Modern petrochemical technology: methods, manufacturing and applications
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| Main Authors: | , , , , , |
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| Format: | Book |
| Language: | English |
| Published: |
Weinheim
WILEY-VCH
[2021]
|
| Subjects: | |
| Online Access: | Kurzbeschreibung Inhaltsverzeichnis Inhaltsverzeichnis |
| Physical Description: | xvii, 296 Seiten Illustrationen, Diagramme |
| ISBN: | 9783527345229 3527345221 |
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MARC
| LEADER | 00000nam a2200000 c 4500 | ||
|---|---|---|---|
| 001 | BV047651160 | ||
| 003 | DE-604 | ||
| 005 | 20220503 | ||
| 007 | t | ||
| 008 | 211221s2021 gw a||| |||| 00||| eng d | ||
| 016 | 7 | |a 1217133127 |2 DE-101 | |
| 020 | |a 9783527345229 |c hbk. |9 978-3-527-34522-9 | ||
| 020 | |a 3527345221 |9 3-527-34522-1 | ||
| 024 | 3 | |a 9783527345229 | |
| 035 | |a (OCoLC)1257481719 | ||
| 035 | |a (DE-599)DNB1217133127 | ||
| 040 | |a DE-604 |b ger |e rda | ||
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| 044 | |a gw |c XA-DE-BW | ||
| 049 | |a DE-11 |a DE-703 | ||
| 084 | |a VN 5450 |0 (DE-625)147569:253 |2 rvk | ||
| 100 | 1 | |a Kulprathipanja, Santi |e Verfasser |0 (DE-588)1237017955 |4 aut | |
| 245 | 1 | 0 | |a Modern petrochemical technology |b methods, manufacturing and applications |c Santi Kulprathipanja, James E. Rekoske, Daniel Wei, Robert V. Slone, Trung Pham, Chunqing Liu |
| 264 | 1 | |a Weinheim |b WILEY-VCH |c [2021] | |
| 264 | 4 | |c © 2021 | |
| 300 | |a xvii, 296 Seiten |b Illustrationen, Diagramme | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 0 | 7 | |a Petrochemie |0 (DE-588)4173958-9 |2 gnd |9 rswk-swf |
| 653 | |a Chemical Engineering | ||
| 653 | |a Chemie | ||
| 653 | |a Chemische Verfahrenstechnik | ||
| 653 | |a Chemistry | ||
| 653 | |a Energie | ||
| 653 | |a Energy | ||
| 653 | |a Erdgas u. Erdöl | ||
| 653 | |a Natural Gas & Petroleum Products | ||
| 653 | |a Petrochemie / Brennstoffindustrie | ||
| 653 | |a Petrochemistry / Fuel | ||
| 653 | |a Process Engineering | ||
| 653 | |a Prozesssteuerung | ||
| 653 | |a CG10: Prozesssteuerung | ||
| 653 | |a CH34: Petrochemie / Brennstoffindustrie | ||
| 653 | |a EG12: Erdgas u. Erdöl | ||
| 653 | |a Petrochemie | ||
| 689 | 0 | 0 | |a Petrochemie |0 (DE-588)4173958-9 |D s |
| 689 | 0 | |5 DE-604 | |
| 700 | 1 | |a Rekoske, James E. |e Verfasser |4 aut | |
| 700 | 1 | |a Wei, Daniel |e Verfasser |4 aut | |
| 700 | 1 | |a Slone, Robert V. |e Verfasser |4 aut | |
| 700 | 1 | |a Pham, Trung |e Verfasser |4 aut | |
| 700 | 1 | |a Liu, Chunqing |e Verfasser |4 aut | |
| 710 | 2 | |a Wiley-VCH |0 (DE-588)16179388-5 |4 pbl | |
| 776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe, PDF |z 978-3-527-81819-8 |
| 776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe, EPUB |z 978-3-527-81817-4 |
| 776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe |z 978-3-527-81816-7 |
| 856 | 4 | 2 | |m X:MVB |u http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-34522-9/ |3 Kurzbeschreibung |
| 856 | 4 | 2 | |m B:DE-101 |q application/pdf |u https://d-nb.info/1217133127/04 |3 Inhaltsverzeichnis |
| 856 | 4 | 2 | |m DNB Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=033035214&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 999 | |a oai:aleph.bib-bvb.de:BVB01-033035214 | ||
Record in the Search Index
