCATALYTIC
REDUCTION
OF
CO
2
WITH
H
2
O
207
OTHER
APPLICATION
209
CONCLUSIONS
AND
FUTURE
PERSPECTIVES
210
REFERENCES
210
15
SURFACE
COORDINATION
IMPROVED
PHOTOCATALYTIC
FIXATION
OF
CO
2
OVER
2D
OXIDE
NANOSHEETS
213
ZHIWEN
WANG
AND
YUJIE
SONG
15.1
INTRODUCTION
213
CONTENTS
XI
15.2
15.3
15.4
15.5
DESIGN
OF
THE
CATALYST
215
PREPARATION
OF
2D
TRANSITION
METAL
OXIDE
NANOSHEETS
218
COORDINATION
OF
CO
2
219
CONCLUSION
AND
PROSPECTS
222
REFERENCES
222
16
RECENT
PROGRESS
ON
LAYERED
DOUBLE
HYDROXIDES-BASED
NANOMATERIALS
FOR
SOLAR
ENERGY
CONVERSION
225
SHA
BAI,
CHENJUN
NING,
TIANYANG
SHEN,
AND
YU-FEI
SONG
16.1
16.2
16.3
16.3.1
16.3.2
16.3.3
16.3.4
16.4
INTRODUCTION
225
PREDICTION
OF
THE
REACTIVITY
VIA
DFT
CALCULATIONS
227
CONTROLLABLE
SYNTHESIS
229
MODULATION
OF
THE
COMPOSITIONS
229
MODULATION
OF
THE
COORDINATION
ENVIRONMENT
231
HYBRIDIZATION
LDHS
WITH
OTHER
MATERIALS
233
TOPOLOGICAL
TRANSFORMATION
OF
LDHS
233
SUMMARY
AND
PERSPECTIVES
235
ACKNOWLEDGMENTS
236
REFERENCES
236
17
THE
SIGNIFICANCE
AND
CURRENT
STATUS
OF
PHOTOCATALYTIC
N2
FIXATION
STUDY
239
TINGTING
DONG
AND
GUOHUI
DONG
17.1
17.2
17.3
17.3.1
17.3.2
17.3.3
17.4
17.4.1
17.4.2
17.4.3
17.4.4
17.5
INTRODUCTION
239
THE
MECHANISM
OF
PHOTOCATALYTIC
N
2
FIXATION
240
INFLUENCING
FACTORS
OF
PHOTOCATALYTIC
N
2
FIXATION
EFFICIENCY
241
N
2
ADSORPTION
ABILITY
OF
PHOTOCATALYST
242
INTRINSIC
PROPERTIES
OF
PHOTOCATALYSTS
242
ENVIRONMENTAL
FACTORS
OF
PHOTOCATALYTIC
REACTION
242
PHOTOCATALYTIC
N
2
FIXATION
MATERIALS
243
METAL
OXIDE
243
HYDROUS
METAL
OXIDE
246
METAL
SULFIDE
246
OTHER
MATERIALS
247
CHALLENGES
AND
OPPORTUNITIES
248
REFERENCES
249
18
PHOTOCATALYTIC
N2
FIXATION:
A
STEP
CLOSER
TO
THE
SOLAR
FARM
253
YUANYI
ZHOU,
COILIN
XIAO,
SONGMEI
SUN,
XIAOMAN
LI,
AND
WENZHONG
WANG
18.1
18.2
18.3
18.4
INTRODUCTION
253
PHOTOCATALYTIC
N
2
FIXATION
254
CURRENT
PROGRESS
255
CHALLENGES
AND
OPPORTUNITIES
263
REFERENCES
265
XII
CONTENTS
PART
IV
APPLICATIONS
OF
PHOTOCATALYSIS
267
19
PHOTOCATALYSIS
FOR
POLLUTION
REMEDIATION
269
REN
SU
19.1
19.1.1
19.1.2
19.2
BASIC
CONCEPT
269
CONSIDERATION
OF
PHOTOCATALYSTS
FOR
POLLUTANT
REMEDIATION
269
CONSIDERATION
OF
REACTION
CONDITIONS
271
REACTANTS,
PRODUCTS,
AND
INTERMEDIATES
ANALYSIS
AND
REACTION
MECHANISMS
272
19.2.1
19.2.2
19.2.3
19.2.4
19.3
DIRECT
ANALYSIS
OF
DECOMPOSED
PRODUCTS
273
INDIRECT:
CONSUMPTION
OF
DYE
MOLECULES
275
RADICALS
SPECIES
275
REACTION
INTERMEDIATES
279
CONCLUDING
REMARKS
AND
PERSPECTIVES
281
ACKNOWLEDGMENT
282
REFERENCES
282
20
BIOMIMETIC
PHOTOCATALYTIC
WASTEWATER
TREATMENT:
