Holdings: Industrial catalysis

Industrial catalysis:

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Bibliographic Details
Main Authors:	Benvenuto, Mark Anthony (Author), Plaumann, Heinz (Author)
Format:	Book
Language:	English
Published:	Berlin ; Boston De Gruyter [2021]
Series:	De Gruyter STEM
Subjects:	Technische Chemie Katalyse
Online Access:	Inhaltsverzeichnis
Physical Description:	XV, 200 Seiten Illustrationen, Diagramme
ISBN:	9783110542844 3110542846

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adam_text	CONTENTS CHAPTER 1 INTRODUCTION - 1 1.1 1.2 1.3 1.4 CATALYSIS - 1 REACTION CHEMISTRY ---- 2 CATALYST PRODUCTION ---- 2 CATALYST FATE ---- 3 REFERENCES ---- 4 CHAPTER 2 HOMOGENEOUS CATALYSIS - 7 2.1 2.2 2.2.1 2.2.2 2.3 INTRODUCTION ---- 7 ADVANTAGES OF A HOMOGENEOUS SYSTEM ---- 8 REACTION CHEMISTRY ---- 8 CATALYST PRODUCTION --- 8 CATALYST FATE - 9 CHAPTER 3 HETEROGENEOUS CATALYSIS - 11 3.1 3.2 3.3 3.4 INTRODUCTION ---- 11 REACTION CHEMISTRY ---- 11 CATALYST PRODUCTION --- 12 CATALYST FATE - 13 REFERENCES ---- 13 CHAPTER 4 ACRYLICS---- 15 4.1 4.2 4.3 4.3.1 4.3.2 4.4 INTRODUCTION ---- 15 REACTION CHEMISTRY ---- 15 CATALYST PRODUCTION ---- 16 POTASSIUM PERSULFATE ---- 16 IRON (II) SULFATE PENTAHYDRATE ---- 16 CATALYST FATE ---- 17 REFERENCES ---- 17 CHAPTER 5 ADIPIC ACID ---- 19 5.1 5.2 5.3 INTRODUCTION ---- 19 CATALYST PRODUCTION ---- 19 CATALYST FATE ---- 20 REFERENCES---- 21 VI CONTENTS CHAPTER 6 AMMONIA ---- 23 6.1 6.2 6.3 6.4 INTRODUCTION ---- 23 REACTION CHEMISTRY ---- 23 CATALYST PRODUCTION -----24 CATALYST FATE ---- 25 REFERENCES ---- 25 CHAPTER 7 AMMONIUM SULFATE ---- 27 7.1 7.2 7.3 7.4 INTRODUCTION ---- 27 REACTION CHEMISTRY ---- 27 CATALYST PRODUCTION ---- 27 CATALYST FATE -----28 REFERENCES ---- 28 CHAPTER 8 BENZENE, TOLUENE, XYLENE (BTX) -----29 8.1 8.2 8.3 8.3.1 8.4 INTRODUCTION ---- 29 REACTION CHEMISTRY ---- 30 CATALYST PRODUCTION --- 30 ALUMINUM OXIDE, AKA ALUMINA, AKA ALUMINUM (III) OXIDE ---- 31 CATALYST FATE - 31 REFERENCES ---- 32 CHAPTER 9 BUTADIENE ---- 33 9.1 9.2 9.3 9.3.1 9.3.2 9.4 INTRODUCTION ---- 33 REACTION CHEMISTRY ---- 33 CATALYST PRODUCTION --- 34 CHROMIUM (III) OXIDE, AKA CHROMIA ---- 34 ALUMINUM OXIDE, AKA ALUMINA, OR ALUMINUM (III) OXIDE -----34 CATALYST FATE ---- 35 REFERENCES ---- 35 CHAPTER 10 CAPROLACTAM - 37 10.1 10.2 10.3 10.4 INTRODUCTION ---- 37 REACTION CHEMISTRY ---- 38 CATALYST PRODUCTION --- 38 CATALYST FATE -----38 REFERENCE ---- 38 CONTENTS VII CHAPTER 11 CHLORINE ---- 39 11.1 INTRODUCTION - 39 11.2 REACTION CHEMISTRY ----- 39 11.3 CATALYST PRODUCTION ----- 40 11.4 CATALYST FATE - 40 REFERENCES ---- 41 CHAPTER 12 CUMENE - 43 12.1 INTRODUCTION ---- 43 12.2 REACTION CHEMISTRY - 43 12.3 CATALYST PRODUCTION -44 12.3.1 