| _version_ | 1804183115408605184 |
|---|---|
| adam_text | CONTENTS
FOREWORD
XI
PREFACE
XIII
PART
I
INTRODUCTION
1
1
REFINERY
AND
PETROCHEMICAL
PROCESSES
3
1.1
INTRODUCTION
3
1.2
PETROLEUM
3
1.2.1
FORMS
OF
PETROLEUM
4
1.2.1.1
GASEOUS
PETROLEUM:
GASEOUS
PETROLEUM
CAN
BE
DEFINED
AS
NATURAL
GAS
OR
SHALE
GAS
4
1.2.1.2
LIQUID
PETROLEUM:
LIQUID
PETROLEUM
CAN
BE
SEPARATED
INTO
LIGHT
CRUDE
OIL
AND
HEAVY
CRUDE
OIL
4
1.2.1.3
SOLID
PETROLEUM:
BITUMEN
5
1.2.2
COMPOSITION
OF
PETROLEUM
5
1.2.3
PETROLEUM
REFINERY
6
1.2.4
PETROLEUM
PRODUCTS
9
1.3
PETROCHEMICAL
BUILDING
BLOCKS
10
REFERENCES
16
2
PETROCHEMICAL
MARKETS
17
2.1
INTRODUCTION
17
2.2
THE
MARKET
FOR
ETHYLENE
18
2.3
THE
MARKET
FOR
PROPYLENE
22
2.4
THE
MARKET
FOR
C4
OLEFINS
AND
DIOLEFINS
26
2.5
THE
MARKET
FOR
AROMATIC
COMPOUNDS
32
2.5.1
THE
MARKET
FOR
BENZENE
32
2.5.2
THE
MARKET
FOR
TOLUENE
34
2.5.3
THE
MARKET
FOR
XYLENE
36
2.6
THE
MARKET
FOR
SYNTHESIS
GAS
37
VI
CONTENTS
2.6.1
2.6.2
THE
MARKET
FOR
AMMONIA
38
THE
MARKET
FOR
METHANOL
39
REFERENCES
40
PART
II
OLEFINS
AND
SYNTHESIS
GAS
43
3
3.1
3.2
3.3
3.3.1
3.3.1.1
3.3.1.2
3.3.1.3
3.3.2
3.3.3
3.3.4
3.3.5
3.4
3.4.1
3.4.2
3.5
3.6
3.6.1
3.6.2
3.6.2.1
3.6.2.2
3.6.2.3
3.6.3
OLEFINS
AND
SYNTHESIS
GAS
PRODUCTION
TECHNOLOGIES
45
INTRODUCTION
45
STEAM
CRACKING
45
LIGHT
PARAFFIN
DEHYDROGENATION
48
PROCESS
AND
CATALYST
48
REACTOR
SECTION
49
PRODUCT
RECOVERY
SECTION
50
CATALYST
REGENERATION
SECTION
50
UOP
C
3
OLEFLEX
COMPLEX
51
UOP
ISO-C
4
OLEFLEX
COMPLEX
54
UOP
C
3
/C
4
OLEFLEX
COMPLEX
56
UOP
MIXED-C
4
OLEFLEX
COMPLEX
56
HEAVY
NORMAL-PARAFFIN
DEHYDROGENATION
57
PRODUCTION
OF
NORMAL-PARAFFINS
58
PRODUCTION
OF
LAB
59
METHANOL
TO
OLEFINS
59
SYNGAS
PRODUCTION
62
REMOVAL
OF
IMPURITIES
IN
RAW
NATURAL
GAS
63
CONVERSION
OF
NATURAL
GAS
TO
SYNGAS
64
STEAM
REFORMING
65
PARTIAL
OXIDATION
65
AUTOTHERMAL
REFORMING
66
COAL
GASIFICATION
TO
SYNGAS
67
REFERENCES
72
4
4.1
4.2
4.2.1
4.2.2
4.2.3
4.3
4.3.1
4.3.2
4.3.3
4.4
4.4.1
4.4.2
4.4.3
USES
OF
OLEFINS
AND
SYNTHESIS
GAS
75
INTRODUCTION
75
USES
OF
ETHYLENE
75
ETHYLENE
TO
POLYETHYLENE
75
ETHYLENE
TO
POLYVINYL
CHLORIDE
77
ETHYLENE
TO
MONOETHYLENE
GLYCOL
78
USES
OF
PROPYLENE
79
PROPYLENE
TO
POLYPROPYLENE
79
PROPYLENE
TO
PROPYLENE
OXIDE
80
PROPYLENE
TO
ACRYLONITRILE
81
USES
OF
SYNGAS
82
SYNGAS
TO
HYDROGEN
82
SYNGAS
TO
AMMONIA
82
SYNGAS
TO
METHANOL
83
REFERENCES
83
CONTENTS
VII
PART
III
AROMATICS
85
5
AROMATIC
PRODUCTION
TECHNOLOGIES
87
5.1
INTRODUCTION
87
5.2
AROMATIC
PRODUCTION
87
5.2.1
REFORMING
TECHNOLOGY
88
5.2.1.1
SEMI-REGENERATIVE
REFORMING
91
5.2.1.2
CYCLIC
REFORMING
91
5.2.1.3
CCR
REFORMING
91
5.2.1.4
HIGH-PRESSURE
VS.
LOW-PRESSURE
CONSIDERATION
94
5.2.2
AROMATIC
TRANSALKYLATION
AND
DISPROPORTIONATION
TECHNOLOGY
95
5.2.2.1
SELECTIVE
TOLUENE
DISPROPORTIONATION
PROCESS
99
5.2.3
ISOMERIZATION OF
AROMATICS
100
5.2.3.1
REACTION
MECHANISM
100
5.2.4
TOLUENE
METHYLATION
103
5.2.5
AROMATIZATION
OF
LIGHT
NAPHTHA/HYDROCARBONS
105
5.2.5.1
MECHANISM
106
5.2.6
CATALYTIC
CRACKING
107
5.2.7
PRODUCTION
FROM
PYROLYSIS
AND
COKING
111
5.2.7.1
STEAM
CRACKING/PYROLYSIS
GASOLINE
111
5.2.7.2
COKE-OVEN
BENZOLE
113
5.2.7.3
BIOMASS
PYROLYSIS
115
5.3
SUMMARY
119
REFERENCES
119
6
USES
OF
AROMATICS
121
6.1
INTRODUCTION
121
6.2
POLYMER
PRODUCTION
FROM
BASIC
AROMATIC
BUILDING
BLOCKS
121
6.2.1
ETHYLBENZENE
AND
STYRENE
PRODUCTION
122
6.2.2
CYCLOHEXANE
TO
NYLON
6,
NYLON
6,6
123
6.2.2.1
ADIPIC
ACID
PRODUCTION
124
6.2.2.2
CAPROLACTAM
SYNTHESIS
125
6.2.23
PROPERTIES
OF
NYLON
6
VS.