FROM
LAB-SCALE
TO
COMMERCIAL
OPERATION
285
JIAQIANG
WANG
F
XIAOQIAN
MA
F
LIANG
JIANG,
JIAO
HE,
DAOMEI
CHEN,
AND
YONGJUAN
CHEN
20.1
20.2
20.3
20.4
INTRODUCTION
285
BIOTEMPLATED
PHOTOCATALYSTS
286
PHOTOCATALYTIC
REACTORS
287
EXAMPLES
FOR
COMMERCIAL
OPERATIONS
OF
SKID-MOUNTED
PHOTOCATALYTIC
REACTORS
290
20.4.1
20.4.2
20.4.3
TREATMENT
OF
WASTEWATER
AT
THE
EXPRESSWAY
SERVICE
AREA
290
TREATMENT
OF
WASTEWATER
AT
THE
HYDROPOWER
STATIONS
292
ADVANCED
TREATMENT
OF
WASTEWATER
FROM
LIGNITE
GASIFICATION
AFTER
BIOLOGICAL
PROCESSES
292
20.5
CHALLENGES
AND
OPPORTUNITIES
292
ACKNOWLEDGMENTS
294
REFERENCES
294
21
PREPARATION
OF
HIGHLY
FUNCTIONAL
TIO2-BASED
THIN-FILM
PHOTOCATALYSTS
BY
ION
ENGINEERING
TECHNIQUES,
PHOTOCATALYSIS,
AND
PHOTO-INDUCED
SUPERHYDROPHILICITY
297
MASATO
TAKEUCHI
AND
MASAKAZU
ANPO
21.1
21.2
21.2.1
INTRODUCTION
297
ION
ENGINEERING
TECHNIQUES
TO
PREPARE
THIN-FILM
PHOTOCATALYSTS
298
TRANSPARENT
TIO,
THIN-FILM
PHOTOCATALYSTS
PREPARED
BY
IONIZED
CLUSTER
BEAM
(ICB)
DEPOSITION
METHOD
298
21.2.2
FUNCTIONAL
TIO
2
-SIO
2
AND
TIO
2
-B
2
O
3
BINARY
OXIDE
THIN-FILM
PHOTOCATALYSTS
PREPARED
BY
MULTI-ION
SOURCE
IONIZED
CLUSTER
BEAM
(ICB)
DEPOSITION
METHOD
303
CONTENTS
|
XIII
21.2.3
PREPARATION
OF
CRYSTALLINE
TIO,
THIN-FILM
PHOTOCATALYSTS
ON THE
POLYCARBONATE
SUBSTRATE
BY
AN
RF-MAGNETRON
SPUTTERING
(RF-MS)
METHOD
306
21.3
CONCLUSIONS
307
REFERENCES
308
22
THE
SURFACE-RELATED
PHOTOCATALYSIS
AND
SUPERWETTABILITY
311
JING
PAN
AND
FAN
XIA
22.1
22.2
22.3
22.4
22.5
INTRODUCTION
311
SURFACES
WITH
PHOTOCATALYTIC
ACTIVITY
312
SURFACES
WITH
SUPERWETTABILITY
314
SURFACES
WITH
BOTH
PHOTOCATALYTIC
ACTIVITY
AND
SUPERWETTABILITY
318
CONCLUSION
AND
OUTLOOK
321
ACKNOWLEDGEMENT
322
REFERENCES
322
INDEX
325 |
| adam_txt |
CONTENTS
UV-VISIBLE
PHOTOCATALYSIS
FOR
CLEAN
ENERGY
PRODUCTION
AND
POLLUTION
REMEDIATION:
MATERIALS,
REACTION
MECHANISMS,
AND
APPLICATIONS
-
A
PREFACE
XV
LIST
OF
CONTRIBUTORS
XIX
1
INTRODUCTION
1
XINCHEN
WANG,
MASAKAZU
ANPO,
AND
XIANZHI
FU
1.1
CHALLENGES
AND
OBJECTIVES
IN
THE
USE
OF
SOLAR
ENERGY
1
1.2
BRIEF
HISTORY
OF
THE
PROGRESS
IN
PHOTOCATALYSTS
AND
PHOTOCATALYTIC
REACTIONS
2
1.3
BRIEF
INTRODUCTION
OF
THE
CHAPTERS
4
1.4
CONCLUSION
AND
PERSPECTIVES
6
REFERENCES
6
PART
I
FUNDAMENTALS
OF
PHOTOCATALYSIS
9
2
VISIBLE-LIGHT
ACTIVE
PHOTOCATALYSTS
IN
POLLUTANT
DEGRADATION/
CONVERSION
WITH
SIMULTANEOUS
HYDROGEN
PRODUCTION
11
AMENE
NASERI,
MORASAE
SAMADI,
AND
ALIREZA
Z,
MOSHFEGH
2.1
INTRODUCTION
11
2.2
PRINCIPLES
OF
SIMULTANEOUS
PHOTOCATALYSIS
13
2.2.1
DUAL-FUNCTIONAL
VS.
