Organometallic compounds: synthesis, reactions, and applications
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| Format: | Book |
| Language: | English |
| Published: |
Weinheim
Wiley-VCH
[2023]
|
| Subjects: | |
| Online Access: | http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-35178-7/ Inhaltsverzeichnis |
| Physical Description: | xxi, 420 Seiten Illustrationen |
| ISBN: | 9783527351787 3527351787 |
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| 084 | |a VH 9700 |0 (DE-625)147384:253 |2 rvk | ||
| 245 | 1 | 0 | |a Organometallic compounds |b synthesis, reactions, and applications |c edited by Dakeshwar Kumar Verma, Jeenat Aslam |
| 264 | 1 | |a Weinheim |b Wiley-VCH |c [2023] | |
| 264 | 4 | |c © 2023 | |
| 300 | |a xxi, 420 Seiten |b Illustrationen | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 0 | 7 | |a Metallorganische Chemie |0 (DE-588)4602390-2 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Metallorganische Verbindungen |0 (DE-588)4038906-6 |2 gnd |9 rswk-swf |
| 653 | |a CH40: Katalyse | ||
| 653 | |a CH72: Koordinationschemie | ||
| 653 | |a CH86: Organometallchemie | ||
| 653 | |a Catalysis | ||
| 653 | |a Chemie | ||
| 653 | |a Chemistry | ||
| 653 | |a Coordination Chemistry | ||
| 653 | |a Katalyse | ||
| 653 | |a Koordinationschemie | ||
| 653 | |a Metallorganische Verbindungen | ||
| 653 | |a Organometallchemie | ||
| 653 | |a Organometallic Chemistry | ||
| 655 | 7 | |0 (DE-588)4143413-4 |a Aufsatzsammlung |2 gnd-content | |
| 689 | 0 | 0 | |a Metallorganische Verbindungen |0 (DE-588)4038906-6 |D s |
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| 689 | 1 | 0 | |a Metallorganische Chemie |0 (DE-588)4602390-2 |D s |
| 689 | 1 | |5 DE-604 | |
| 700 | 1 | |a Verma, Dakeshwar Kumar |0 (DE-588)1289294488 |4 edt | |
| 700 | 1 | |a Aslam, Jeenat |0 (DE-588)1280155973 |4 edt | |
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| 776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe, EPUB |z 978-3-527-84093-9 |
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| adam_text | CONTENTS
PREFACE
XIX
ABOUT
THE
EDITORS
XXI
1
ORGANOMETALLIC
COMPOUNDS:
THE
FUNDAMENTAL
ASPECTS
1
GEETHA
B.
MARKANDEYA
AND
SRINIVASA
BUDAGUMPI
1.1
1.1.1
1.1.2
1.1.3
1.2
1.2.1
1.2.2
1.2.3
1.2.4
1.2.5
1.2.6
1.2.7
INTRODUCTION
1
ORGANOMETALLIC
CHEMISTRY
1
ORGANOMETALLIC
COMPOUNDS
1
STRUCTURE
OF
ORGANOMETALLIC
COMPOUND
1
MILESTONES
IN
ORGANOMETALLIC
COMPOUNDS
2
EQUATION
(1.1):
SYNTHESIS
OF
FIRST
ORGANOMETALLIC
COMPOUND
2
EQUATION
(1.2):
PREPARATION
OF
ZEISE
S
SALT
2
EQUATIONS
(1.3)-(1.5):
PREPARATION
OF
ORGANOCHLOROSILANE
COMPOUND
3
EQUATION
(1.6):
SYNTHESIS
OF
FIRST
METAL
CARBONYL
COMPOUND
3
EQUATION
(1.7):
SYNTHESIS
OF
FIRST
BINARY
METAL
CARBONYL
COMPLEX
3
EQUATION
(1.8):
BARBIER
REACTION
3
EQUATION
(1.9):
SYNTHESIS
OF
ORGANIC
COMPOUND
USING
A
GRIGNARD
REAGENT
4
1.2.8
1.2.9
1.2.10
1.2.11
1.2.12
1.2.13
1.2.14
1.2.15
1.2.16
1.3
1.4
1.5
1.5.1
1.5.1.1
1.5.1.2
EQUATIONS
(1.10)
AND
(1.11):
SYNTHESIS
OF
ALKYLLITHIUM
COMPOUND
4
EQUATIONS
(1.12)
AND
(1.13):
SYNTHESIS
OF
ORGANOLITHIUM
COMPOUND
4
EQUATION
(1.14):
HYDROFORMYLATION
REACTION
4
EQUATION
(1.15):
SYNTHESIS
OF
ORGANOCHLOROSILANE
COMPOUND
4
EQUATION
(1.16):
TRIMERIZATION
OF
ACETYLENE
5
EQUATION
(1.17):
SYNTHESIS
OF
FERROCENE
5
EQUATION
(1.18):
ASYMMETRIC
CATALYSIS
REACTION
5
EQUATION
(1.19):
PALLADIUM
CATALYZED
SUZUKI
COUPLING
REACTION
6
EQUATION
(1.20):
SYNTHESIS
OF
BUCKY
FERROCENE
8
STABILITY
OF
ORGANOMETALLIC
COMPOUNDS
9
PROPERTIES
OF
ORGANOMETALLIC
COMPOUNDS
9
BASIC
CONCEPTS
IN
ORGANOMETALLIC
COMPOUNDS
9
18-ELECTRON
RULE
9
STATEMENT
OF
18
ELECTRON
RULE
10
EXAMPLES
11
VI
J
CONTENTS
1.5.2
II
-BACK
BONDING
OR
BACK
DONATION
12
1.5.3
HAPTICITY
N
12
1.6
HAPTICITY
OF
LIGANDS
12
1.7
CHANGE
IN
HAPTICITY
13
1.8
HAPTICITY
VERSES
DENTICITY
14
1.9
COUNTING
OF
ELECTRONS
AND
FINDING
OUT
METAL-METAL
BONDS
15
1.9.1
CALCULATING
THE
NUMBER
OF
METAL-METAL
BONDS
15
1.9.2
WRITING
THE
PROBABLE
STRUCTURE
OF
COMPOUND
15
1.9.3
HOW
TO
DRAW
THE
PROBABLE
STRUCTURE
OF
NI(N
-C,H,)
(N3-C,H,)
15
1.9.4
HOW
TO
DRAW
THE
PROBABLE
STRUCTURE
OF
(U-CO)-[N5-CPRH],(CO)
15
1.10
METALS
OF
ORGANOMETALLIC
COMPOUNDS
16
1.10.1
ORGANOMETALLIC
COMPOUNDS
OF
TRANSITION
METALS
17
1.10.2
THE
BONDING
AND
STRUCTURE
IN
DIFFERENT
METAL
COMPLEXES
17
1.10.2.1
ALKENE
COMPLEXES
17
1.10.2.2
ALLYL
COMPLEXES
17
1.10.2.3
CARBONYL
COMPLEXES
17
1.10.2.4
METALLOCENES
18
1.10.2.5
DIHYDROGEN
COMPLEXES
18
1.10.2.6
TRANSITION
METAL
CARBENE
COMPLEX
18
1.11
IMPORTANCE OF
ORGANOMETALLIC
COMPOUNDS
19
1.11.1
TYPES
OF
ORGANOMETALLIC
COMPOUNDS
19
1.11.2
USES
OF
ORGANOMETALLIC
COMPOUNDS
20
1.12
CONCLUSIONS
20
REFERENCES
21
2
NOMENCLATURE
OF
ORGANOMETALLIC
COMPOUNDS
25
RAJ
K.
RATHORE,
SADHUCHORAN
MALLICK,
AND
BHAVABHUTI
PRASAD
2.1
INTRODUCTION
25
2.2
AIM
OF
THE
NOMENCLATURE
26
2.3
TYPE
OF
NOMENCLATURE
SYSTEM
26
2.3.1
BINARY
NOMENCLATURE
26
2.3.2
SUBSTITUTIVE
NOMENCLATURE
27
2.3.3
ADDITIVE
NOMENCLATURE
OR
COORDINATION
NOMENCLATURE
27
2.4
CONCEPTS
AND
CONVENTIONS
28
2.4.1
OXIDATION
NUMBER
28
2.4.2
COORDINATION
NUMBER
29
2.4.3
CHELATION
29
2.4.4
LIGANDS
29
2.4.5
SPECIFYING
CONNECTIVITY
-
THE
KAPPA
(
K
)
CONVENTION
30
2.4.6
BRIDGING
LIGANDS
-
THE
MU
(U)
CONVENTION
31
2.4.7
HAPTICITY
-
THE
ETA
(N)
CONVENTION
33
2.5
REGULATIONS
CONCERNING
THE
NOMENCLATURE
OF
TRANSITION
ELEMENT
ORGANOMETALLIC
COMPOUNDS
36
REFERENCES
46
CONTENTS
VII
3
CLASSIFICATION
OF
ORGANOMETALLIC
COMPOUNDS
47
MUKESH
K.
TYAGI,
GOKUL
R.
NISHAD,
DAKESHWAR
KUMAR
VERMA,
LEI
GUO,
AND
ELYOR
BERDIMURODOV
3.1
3.2
3.2.1
3.2.2
3.2.3
3.2.4
3.2.4.1
3.3
3.3.1
3.3.2
3.3.2.1
3.3.2.2
3.3.2.3
3.3.2.4
3.3.2.5
3.3.2.6
3.3.2.7
3.3.2.8
3.4
3.4.1
3.4.2
3.5
3.5.1
3.5.2
3.6
3.6.1
3.6.2
3.6.3
3.7
INTRODUCTION
47
CLASSIFICATION
OF
ORGANOMETALLIC
COMPOUND
48
SIGMA-BONDED
ORGANOMETALLIC
COMPOUND
48
X-BONDED
ORGANOMETALLIC
COMPOUNDS
50
IONIC
BONDED
ORGANOMETALLIC
COMPOUNDS
51
MULTICENTERED
BONDED
ORGANOMETALLIC
COMPOUNDS
53
BASED
ON
HEPTACITY
(N1
TO
N8):
53
GRIGNARD
REAGENT
(G.R.)