NYLON
6,6
128
6.2.3
PRODUCTION
OF
CUMENE
128
6.23.1
BISPHENOL
A
PRODUCTION
130
6.23.2
PRODUCTION
OF
NITROBENZENE
130
6.233
PRODUCTION
OF
ANILINE
131
6.2.3.4
PRODUCTION
OF
MDI
AND
POLY-MDI
(PMDI)
131
6.23.5
PRODUCTION
OF
TOLUENE
DIISOCYANATE
(TDI)
131
6.23.6
PRODUCTION
OF
POLYURETHANE
132
6.23.7
ALKYLBENZENES
AND
ALKYLBENZENE
SULFONATES
132
6.2.3.8
MALEIC
ANHYDRIDE
FROM
BENZENE
133
6.23.9
DICHLORODIPHENYLTRICHLOROETHANE
(DDT)
FROM
BENZENE
133
6.3
RESINS
AND
CHEMICALS
PRODUCTION
133
6.3.1
UNSATURATED
POLYESTER
RESINS
SYNTHESIS
138
6.3.2
ALKYD
RESIN
SYNTHESIS:
139
VIII
CONTENTS
6.3.3
P-XYLENE
OXIDATION
TO
TEREPHTHALIC
ACID
139
6.3.4
POLYETHYLENE
TEREPHTHALATE),
PET,
AND
POLYETHYLENE
NAPHTHALATE),
PEN
141
6.4
SUMMARY
142
ACKNOWLEDGMENTS
142
REFERENCES
143
PART
IV
INDUSTRIAL
SEPARATION
145
7
ADSORPTION
147
7.1
PRINCIPLE
OF
ADSORPTION
147
7.2
ADSORBENTS
148
7.2.1
ZEOLITE
ADSORBENTS
148
7.2.2
ZEOLITE
SYNTHESIS
150
7.2.3
FORMING
ZEOLITE
POWDERS
INTO
USABLE
SHAPES
152
7.2.3.1
PELLETIZATION
OF
ZEOLITE
POWDER
TO
EXTRUDATE
ADSORBENT
153
7.
2.3.2
ACCRETION
OF
ZEOLITE
POWDER
TO
BEAD
ADSORBENT
153
7.3
BULK
LIQUID-ADSORPTIVE
SEPARATION
154
7.3.1
MODES
OF
LIQUID-ADSORPTIVE
SEPARATION
154
7.3.1.1
ADSORPTION
ISOTHERMS
156
7.3.1.2
PULSE-TEST
PROCEDURE
156
7.3.1.3
BREAKTHROUGH
PROCEDURE
157
7.3.1.4
SIMULATED
MOVING-BED
OPERATION:
SORBEX
TECHNOLOGY
158
7.3.2
LIQUID-ADSORPTIVE
SEPARATION
PROCESSES
159
7.3.2.1
EQUILIBRIUM-SELECTIVE
ADSORPTION
159
73.2.2
RATE-SELECTIVE
ADSORPTION
166
73.23
SHAPE-SELECTIVE
ADSORPTION
168
7.3.2.4
ION
EXCHANGE
169
73.2.5
REACTIVE
ADSORPTION
170
7.4
COMMERCIAL
BULK
LIQUID-ADSORPTIVE
PROCESS
170
7.4.1
PAREX
170
7.4.2
MX
SORBEXYY
173
ACKNOWLEDGMENT
174
REFERENCES
174
8
DISTILLATION
179
8.1
INTRODUCTION
TO
DISTILLATION
179
8.2
PRINCIPLES
AND
SYSTEMS
181
8.2.1
VAPOR-LIQUID
EQUILIBRIUM
(VLE)
THEORY
181
8.2.2
MCCABE-THIELE
DIAGRAM
182
8.2.3
FACTORS
FOR
VLE-BASED
DISTILLATION
DESIGN
184
8.2.3.1
RELATIVE
VOLATILITY
184
8.23.2
ACTIVITY
COEFFICIENT
185
8.233
SOLUBILITY
185
8.2.3.4
AZEOTROPES:
MAXIMUM
CONCENTRATION
LIMIT
185
8.23.5
SURFACE
AREA
186
CONTENTS
IX
8.2.4
8.2.4.1
8.2.4.2
8.3
8.3.1
8.3.2
8.3.3
8.4
8.4.1
8.4.2
8.5
8.5.1
8.5.2
8.5.3
8.5.4
8.5.5
OPERATING
MODES
OF
DISTILLATION
186
BATCH
VS.
CONTINUOUS
186
TRAY
VS.