ALUMINUM CHLORIDE ---- 44 12.3.2 PHOSPHORIC ACID ----- 44 12.4 CATALYST FATE ---- 45 REFERENCES ---- 45 CHAPTER 13 CYCLOHEXANE - - 47 13.1 INTRODUCTION ---- 47 13.2 REACTION CHEMISTRY ----- 48 13.3 CATALYST PRODUCTION - 48 13.4 CATALYST FATE ---- 49 REFERENCES ---- 50 CHAPTER 14 ETHANOL ---- 51 14.1 INTRODUCTION ---- 51 14.2 REACTION CHEMISTRY ----- 51 14.2.1 FROM STARCHES - 51 14.2.2 FROM ETHYLENE ---- 52 14.3 CATALYST PRODUCTION ----- 53 14.3.1 YEASTS ---- 53 14.3.2 PHOSPHORIC ACID - 53 14.3.3 SILICA ---- 54 14.3.4 DIATOMACEOUS EARTH ----- 54 14.4 CATALYST FATE ---- 55 REFERENCES ---- 55 VIII - CONTENTS CHAPTER 15 ETHYLENE ---- 57 15.1 15.2 15.3 15.3.1 15.4 INTRODUCTION ---- 57 REACTION CHEMISTRY ---- 57 CATALYST PRODUCTION --- 57 ALUMINUM OXIDE ---- 57 CATALYST FATE - 58 REFERENCES - 58 CHAPTER 16 ETHYLENE DICHLORIDE - 59 16.1 16.2 16.3 16.3.1 16.3.2 16.4 INTRODUCTION ---- 59 REACTION CHEMISTRY - 59 CATALYST PRODUCTION - 60 IRON (III) CHLORIDE - FECI 3 , AKA FERRIC CHLORIDE - 60 COPPER (II) CHLORIDE - CUCL 2 ---- 61 CATALYST FATE - 61 REFERENCES - 62 CHAPTER 17 ETHYLENE GLYCOL - 63 17.1 17.2 17.3 17.3.1 17.4 INTRODUCTION ---- 63 REACTION CHEMISTRY ---- 64 CATALYST PRODUCTION - 64 SILVER (1) OXIDE - 64 CATALYST FATE - 64 REFERENCES - 65 CHAPTER 18 ETHYLENE OXIDE ---- 67 18.1 18.2 18.3 18.3.1 18.4 INTRODUCTION ---- 67 REACTION CHEMISTRY - 67 CATALYST PRODUCTION - 68 SILVER (1) OXIDE - 68 CATALYST FATE - 68 REFERENCES -----69 CHAPTER 19 FORMALDEHYDE - 71 19.1 19.2 19.3 INTRODUCTION ---- 71 REACTION CHEMISTRY ---- 72 CATALYST PRODUCTION ---- 72 CONTENTS - IX 19.3.1 SILVER ---- 72 19.3.2 IRON OXIDE WITH MOLYBDENUM AND/OR VANADIUM - 74 19.4 CATALYST FATE ----- 74 REFERENCES ---- 75 CHAPTER 20 HYDROGEN ---- 77 20.1 INTRODUCTION ---- 77 20.2 REACTION CHEMISTRY ----- 77 20.3 CATALYST PRODUCTION ----- 78 20.4 CATALYST FATE ---- 78 REFERENCES - 78 CHAPTER 21 HYDROGEN PEROXIDE - 79 21.1 INTRODUCTION ---- 79 21.2 REACTION CHEMISTRY - 80 21.3 CATALYST PRODUCTION - 81 21.4 CATALYST FATE ---- 82 REFERENCES - 82 CHAPTER 22 ISOPROPANOL - 83 22.1 INTRODUCTION -----83 22.2 REACTION CHEMISTRY ------83 22.3 CATALYST PRODUCTION - 84 22.3.1 PHOSPHORIC ACID ----- 84 22.3.2 TUNGSTEN CATALYST ----- 84 22.3.3 RANEY NICKEL ---- 85 22.4 CATALYST FATE ----- 85 REFERENCES - 85 CHAPTER 23 LINEAR ALPHA OLEFINS - 87 23.1 INTRODUCTION -----87 23.2 REACTION CHEMISTRY - 87 23.3 CATALYST PRODUCTION - 88 23.3.1 THE INEOS PROCESS ---- 88 23.3.2 THE GULF PROCESS ----- 89 23.3.3 SHOP ---- 89 23.3.4 CHEVRON PHILLIPS ----- 89 23.3.5 IDEMITSU ---- 89 X CONTENTS 23.3.6 23.3.7 23.3.8 23.4 EXXON RESEARCH AND ENGINEERING ---- 90 DUPONT -----90 IHS -----90 CATALYST FATE - 91 REFERENCES ---- 91 CHAPTER 24 METHANOL ---- 93 24.1 24.2 