54
PHYSICAL
PROPERTIES
54
CHEMICAL
PROPERTIES
54
ALKANES
54
ALKENES
56
ALKYNES
56
ETHERS
56
REACTION
WITH
CARBON
DIOXIDE
56
INSERTION
REACTION
56
SYNTHESIS
OF
SILICONES
56
NUCLEOPHILIC
SUBSTITUTION
57
ORGANOZINC
COMPOUNDS
59
PHYSICAL
PROPERTIES
59
CHEMICAL
PROPERTIES
59
ORGANOLITHIUM
COMPOUNDS
61
REACTION
RESEMBLING
GRIGNARD
REAGENTS
61
REACTIONS DIFFERENT
FROM
GRIGNARD
REAGENTS
64
ORGANOSULFUR
COMPOUNDS
65
PHYSICAL
PROPERTIES
65
CHEMICAL
PROPERTIES
65
PROPERTIES
DIFFERENT
FROM
ALCOHOLS
67
CONCLUSION
69
REFERENCES
69
4
SYNTHESIS
METHODS
OF
ORGANOMETALLIC
COMPOUNDS
71
OMAR
DAGDAG,
RAJESH
HALDHAR,
SEONG-CHEOL
KIM,
ELYOR
BERDIMURODOV,
EKEMINI
D.
AKPAN,
AND
ENO
E.
EBENSO
4.1
4.2
4.2.1
INTRODUCTION
71
SYNTHESIS
METHODS
OF
ORGANOMETALLIC
COMPOUNDS
72
ELECTROCHEMICAL
METHODS
FOR
THE
SYNTHESIS
OF
ORGANOMETALLIC
COMPOUNDS
72
4.2.1.1
4.2.1.2
SYNTHESIS
OF
CYANO
CU(I)
COMPLEXES
IN
THE
ELECTROCHEMICAL
CELL
72
SYNTHESIS
OF
AN
ORGANORHENIUM
CYCLOPENTADIENYL
COMPLEX
IN
THE
ELECTROCHEMICAL
CELL
72
VIII
CONTENTS
4.2.13
SYNTHESIS
OF
N-HETEROCYCLIC
CARBENE
COMPLEXES
IN
THE
ELECTROCHEMICAL
CELL
73
4.2.1.4
SYNTHESIS
OF
ORGANOCOPPER
(I)
T-COMPLEXES
IN
THE
ELECTROCHEMICAL
CELL
73
4.2.1.5
4.2.2
SYNTHESIS
OF
ORGANONICKEL
O-COMPLEXES
IN
THE
ELECTROCHEMICAL
CELL
73
SYNTHESIS
OF
ORGANIC
COMPOUNDS
IN
THE
ELECTROCHEMICAL
CELL
BY
METAL
ORGANIC
CATALYSTS
75
4.2.2.1
THE
SYNTHESIS
OF
ORGANIC
COMPOUNDS
IN
THE
ELECTROCHEMICAL
CELL
BY
THE
NI-ORGANIC
CATALYZE
75
4.2.2.2
THE
SYNTHESIS
OF
ORGANIC
COMPOUNDS
IN
THE
ELECTROCHEMICAL
CELL
BY
THE
PD-ORGANIC
CATALYSES
75
4.2.23
SYNTHESIS
OF
ORGANIC
COMPOUNDS
IN
THE
ELECTROCHEMICAL
CELL
BY
THE
SM-ORGANIC
CATALYSES
78
4.23
4.23.1
4.23.2
4.2.33
4.23.4
4.23.5
4.23.6
43
SYNTHESIS
OF
ORGANOMETALLIC
NUCLEOSIDES
79
A
CATEGORY:
MAIN
COMPOUNDS
79
A1
SUBCATEGORY:
MAIN
COMPOUNDS
79
B
CATEGORY:
MAIN
COMPOUNDS
80
C
CATEGORY:
MAIN
COMPOUNDS
81
C1
SUBCATEGORY:
MAIN
COMPOUNDS
81
D
CATEGORIES:
MAIN
COMPOUNDS
82
CONCLUSIONS
84
ACKNOWLEDGMENT
84
AUTHORS
CONTRIBUTIONS
84
CONFLICTS
OF
INTEREST
84
REFERENCES
84
5
METAL
CARBONYLS:
SYNTHESIS,
PROPERTIES,
AND
STRUCTURE
87
RAMESH
RENGAN
5.1
5.2
5.2.1
5.2.1.1
5.2.1.2
5.2.2
INTRODUCTION
87
CLASSIFICATION
OF
METAL
CARBONYLS
87
CLASSIFICATION
BASED
ON
COORDINATED
LIGANDS
87
HOMOLEPTIC
CARBONYLS
88
HETEROLEPTIC
CARBONYLS
88
CLASSIFICATION
BASED
ON
NUMBER
OF
METALS
AND
THE
CONSTITUTION
OF
CARBONYLS
88
5.2.2.1
5.2.2.2
53
53.1
53.2
533
5.3.4
5.4
5.4.1
5.4.2
MONONUCLEAR
CARBONYL
COMPLEXES
88
POLYNUCLEAR
CARBONYL
COMPLEXES
89
SYNTHESIS
OF
METAL
CARBONYLS
90
DIRECT
REACTION
OF
METAL
WITH
CARBON
MONOXIDE
90
REDUCTIVE
CARBONYLATION
90
PHOTOLYSIS
AND
THERMOLYSIS
91
ABSTRACTION
OF
CO
FROM
A
REACTIVE
ORGANIC
CARBONYL
COMPOUNDS
91
PROPERTIES
OF
METAL
CARBONYLS
92
PHYSICAL
PROPERTIES
92
CHEMICAL
PROPERTIES
92
CONTENTS
IX
5.4.2.1
5.4.2.2
5.4.2.3
5.4.2.4
5.4.2.5
5.4.2.6
5.4.2.7
5.5
5.5.1
5.5.2
5.6
5.6.1
5.7
5.8
LIGAND
SUBSTITUTION
REACTIONS
92
REACTION
WITH
SODIUM
METAL
95
REACTION
WITH
SODIUM
HYDROXIDE
95
REACTION
WITH
HALOGENS
95
REACTION
WITH
HYDROGEN
96
REACTION
WITH
NITRICOXIDE
(NO)
96
DISPROPORTIONATION
96
STRUCTURE
OF
METAL
CARBONYLS
97
STRUCTURES
OF
SOME
MONONUCLEAR
CARBONYL
COMPLEXES
97
STRUCTURES
OF
SOME
BI
AND
POLYNUCLEAR
CARBONYL
COMPLEXES
98
BONDING
IN
METAL
CARBONYLS
99
FORMATION
OF
MIXED
ATOMIC
ORBITALS
99
SYNERGISTIC
EFFECT
103
CONCLUSION
103
FURTHER
READING
104
REFERENCES
104
6
METAL-CARBON
MULTIPLE
BONDED
COMPOUNDS
107
RAKESH
KUMAR
SAHU,
MUKESH
KUMAR
TYAGI,
AND
RAJESH
HALDHAR
6.1
6.2
6.3
6.3.1
6.3.2
6.4
6.4.1
6.4.2
6.5
6.5.1
6.5.1.1
6.5.1.2
6.5.2
6.6
6.6.1
6.6.2
6.7
INTRODUCTION
107
NOMENCLATURE
109
CLASSIFICATIONS
111
METAL-ALKYLIDENE
COMPLEXES
111
METAL-ALKYLIDYNE
COMPLEXES
111
STRUCTURE
111
ALKYLIDENE
(CARBENE)
111
CARBYNE
(ALKYLIDYNE)
113
PREPARATION
METHODS
114
METAL-ALKYLIDENE
COMPLEXES
114
BY
NUCLEOPHILIC
CARBENE
115
BY
ELECTROPHILIC
ALKYLIDENES
116
METAL-ALKYLIDYNE
COMPLEXES
118
IMPORTANT
REACTIONS
119
REACTION
OF
ALKYLIDENE
METATHESIS
119
IMPORTANT
REACTION
OF
ALKYLIDYNE
METATHESIS
124
APPLICATIONS
125
REFERENCES
127
7
METALLOCENE:
SYNTHESIS,
PROPERTIES,
AND
STRUCTURE
131
AMARPREET
K.
BHATIA,
PRIYANKA
SINGH,
AND
SHIPPI
DEWANGAN
7.1
7.2
7.3
7.4
7.4.1
INTRODUCTION
131
STRUCTURE
OF
METALLOCENE
132
SYNTHESIS
OF
METALLOCENE
134
CHEMICAL
PROPERTIES
OF
METALLOCENE
136
FERROCENE
AND
ITS
DERIVATIVES
136
X
CONTENTS
7.4.2
7.4.3
7.4.4
7.4.4.1
7.4.4.2
7.4.4.3
7.5
OTHER
METALLOCENE
SANDWICHES
138
MAIN-GROUP
METALLOCENE
139
METAL-BIS-ARENE
SANDWICH
COMPLEXES
140
GENERAL
VIEW
140
STRUCTURE
142
REACTIONS
142
CONCLUSION
144
REFERENCES
144
8
G-COMPLEXES,
^-COMPLEXES,
AND
N -CYYR,
CARBOCYCLIC
POLYENES-BASED
ORGANOMETALLIC
COMPOUNDS
147
SHIPPI
DEWANGAN,
JEENAT
ASLAM,
AND
AMARPREET
K.