PACKED
COLUMN
187
DISTILLATION
COLUMNS
AND
TRAYS
188
FLOW
WITHIN
THE
DISTILLATION
COLUMN
188
MULTICOMPONENT
DISTILLATION
189
TRAY
TYPES:
SIEVE,
VALVE,
BUBBLE-CAP
190
DISTILLATION
PACKING
MATERIALS
192
RANDOM
PACKING
193
STRUCTURED
PACKING
194
COMMERCIAL
EXAMPLES
195
CRUDE
OIL
DISTILLATION
195
EXTRACTIVE
DISTILLATION
198
AZEOTROPIC
DISTILLATION
198
DIVIDING
WALL
COLUMN
DISTILLATION
198
REACTIVE
DISTILLATION
200
REFERENCES
200
9
9.1
9.2
9.2.1
9.2.1.1
9.2.1.2
9.2.2
9.2.2.1
9.2.2.2
9.2.3
9.2.3.1
9.2.3.2
9.3
9.4
9.5
MEMBRANES
203
PRINCIPLE
AND
BACKGROUND
203
TYPES
AND
PREPARATION
OF
MEMBRANES
204
POLYMERIC
MEMBRANES
205
FUNDAMENTALS
OF
POLYMERIC
MEMBRANES
205
PREPARATION
OF
POLYMERIC
MEMBRANES
207
INORGANIC
MEMBRANES
213
INTRODUCTION
TO
MICROPOROUS
CRYSTALLINE
INORGANIC
MEMBRANES
214
PREPARATION
OF
MICROPOROUS
CRYSTALLINE
INORGANIC
MEMBRANES
215
MIXED-MATRIX
MEMBRANES
218
INTRODUCTION
TO
MIXED-MATRIX
MEMBRANES
219
PREPARATION
OF
MIXED-MATRIX
MEMBRANES
221
MEMBRANE
MODULES
223
MEMBRANE
REACTORS
225
COMMERCIAL
APPLICATIONS
OF
MEMBRANES
227
REFERENCES
235
10
10.1
10.2
10.3
10.3.1
10.3.1.1
10.3.1.2
10.3.1.3
10.3.2
10.4
10.4.1
ABSORPTION
241
INTRODUCTION
TO
ABSORPTION
241
ACID
GAS
REMOVAL
243
CHEMICAL
SOLVENT
245
AMINES
PROCESS
246
MONOETHANOLAMINE
(PRIMARY
AMINE)
248
DIETHANOLAMINE
(SECONDARY
AMINE)
248
METHYLDIETHANOLAMINE
(TERTIARY
AMINE)
248
BENFIELDYY
PROCESS
249
PHYSICAL
SOLVENT
251
SOLVENT
SELECTION
252
X
CONTENTS
10.4.1.1
DMEPG
(DIMETHYL
ETHER
OF
POLYETHYLENE
GLYCOL,
(CH
3
O(C
2
H
4
O)
N
CH
3
))
252
10.4.1.2
MEOH
(METHANOL,
H
3
C0H)
253
10.4.1.3
PC
(PROPYLENE
CARBONATE,
C
4
H
6
O
3
)
254
10.4.2
FLOW
SCHEMES
254
10.4.3
SELEXOLYY
PROCESS
255
10.5
ADDITIONAL
COMMERCIAL
USES
OF
ABSORPTION
257
10.5.1
GLYCOL
DEHYDRATION
257
10.5.2
ORGANICS
FROM
AIR
(AIR
STRIPPING)
259
REFERENCES
259
11
EXTRACTION
TECHNOLOGY
261
11.1
INTRODUCTION
261
11.2
EXTRACTION
PROCESSES
261
11.2.1
LIQUID-LIQUID
EXTRACTION
(LLE)
261
11.2.2
SUPERCRITICAL
FLUID
EXTRACTION
(SCFE)
263
11.2.3
LIQUID-LIQUID
EXTRACTION
VS.
SUPERCRITICAL
FLUID
EXTRACTION
264
11.3
SOLVENTS
264
11.3.1
SELECTIVITY
264
11.3.2
RECOVERABILITY
265
11.3.3
IMMISCIBLE
265
11.3.4
DENSITY
265
11.3.5
CHEMICAL
STABILITY
265
11.3.6
LOADING
CAPACITY
(L
A
)
265
11.4
EXTRACTORS
266
11.4.1
SIMPLE
EXTRACTOR
266
11.4.1.1
SIEVE-TRAY
COLUMN
266
11.4.1.2
PACKED
COLUMN
267
11.4.2
MECHANICAL
EXTRACTORS
268
11.4.2.1
ROTARY
AND
RECIPROCAL
EXTRACTORS
268
11.4.2.2
CENTRIFUGAL
EXTRACTORS
268
11.4.3
SIMPLE
EXTRACTORS
VS.