CONVENTIONAL
PHOTOCATALYSTS
13
2.2.2
REACTION
EFFICIENCY
EVALUATION
15
2.3
COOPERATION
PHOTOCATALYSTS
FOR
ORGANIC
POLLUTANT
DEGRADATION/CONVERSION
AND
H
2
FUEL
PRODUCTION
16
2.3.1
PHOTOCATALYST
DESIGN
16
2.3.2
ORGANIC
SUBSTRATE
TYPE
19
2.3.3
REACTION
CONDITIONS
21
2.4
CONCLUSIONS
23
ACKNOWLEDGMENT
24
REFERENCES
24
VI
CONTENTS
3
SELECTIVE
OXIDATION
OF
ALCOHOLS
USING
CARBON
NITRIDE
PHOTOCATALYSTS
27
OLEKSANDR
SAVATEEV
3.1
3.2
3.3
3.4
3.4.1
3.4.2
3.4.3
3.4.4
INTRODUCTION
27
HEPTAZINE-BASED
GRAPHITIC
CARBON
NITRIDES
28
MECHANISM
OF
ALCOHOLS
OXIDATION
BY
CARBON
NITRIDES
29
IMPROVING
SELECTIVITY
OF
ALCOHOLS
OXIDATION
32
OPTIMIZING
REACTION
TIME
AND
CONVERSION
OF
ALCOHOL
32
SUBSTITUTING
02
BY
OTHER
OXIDANTS
35
COMBINING
CARBON
NITRIDE
PHOTOCATALYST
WITH
H
2
EVOLVING
CATALYST
36
EMPLOYING
PHOTO-CHARGEABLE
IONIC
CARBON
NITRIDES
UNDER
ANAEROBIC
CONDITIONS
36
3.5
CONCLUSION
38
REFERENCES
38
4
APPLICATION
OF
S-SCHEME
HETEROJUNCTION
PHOTOCATALYST
41
CHUANBIAO
BIE
AND
JIAGUO
YU
4.1
4.2
4.3
4.4
4.5
4.6
4.7
4.8
INTRODUCTION
41
HYDROGEN
EVOLUTION
44
CARBON
DIOXIDE
REDUCTION
46
POLLUTANT
DEGRADATION
48
HYDROGEN
PEROXIDE
PRODUCTION
50
DISINFECTION
AND
STERILIZATION
52
ORGANIC
SYNTHESIS
54
CONCLUSION
AND
OUTLOOK
55
REFERENCES
56
5
THE
ROLE
OF
THE
DEFECTS
ON
THE
PHOTOCATALYTIC
REACTIONS
ON
ZNO
59
ZHONGMING
WANG,
WENXIN
DAI,
AND
XIANZHI
FU
5.1
5.2
5.2.1
5.2.2
5.2.3
5.3
INTRODUCTION
59
TYPES
OF
SURFACE
DEFECTS
AND
THEIR
ELECTRICAL
STRUCTURE
60
OXYGEN
VACANCIES
60
ZINC
VACANCIES
60
INTERSTITIAL
OXYGEN
AND
ZINC
61
CONTROLLABLE
PREPARATION
AND
CHARACTERIZATION
OF
SURFACE
VACANCY
DEFECTS
62
5.3.1
5.3.1.1
5.3.1.2
5.3.1.3
CONTROLLABLE
PREPARATION
OF
SURFACE
VACANCY
DEFECTS
62
FORMATION
OF
VACANCY
DEFECTS
VIA
ANNEALING
AT
DIFFERENT
CONDITIONS
62
FORMATION
OF
VACANCY
DEFECTS
VIA
METAL
AND
NONMETAL
DOPING
63
FORMATION
OF
ZNO
WITH
VACANCY
DEFECTS
VIA
HIGH-ENERGY
ELECTRONS
AND
LIGHT
IRRADIATION
64
5.3.2
5.3.2.1
5.3.2.2
CHARACTERIZATION
OF
SURFACE
VACANCY
DEFECTS
64
RAMAN
SPECTROSCOPY
64
X-RAY
PHOTOELECTRON
(XPS)
SPECTROSCOPY
64
CONTENTS
VII
5.3.23
53.2.4
5.4
5.4.1
5.4.2
ELECTRON
PARAMAGNETIC
RESONANCE
(EPR)
SPECTROSCOPY
65
PHOTOLUMINESCENCE
(PL)
SPECTRA
66
MECHANISM
OF
SURFACE
DEFECTS
ON
PHOTOCATALYTIC
REACTION
BEHAVIOR
66
ROLES
OF
DEFECTS
IN
GAS
ADSORPTION
66
DEFECTS
FUNCTION
AS
A
DOUBLE-EDGED
SWORD
IN
REGULATING
PHOTOCATALYTIC
PERFORMANCE
69
5.4.3
5.43.1
5.43.2
DEFECT
ENGINEERING
REGULATES
PHOTOCORROSION
OF
ZNO
70
RELATIONSHIP
BETWEEN
DEFECTS
AND
PHOTOCORROSION
70
CONSTRUCTING
AN
ELECTRON
CHANNEL
THROUGH
ELECTRON
TRANSFER
UPON
THE
ADSORPTION
OF
MOLECULES
AND
ITS
ROLE
IN INHIBITING
PHOTOCORROSION
OF
ZNO
70
5.5
CONCLUSIONS
AND
PROSPECTS
72
REFERENCES
73
PART
II
PHOTOCATALYTIC
SPLITTING
OF
WATER
TO
PRODUCE
HYDROGEN
77
6
STRATEGIES
FOR
PROMOTING
OVERALL
WATER
SPLITTING
WITH
PARTICULATE
PHOTOCATALYSTS
VIA
SINGLE-STEP
VISIBLE-LIGHT
PHOTOEXCITATION
79
JIADONG
XIAO,
XIAOPING
TAO,
AND
KAZUNARI
DOMEN
6.1
6.2
INTRODUCTION
79
SRTIO,:AL/RH/CR,O,/COOOH:
A
MODEL
PARTICULATE
OWS
PHOTOCATALYST
81
6.3
CURRENT
STRATEGIES
PROMOTING
OWS
WITH
VISIBLE-LIGHT-ACTIVATED
PARTICULATE
PHOTOCATALYSTS
82
6.3.1
63.1.1
63.1.2
6.3.2
6.3.3
6.4
DEFECT
CONTROL
OF
THE
SEMICONDUCTOR
MATERIAL
83
NEW
PRECURSOR
DESIGNS
83
ALIOVALENT
DOPING
84
DUAL-COCATALYST
LOADING
86
SURFACE
NANOLAYER
COATING
88
CONCLUDING
REMARKS
89
ACKNOWLEDGMENTS
89
REFERENCES
90
7
INTEGRATION
OF
REDOX
COCATALYSTS
FOR
PHOTOCATALYTIC
HYDROGEN
EVOLUTION
93
MUHAMMAD
TAYYAB,
YUJIE
LIU,
ZEHONG
XU,
SUMMAN
AMAN,
WENHUI
YUE,
RANA
M.