BHATIA
8.1
8.2
8.2.1
8.2.1.1
8.2.1.2
8.2.1.3
8.2.1.4
8.2.2
8.2.2.1
8.2.2.2
8.2.2.3
8.2.2.4
8.3
8.3.1
8.3.1.1
8.3.1.2
8.3.1.3
8.3.2
8.3.3
8.3.4
8.3.4.1
8.3.4.2
8.3.4.3
8.4
INTRODUCTION
147
O-BOND
CONTAINING
ORGANOMETALLIC
COMPOUNDS
148
METAL
CARBONYL
148
GENERAL
OVERVIEW
148
SYNTHESES
OF
METAL
CARBONYLS
148
STRUCTURE
OF
METAL
CARBONYLS
149
REACTIONS
OF
METAL
CARBONYLS
150
METAL-ALKYL,
-VINYL,
AND
-HYDRIDE
COMPLEXES
150
METAL
ALKYLS
150
METAL
VINYLS
152
METAL
HYDRIDES
152
METAL-CARBENE
COMPLEXES
154
X-BOND
CONTAINING
ORGANOMETALLIC
COMPOUNDS
156
METAL-OLEFIN
COMPLEXES
156
GENERAL
OVERVIEW
156
SYNTHESES
OF
METAL-OLEFIN
COMPLEXES
157
REACTIONS
OF
METAL-OLEFIN
COMPLEXES
157
METAL-DIENE
COMPLEXES
157
METAL-ALKYNE
COMPLEXES
158
K-ALLYL
COMPLEXES
158
STRUCTURE
OF
A-ALLYL
COMPLEXES
158
SYNTHESES
OF
A
ALLYL
COMPLEXES
159
REACTIONS
OF
A
ALLYL
COMPLEXES
160
N
-CAR,
CARBOCYCLIC
POLYENES
CONTAINING
ORGANOMETALLIC
COMPOUNDS
161
8.4.1
8.4.2
8.4.3
8.4.3.1
8.4.3.2
8.4.3.3
8.4.3.4
8.4.3.5
CYCLOPROPENYLS,
N3-C3R,
161
CYCLOBUTADIENES,
N4-C4R4
161
CYCLOPENTADIENYLS,
N5
-
C
5
R,
162
GENERAL
OVERVIEW
162
STRUCTURE
OF
METALLOCENE
162
SYNTHESES
OF
METALLOCENE
163
CHEMICAL
PROPERTIES
OF
METALLOCENE
164
APPLICATIONS
OF
METALLOCENE
165
CONTENTS
XI
8.5
CONCLUSION
166
REFERENCES
166
9
ORGANOMETALLIC
COMPLEXES
OF
THE
LANTHANIDES
AND
ACTINIDES
169
SHIPPI
DEWANGAN,
AMARPREET
K.
BHATIA,
AND
PRIYANKA
SINGH
9.1
9.2
9.2.1
9.2.2
9.2.3
9.2.4
9.2.5
9.3
9.3.1
9.3.1.1
9.3.1.2
9.4
9.4.1
9.4.2
9.4.3
9.4.3.1
9.5
9.5.1
9.5.2
9.5.3
9.5.4
9.6
9.6.1
9.6.2
9.6.3
9.6.4
9.6.5
9.6.6
9.6.7
9.6.8
9.6.9
9.6.10
9.6.11
9.6.12
9.6.13
9.7
9.7.1
9.7.1.1
9.7.1.2
INTRODUCTION
169
METHODS
OF
PREPARATION
169
SALT
ELIMINATION
171
METAL
VAPOR
SYNTHESIS
METHOD
173
METATHESIS
REACTION
METHOD
174
O-BOND
METATHESIS
174
ACID-BASE
METHOD
175
ORGANOMETALLIC
COMPOUNDS
OF
LANTHANIDES
175
TYPES
175
O-BONDED
COMPLEXES
176
N-BONDED
ORGANOMETALLIC
COMPOUNDS
177
ORGANOMETALLIC
COMPOUNDS
OF
ACTINIDES
180
TYPES
180
O-BONDED
COMPLEXES
180
K-BONDED
COMPLEXES
182
CYCLOPENTADIENYL
DERIVATIVES
182
STABILITY
185
MAINTAINING
ANHYDROUS
AND
ANAEROBIC
CONDITIONS
185
AVOIDING
ELIMINATION
REACTIONS
186
BLOCKING
THE
COORDINATION
SITES
186
DONOR-FUNCTIONALIZED
CHELATING
PENDANT
DONOR
LIGANDS
186
PROPERTIES
186
THERMODYNAMIC
AND
KINETIC
CONSIDERATIONS
187
SOLVATION
187
AGGREGATION
187
DONOR-ACCEPTOR
INTERACTIONS
187
SALT
OCCLUSION
OR
ATE
COMPLEXATION
188
NEUTRAL
A-DONOR
LIGATION
188
AGOSTIC
INTERACTIONS
189
COMPLEX
AGGLOMERATION
189
LIGAND
EXCHANGE
AND
REDISTRIBUTION
REACTIONS
189
INSERTION
REACTIONS
190
ELIMINATION
REACTIONS
190
REDOX
CHEMISTRY
191
REACTION
SEQUENCES
-
CATALYTIC
CYCLES
192
APPLICATIONS
OF
ORGANOLANTHANOIDS
AND
ORGANOACTINOIDS
193
CATALYTIC
APPLICATIONS
193
CATALYSIS
OF
POLYMERIZATION
193
CATALYSTS
AND
REAGENTS
FOR
REDUCTION
PROCESSES
193
XII
CONTENTS
9.7.1.3
9.7.2
9.8
CATALYSTS
AND
REAGENTS
FOR
OXIDATION
PROCESSES
195
MISCELLANEOUS
APPLICATIONS
197
CONCLUSION
197
FURTHER
READING
197
10
BIOORGANOMETALLIC
CHEMISTRY
201
PRIYANKA
TIWARI
10.1
10.2
10.2.1
10.2.2
10.2.3
10.2.4
10.2.5
10.3
10.3.1
10.3.2
10.3.3
10.3.3.1
10.3.3.2
10.3.3.3
10.3.3.4
10.4
10.4.1
10.4.2
10.5
10.6
10.7
INTRODUCTION
201
COBALAMIN:
VITAMIN
B
12
-COENZYME
202
OCCURRENCE
AND
FUNCTION
202
STRUCTURE
202
B^-DEPENDENT
ENZYMES
203
OCCURRENCE
203
FUNCTION
203
METALLOPROTEINS
204
OCCURRENCE
204
FUNCTIONS
204
ELECTRON
TRANSFERASES
204
FLAVODOXINS
205
BLUE
COPPER
PROTEINS
205
IRON-SULFUR
PROTEINS
205
CYTOCHROMES
207
OXIDOREDUCTASE
207
IRON-PORPHYRIN
COMPLEXES
208
MONOOXYGENASES
208
NITROGENASES-CATALYZING
NITROGEN
FIXATION
209
NICKEL
ENZYMES:
CODH
211
CONCLUSION
212
REFERENCES
213
11
IMPORTANT
REACTIONS
OF
ORGANOMETALLIC
COMPOUNDS
215
SANDEEP
K.
VAISHNAV
AND
PRIYANKA
SINGH
11.1
11.2
11.2.1
11.2.1.1
11.2.1.2
11.2.1.3
11.2.2
11.2.2.1
11.2.2.2
11.2.2.3
11.2.2.4
11.3
11.3.1.1
INTRODUCTION
215
REACTIONS INVOLVING
GAIN
OR
LOSS
OF
LIGANDS
215
ASSOCIATIVE
AND
DISSOCIATIVE
SUBSTITUTION
216
DISSOCIATION
OF
CARBONYLS
216
DISSOCIATION
OF
NITROSYLS
217
DISSOCIATION
OF
PHOSPHINE
217
OXIDATIVE
ADDITION
AND
C
-
H
BOND
ACTIVATION
218
MECHANISM
219
BINUCLEAR
OXIDATIVE
ADDITION
221
CYCLOMETALLATIONS
222
NUCLEOPHILIC
DISPLACEMENT
222
REDUCTIVE
ELIMINATION
AND
PD-CATALYZED
CROSS
COUPLING
223
BINUCLEAR
REDUCTIVE
ELIMINATION
224
CONTENTS
|
XIII
11.4
11.4.1
11.4.1.1
11.4.1.2
11.4.1.3
11.4.2
11.4.2.1
11.4.3
11.4.3.1
11.5
REACTIONS INVOLVING
MODIFICATION
OF
LIGANDS
225
INSERTION
225
CARBONYL
INSERTION
(ALKYL
MIGRATION)
226
OLEFIN
INSERTION
230
OTHER
INSERTION
REACTION
232
HYDRIDE
ELIMINATION
233
AVOIDANCE
OF
P-HYDROGEN
ELIMINATION
235
ABSTRACTION
236
NUCLEOPHILIC
ABSTRACTION
237
CONCLUSION
240
REFERENCES
240
12
CHARACTERIZATION
TECHNIQUES
OF
ORGANOMETALLIC
COMPOUNDS
245
JAVAD
B.
M.
PARAMBATH
AND
AHMED
A.
MOHAMED
12.1
12.2
12.2.1
12.2.2
12.2.3
12.2.4
12.2.5
12.2.6
12.3
12.3.1
12.3.2
12.3.3
12.3.4
12.3.5
12.4
INTRODUCTION
245
CONVENTIONAL
METHODS
246
NUCLEAR
MAGNETIC
RESONANCE
(NMR)
SPECTROSCOPY
246
INFRARED
AND
RAMAN
SPECTROSCOPY
248
UV-VISIBLE
SPECTROSCOPY
251
X-RAY
CRYSTALLOGRAPHY
252
MASS
SPECTROSCOPY
253
ELEMENTAL
ANALYSIS
255
UNCONVENTIONAL
METHODS
256
NEUTRON
ACTIVATION
ANALYSIS
256
X-RAY
PHOTOELECTRON
SPECTROSCOPY
256
ELECTRON
DIFFRACTION
CRYSTALLOGRAPHY
AND
MICROELECTRON
DIFFRACTION
258
MOSSBAUER
SPECTROSCOPY
259
ELECTROANALYTICAL
METHODS
259
CONCLUSION
260
REFERENCES
261
13
ORGANOMETALLIC
REAGENTS
267
RANJAN
K.
BOSAK
AND
ASHISH
K.