MECHANICAL
EXTRACTORS
269
11.5
INDUSTRIAL
EXTRACTION
269
11.5.1
HYDROMETALLURGY
EXTRACTION
269
11.5.1.1
ZIRCONIUM/HAFNIUM
SEPARATION
270
11.5.1.2
URANIUM/PLUTONIUM
SEPARATION
272
11.5.2
HYDROCARBON
EXTRACTION
272
11.5.2.1
M-XYLENE/XYLENE
ISOMER
SEPARATION
272
11.5.2.2
SULFOLANE
PROCESS
274
11.5.2.3
MEROX
PROCESS
277
11.6
SUMMARY
280
ACKNOWLEDGMENTS
280
REFERENCES
281
INDEX
283
|
| adam_txt |
CONTENTS
FOREWORD
XI
PREFACE
XIII
PART
I
INTRODUCTION
1
1
REFINERY
AND
PETROCHEMICAL
PROCESSES
3
1.1
INTRODUCTION
3
1.2
PETROLEUM
3
1.2.1
FORMS
OF
PETROLEUM
4
1.2.1.1
GASEOUS
PETROLEUM:
GASEOUS
PETROLEUM
CAN
BE
DEFINED
AS
NATURAL
GAS
OR
SHALE
GAS
4
1.2.1.2
LIQUID
PETROLEUM:
LIQUID
PETROLEUM
CAN
BE
SEPARATED
INTO
LIGHT
CRUDE
OIL
AND
HEAVY
CRUDE
OIL
4
1.2.1.3
SOLID
PETROLEUM:
BITUMEN
5
1.2.2
COMPOSITION
OF
PETROLEUM
5
1.2.3
PETROLEUM
REFINERY
6
1.2.4
PETROLEUM
PRODUCTS
9
1.3
PETROCHEMICAL
BUILDING
BLOCKS
10
REFERENCES
16
2
PETROCHEMICAL
MARKETS
17
2.1
INTRODUCTION
17
2.2
THE
MARKET
FOR
ETHYLENE
18
2.3
THE
MARKET
FOR
PROPYLENE
22
2.4
THE
MARKET
FOR
C4
OLEFINS
AND
DIOLEFINS
26
2.5
THE
MARKET
FOR
AROMATIC
COMPOUNDS
32
2.5.1
THE
MARKET
FOR
BENZENE
32
2.5.2
THE
MARKET
FOR
TOLUENE
34
2.5.3
THE
MARKET
FOR
XYLENE
36
2.6
THE
MARKET
FOR
SYNTHESIS
GAS
37
VI
CONTENTS
2.6.1
2.6.2
THE
MARKET
FOR
AMMONIA
38
THE
MARKET
FOR
METHANOL
39
REFERENCES
40
PART
II
OLEFINS
AND
SYNTHESIS
GAS
43
3
3.1
3.2
3.3
3.3.1
3.3.1.1
3.3.1.2
3.3.1.3
3.3.2
3.3.3
3.3.4
3.3.5
3.4
3.4.1
3.4.2
3.5
3.6
3.6.1
3.6.2
3.6.2.1
3.6.2.2
3.6.2.3
3.6.3
OLEFINS
AND
SYNTHESIS
GAS
PRODUCTION
TECHNOLOGIES
45
INTRODUCTION
45
STEAM
CRACKING
45
LIGHT
PARAFFIN
DEHYDROGENATION
48
PROCESS
AND
CATALYST
48
REACTOR
SECTION
49
PRODUCT
RECOVERY
SECTION
50
CATALYST
REGENERATION
SECTION
50
UOP
C
3
OLEFLEX
COMPLEX
51
UOP
ISO-C
4
OLEFLEX
COMPLEX
54
UOP
C
3
/C
4
OLEFLEX
COMPLEX
56
UOP
MIXED-C
4
OLEFLEX
COMPLEX
56
HEAVY
NORMAL-PARAFFIN
DEHYDROGENATION
57
PRODUCTION
OF
NORMAL-PARAFFINS
58
PRODUCTION
OF
LAB
59
METHANOL
TO
OLEFINS
59
SYNGAS
PRODUCTION
62
REMOVAL
OF
IMPURITIES
IN
RAW
NATURAL
GAS
63
CONVERSION
OF
NATURAL
GAS
TO
SYNGAS
64
STEAM
REFORMING
65
PARTIAL
OXIDATION
65
AUTOTHERMAL
REFORMING
66
COAL
GASIFICATION
TO
SYNGAS
67
REFERENCES
72
4
4.1
4.2
4.2.1
4.2.2
4.2.3
4.3
4.3.1
4.3.2
4.3.3
4.4
4.4.1
4.4.2
4.4.3
USES
OF
OLEFINS
AND
SYNTHESIS
GAS
75
INTRODUCTION
75
USES
OF
ETHYLENE
75
ETHYLENE
TO
POLYETHYLENE
75
ETHYLENE
TO
POLYVINYL
CHLORIDE
77
ETHYLENE
TO
MONOETHYLENE
GLYCOL
78
USES
OF
PROPYLENE
79
PROPYLENE
TO
POLYPROPYLENE
79
PROPYLENE
TO
PROPYLENE
OXIDE
80
PROPYLENE
TO
ACRYLONITRILE
81
USES
OF
SYNGAS
82
SYNGAS
TO
HYDROGEN
82
SYNGAS
TO
AMMONIA
82
SYNGAS
TO
METHANOL
83
REFERENCES
83
CONTENTS
VII
PART
III
AROMATICS
85
5
AROMATIC
PRODUCTION
TECHNOLOGIES
87
5.1
INTRODUCTION
87
5.2
AROMATIC
PRODUCTION
87
5.2.1
REFORMING
TECHNOLOGY
88
5.2.1.1
SEMI-REGENERATIVE
REFORMING
91
5.2.1.2
CYCLIC
REFORMING
91
5.2.1.3
CCR
REFORMING
91
5.2.1.4
HIGH-PRESSURE
VS.