IRFAN,
LIANG
ZHOU,
AND
J
INLONG
ZHANG
7.1
7.2
7.2.1
INTRODUCTION
93
FUNDAMENTALS
OF
DUAL
COCATALYSTS
95
CLASSIFICATION
OF
COCATALYSTS
ON
THE
BASIS
OF
THE
FUNCTIONAL
MECHANISM
95
7.2.2
THE
ADVANTAGES
OF
THE
DESIGN
OF
DUAL
COCATALYSTS
96
VIII
CONTENTS
7.2.3
7.2.4
7.3
THE
EFFECT
OF
REDOX
COCATALYST
PARAMETERS
ON
PHOTOCATALYSIS
96
DESIGN
PRINCIPLES
OF
DUAL
COCATALYSTS
97
RECENT
ADVANCES
IN
THE
CONFIGURATION
OF
DUAL
REDOX
COCATALYSTS/PHOTOCATALYST
98
7.3.1
7.3.2
7.3.2.1
7.3.2.2
7.3.2.3
7.3.2.4
7.4
7.5
RANDOM
DISTRIBUTION
98
SPATIALLY
SEPARATED
DISTRIBUTION
99
TIP/SIDE
DISTRIBUTION
99
YORK-SHELL
DISTRIBUTION
101
FACET-DEPENDENT
DISTRIBUTION
102
CENTER/EDGE
DISTRIBUTION
103
MAJOR
TYPES
OF
PHOTOCATALYTIC
WATER
SPLITTING
103
CONCLUSIONS
105
REFERENCES
105
8
POLYMERIC
CARBON
NITRIDE-BASED
MATERIALS
IN
AQUEOUS
SUSPENSIONS
FOR
WATER
PHOTO-SPLITTING
AND
PHOTO-REFORMING
OF
BIOMASS
AQUEOUS
SOLUTIONS
TO
GENERATE
H2
109
E.I.
GARCIA-LOPEZ,
G.
MARCI,
AND
L.
PALMISANO
8.1
8.2
8.3
INTRODUCTION
109
G-C
3
N
4
-BASED
PHOTOCATALYSTS
FOR
H2
PRODUCTION
112
CONCLUSIONS
116
REFERENCES
116
9
ORGANIC
SUPRAMOLECULAR
MATERIALS
FOR
PHOTOCATALYTIC
SPLITTING
OF
WATER
TO
PRODUCE
HYDROGEN
119
XIANJIE
CHEN
AND
YONGFA
ZHU
9.1
9.2
9.2.1
9.2.2
INTRODUCTION
119
ORGANIC
SUPRAMOLECULAR
PHOTOCATALYSTS
FOR
WATER
SPLITTING
121
PDI-BASED
SUPRAMOLECULAR
PHOTOCATALYSTS
FOR
HYDROGEN
PRODUCTION
123
PORPHYRIN-BASED
SUPRAMOLECULAR
PHOTOCATALYSTS
FOR
HYDROGEN
PRODUCTION
127
9.3
CONCLUSION
AND
PERSPECTIVES
133
REFERENCES
134
10
VISIBLE
LIGHT-RESPONSIVE
TIO,
THIN-FILM
PHOTOCATALYSTS
FOR
THE
SEPARATE
EVOLUTION
OF
H
2
AND
02
FROM
WATER
137
ASWOTHY
RAJAN,
BERNAURDSHAW
NEPPOLIAN,
AND
MASAKAZU
ANPO
10.1
10.1.1
10.1.2
INTRODUCTION
137
FABRICATION
OF
VISIBLE
LIGHT-RESPONSIVE
TIO
2
THIN
FILMS
138
CHARACTERISTICS
OF
THE
VISIBLE
LIGHT-RESPONSIVE
TIO
2
THIN
FILMS
FABRICATED
BY
RF-MS
DEPOSITION
METHOD
138
CONTENTS
IX
10.1.2.1
EFFECT
OF
THE
DISTANCE
BETWEEN
THE
TARGET
AND
SUBSTRATE
(DR-S)
AND
SUBSTRATE
TEMPERATURE
(TS)
139
10.1.2.2
10.1.2.3
10.2
EFFECT
OF
THE
PRESSURE
OF
SPUTTERING
AR
GAS
141
EFFECT
OF
SURFACE
TREATMENTS
ON
THE
TIO,
THIN
FILMS
142
PHOTOELECTROCHEMICAL
PROPERTIES
OF
TIO
2
THIN
FILMS
FABRICATED
BY
RF-MS
METHOD
144
10.2.1
SETUP
THE
REACTOR
FOR
SEPARATE
EVOLUTION
OF
H2
AND
O
2
IN THE
PHOTOCATALYTIC
SPLITTING
OF
H,O
144
10.3
SEPARATE
EVOLUTION
OF
PURE
H2
AND
O
2
USING
A
VISIBLE
LIGHT-RESPONSIVE
TIO,
THIN-FILM
PHOTOCATALYST
FABRICATED
BY RF-MS
DEPOSITION
METHOD
AND
THE
FACTORS
AFFECTING
THE
EFFICIENCY
145
10.4
TOWARD
GREENER
PATHWAY:
INTEGRATION
OF
THE
REACTION
SYSTEM
OF
THE
PHOTOCATALYTIC
SPLITTING
OF
WATER
WITH
AN
ARTIFICIAL
PLANT
FACTORY
149
10.5
CONCLUSION
AND
PERSPECTIVE
150
REFERENCES
151
11
DEVELOPMENT
OF
HIGHLY
EFFICIENT
CDS-BASED
PHOTOCATALYSTS
FOR
HYDROGEN
PRODUCTION:
STRUCTURAL
MODIFICATION,
DURABILITY,
AND
MECHANISM
153
WEI
LI
AND
CHUANYI
WANG
11.1
11.2
11.2.1
11.2.2
11.2.3
11.2.4
11.3
INTRODUCTION
153
CDS-BASED
PHOTOCATALYSIS
154
CONSTRUCTION
OF
P-N
TYPE
BI,O,/CDS
HETEROSTRUCTURE
154
CONSTRUCTION
OF
CDS@H-BN
HETEROSTRUCTURE
ON
RGO
NANOSHEETS
156
N-DOPED
CDS
NANOCATALYST
158
PD
SINGLE-ATOM
DECORATED
CDS
NANOCATALYST