ASOTKAR
13.1
13.1.1
13.1.2
13.1.2.1
13.1.2.2
13.1.2.3
13.1.2.4
13.1.2.5
13.1.2.6
13.2
13.2.1
ORGANOBORON
REAGENTS
267
INTRODUCTION
267
MAIN
ORGANOBORON
REAGENTS
AND
THEIR
REACTIONS
267
HYDROBORATION
AND
SUBSEQUENT
REACTIONS
267
SUZUKI
COUPLING
273
ACYLTRIFLUOROBORATES
277
ALLYLATION
278
CHAN-LAM
COUPLING
279
PETASIS
REACTION
279
ORGANOCOPPER
REAGENTS
280
INTRODUCTION
280
XIV
CONTENTS
13.2.2
TYPES
OF
ORGANOCUPRATES
REAGENTS
281
13.2.2.1
GILMAN
REAGENT
(R
2
CUM)
281
13.2.2.2
HIGHER
ORDER
ORGANOCUPRATES
(RCUCNLI,)
282
13.2.2.3
GRIGNARD
COPPER(I)
REAGENTS
(RMGX-CUY)
282
13.2.3
REACTIONS
OF
ORGANOCUPRATES
283
13.2.3.1
INCREASING
CHAIN
LENGTH
OF
ALKYL
HALIDES
283
13.2.3.2
ALKYLATION
OF
THE
ALLYLIC
HALIDES
284
13.2.3.3
REACTION
WITH
VINYL
HALIDES
284
13.2.3.4
ALKYLATION
OF
ACYL
HALIDES
284
13.2.3.5
EPOXIDE
OPENING
285
13.2.3.6
CONJUGATE
ADDITIONS
285
13.2.3.7
CONJUGATE
ADDITION
IN
PRESENCE
OF
LEWIS
ACID
AND
ELECTROPHILES
286
13.2.3.8
O-TRAPPING
AND
C-TRAPPING
REACTION
287
13.2.3.9
SYNTHESIS
OF
ALLENES
287
13.3
ORGANOPALLADIUM
REAGENTS
288
13.3.1
INTRODUCTION
288
13.3.2
TYPES
OF
C-C
CROSS-COUPLING
REACTION
CATALYZED
BY
PALLADIUM
METAL
289
13.3.2.1
HECK
REACTION
289
13.3.2.2
NEGISHI
COUPLING
290
13.3.2.3
SUZUKI
COUPLING
291
13.3.2.4
STILLE
COUPLING
291
13.3.2.5
KUMADA
COUPLING
292
13.3.2.6
HIYAMA
COUPLING
293
13.3.2.7
SONOGASHIRA
COUPLING
293
13.3.2.8
BUTCHWALD-HARTWIG
COUPLING
294
13.3.2.9
CYANATION
REACTION
294
13.3.2.10
CARBONYLATION
REACTION
295
13.4
GRIGNARD
REAGENTS
296
13.4.1
INTRODUCTION
296
13.4.2
SYNTHESIS
296
13.4.3
REACTIVITY
297
REFERENCES
298
14
HOMOGENEOUS
AND
HETEROGENEOUS
CATALYSIS
BY
ORGANOMETALLIC
COMPLEXES
301
RATNAKAR
D.
SHUKLA,
BHAWNA
JAIN,
KULESHWAR
PATEL,
PRIYANKA
SINGH,
DAKESHWAR
KUMAR
VERMA,
REEMA
SAHU,
AND
RAGHVENDRA
K.
MISHRA
14.1
INTRODUCTION
301
14.2
ORGANOMETALLIC
COMPOUNDS
AND
HOMOGENEOUS
CATALYSIS
302
14.3
CATALYTIC
ELEMENTARY
REACTIONS
303
14.3.1
ISOMERIZATION
304
14.3.2
ALKENE
ISOMERIZATION
305
14.3.3
ALKYNE
ISOMERIZATION
305
14.3.4
DIENE
ISOMERIZATION
306
CONTENTS
XV
14.4
14.5
14.6
14.7
14.8
14.9
14.9.1
14.9.1.1
14.9.2
14.9.3
14.10
HYDROGENATION
306
CARBON-CARBON
BOND
FORMATION
307
METATHESIS
308
OXIDATION
309
REACTIONS
WITH
CARBON
MONOXIDE
311
HETEROGENOUS
CATALYSIS
311
ZIEGLER-NATTA
CATALYST
313
STEREOREGULARITY
313
WATER
GAS
REACTION
315
ZEOLITES
316
CONCLUSION
317
REFERENCES
318
15
CLUSTER
COMPOUNDS:
BORANES,
HETEROBORANES,
AND
METALLABORANES
321
ELYOR
BERDIMURODOV,
KHASON
BERDIMURODOV,
ABDUVALI
KHOLIKOV,
KHAMDOM
AKBAROV,
OMAR
DAGDAG,
BRAHIM
EL
IBRAHIMI,
AND
DAKESHWAR
KUMAR
VERMA
15.1
15.1.1
INTRODUCTION
321
FUNDAMENTALS
OF
CLUSTER
COMPOUNDS:
BORANES,
HETEROBORANES,
AND
METALLABORANES
321
15.2
15.2.1
MAIN
PART
324
CLUSTER
COMPOUNDS
OF
BORANES
AND
HETEROBORANES:
SYNTHESIS,
REACTIONS,
AND
APPLICATIONS
324
15.2.1.1
15.2.1.2
15.2.1.3
15.2.1.4
15.2.2
BASICS
324
SYNTHESIS
324
REACTIONS
324
APPLICATIONS
327
CLUSTER
COMPOUNDS
OF
METALLABORANES:
SYNTHESIS,
REACTIONS,
AND
APPLICATIONS
327
15.2.2.1
15.2.2.2
15.2.2.3
15.2.2.4
15.3
BASICS
327
SYNTHESIS
327
REACTIONS
330
APPLICATIONS
330
CONCLUSION
332
REFERENCES
332
16
APPLICATIONS
OF
ORGANOMETALLIC
COMPOUNDS
FOR
CARBON
DIOXIDE
FIXATION,
REDUCTION,
GAS
ADSORPTION,
AND
GAS
PURIFICATION
335
ZHOVETA
YHOBU,
MONICA
VIJAYAKUMOR,
NAGARAJU
D.
HANUMANTHARAYUDU,
AND
SRINIVASA
BUDOGUMPI
16.1
16.2
16.2.1
16.2.2
ORGANOMETALLIC
COMPOUNDS
FOR
FIXATION
OF
CO
2
335
ORGANOMETALLIC
COMPOUNDS
IN
REDUCTION
OF
CO
2
336
NICKEL
COMPLEXES
338
IRON
AND
MANGANESE
COMPLEXES
339
XVI
CONTENTS
16.2.3
16.2.4
16.2.5
16.2.6
16.3
16.3.1
16.3.2
16.3.2.1
16.3.2.2
16.4
16.4.1
16.4.2
16.4.3
COPPER
AND
COBALT
COMPLEXES
341
PALLADIUM
COMPLEXES
342
RUTHENIUM,
RHENIUM,
AND
RHODIUM
COMPLEXES
343
N-HETEROCYCLIC
CARBENES
344
ORGANOMETALLIC
COMPOUNDS
IN
GAS
ADSORPTION
AND
PURIFICATION
346
METAL
ORGANIC
FRAMEWORKS
(MOFS)
FOR
GAS
ADSORPTION
347
CLASSIFICATION
OF
MOFS
AS
ADSORBENTS
FOR
GAS
SEPARATION
348
RIGID
MOFS
AS
ADSORBENTS
FOR
SELECTIVE
GAS
SEPARATION
348
FLEXIBLE
MOFS
AS
ADSORBENTS
FOR
GAS
SEPARATION
349
GAS
PURIFICATION
WITH
MOFS
352
KINETIC
SEPARATION
352
QUANTUM
SIEVING
EFFECT
FOR
H2/D2
SEPARATION
352
MEMBRANE-BASED
GAS
SEPARATION
353
REFERENCES
353
17
EMERGING
ROLE
OF
ORGANOMETALLIC
COMPOUNDS
FOR
DRUG
DELIVERY,
RENEWABLE
ENERGY,
AND
WASTEWATER
TREATMENT
357
SHOKOH
PARHAM,
HADI
SARVARI,
SEYED-SHIRIN
PARHAM,
AND
HADI
NUR
17.1
17.2
17.3
17.4
17.5
17.6
17.7
INTRODUCTION
357
ORGANOMETALLIC
COMPOUNDS
359
ORGANOMETALLIC
COMPOUNDS
FOR
DRUG
DELIVERY
363
ORGANOMETALLIC
COMPOUNDS
FOR
RENEWABLE
ENERGY
364
ORGANOMETALLIC
COMPOUNDS
FOR
WASTEWATER
TREATMENT
365
CONCLUSION
366
OUTLOOK
366
ACKNOWLEDGMENT
367
REFERENCES
367
18
COMPUTATIONAL
APPROACHES
IN
SOME
IMPORTANT
ORGANOMETALLIC
CATALYSIS
REACTION
375
PRATIBHA
GUMASTA,
NARESH
C.
DESHMUKH,
ASEEL
A,
KADHEM,
SNEHLATA
KATHERIA,
REENA
RAWAT,
AND
BHAWANA
JAIN
18.1
18.2
18.2.1
18.2.2
18.3
18.3.1
18.3.1.1
18.3.1.2
18.3.2
18.3.2.1
18.3.2.2
18.3.2.3
18.3.2.4
INTRODUCTION
375
COMPUTATIONAL
METHOD
376
GEOMETRY
CALCULATION
377
ENERGY
378
ORGANOMETALLIC
CATALYSIS
REACTIONS
379
PALLADIUM
379
C
-
H
BOND
ACTIVATION
380
COUPLING
REACTIONS
382
NICKEL
386
COUPLING
REACTIONS
386
C
-
O
BOND
ACTIVATION
388
CYCLIZATION
REACTIONS
389
OLEFIN
FUNCTIONALIZATION
389
CONTENTS
XVII
18.3.3
RHODIUM
390
18.3.3.1
HYDROGENATION
390
18.3.3.2
OLEFIN
FUNCTIONALIZATION
391
18.3.3.3
REACTIONS
OF
RH
CARBENOIDS
AND
NITRENOIDS
391
18.3.4
IRIDIUM
394
18.3.4.1
HYDROGENATION
394
18.3.4.2
OTHER
BOND
ACTIVATIONS
396
18.4
CONCLUSION
396
REFERENCES
397
INDEX
409
|
| adam_txt |
CONTENTS
PREFACE
XIX
ABOUT
THE
EDITORS
XXI
1
ORGANOMETALLIC
COMPOUNDS:
THE
FUNDAMENTAL
ASPECTS
1
GEETHA
B.