LOW-PRESSURE
CONSIDERATION
94
5.2.2
AROMATIC
TRANSALKYLATION
AND
DISPROPORTIONATION
TECHNOLOGY
95
5.2.2.1
SELECTIVE
TOLUENE
DISPROPORTIONATION
PROCESS
99
5.2.3
ISOMERIZATION OF
AROMATICS
100
5.2.3.1
REACTION
MECHANISM
100
5.2.4
TOLUENE
METHYLATION
103
5.2.5
AROMATIZATION
OF
LIGHT
NAPHTHA/HYDROCARBONS
105
5.2.5.1
MECHANISM
106
5.2.6
CATALYTIC
CRACKING
107
5.2.7
PRODUCTION
FROM
PYROLYSIS
AND
COKING
111
5.2.7.1
STEAM
CRACKING/PYROLYSIS
GASOLINE
111
5.2.7.2
COKE-OVEN
BENZOLE
113
5.2.7.3
BIOMASS
PYROLYSIS
115
5.3
SUMMARY
119
REFERENCES
119
6
USES
OF
AROMATICS
121
6.1
INTRODUCTION
121
6.2
POLYMER
PRODUCTION
FROM
BASIC
AROMATIC
BUILDING
BLOCKS
121
6.2.1
ETHYLBENZENE
AND
STYRENE
PRODUCTION
122
6.2.2
CYCLOHEXANE
TO
NYLON
6,
NYLON
6,6
123
6.2.2.1
ADIPIC
ACID
PRODUCTION
124
6.2.2.2
CAPROLACTAM
SYNTHESIS
125
6.2.23
PROPERTIES
OF
NYLON
6
VS.
NYLON
6,6
128
6.2.3
PRODUCTION
OF
CUMENE
128
6.23.1
BISPHENOL
A
PRODUCTION
130
6.23.2
PRODUCTION
OF
NITROBENZENE
130
6.233
PRODUCTION
OF
ANILINE
131
6.2.3.4
PRODUCTION
OF
MDI
AND
POLY-MDI
(PMDI)
131
6.23.5
PRODUCTION
OF
TOLUENE
DIISOCYANATE
(TDI)
131
6.23.6
PRODUCTION
OF
POLYURETHANE
132
6.23.7
ALKYLBENZENES
AND
ALKYLBENZENE
SULFONATES
132
6.2.3.8
MALEIC
ANHYDRIDE
FROM
BENZENE
133
6.23.9
DICHLORODIPHENYLTRICHLOROETHANE
(DDT)
FROM
BENZENE
133
6.3
RESINS
AND
CHEMICALS
PRODUCTION
133
6.3.1
UNSATURATED
POLYESTER
RESINS
SYNTHESIS
138
6.3.2
ALKYD
RESIN
SYNTHESIS:
139
VIII
CONTENTS
6.3.3
P-XYLENE
OXIDATION
TO
TEREPHTHALIC
ACID
139
6.3.4
POLYETHYLENE
TEREPHTHALATE),
PET,
AND
POLYETHYLENE
NAPHTHALATE),
PEN
141
6.4
SUMMARY
142
ACKNOWLEDGMENTS
142
REFERENCES
143
PART
IV
INDUSTRIAL
SEPARATION
145
7
ADSORPTION
147
7.1
PRINCIPLE
OF
ADSORPTION
147
7.2
ADSORBENTS
148
7.2.1
ZEOLITE
ADSORBENTS
148
7.2.2
ZEOLITE
SYNTHESIS
150
7.2.3
FORMING
ZEOLITE
POWDERS
INTO
USABLE
SHAPES
152
7.2.3.1
PELLETIZATION
OF
ZEOLITE
POWDER
TO
EXTRUDATE
ADSORBENT
153
7.
2.3.2
ACCRETION
OF
ZEOLITE
POWDER
TO
BEAD
ADSORBENT
153
7.3
BULK
LIQUID-ADSORPTIVE
SEPARATION
154
7.3.1
MODES
OF
LIQUID-ADSORPTIVE
SEPARATION
154
7.3.1.1
ADSORPTION
ISOTHERMS
156
7.3.1.2
PULSE-TEST
PROCEDURE
156
7.3.1.3
BREAKTHROUGH
PROCEDURE
157
7.3.1.4
SIMULATED
MOVING-BED
OPERATION:
SORBEX
TECHNOLOGY
158
7.3.2
LIQUID-ADSORPTIVE
SEPARATION
PROCESSES
159
7.3.2.1
EQUILIBRIUM-SELECTIVE
ADSORPTION
159
73.2.2
RATE-SELECTIVE
ADSORPTION
166
73.23
SHAPE-SELECTIVE
ADSORPTION
168
7.3.2.4
ION
EXCHANGE
169
73.2.5
REACTIVE
ADSORPTION
170
7.4
COMMERCIAL
BULK
LIQUID-ADSORPTIVE
PROCESS
170
7.4.1
PAREX
170
7.4.2
MX
SORBEXYY
173
ACKNOWLEDGMENT
174
REFERENCES
174
8
DISTILLATION
179
8.1
INTRODUCTION
TO
DISTILLATION
179
8.2
PRINCIPLES
AND
SYSTEMS
181
8.2.1
VAPOR-LIQUID
EQUILIBRIUM
(VLE)
THEORY
181
8.2.2
MCCABE-THIELE
DIAGRAM
182
8.2.3
FACTORS
FOR
VLE-BASED
DISTILLATION
DESIGN
184
8.2.3.1
RELATIVE
VOLATILITY
184
8.23.2
ACTIVITY
COEFFICIENT
185
8.233
SOLUBILITY
185
8.2.3.4
AZEOTROPES:
MAXIMUM
CONCENTRATION
LIMIT
185
8.23.5
SURFACE
AREA
186
CONTENTS
IX
8.2.4
8.2.4.1
8.2.4.2
8.3
8.3.1
8.3.2
8.3.3
8.4
8.4.1
8.4.2
8.5
8.5.1
8.5.2
8.5.3
8.5.4
8.5.5
OPERATING
MODES
OF
DISTILLATION
186
BATCH
VS.