24.3 24.4 INTRODUCTION ---- 93 REACTION CHEMISTRY ---- 93 CATALYST PRODUCTION ---- 94 CATALYST FATE - 94 REFERENCES -----94 CHAPTER 25 NITRIC ACID ---- 95 25.1 25.2 25.3 25.4 INTRODUCTION ---- 95 REACTION CHEMISTRY ---- 95 CATALYST PRODUCTION -----96 CATALYST FATE - 97 REFERENCES ---- 97 CHAPTER 26 NYLON -----99 26.1 26.1.1 26.2 26.3 26.3.1 26.3.2 26.4 INTRODUCTION -----99 TYPES OF NYLON -----99 REACTION CHEMISTRY ---- 100 CATALYST PRODUCTION - 100 WITH DINITRILES ---- 100 OTHER ACIDS ---- 101 CATALYST FATE - 101 REFERENCES ---- 101 CHAPTER 27 PHENOL ---- 103 27.1 27.2 27.2.1 27.2.2 INTRODUCTION ---- 103 REACTION CHEMISTRY ---- 103 THE CUMENE PROCESS ---- 104 OTHER METHODS OF PHENOL PRODUCTION ---- 104 CONTENTS - - XI 27.3 27.4 CATALYST PRODUCTION - 104 CATALYST FATE - 105 REFERENCES ---- 105 CHAPTER 28 PHOSGENE - 107 28.1 28.2 28.3 28.4 INTRODUCTION ---- 107 REACTION CHEMISTRY ---- 108 CATALYST PRODUCTION --- 108 CATALYST FATE - 108 REFERENCES - 109 CHAPTER 29 POLYCARBONATE - 111 29.1 29.2 29.3 29.3.1 29.3.2 29.4 INTRODUCTION ---- 111 REACTION CHEMISTRY ---- 112 CATALYST PRODUCTION --- 112 TITANIUM CATALYST - 112 ZINC GLUTARATE ---- 112 CATALYST FATE - 113 REFERENCES - 113 CHAPTER 30 POLYESTER, POLYETHYLENE TEREPHTHALATE (PETE) - 115 30.1 30.2 30.3 30.3.1 30.3.2 30.3.3 30.3.4 30.4 INTRODUCTION ---- 115 REACTION CHEMISTRY ---- 116 CATALYST PRODUCTION - 117 ANTIMONY TRIOXIDE (SB 2 0 3 , AKA ANTIMONY (III) OXIDE) ---- 117 ANTIMONY TRIACETATE (SB(C 2 H 3 O 2 )3) ---- 118 TITANIUM DIOXIDE (TIO 2 ) - 118 GERMANIUM DIOXIDE (GEO 2 ) ---- 118 CATALYST FATE - 119 REFERENCES---- 119 CHAPTER 31 POLYETHYLENE - 121 31.1 31.2 31.3 31.3.1 31.3.2 31.3.3 INTRODUCTION ---- 121 REACTION CHEMISTRY ---- 122 CATALYST PRODUCTION - 123 SI0 2 -SILICA - 123 ZIEGLER-NATTA CATALYSTS ---- 123 TITANIUM TETRACHLORIDE ON A SUPPORT OF MAGNESIUM CHLORIDE ---- 123 XII ----- CONTENTS 31.3.4 31.3.5 31.4 METALLOCENES ---- 124 METHYLALUMINOXANE COCATALYST (MAO) ---- 126 CATALYST FATE ---- 126 REFERENCES ---- 127 CHAPTER 32 POLYPROPYLENE - 129 32.1 32.2 32.3 32.3.1 32.3.2 32.4 INTRODUCTION ---- 129 REACTION CHEMISTRY ---- 130 CATALYST PRODUCTION --- 130 DIETHYLALUMINUM HALIDE, (CH 3 CH 2 ) 2 AIX 3 ---- 131 METALLOCENES ---- 131 CATALYST FATE ---- 132 REFERENCES ---- 132 CHAPTER 33 POLYSTYRENE---- 135 33.1 33.2 33.3 33.3.1 33.3.2 33.4 INTRODUCTION ---- 135 REACTION CHEMISTRY ---- 136 CATALYST PRODUCTION ---- 138 FOR STYRENE ---- 138 FOR POLYSTYRENE ---- 138 CATALYST FATE - 139 REFERENCES ---- 139 CHAPTER 34 POLYTETRAFLUOROETHYLENE - 141 34.1 34.2 34.3 34.3.1 34.3.2 34.3.3 34.3.4 INTRODUCTION ---- 141 REACTION CHEMISTRY ---- 141 CATALYST PRODUCTION ---- 142 ZINC (II) CHLORIDE, ZNCL 2 ---- 142 SILVER (1) NITRATE, AGN0 3 ---- 