MARKANDEYA
AND
SRINIVASA
BUDAGUMPI
1.1
1.1.1
1.1.2
1.1.3
1.2
1.2.1
1.2.2
1.2.3
1.2.4
1.2.5
1.2.6
1.2.7
INTRODUCTION
1
ORGANOMETALLIC
CHEMISTRY
1
ORGANOMETALLIC
COMPOUNDS
1
STRUCTURE
OF
ORGANOMETALLIC
COMPOUND
1
MILESTONES
IN
ORGANOMETALLIC
COMPOUNDS
2
EQUATION
(1.1):
SYNTHESIS
OF
FIRST
ORGANOMETALLIC
COMPOUND
2
EQUATION
(1.2):
PREPARATION
OF
ZEISE
'
S
SALT
2
EQUATIONS
(1.3)-(1.5):
PREPARATION
OF
ORGANOCHLOROSILANE
COMPOUND
3
EQUATION
(1.6):
SYNTHESIS
OF
FIRST
METAL
CARBONYL
COMPOUND
3
EQUATION
(1.7):
SYNTHESIS
OF
FIRST
BINARY
METAL
CARBONYL
COMPLEX
3
EQUATION
(1.8):
BARBIER
REACTION
3
EQUATION
(1.9):
SYNTHESIS
OF
ORGANIC
COMPOUND
USING
A
GRIGNARD
REAGENT
4
1.2.8
1.2.9
1.2.10
1.2.11
1.2.12
1.2.13
1.2.14
1.2.15
1.2.16
1.3
1.4
1.5
1.5.1
1.5.1.1
1.5.1.2
EQUATIONS
(1.10)
AND
(1.11):
SYNTHESIS
OF
ALKYLLITHIUM
COMPOUND
4
EQUATIONS
(1.12)
AND
(1.13):
SYNTHESIS
OF
ORGANOLITHIUM
COMPOUND
4
EQUATION
(1.14):
HYDROFORMYLATION
REACTION
4
EQUATION
(1.15):
SYNTHESIS
OF
ORGANOCHLOROSILANE
COMPOUND
4
EQUATION
(1.16):
TRIMERIZATION
OF
ACETYLENE
5
EQUATION
(1.17):
SYNTHESIS
OF
FERROCENE
5
EQUATION
(1.18):
ASYMMETRIC
CATALYSIS
REACTION
5
EQUATION
(1.19):
PALLADIUM
CATALYZED
SUZUKI
COUPLING
REACTION
6
EQUATION
(1.20):
SYNTHESIS
OF
BUCKY
FERROCENE
8
STABILITY
OF
ORGANOMETALLIC
COMPOUNDS
9
PROPERTIES
OF
ORGANOMETALLIC
COMPOUNDS
9
BASIC
CONCEPTS
IN
ORGANOMETALLIC
COMPOUNDS
9
18-ELECTRON
RULE
9
STATEMENT
OF
18
ELECTRON
RULE
10
EXAMPLES
11
VI
J
CONTENTS
1.5.2
II
-BACK
BONDING
OR
BACK
DONATION
12
1.5.3
HAPTICITY
N
12
1.6
HAPTICITY
OF
LIGANDS
12
1.7
CHANGE
IN
HAPTICITY
13
1.8
HAPTICITY
VERSES
DENTICITY
14
1.9
COUNTING
OF
ELECTRONS
AND
FINDING
OUT
METAL-METAL
BONDS
15
1.9.1
CALCULATING
THE
NUMBER
OF
METAL-METAL
BONDS
15
1.9.2
WRITING
THE
PROBABLE
STRUCTURE
OF
COMPOUND
15
1.9.3
HOW
TO
DRAW
THE
PROBABLE
STRUCTURE
OF
NI(N
'
-C,H,)
(N3-C,H,)
15
1.9.4
HOW
TO
DRAW
THE
PROBABLE
STRUCTURE
OF
(U-CO)-[N5-CPRH],(CO)
15
1.10
METALS
OF
ORGANOMETALLIC
COMPOUNDS
16
1.10.1
ORGANOMETALLIC
COMPOUNDS
OF
TRANSITION
METALS
17
1.10.2
THE
BONDING
AND
STRUCTURE
IN
DIFFERENT
METAL
COMPLEXES
17
1.10.2.1
ALKENE
COMPLEXES
17
1.10.2.2
ALLYL
COMPLEXES
17
1.10.2.3
CARBONYL
COMPLEXES
17
1.10.2.4
METALLOCENES
18
1.10.2.5
DIHYDROGEN
COMPLEXES
18
1.10.2.6
TRANSITION
METAL
CARBENE
COMPLEX
18
1.11
IMPORTANCE OF
ORGANOMETALLIC
COMPOUNDS
19
1.11.1
TYPES
OF
ORGANOMETALLIC
COMPOUNDS
19
1.11.2
USES
OF
ORGANOMETALLIC
COMPOUNDS
20
1.12
CONCLUSIONS
20
REFERENCES
21
2
NOMENCLATURE
OF
ORGANOMETALLIC
COMPOUNDS
25
RAJ
K.
RATHORE,
SADHUCHORAN
MALLICK,
AND
BHAVABHUTI
PRASAD
2.1
INTRODUCTION
25
2.2
AIM
OF
THE
NOMENCLATURE
26
2.3
TYPE
OF
NOMENCLATURE
SYSTEM
26
2.3.1
BINARY
NOMENCLATURE
26
2.3.2
SUBSTITUTIVE
NOMENCLATURE
27
2.3.3
ADDITIVE
NOMENCLATURE
OR
COORDINATION
NOMENCLATURE
27
2.4
CONCEPTS
AND
CONVENTIONS
28
2.4.1
OXIDATION
NUMBER
28
2.4.2
COORDINATION
NUMBER
29
2.4.3
CHELATION
29
2.4.4
LIGANDS
29
2.4.5
SPECIFYING
CONNECTIVITY
-
THE
KAPPA
(
K
)
CONVENTION
30
2.4.6
BRIDGING
LIGANDS
-
THE
MU
(U)
CONVENTION
31
2.4.7
HAPTICITY
-
THE
ETA
(N)
CONVENTION
33
2.5
REGULATIONS
CONCERNING
THE
NOMENCLATURE
OF
TRANSITION
ELEMENT
ORGANOMETALLIC
COMPOUNDS
36
REFERENCES
46
CONTENTS
VII
3
CLASSIFICATION
OF
ORGANOMETALLIC
COMPOUNDS
47
MUKESH
K.
TYAGI,
GOKUL
R.
NISHAD,
DAKESHWAR
KUMAR
VERMA,
LEI
GUO,
AND
ELYOR
BERDIMURODOV
3.1
3.2
3.2.1
3.2.2
3.2.3
3.2.4
3.2.4.1
3.3
3.3.1
3.3.2
3.3.2.1
3.3.2.2
3.3.2.3
3.3.2.4
3.3.2.5
3.3.2.6
3.3.2.7
3.3.2.8
3.4
3.4.1
3.4.2
3.5
3.5.1
3.5.2
3.6
3.6.1
3.6.2
3.6.3
3.7
INTRODUCTION
47
CLASSIFICATION
OF
ORGANOMETALLIC
COMPOUND
48
SIGMA-BONDED
ORGANOMETALLIC
COMPOUND
48
X-BONDED
ORGANOMETALLIC
COMPOUNDS
50
IONIC
BONDED
ORGANOMETALLIC
COMPOUNDS
51
MULTICENTERED
BONDED
ORGANOMETALLIC
COMPOUNDS
53
BASED
ON
HEPTACITY
(N1
TO
N8):
53
GRIGNARD
REAGENT
(G.R.)
54
PHYSICAL
PROPERTIES
54
CHEMICAL
PROPERTIES
54
ALKANES
54
ALKENES
56
ALKYNES
56
ETHERS
56
REACTION
WITH
CARBON
DIOXIDE
56
INSERTION
REACTION
56
SYNTHESIS
OF
SILICONES
56
NUCLEOPHILIC
SUBSTITUTION
57
ORGANOZINC
COMPOUNDS
59
PHYSICAL
PROPERTIES
59
CHEMICAL
PROPERTIES
59
ORGANOLITHIUM
COMPOUNDS
61
REACTION
RESEMBLING
GRIGNARD
REAGENTS
61
REACTIONS DIFFERENT
FROM
GRIGNARD
REAGENTS
64
ORGANOSULFUR
COMPOUNDS
65
PHYSICAL
PROPERTIES
65
CHEMICAL
PROPERTIES
65
PROPERTIES
DIFFERENT
FROM
ALCOHOLS
67
CONCLUSION
69
REFERENCES
69
4
SYNTHESIS
METHODS
OF
ORGANOMETALLIC
COMPOUNDS
71
OMAR
DAGDAG,
RAJESH
HALDHAR,
SEONG-CHEOL
KIM,
ELYOR
BERDIMURODOV,
EKEMINI
D.
AKPAN,
AND
ENO
E.