CONTINUOUS
186
TRAY
VS.
PACKED
COLUMN
187
DISTILLATION
COLUMNS
AND
TRAYS
188
FLOW
WITHIN
THE
DISTILLATION
COLUMN
188
MULTICOMPONENT
DISTILLATION
189
TRAY
TYPES:
SIEVE,
VALVE,
BUBBLE-CAP
190
DISTILLATION
PACKING
MATERIALS
192
RANDOM
PACKING
193
STRUCTURED
PACKING
194
COMMERCIAL
EXAMPLES
195
CRUDE
OIL
DISTILLATION
195
EXTRACTIVE
DISTILLATION
198
AZEOTROPIC
DISTILLATION
198
DIVIDING
WALL
COLUMN
DISTILLATION
198
REACTIVE
DISTILLATION
200
REFERENCES
200
9
9.1
9.2
9.2.1
9.2.1.1
9.2.1.2
9.2.2
9.2.2.1
9.2.2.2
9.2.3
9.2.3.1
9.2.3.2
9.3
9.4
9.5
MEMBRANES
203
PRINCIPLE
AND
BACKGROUND
203
TYPES
AND
PREPARATION
OF
MEMBRANES
204
POLYMERIC
MEMBRANES
205
FUNDAMENTALS
OF
POLYMERIC
MEMBRANES
205
PREPARATION
OF
POLYMERIC
MEMBRANES
207
INORGANIC
MEMBRANES
213
INTRODUCTION
TO
MICROPOROUS
CRYSTALLINE
INORGANIC
MEMBRANES
214
PREPARATION
OF
MICROPOROUS
CRYSTALLINE
INORGANIC
MEMBRANES
215
MIXED-MATRIX
MEMBRANES
218
INTRODUCTION
TO
MIXED-MATRIX
MEMBRANES
219
PREPARATION
OF
MIXED-MATRIX
MEMBRANES
221
MEMBRANE
MODULES
223
MEMBRANE
REACTORS
225
COMMERCIAL
APPLICATIONS
OF
MEMBRANES
227
REFERENCES
235
10
10.1
10.2
10.3
10.3.1
10.3.1.1
10.3.1.2
10.3.1.3
10.3.2
10.4
10.4.1
ABSORPTION
241
INTRODUCTION
TO
ABSORPTION
241
ACID
GAS
REMOVAL
243
CHEMICAL
SOLVENT
245
AMINES
PROCESS
246
MONOETHANOLAMINE
(PRIMARY
AMINE)
248
DIETHANOLAMINE
(SECONDARY
AMINE)
248
METHYLDIETHANOLAMINE
(TERTIARY
AMINE)
248
BENFIELDYY
PROCESS
249
PHYSICAL
SOLVENT
251
SOLVENT
SELECTION
252
X
CONTENTS
10.4.1.1
DMEPG
(DIMETHYL
ETHER
OF
POLYETHYLENE
GLYCOL,
(CH
3
O(C
2
H
4
O)
N
CH
3
))
252
10.4.1.2
MEOH
(METHANOL,
H
3
C0H)
253
10.4.1.3
PC
(PROPYLENE
CARBONATE,
C
4
H
6
O
3
)
254
10.4.2
FLOW
SCHEMES
254
10.4.3
SELEXOLYY
PROCESS
255
10.5
ADDITIONAL
COMMERCIAL
USES
OF
ABSORPTION
257
10.5.1
GLYCOL
DEHYDRATION
257
10.5.2
ORGANICS
FROM
AIR
(AIR
STRIPPING)
259
REFERENCES
259
11
EXTRACTION
TECHNOLOGY
261
11.1
INTRODUCTION
261
11.2
EXTRACTION
PROCESSES
261
11.2.1
LIQUID-LIQUID
EXTRACTION
(LLE)
261
11.2.2
SUPERCRITICAL
FLUID
EXTRACTION
(SCFE)
263
11.2.3
LIQUID-LIQUID
EXTRACTION
VS.
SUPERCRITICAL
FLUID
EXTRACTION
264
11.3
SOLVENTS
264
11.3.1
SELECTIVITY
264
11.3.2
RECOVERABILITY
265
11.3.3
IMMISCIBLE
265
11.3.4
DENSITY
265
11.3.5
CHEMICAL
STABILITY
265
11.3.6
LOADING
CAPACITY
(L
A
)
265
11.4
EXTRACTORS
266
11.4.1
SIMPLE
EXTRACTOR
266
11.4.1.1
SIEVE-TRAY
COLUMN
266
11.4.1.2
PACKED
COLUMN
267
11.4.2
MECHANICAL
EXTRACTORS
268
11.4.2.1
ROTARY
AND
RECIPROCAL
EXTRACTORS
268
11.4.2.2
CENTRIFUGAL
EXTRACTORS
268
11.4.3
SIMPLE
EXTRACTORS
VS.