163
SUMMARY
AND
PROSPECT
167
REFERENCES
167
12
THEORETICAL
STUDIES
ON
PHOTOCATALYTIC
H2
PRODUCTION
FROM
H
2
O
171
KANGKANG
LIAN,
ZHONGHUI
WANG,
AND
SEN
LIN
12.1
12.2
12.2.1
12.2.2
12.3
12.3.1
12.3.2
12.4
INTRODUCTION
171
3D
PHOTOCATALYSTS
172
BAND
STRUCTURE
ENGINEERING
172
CARRIER
SEPARATION
174
2D
PHOTOCATALYSTS
177
BAND
STRUCTURE
ENGINEERING
177
CARRIER
SEPARATION
181
SUMMARY
AND
PERSPECTIVES
183
ACKNOWLEDGMENTS
184
REFERENCES
184
CONTENTS
PART
III
PHOTOCATALYTIC
REDUCTION
OF
CO2
AND
FIXATION
OF
N2
187
13
PROGRESS
IN
DEVELOPMENT
OF
COCATALYSTS
FOR
THE
PHOTOCATALYTIC
CONVERSION
OF
CO2
USING
H2O
AS
AN
ELECTRON
DONOR
189
XUANWEN
XU,
TSUNEHIRO
TANAKA,
AND
KENTARO
TERAMURA
13.1
13.1.1
13.1.2
13.2
BACKGROUND
189
PHOTOCATALYSIS
189
PHOTOCATALYTIC
CONVERSION
OF
CO
2
USING
H,O
AS
AN
ELECTRON
DONOR
189
COCATALYSTS
MATTER:
HIGHLY
SELECTIVE
PHOTOCATALYTIC
CONVERSION
OF
CO
2
USING
H2O
AS
THE
ELECTRON
DONOR
191
13.2.1
13.2.1.1
13.2.1.2
13.2.2
METAL
COCATALYSTS
191
COMPARISON
OF
PT,
PD,
AU,
CU,
ZN,
AND
AG
191
AG
NANOPARTICLES
191
FACTORS
INFLUENCING
THE
PERFORMANCE
OF
AG
NANOPARTICLES
AS
COCATALYSTS
192
13.2.2.1
13.2.2.2
13.2.2.3
13.2.3
13.3
13.4
ADDITIVES
192
PHOTOCATALYST
SURFACE
PROPERTIES
192
SIZES,
LOCATION,
AND
MORPHOLOGIES
OF
AG
NANOPARTICLES
193
DUAL
COCATALYSTS
BASED
ON
AG
NANOPARTICLES
193
NONMETAL
COCATALYSTS
194
CONCLUSION
AND
PERSPECTIVES
194
REFERENCES
195
14
PREPARATION,
CHARACTERIZATION,
AND
PHOTOCATALYSTS
'
APPLICATION
OF
SILICAS/SILICATES
WITH
NANOSPACES
CONTAINING
SINGLE-SITE
TI-OXO
SPECIES
199
MASASHI
MORITA
AND
MAKOTO
OGAWA
14.1
14.2
INTRODUCTION
199
MATERIALS
VARIATION
OF
SINGLE-SITE
TI-OXO
SPECIES
IN
NANOSPACE
MATERIALS
200
14.2.1
14.2.2
14.2.3
14.2.4
14.3
14.3.1
14.3.2
14.4
CHARACTERIZATION
OF
TI-OXO
SPECIES
200
TI-CONTAINING
ZEOLITES
AND
MESOPOROUS
SILICAS/SILICATES
200
MOLECULAR
CLUSTER
OF
TI
SINGLE-SITE
IN
SILICA-BASED
MATERIALS
204
OTHER
TI-CONTAINING
NANOSPACE
MATERIALS
205
APPLICATIONS
207
PHOTOCATALYTIC
REDUCTION
OF
CO
2
WITH
H
2
O
207
OTHER
APPLICATION
209
CONCLUSIONS
AND
FUTURE
PERSPECTIVES
210
REFERENCES
210
15
SURFACE
COORDINATION
IMPROVED
PHOTOCATALYTIC
FIXATION
OF
CO
2
OVER
2D
OXIDE
NANOSHEETS
213
ZHIWEN
WANG
AND
YUJIE
SONG
15.1
INTRODUCTION
213
CONTENTS
XI
15.2
15.3
15.4
15.5
DESIGN
OF
THE
CATALYST
215
PREPARATION
OF
2D
TRANSITION
METAL
OXIDE
NANOSHEETS
218
COORDINATION
OF
CO
2
219
CONCLUSION
AND
PROSPECTS
222
REFERENCES
222
16
RECENT
PROGRESS
ON
LAYERED
DOUBLE
HYDROXIDES-BASED
NANOMATERIALS
FOR
SOLAR
ENERGY
CONVERSION
225
SHA
BAI,
CHENJUN
NING,
TIANYANG
SHEN,
AND
YU-FEI
SONG
16.1
16.2
16.3
16.3.1
16.3.2
16.3.3
16.3.4
16.4
INTRODUCTION
225
PREDICTION
OF
THE
REACTIVITY
VIA
DFT
CALCULATIONS
227
CONTROLLABLE
SYNTHESIS
229
MODULATION
OF
THE
COMPOSITIONS
229
MODULATION
OF
THE
COORDINATION
ENVIRONMENT
231
HYBRIDIZATION
LDHS
WITH
OTHER
MATERIALS
233
TOPOLOGICAL
TRANSFORMATION
OF
LDHS
233
SUMMARY
AND
PERSPECTIVES
235
ACKNOWLEDGMENTS
236
REFERENCES
236
17
THE
SIGNIFICANCE
AND
CURRENT
STATUS
OF
PHOTOCATALYTIC
N2
FIXATION
STUDY
239
TINGTING
DONG
AND
GUOHUI
DONG
17.1
17.2
17.3
17.3.1
17.3.2
17.3.3
17.4
17.4.1
17.4.2
17.4.3
17.4.4
17.5
INTRODUCTION
239
THE