EBENSO
4.1
4.2
4.2.1
INTRODUCTION
71
SYNTHESIS
METHODS
OF
ORGANOMETALLIC
COMPOUNDS
72
ELECTROCHEMICAL
METHODS
FOR
THE
SYNTHESIS
OF
ORGANOMETALLIC
COMPOUNDS
72
4.2.1.1
4.2.1.2
SYNTHESIS
OF
CYANO
CU(I)
COMPLEXES
IN
THE
ELECTROCHEMICAL
CELL
72
SYNTHESIS
OF
AN
ORGANORHENIUM
CYCLOPENTADIENYL
COMPLEX
IN
THE
ELECTROCHEMICAL
CELL
72
VIII
CONTENTS
4.2.13
SYNTHESIS
OF
N-HETEROCYCLIC
CARBENE
COMPLEXES
IN
THE
ELECTROCHEMICAL
CELL
73
4.2.1.4
SYNTHESIS
OF
ORGANOCOPPER
(I)
T-COMPLEXES
IN
THE
ELECTROCHEMICAL
CELL
73
4.2.1.5
4.2.2
SYNTHESIS
OF
ORGANONICKEL
O-COMPLEXES
IN
THE
ELECTROCHEMICAL
CELL
73
SYNTHESIS
OF
ORGANIC
COMPOUNDS
IN
THE
ELECTROCHEMICAL
CELL
BY
METAL
ORGANIC
CATALYSTS
75
4.2.2.1
THE
SYNTHESIS
OF
ORGANIC
COMPOUNDS
IN
THE
ELECTROCHEMICAL
CELL
BY
THE
NI-ORGANIC
CATALYZE
75
4.2.2.2
THE
SYNTHESIS
OF
ORGANIC
COMPOUNDS
IN
THE
ELECTROCHEMICAL
CELL
BY
THE
PD-ORGANIC
CATALYSES
75
4.2.23
SYNTHESIS
OF
ORGANIC
COMPOUNDS
IN
THE
ELECTROCHEMICAL
CELL
BY
THE
SM-ORGANIC
CATALYSES
78
4.23
4.23.1
4.23.2
4.2.33
4.23.4
4.23.5
4.23.6
43
SYNTHESIS
OF
ORGANOMETALLIC
NUCLEOSIDES
79
A
CATEGORY:
MAIN
COMPOUNDS
79
A1
SUBCATEGORY:
MAIN
COMPOUNDS
79
B
CATEGORY:
MAIN
COMPOUNDS
80
C
CATEGORY:
MAIN
COMPOUNDS
81
C1
SUBCATEGORY:
MAIN
COMPOUNDS
81
D
CATEGORIES:
MAIN
COMPOUNDS
82
CONCLUSIONS
84
ACKNOWLEDGMENT
84
AUTHORS
CONTRIBUTIONS
84
CONFLICTS
OF
INTEREST
84
REFERENCES
84
5
METAL
CARBONYLS:
SYNTHESIS,
PROPERTIES,
AND
STRUCTURE
87
RAMESH
RENGAN
5.1
5.2
5.2.1
5.2.1.1
5.2.1.2
5.2.2
INTRODUCTION
87
CLASSIFICATION
OF
METAL
CARBONYLS
87
CLASSIFICATION
BASED
ON
COORDINATED
LIGANDS
87
HOMOLEPTIC
CARBONYLS
88
HETEROLEPTIC
CARBONYLS
88
CLASSIFICATION
BASED
ON
NUMBER
OF
METALS
AND
THE
CONSTITUTION
OF
CARBONYLS
88
5.2.2.1
5.2.2.2
53
53.1
53.2
533
5.3.4
5.4
5.4.1
5.4.2
MONONUCLEAR
CARBONYL
COMPLEXES
88
POLYNUCLEAR
CARBONYL
COMPLEXES
89
SYNTHESIS
OF
METAL
CARBONYLS
90
DIRECT
REACTION
OF
METAL
WITH
CARBON
MONOXIDE
90
REDUCTIVE
CARBONYLATION
90
PHOTOLYSIS
AND
THERMOLYSIS
91
ABSTRACTION
OF
CO
FROM
A
REACTIVE
ORGANIC
CARBONYL
COMPOUNDS
91
PROPERTIES
OF
METAL
CARBONYLS
92
PHYSICAL
PROPERTIES
92
CHEMICAL
PROPERTIES
92
CONTENTS
IX
5.4.2.1
5.4.2.2
5.4.2.3
5.4.2.4
5.4.2.5
5.4.2.6
5.4.2.7
5.5
5.5.1
5.5.2
5.6
5.6.1
5.7
5.8
LIGAND
SUBSTITUTION
REACTIONS
92
REACTION
WITH
SODIUM
METAL
95
REACTION
WITH
SODIUM
HYDROXIDE
95
REACTION
WITH
HALOGENS
95
REACTION
WITH
HYDROGEN
96
REACTION
WITH
NITRICOXIDE
(NO)
96
DISPROPORTIONATION
96
STRUCTURE
OF
METAL
CARBONYLS
97
STRUCTURES
OF
SOME
MONONUCLEAR
CARBONYL
COMPLEXES
97
STRUCTURES
OF
SOME
BI
AND
POLYNUCLEAR
CARBONYL
COMPLEXES
98
BONDING
IN
METAL
CARBONYLS
99
FORMATION
OF
MIXED
ATOMIC
ORBITALS
99
SYNERGISTIC
EFFECT
103
CONCLUSION
103
FURTHER
READING
104
REFERENCES
104
6
METAL-CARBON
MULTIPLE
BONDED
COMPOUNDS
107
RAKESH
KUMAR
SAHU,
MUKESH
KUMAR
TYAGI,
AND
RAJESH
HALDHAR
6.1
6.2
6.3
6.3.1
6.3.2
6.4
6.4.1
6.4.2
6.5
6.5.1
6.5.1.1
6.5.1.2
6.5.2
6.6
6.6.1
6.6.2
6.7
INTRODUCTION
107
NOMENCLATURE
109
CLASSIFICATIONS
111
METAL-ALKYLIDENE
COMPLEXES
111
METAL-ALKYLIDYNE
COMPLEXES
111
STRUCTURE
111
ALKYLIDENE
(CARBENE)
111
CARBYNE
(ALKYLIDYNE)
113
PREPARATION
METHODS
114
METAL-ALKYLIDENE
COMPLEXES
114
BY
NUCLEOPHILIC
CARBENE
115
BY
ELECTROPHILIC
ALKYLIDENES
116
METAL-ALKYLIDYNE
COMPLEXES
118
IMPORTANT
REACTIONS
119
REACTION
OF
ALKYLIDENE
METATHESIS
119
IMPORTANT
REACTION
OF
ALKYLIDYNE
METATHESIS
124
APPLICATIONS
125
REFERENCES
127
7
METALLOCENE:
SYNTHESIS,
PROPERTIES,
AND
STRUCTURE
131
AMARPREET
K.
BHATIA,
PRIYANKA
SINGH,
AND
SHIPPI
DEWANGAN
7.1
7.2
7.3
7.4
7.4.1
INTRODUCTION
131
STRUCTURE
OF
METALLOCENE
132
SYNTHESIS
OF
METALLOCENE
134
CHEMICAL
PROPERTIES
OF
METALLOCENE
136
FERROCENE
AND
ITS
DERIVATIVES
136
X
CONTENTS
7.4.2
7.4.3
7.4.4
7.4.4.1
7.4.4.2
7.4.4.3
7.5
OTHER
METALLOCENE
SANDWICHES
138
MAIN-GROUP
METALLOCENE
139
METAL-BIS-ARENE
SANDWICH
COMPLEXES
140
GENERAL
VIEW
140
STRUCTURE
142
REACTIONS
142
CONCLUSION
144
REFERENCES
144
8
G-COMPLEXES,
^-COMPLEXES,
AND
N"-CYYR,
CARBOCYCLIC
POLYENES-BASED
ORGANOMETALLIC
COMPOUNDS
147
SHIPPI
DEWANGAN,
JEENAT
ASLAM,
AND
AMARPREET
K.
BHATIA
8.1
8.2
8.2.1
8.2.1.1
8.2.1.2
8.2.1.3
8.2.1.4
8.2.2
8.2.2.1
8.2.2.2
8.2.2.3
8.2.2.4
8.3
8.3.1
8.3.1.1
8.3.1.2
8.3.1.3
8.3.2
8.3.3
8.3.4
8.3.4.1
8.3.4.2
8.3.4.3
8.4
INTRODUCTION
147
O-BOND
CONTAINING
ORGANOMETALLIC
COMPOUNDS
148
METAL
CARBONYL
148
GENERAL
OVERVIEW
148
SYNTHESES
OF
METAL
CARBONYLS
148
STRUCTURE
OF
METAL
CARBONYLS
149
REACTIONS
OF
METAL
CARBONYLS
150
METAL-ALKYL,
-VINYL,
AND
-HYDRIDE
COMPLEXES
150
METAL
ALKYLS
150
METAL
VINYLS
152
METAL
HYDRIDES
152
METAL-CARBENE
COMPLEXES
154
X-BOND
CONTAINING
ORGANOMETALLIC
COMPOUNDS
156
METAL-OLEFIN
COMPLEXES
156
GENERAL
OVERVIEW
156
SYNTHESES
OF
METAL-OLEFIN
COMPLEXES
157
REACTIONS
OF
METAL-OLEFIN
COMPLEXES
157
METAL-DIENE
COMPLEXES
157
METAL-ALKYNE
COMPLEXES
158
K-ALLYL
COMPLEXES
158
STRUCTURE
OF
A-ALLYL
COMPLEXES
158
SYNTHESES
OF
A
ALLYL
COMPLEXES
159
REACTIONS
OF
A
ALLYL
COMPLEXES
160
N
"
-CAR,
CARBOCYCLIC
POLYENES
CONTAINING
ORGANOMETALLIC
COMPOUNDS
161
8.4.1
8.4.2
8.4.3
8.4.3.1
8.4.3.2
8.4.3.3
8.4.3.4
8.4.3.5
CYCLOPROPENYLS,
N3-C3R,
161
CYCLOBUTADIENES,
N4-C4R4
161
CYCLOPENTADIENYLS,
N5
-
C
5
R,
162
GENERAL
OVERVIEW
162
STRUCTURE
OF
METALLOCENE
162
SYNTHESES
OF
METALLOCENE
163
CHEMICAL
PROPERTIES
OF
METALLOCENE
164
APPLICATIONS
OF
METALLOCENE
165
CONTENTS
XI
8.5
CONCLUSION
166
REFERENCES
166
9
ORGANOMETALLIC
COMPLEXES
OF
THE
LANTHANIDES
AND
ACTINIDES
169
SHIPPI
DEWANGAN,
AMARPREET
K.