MECHANICAL
EXTRACTORS
269
11.5
INDUSTRIAL
EXTRACTION
269
11.5.1
HYDROMETALLURGY
EXTRACTION
269
11.5.1.1
ZIRCONIUM/HAFNIUM
SEPARATION
270
11.5.1.2
URANIUM/PLUTONIUM
SEPARATION
272
11.5.2
HYDROCARBON
EXTRACTION
272
11.5.2.1
M-XYLENE/XYLENE
ISOMER
SEPARATION
272
11.5.2.2
SULFOLANE
PROCESS
274
11.5.2.3
MEROX
PROCESS
277
11.6
SUMMARY
280
ACKNOWLEDGMENTS
280
REFERENCES
281
INDEX
283 |
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| any_adam_object_boolean | 1 |
| author | Kulprathipanja, Santi Rekoske, James E. Wei, Daniel Slone, Robert V. Pham, Trung Liu, Chunqing |
| author_GND | (DE-588)1237017955 |
| author_facet | Kulprathipanja, Santi Rekoske, James E. Wei, Daniel Slone, Robert V. Pham, Trung Liu, Chunqing |
| author_role | aut aut aut aut aut aut |
| author_sort | Kulprathipanja, Santi |
| author_variant | s k sk j e r je jer d w dw r v s rv rvs t p tp c l cl |
| building | Verbundindex |
| bvnumber | BV047651160 |
| classification_rvk | VN 5450 |
| ctrlnum | (OCoLC)1257481719 (DE-599)DNB1217133127 |
| discipline | Chemie / Pharmazie |
| discipline_str_mv | Chemie / Pharmazie |
| format | Book |
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| id | DE-604.BV047651160 |
| illustrated | Illustrated |
| index_date | 2024-07-03T18:49:59Z |
| indexdate | 2024-07-10T09:18:19Z |
| institution | BVB |
| institution_GND | (DE-588)16179388-5 |
| isbn | 9783527345229 3527345221 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-033035214 |
| oclc_num | 1257481719 |
| open_access_boolean | |
| owner | DE-11 DE-703 |
| owner_facet | DE-11 DE-703 |
| physical | xvii, 296 Seiten Illustrationen, Diagramme |
| publishDate | 2021 |
| publishDateSearch | 2021 |
| publishDateSort | 2021 |
| publisher | WILEY-VCH |
| record_format | marc |
| spelling | Kulprathipanja, Santi Verfasser (DE-588)1237017955 aut Modern petrochemical technology methods, manufacturing and applications Santi Kulprathipanja, James E. Rekoske, Daniel Wei, Robert V. Slone, Trung Pham, Chunqing Liu Weinheim WILEY-VCH [2021] © 2021 xvii, 296 Seiten Illustrationen, Diagramme txt rdacontent n rdamedia nc rdacarrier Petrochemie (DE-588)4173958-9 gnd rswk-swf Chemical Engineering Chemie Chemische Verfahrenstechnik Chemistry Energie Energy Erdgas u. Erdöl Natural Gas & Petroleum Products Petrochemie / Brennstoffindustrie Petrochemistry / Fuel Process Engineering Prozesssteuerung CG10: Prozesssteuerung CH34: Petrochemie / Brennstoffindustrie EG12: Erdgas u. Erdöl Petrochemie Petrochemie (DE-588)4173958-9 s DE-604 Rekoske, James E. Verfasser aut Wei, Daniel Verfasser aut Slone, Robert V. Verfasser aut Pham, Trung Verfasser aut Liu, Chunqing Verfasser aut Wiley-VCH (DE-588)16179388-5 pbl Erscheint auch als Online-Ausgabe, PDF 978-3-527-81819-8 Erscheint auch als Online-Ausgabe, EPUB 978-3-527-81817-4 Erscheint auch als Online-Ausgabe 978-3-527-81816-7 X:MVB http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-34522-9/ Kurzbeschreibung B:DE-101 application/pdf https://d-nb.info/1217133127/04 Inhaltsverzeichnis DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=033035214&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Kulprathipanja, Santi Rekoske, James E. Wei, Daniel Slone, Robert V. Pham, Trung Liu, Chunqing Modern petrochemical technology methods, manufacturing and applications Petrochemie (DE-588)4173958-9 gnd |
| subject_GND | (DE-588)4173958-9 |
| title | Modern petrochemical technology methods, manufacturing and applications |
| title_auth | Modern petrochemical technology methods, manufacturing and applications |
| title_exact_search | Modern petrochemical technology methods, manufacturing and applications |
| title_exact_search_txtP | Modern petrochemical technology methods, manufacturing and applications |
| title_full | Modern petrochemical technology methods, manufacturing and applications Santi Kulprathipanja, James E. Rekoske, Daniel Wei, Robert V. Slone, Trung Pham, Chunqing Liu |
| title_fullStr | Modern petrochemical technology methods, manufacturing and applications Santi Kulprathipanja, James E. Rekoske, Daniel Wei, Robert V. Slone, Trung Pham, Chunqing Liu |
| title_full_unstemmed | Modern petrochemical technology methods, manufacturing and applications Santi Kulprathipanja, James E. Rekoske, Daniel Wei, Robert V. Slone, Trung Pham, Chunqing Liu |
| title_short | Modern petrochemical technology |
| title_sort | modern petrochemical technology methods manufacturing and applications |
| title_sub | methods, manufacturing and applications |
| topic | Petrochemie (DE-588)4173958-9 gnd |
| topic_facet | Petrochemie |
| url | http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-34522-9/ https://d-nb.info/1217133127/04 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=033035214&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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