MECHANISM
OF
PHOTOCATALYTIC
N
2
FIXATION
240
INFLUENCING
FACTORS
OF
PHOTOCATALYTIC
N
2
FIXATION
EFFICIENCY
241
N
2
ADSORPTION
ABILITY
OF
PHOTOCATALYST
242
INTRINSIC
PROPERTIES
OF
PHOTOCATALYSTS
242
ENVIRONMENTAL
FACTORS
OF
PHOTOCATALYTIC
REACTION
242
PHOTOCATALYTIC
N
2
FIXATION
MATERIALS
243
METAL
OXIDE
243
HYDROUS
METAL
OXIDE
246
METAL
SULFIDE
246
OTHER
MATERIALS
247
CHALLENGES
AND
OPPORTUNITIES
248
REFERENCES
249
18
PHOTOCATALYTIC
N2
FIXATION:
A
STEP
CLOSER
TO
THE
SOLAR
FARM
253
YUANYI
ZHOU,
COILIN
XIAO,
SONGMEI
SUN,
XIAOMAN
LI,
AND
WENZHONG
WANG
18.1
18.2
18.3
18.4
INTRODUCTION
253
PHOTOCATALYTIC
N
2
FIXATION
254
CURRENT
PROGRESS
255
CHALLENGES
AND
OPPORTUNITIES
263
REFERENCES
265
XII
CONTENTS
PART
IV
APPLICATIONS
OF
PHOTOCATALYSIS
267
19
PHOTOCATALYSIS
FOR
POLLUTION
REMEDIATION
269
REN
SU
19.1
19.1.1
19.1.2
19.2
BASIC
CONCEPT
269
CONSIDERATION
OF
PHOTOCATALYSTS
FOR
POLLUTANT
REMEDIATION
269
CONSIDERATION
OF
REACTION
CONDITIONS
271
REACTANTS,
PRODUCTS,
AND
INTERMEDIATES
ANALYSIS
AND
REACTION
MECHANISMS
272
19.2.1
19.2.2
19.2.3
19.2.4
19.3
DIRECT
ANALYSIS
OF
DECOMPOSED
PRODUCTS
273
INDIRECT:
CONSUMPTION
OF
DYE
MOLECULES
275
RADICALS
SPECIES
275
REACTION
INTERMEDIATES
279
CONCLUDING
REMARKS
AND
PERSPECTIVES
281
ACKNOWLEDGMENT
282
REFERENCES
282
20
BIOMIMETIC
PHOTOCATALYTIC
WASTEWATER
TREATMENT:
FROM
LAB-SCALE
TO
COMMERCIAL
OPERATION
285
JIAQIANG
WANG
F
XIAOQIAN
MA
F
LIANG
JIANG,
JIAO
HE,
DAOMEI
CHEN,
AND
YONGJUAN
CHEN
20.1
20.2
20.3
20.4
INTRODUCTION
285
BIOTEMPLATED
PHOTOCATALYSTS
286
PHOTOCATALYTIC
REACTORS
287
EXAMPLES
FOR
COMMERCIAL
OPERATIONS
OF
SKID-MOUNTED
PHOTOCATALYTIC
REACTORS
290
20.4.1
20.4.2
20.4.3
TREATMENT
OF
WASTEWATER
AT
THE
EXPRESSWAY
SERVICE
AREA
290
TREATMENT
OF
WASTEWATER
AT
THE
HYDROPOWER
STATIONS
292
ADVANCED
TREATMENT
OF
WASTEWATER
FROM
LIGNITE
GASIFICATION
AFTER
BIOLOGICAL
PROCESSES
292
20.5
CHALLENGES
AND
OPPORTUNITIES
292
ACKNOWLEDGMENTS
294
REFERENCES
294
21
PREPARATION
OF
HIGHLY
FUNCTIONAL
TIO2-BASED
THIN-FILM
PHOTOCATALYSTS
BY
ION
ENGINEERING
TECHNIQUES,
PHOTOCATALYSIS,
AND
PHOTO-INDUCED
SUPERHYDROPHILICITY
297
MASATO
TAKEUCHI
AND
MASAKAZU
ANPO
21.1
21.2
21.2.1
INTRODUCTION
297
ION
ENGINEERING
TECHNIQUES
TO
PREPARE
THIN-FILM
PHOTOCATALYSTS
298
TRANSPARENT
TIO,
THIN-FILM
PHOTOCATALYSTS
PREPARED
BY
IONIZED
CLUSTER
BEAM
(ICB)
DEPOSITION
METHOD
298
21.2.2
FUNCTIONAL
TIO
2
-SIO
2
AND
TIO
2
-B
2
O
3
BINARY
OXIDE
THIN-FILM
PHOTOCATALYSTS
PREPARED
BY
MULTI-ION
SOURCE
IONIZED
CLUSTER
BEAM
(ICB)
DEPOSITION
METHOD
303
CONTENTS
|
XIII
21.2.3
PREPARATION
OF
CRYSTALLINE
TIO,
THIN-FILM
PHOTOCATALYSTS
ON THE
POLYCARBONATE
SUBSTRATE
BY
AN
RF-MAGNETRON
SPUTTERING
(RF-MS)
METHOD
306
21.3
CONCLUSIONS
307
REFERENCES
308
22
THE
SURFACE-RELATED
PHOTOCATALYSIS
AND
SUPERWETTABILITY
311
JING
PAN
AND
FAN
XIA
22.1
22.2
22.3
22.4
22.5
INTRODUCTION
311
SURFACES
WITH
PHOTOCATALYTIC
ACTIVITY
312
SURFACES
WITH
SUPERWETTABILITY
314
SURFACES
WITH
BOTH
PHOTOCATALYTIC
ACTIVITY
AND
SUPERWETTABILITY
318
CONCLUSION
AND
OUTLOOK
321
ACKNOWLEDGEMENT
322
REFERENCES
322
INDEX
325 |
| any_adam_object | 1 |
| any_adam_object_boolean | 1 |
| author2 | Wang, Xinchen Anpo, Masakazu 1946- Fu, Xianzhi |