BHATIA,
AND
PRIYANKA
SINGH
9.1
9.2
9.2.1
9.2.2
9.2.3
9.2.4
9.2.5
9.3
9.3.1
9.3.1.1
9.3.1.2
9.4
9.4.1
9.4.2
9.4.3
9.4.3.1
9.5
9.5.1
9.5.2
9.5.3
9.5.4
9.6
9.6.1
9.6.2
9.6.3
9.6.4
9.6.5
9.6.6
9.6.7
9.6.8
9.6.9
9.6.10
9.6.11
9.6.12
9.6.13
9.7
9.7.1
9.7.1.1
9.7.1.2
INTRODUCTION
169
METHODS
OF
PREPARATION
169
SALT
ELIMINATION
171
METAL
VAPOR
SYNTHESIS
METHOD
173
METATHESIS
REACTION
METHOD
174
O-BOND
METATHESIS
174
ACID-BASE
METHOD
175
ORGANOMETALLIC
COMPOUNDS
OF
LANTHANIDES
175
TYPES
175
O-BONDED
COMPLEXES
176
N-BONDED
ORGANOMETALLIC
COMPOUNDS
177
ORGANOMETALLIC
COMPOUNDS
OF
ACTINIDES
180
TYPES
180
O-BONDED
COMPLEXES
180
K-BONDED
COMPLEXES
182
CYCLOPENTADIENYL
DERIVATIVES
182
STABILITY
185
MAINTAINING
ANHYDROUS
AND
ANAEROBIC
CONDITIONS
185
AVOIDING
ELIMINATION
REACTIONS
186
BLOCKING
THE
COORDINATION
SITES
186
DONOR-FUNCTIONALIZED
CHELATING
PENDANT
DONOR
LIGANDS
186
PROPERTIES
186
THERMODYNAMIC
AND
KINETIC
CONSIDERATIONS
187
SOLVATION
187
AGGREGATION
187
DONOR-ACCEPTOR
INTERACTIONS
187
SALT
OCCLUSION
OR
ATE
COMPLEXATION
188
NEUTRAL
A-DONOR
LIGATION
188
AGOSTIC
INTERACTIONS
189
COMPLEX
AGGLOMERATION
189
LIGAND
EXCHANGE
AND
REDISTRIBUTION
REACTIONS
189
INSERTION
REACTIONS
190
ELIMINATION
REACTIONS
190
REDOX
CHEMISTRY
191
REACTION
SEQUENCES
-
CATALYTIC
CYCLES
192
APPLICATIONS
OF
ORGANOLANTHANOIDS
AND
ORGANOACTINOIDS
193
CATALYTIC
APPLICATIONS
193
CATALYSIS
OF
POLYMERIZATION
193
CATALYSTS
AND
REAGENTS
FOR
REDUCTION
PROCESSES
193
XII
CONTENTS
9.7.1.3
9.7.2
9.8
CATALYSTS
AND
REAGENTS
FOR
OXIDATION
PROCESSES
195
MISCELLANEOUS
APPLICATIONS
197
CONCLUSION
197
FURTHER
READING
197
10
BIOORGANOMETALLIC
CHEMISTRY
201
PRIYANKA
TIWARI
10.1
10.2
10.2.1
10.2.2
10.2.3
10.2.4
10.2.5
10.3
10.3.1
10.3.2
10.3.3
10.3.3.1
10.3.3.2
10.3.3.3
10.3.3.4
10.4
10.4.1
10.4.2
10.5
10.6
10.7
INTRODUCTION
201
COBALAMIN:
VITAMIN
B
12
-COENZYME
202
OCCURRENCE
AND
FUNCTION
202
STRUCTURE
202
B^-DEPENDENT
ENZYMES
203
OCCURRENCE
203
FUNCTION
203
METALLOPROTEINS
204
OCCURRENCE
204
FUNCTIONS
204
ELECTRON
TRANSFERASES
204
FLAVODOXINS
205
BLUE
COPPER
PROTEINS
205
IRON-SULFUR
PROTEINS
205
CYTOCHROMES
207
OXIDOREDUCTASE
207
IRON-PORPHYRIN
COMPLEXES
208
MONOOXYGENASES
208
NITROGENASES-CATALYZING
NITROGEN
FIXATION
209
NICKEL
ENZYMES:
CODH
211
CONCLUSION
212
REFERENCES
213
11
IMPORTANT
REACTIONS
OF
ORGANOMETALLIC
COMPOUNDS
215
SANDEEP
K.
VAISHNAV
AND
PRIYANKA
SINGH
11.1
11.2
11.2.1
11.2.1.1
11.2.1.2
11.2.1.3
11.2.2
11.2.2.1
11.2.2.2
11.2.2.3
11.2.2.4
11.3
11.3.1.1
INTRODUCTION
215
REACTIONS INVOLVING
GAIN
OR
LOSS
OF
LIGANDS
215
ASSOCIATIVE
AND
DISSOCIATIVE
SUBSTITUTION
216
DISSOCIATION
OF
CARBONYLS
216
DISSOCIATION
OF
NITROSYLS
217
DISSOCIATION
OF
PHOSPHINE
217
OXIDATIVE
ADDITION
AND
C
-
H
BOND
ACTIVATION
218
MECHANISM
219
BINUCLEAR
OXIDATIVE
ADDITION
221
CYCLOMETALLATIONS
222
NUCLEOPHILIC
DISPLACEMENT
222
REDUCTIVE
ELIMINATION
AND
PD-CATALYZED
CROSS
COUPLING
223
BINUCLEAR
REDUCTIVE
ELIMINATION
224
CONTENTS
|
XIII
11.4
11.4.1
11.4.1.1
11.4.1.2
11.4.1.3
11.4.2
11.4.2.1
11.4.3
11.4.3.1
11.5
REACTIONS INVOLVING
MODIFICATION
OF
LIGANDS
225
INSERTION
225
CARBONYL
INSERTION
(ALKYL
MIGRATION)
226
OLEFIN
INSERTION
230
OTHER
INSERTION
REACTION
232
HYDRIDE
ELIMINATION
233
AVOIDANCE
OF
P-HYDROGEN
ELIMINATION
235
ABSTRACTION
236
NUCLEOPHILIC
ABSTRACTION
237
CONCLUSION
240
REFERENCES
240
12
CHARACTERIZATION
TECHNIQUES
OF
ORGANOMETALLIC
COMPOUNDS
245
JAVAD
B.
M.
PARAMBATH
AND
AHMED
A.
MOHAMED
12.1
12.2
12.2.1
12.2.2
12.2.3
12.2.4
12.2.5
12.2.6
12.3
12.3.1
12.3.2
12.3.3
12.3.4
12.3.5
12.4
INTRODUCTION
245
CONVENTIONAL
METHODS
246
NUCLEAR
MAGNETIC
RESONANCE
(NMR)
SPECTROSCOPY
246
INFRARED
AND
RAMAN
SPECTROSCOPY
248
UV-VISIBLE
SPECTROSCOPY
251
X-RAY
CRYSTALLOGRAPHY
252
MASS
SPECTROSCOPY
253
ELEMENTAL
ANALYSIS
255
UNCONVENTIONAL
METHODS
256
NEUTRON
ACTIVATION
ANALYSIS
256
X-RAY
PHOTOELECTRON
SPECTROSCOPY
256
ELECTRON
DIFFRACTION
CRYSTALLOGRAPHY
AND
MICROELECTRON
DIFFRACTION
258
MOSSBAUER
SPECTROSCOPY
259
ELECTROANALYTICAL
METHODS
259
CONCLUSION
260
REFERENCES
261
13
ORGANOMETALLIC
REAGENTS
267
RANJAN
K.
BOSAK
AND
ASHISH
K.
ASOTKAR
13.1
13.1.1
13.1.2
13.1.2.1
13.1.2.2
13.1.2.3
13.1.2.4
13.1.2.5
13.1.2.6
13.2
13.2.1
ORGANOBORON
REAGENTS
267
INTRODUCTION
267
MAIN
ORGANOBORON
REAGENTS
AND
THEIR
REACTIONS
267
HYDROBORATION
AND
SUBSEQUENT
REACTIONS
267
SUZUKI
COUPLING
273
ACYLTRIFLUOROBORATES
277
ALLYLATION
278
CHAN-LAM
COUPLING
279
PETASIS
REACTION
279
ORGANOCOPPER
REAGENTS
280
INTRODUCTION
280
XIV
CONTENTS
13.2.2
TYPES
OF
ORGANOCUPRATES
REAGENTS
281
13.2.2.1
GILMAN
REAGENT
(R
2
CUM)
281
13.2.2.2
HIGHER
ORDER
ORGANOCUPRATES
(RCUCNLI,)
282
13.2.2.3
GRIGNARD
COPPER(I)
REAGENTS
(RMGX-CUY)
282
13.2.3
REACTIONS
OF
ORGANOCUPRATES
283
13.2.3.1
INCREASING
CHAIN
LENGTH
OF
ALKYL
HALIDES
283
13.2.3.2
ALKYLATION
OF
THE
ALLYLIC
HALIDES
284
13.2.3.3
REACTION
WITH
VINYL
HALIDES
284
13.2.3.4
ALKYLATION
OF
ACYL
HALIDES
284
13.2.3.5
EPOXIDE
OPENING
285
13.2.3.6
CONJUGATE
ADDITIONS
285
13.2.3.7
CONJUGATE
ADDITION
IN
PRESENCE
OF
LEWIS
ACID
AND
ELECTROPHILES
286
13.2.3.8
O-TRAPPING
AND
C-TRAPPING
REACTION
287
13.2.3.9
SYNTHESIS
OF
ALLENES
287
13.3
ORGANOPALLADIUM
REAGENTS
288
13.3.1
INTRODUCTION
288
13.3.2
TYPES
OF
C-C
CROSS-COUPLING
REACTION
CATALYZED
BY
PALLADIUM
METAL
289
13.3.2.1
HECK
REACTION
289
13.3.2.2
NEGISHI
COUPLING
290
13.3.2.3
SUZUKI
COUPLING
291
13.3.2.4
STILLE
COUPLING
291
13.3.2.5
KUMADA
COUPLING
292
13.3.2.6
HIYAMA
COUPLING
293
13.3.2.7
SONOGASHIRA
COUPLING
293
13.3.2.8
BUTCHWALD-HARTWIG
COUPLING
294
13.3.2.9
CYANATION
REACTION
294
13.3.2.10
CARBONYLATION
REACTION
295
13.4
GRIGNARD
REAGENTS
296
13.4.1
INTRODUCTION
296
13.4.2
SYNTHESIS
296
13.4.3
REACTIVITY
297
REFERENCES
298
14
HOMOGENEOUS
AND
HETEROGENEOUS
CATALYSIS
BY
ORGANOMETALLIC
COMPLEXES
301
RATNAKAR
D.
SHUKLA,
BHAWNA
JAIN,
KULESHWAR
PATEL,
PRIYANKA
SINGH,
DAKESHWAR
KUMAR
VERMA,
REEMA
SAHU,
AND
RAGHVENDRA
K.
MISHRA
14.1
INTRODUCTION
301
14.2
ORGANOMETALLIC
COMPOUNDS
AND
HOMOGENEOUS
CATALYSIS
302
14.3
CATALYTIC
ELEMENTARY
REACTIONS
303
14.3.1
ISOMERIZATION
304
14.3.2
ALKENE
ISOMERIZATION
305
14.3.3
ALKYNE
ISOMERIZATION
305
14.3.4
DIENE
ISOMERIZATION
306
CONTENTS
XV
14.4
14.5
14.6
14.7
14.8
14.9
14.9.1
14.9.1.1
14.9.2
14.9.3
14.10
HYDROGENATION
306
CARBON-CARBON
BOND
FORMATION
307
METATHESIS
308
OXIDATION
309
REACTIONS
WITH
CARBON
MONOXIDE
311
HETEROGENOUS
CATALYSIS
311
ZIEGLER-NATTA
CATALYST
313
STEREOREGULARITY
313
WATER
GAS
REACTION
315
ZEOLITES
316
CONCLUSION
317
REFERENCES
318
15
CLUSTER
COMPOUNDS:
BORANES,
HETEROBORANES,
AND
METALLABORANES
321
ELYOR
BERDIMURODOV,
KHASON
BERDIMURODOV,
ABDUVALI
KHOLIKOV,
KHAMDOM
AKBAROV,
OMAR
DAGDAG,
BRAHIM
EL
IBRAHIMI,
AND
DAKESHWAR
KUMAR
VERMA
15.1
15.1.1
INTRODUCTION
321
FUNDAMENTALS
OF
CLUSTER
COMPOUNDS:
BORANES,
HETEROBORANES,
AND
METALLABORANES
321
15.2
15.2.1
MAIN
PART
324
CLUSTER
COMPOUNDS
OF
BORANES
AND
HETEROBORANES:
SYNTHESIS,
REACTIONS,
AND
APPLICATIONS
324
15.2.1.1
15.2.1.2
15.2.1.3
15.2.1.4
15.2.2
BASICS
324
SYNTHESIS
324
REACTIONS
324
APPLICATIONS
327
CLUSTER
COMPOUNDS
OF
METALLABORANES:
SYNTHESIS,
REACTIONS,
AND
APPLICATIONS
327
15.2.2.1
15.2.2.2
15.2.2.3
15.2.2.4
15.3
BASICS
327
SYNTHESIS
327
REACTIONS
330
APPLICATIONS
330
CONCLUSION
332
REFERENCES
332
16
APPLICATIONS
OF
ORGANOMETALLIC
COMPOUNDS
FOR
CARBON
DIOXIDE
FIXATION,
REDUCTION,
GAS
ADSORPTION,
AND
GAS
PURIFICATION
335
ZHOVETA
YHOBU,
MONICA
VIJAYAKUMOR,
NAGARAJU
D.
HANUMANTHARAYUDU,
AND
SRINIVASA
BUDOGUMPI
16.1
16.2
16.2.1
16.2.2
ORGANOMETALLIC
COMPOUNDS
FOR
FIXATION
OF
CO
2
335
ORGANOMETALLIC
COMPOUNDS
IN
REDUCTION
OF
CO
2
336
NICKEL
COMPLEXES
338
IRON
AND
MANGANESE
COMPLEXES
339
XVI
CONTENTS
16.2.3
16.2.4
16.2.5
16.2.6
16.3
16.3.1
16.3.2
16.3.2.1
16.3.2.2
16.4
16.4.1
16.4.2
16.4.3
COPPER
AND
COBALT
COMPLEXES
341
PALLADIUM
COMPLEXES
342
RUTHENIUM,
RHENIUM,
AND
RHODIUM
COMPLEXES
343
N-HETEROCYCLIC
CARBENES
344
ORGANOMETALLIC
COMPOUNDS
IN
GAS
ADSORPTION
AND
PURIFICATION
346
METAL
ORGANIC
FRAMEWORKS
(MOFS)
FOR
GAS
ADSORPTION
347
CLASSIFICATION
OF
MOFS
AS
ADSORBENTS
FOR
GAS
SEPARATION
348
RIGID
MOFS
AS
ADSORBENTS
FOR
SELECTIVE
GAS
SEPARATION
348
FLEXIBLE
MOFS
AS
ADSORBENTS
FOR
GAS
SEPARATION
349
GAS
PURIFICATION
WITH
MOFS
352
KINETIC
SEPARATION
352
QUANTUM
SIEVING
EFFECT
FOR
H2/D2
SEPARATION
352
MEMBRANE-BASED
GAS
SEPARATION
353
REFERENCES
353
17
EMERGING
ROLE
OF
ORGANOMETALLIC
COMPOUNDS
FOR
DRUG
DELIVERY,
RENEWABLE
ENERGY,
AND
WASTEWATER
TREATMENT
357
SHOKOH
PARHAM,
HADI
SARVARI,
SEYED-SHIRIN
PARHAM,
AND
HADI
NUR
17.1
17.2
17.3
17.4
17.5
17.6
17.7
INTRODUCTION
357
ORGANOMETALLIC
COMPOUNDS
359
ORGANOMETALLIC
COMPOUNDS
FOR
DRUG
DELIVERY
363
ORGANOMETALLIC
COMPOUNDS
FOR
RENEWABLE
ENERGY
364
ORGANOMETALLIC
COMPOUNDS
FOR
WASTEWATER
TREATMENT
365
CONCLUSION
366
OUTLOOK
366
ACKNOWLEDGMENT
367
REFERENCES
367
18
COMPUTATIONAL
APPROACHES
IN
SOME
IMPORTANT
ORGANOMETALLIC
CATALYSIS
REACTION
375
PRATIBHA
GUMASTA,
NARESH
C.
DESHMUKH,
ASEEL
A,
KADHEM,
SNEHLATA
KATHERIA,
REENA
RAWAT,
AND
BHAWANA
JAIN
18.1
18.2
18.2.1
18.2.2
18.3
18.3.1
18.3.1.1
18.3.1.2
18.3.2
18.3.2.1
18.3.2.2
18.3.2.3
18.3.2.4
INTRODUCTION
375
COMPUTATIONAL
METHOD
376
GEOMETRY
CALCULATION
377
ENERGY
378
ORGANOMETALLIC
CATALYSIS
REACTIONS
379
PALLADIUM
379
C
-
H
BOND
ACTIVATION
380
COUPLING
REACTIONS
382
NICKEL
386
COUPLING
REACTIONS
386
C
-
O
BOND
ACTIVATION
388
CYCLIZATION
REACTIONS
389
OLEFIN
FUNCTIONALIZATION
389
CONTENTS
XVII
18.3.3
RHODIUM
390
18.3.3.1
HYDROGENATION
390
18.3.3.2
OLEFIN
FUNCTIONALIZATION
391
18.3.3.3
REACTIONS
OF
RH
CARBENOIDS
AND
NITRENOIDS
391
18.3.4
IRIDIUM
394
18.3.4.1
HYDROGENATION
394
18.3.4.2
OTHER
BOND
ACTIVATIONS
396
18.4
CONCLUSION
396
REFERENCES
397
INDEX
409 |
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| genre_facet | Aufsatzsammlung |
| id | DE-604.BV048815905 |
| illustrated | Illustrated |
| index_date | 2024-07-03T21:31:30Z |
| indexdate | 2024-07-10T09:46:45Z |
| institution | BVB |
| institution_GND | (DE-588)16179388-5 |
| isbn | 9783527351787 3527351787 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-034081735 |
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| physical | xxi, 420 Seiten Illustrationen |
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| spelling | Organometallic compounds synthesis, reactions, and applications edited by Dakeshwar Kumar Verma, Jeenat Aslam Weinheim Wiley-VCH [2023] © 2023 xxi, 420 Seiten Illustrationen txt rdacontent n rdamedia nc rdacarrier Metallorganische Chemie (DE-588)4602390-2 gnd rswk-swf Metallorganische Verbindungen (DE-588)4038906-6 gnd rswk-swf CH40: Katalyse CH72: Koordinationschemie CH86: Organometallchemie Catalysis Chemie Chemistry Coordination Chemistry Katalyse Koordinationschemie Metallorganische Verbindungen Organometallchemie Organometallic Chemistry (DE-588)4143413-4 Aufsatzsammlung gnd-content Metallorganische Verbindungen (DE-588)4038906-6 s DE-604 Metallorganische Chemie (DE-588)4602390-2 s Verma, Dakeshwar Kumar (DE-588)1289294488 edt Aslam, Jeenat (DE-588)1280155973 edt Wiley-VCH (DE-588)16179388-5 pbl Erscheint auch als Online-Ausgabe, EPUB 978-3-527-84093-9 Erscheint auch als Online-Ausgabe, PDF 978-3-527-84092-2 Erscheint auch als Online-Ausgabe, oBook 978-3-527-84094-6 X:MVB http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-35178-7/ DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=034081735&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Organometallic compounds synthesis, reactions, and applications Metallorganische Chemie (DE-588)4602390-2 gnd Metallorganische Verbindungen (DE-588)4038906-6 gnd |
| subject_GND | (DE-588)4602390-2 (DE-588)4038906-6 (DE-588)4143413-4 |
| title | Organometallic compounds synthesis, reactions, and applications |
| title_auth | Organometallic compounds synthesis, reactions, and applications |
| title_exact_search | Organometallic compounds synthesis, reactions, and applications |
| title_exact_search_txtP | Organometallic compounds synthesis, reactions, and applications |
| title_full | Organometallic compounds synthesis, reactions, and applications edited by Dakeshwar Kumar Verma, Jeenat Aslam |
| title_fullStr | Organometallic compounds synthesis, reactions, and applications edited by Dakeshwar Kumar Verma, Jeenat Aslam |
| title_full_unstemmed | Organometallic compounds synthesis, reactions, and applications edited by Dakeshwar Kumar Verma, Jeenat Aslam |
| title_short | Organometallic compounds |
| title_sort | organometallic compounds synthesis reactions and applications |
| title_sub | synthesis, reactions, and applications |
| topic | Metallorganische Chemie (DE-588)4602390-2 gnd Metallorganische Verbindungen (DE-588)4038906-6 gnd |
| topic_facet | Metallorganische Chemie Metallorganische Verbindungen Aufsatzsammlung |
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