| author2_role | edt edt edt |
| author2_variant | x w xw m a ma x f xf |
| author_GND | (DE-588)1217442359 (DE-588)1203405898 (DE-588)1217442480 (DE-588)171963172 |
| author_facet | Wang, Xinchen Anpo, Masakazu 1946- Fu, Xianzhi |
| building | Verbundindex |
| bvnumber | BV049072104 |
| classification_rvk | VE 8300 VE 7040 ZP 3700 VK 5570 |
| ctrlnum | (OCoLC)1387595348 (DE-599)DNB1270837575 |
| dewey-full | 665.81 541.351 621.31244 |
| dewey-hundreds | 600 - Technology (Applied sciences) 500 - Natural sciences and mathematics |
| dewey-ones | 665 - Industrial oils, fats, waxes & gases 541 - Physical chemistry 621 - Applied physics |
| dewey-raw | 665.81 541.351 621.31244 |
| dewey-search | 665.81 541.351 621.31244 |
| dewey-sort | 3665.81 |
| dewey-tens | 660 - Chemical engineering 540 - Chemistry and allied sciences 620 - Engineering and allied operations |
| discipline | Chemie / Pharmazie Elektrotechnik / Elektronik / Nachrichtentechnik Energietechnik |
| discipline_str_mv | Chemie / Pharmazie Elektrotechnik / Elektronik / Nachrichtentechnik Energietechnik |
| format | Book |
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| id | DE-604.BV049072104 |
| illustrated | Illustrated |
| index_date | 2024-07-03T22:27:28Z |
| indexdate | 2024-10-28T13:01:13Z |
| institution | BVB |
| institution_GND | (DE-588)16179388-5 |
| isbn | 9783527350506 3527350500 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-034334034 |
| oclc_num | 1387595348 |
| open_access_boolean | |
| owner | DE-703 DE-11 |
| owner_facet | DE-703 DE-11 |
| physical | xxxv, 340 Seiten Illustrationen, Diagramme |
| publishDate | 2023 |
| publishDateSearch | 2023 |
| publishDateSort | 2023 |
| publisher | Wiley-VCH |
| record_format | marc |
| spelling | UV-visible photocatalysis for clean energy production and pollution remediation materials, reaction mechanisms, and applications edited by Xinchen Wang, Masakazu Anpo, and Xianzhi Fu ; with a foreword by Professor Detlef Bahnemann Weinheim, Germany Wiley-VCH [2023] © 2023 xxxv, 340 Seiten Illustrationen, Diagramme txt rdacontent n rdamedia nc rdacarrier Wasserstofferzeugung (DE-588)4189271-9 gnd rswk-swf Sonnenstrahlung (DE-588)4139254-1 gnd rswk-swf Schadstoffverringerung (DE-588)4194323-5 gnd rswk-swf Fotokatalyse (DE-588)4193873-2 gnd rswk-swf Catalysis Chemie Chemistry Energie Energy Environmental Chemistry Environmental Science Environmental Studies Katalyse Photokatalyse Solar Energy & Photovoltaics Solarenergie Solarenergie u. Photovoltaik Umweltchemie Umweltforschung Umweltwissenschaften CH20: Umweltchemie CH40: Katalyse EG34: Solarenergie u. Photovoltaik EN60: Umweltwissenschaften Fotokatalyse (DE-588)4193873-2 s Sonnenstrahlung (DE-588)4139254-1 s Wasserstofferzeugung (DE-588)4189271-9 s Schadstoffverringerung (DE-588)4194323-5 s DE-604 Wang, Xinchen (DE-588)1217442359 edt Anpo, Masakazu 1946- (DE-588)1203405898 edt Fu, Xianzhi (DE-588)1217442480 edt Bahnemann, Detlef 1953- (DE-588)171963172 wpr Wiley-VCH (DE-588)16179388-5 pbl Erscheint auch als Online-Ausgabe, PDF 978-3-527-83797-7 Erscheint auch als Online-Ausgabe, EPUB 978-3-527-83798-4 Erscheint auch als Online-Ausgabe, oBook 978-3-527-83799-1 X:MVB http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-35050-6/ B:DE-101 application/pdf https://d-nb.info/1270837575/04 Inhaltsverzeichnis DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=034334034&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p dnb 20230623 DE-101 https://d-nb.info/provenance/plan#dnb 2\p dnb 20230623 DE-101 https://d-nb.info/provenance/plan#dnb 3\p dnb 20230623 DE-101 https://d-nb.info/provenance/plan#dnb |
| spellingShingle | UV-visible photocatalysis for clean energy production and pollution remediation materials, reaction mechanisms, and applications Wasserstofferzeugung (DE-588)4189271-9 gnd Sonnenstrahlung (DE-588)4139254-1 gnd Schadstoffverringerung (DE-588)4194323-5 gnd Fotokatalyse (DE-588)4193873-2 gnd |
| subject_GND | (DE-588)4189271-9 (DE-588)4139254-1 (DE-588)4194323-5 (DE-588)4193873-2 |
| title | UV-visible photocatalysis for clean energy production and pollution remediation materials, reaction mechanisms, and applications |
| title_auth | UV-visible photocatalysis for clean energy production and pollution remediation materials, reaction mechanisms, and applications |
| title_exact_search | UV-visible photocatalysis for clean energy production and pollution remediation materials, reaction mechanisms, and applications |
| title_exact_search_txtP | UV-visible photocatalysis for clean energy production and pollution remediation materials, reaction mechanisms, and applications |
| title_full | UV-visible photocatalysis for clean energy production and pollution remediation materials, reaction mechanisms, and applications edited by Xinchen Wang, Masakazu Anpo, and Xianzhi Fu ; with a foreword by Professor Detlef Bahnemann |
| title_fullStr | UV-visible photocatalysis for clean energy production and pollution remediation materials, reaction mechanisms, and applications edited by Xinchen Wang, Masakazu Anpo, and Xianzhi Fu ; with a foreword by Professor Detlef Bahnemann |
| title_full_unstemmed | UV-visible photocatalysis for clean energy production and pollution remediation materials, reaction mechanisms, and applications edited by Xinchen Wang, Masakazu Anpo, and Xianzhi Fu ; with a foreword by Professor Detlef Bahnemann |
| title_short | UV-visible photocatalysis for clean energy production and pollution remediation |
| title_sort | uv visible photocatalysis for clean energy production and pollution remediation materials reaction mechanisms and applications |
| title_sub | materials, reaction mechanisms, and applications |
| topic | Wasserstofferzeugung (DE-588)4189271-9 gnd Sonnenstrahlung (DE-588)4139254-1 gnd Schadstoffverringerung (DE-588)4194323-5 gnd Fotokatalyse (DE-588)4193873-2 gnd |
| topic_facet | Wasserstofferzeugung Sonnenstrahlung Schadstoffverringerung Fotokatalyse |
| url | http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-35050-6/ https://d-nb.info/1270837575/04 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=034334034&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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