142 METHANOL, CH 3 OH ---- 142 AMMONIUM PERSULFATE, NH 4 S 2 0 8 ---- 142 REFERENCES ---- 143 CHAPTER 35 POLYVINYL CHLORIDE (PVC) ---- 145 35.1 35.2 35.3 INTRODUCTION ---- 145 REACTION CHEMISTRY ---- 146 CATALYST PRODUCTION --- 146 CONTENTS - - XIII 35.4 CATALYST FATE ---- 147 REFERENCES ---- 147 CHAPTER 36 PROPYLENE---- 149 36.1 INTRODUCTION ---- 149 36.2 REACTION CHEMISTRY ---- 149 36.3 CATALYST PRODUCTION ---- 150 36.3.1 RHENIUM OXIDE (AKA, DIRHENIUM HEPTOXIDE) ---- 150 36.3.2 MOLYBDENUM OXIDE (MOO 3 ) ---- 151 36.4 CATALYST FATE ---- 151 REFERENCES - 151 CHAPTER 37 PROPYLENE OXIDE AND PROPYLENE GLYCOL - 153 37.1 INTRODUCTION ---- 153 37.2 REACTION CHEMISTRY ---- 153 37.3 CATALYST PRODUCTION ---- 155 37.3.1 TS-1, TITANIUM SILICATE ---- 155 37.3.2 SULFURIC ACID, CATALYTICALLY ----- 156 37.3.3 ALKALI, FOR PROPYLENE GLYCOL PRODUCTION ---- 156 37.4 CATALYST FATE ----- 156 REFERENCES ---- 157 CHAPTER 38 RUBBER---- 159 38.1 INTRODUCTION ---- 159 38.2 SYNTHETIC RUBBERS AND USE IN TIRES ---- 160 38.2.1 POLYISOPRENE ---- 161 38.2.2 POLYBUTADIENE ---- 162 38.2.3 ETHYLENE-PROPYLENE-DIENE RUBBERS ----- 164 38.2.4 OTHERS - 165 38.3 TIRE CONSTRUCTION AND COMPOUNDING ------ 167 REFERENCES ---- 167 CHAPTER 39 STYRENE ---- 169 39.1 INTRODUCTION - 169 39.2 REACTION CHEMISTRY ----- 169 39.3 CATALYST PRODUCTION ----- 170 39.3.1 FE 2 O 3 ---- 170 XIV - CONTENTS 39.4 CATALYST FATE ---- 170 REFERENCES - 170 CHAPTER 40 SULFURIC ACID - 171 40.1 INTRODUCTION ---- 171 40.2 REACTION CHEMISTRY - 171 40.3 CATALYST PRODUCTION ----- 172 40.4 CATALYST FATE ---- 172 REFERENCES - 173 CHAPTER 41 TOLUENE DIISOCYANATE - 175 41.1 INTRODUCTION ---- 175 41.2 REACTION CHEMISTRY ----- 175 41.3 CATALYST PRODUCTION ----- 176 41.4 CATALYST FATE ---- 176 REFERENCES - 177 CHAPTER 42 VINYL ACETATE - 179 42.1 INTRODUCTION ---- 179 42.2 REACTION CHEMISTRY ----- 179 42.3 CATALYST PRODUCTION - 179 42.3.1 CATALYST FORM ---- 181 42.4 CATALYST FATE ---- 181 REFERENCES - 181 CHAPTER 43 VINYL CHLORIDE MONOMER - 183 43.1 INTRODUCTION ---- 183 43.2 REACTION CHEMISTRY ------ 184 43.3 CATALYST PRODUCTION ----- 185 43.3.1 MERCURY (II) CHLORIDE, HGCI 2 185 43.4 CATALYST FATE ---- 185 REFERENCES - 186 CHAPTER 44 VITAMINS - 187 44.1 INTRODUCTION ---- 187 44.2 REACTION CHEMISTRY AND SYNTHESES ---- 187 44.2.1 VITAMIN A ---- 187 CONTENTS ----- XV 44.2.2 VITAMIN BJ OR THIAMINE ---- 188 44.2.3 VITAMIN B 2 OR RIBOFLAVIN - 188 44.2.4 VITAMIN B 3 , OFTEN NIACIN ---- 189 44.2.5 VITAMIN B 5 OR PANTOTHENIC ACID - 189 44.2.6 VITAMIN B 6 OR PYRIDOXINE - 190 44.2.7 VITAMIN B 7 OR BIOTIN - 190 44.2.8 VITAMIN B 9 OR FOLIC ACID ---- 191 44.2.9 VITAMIN B 12 OR CYANOCOBALAMIN ---- 191 44.2.10 VITAMIN C OR ASCORBIC ACID - 193 44.2.11 VITAMIN D OR CHOLECALCIFEROL - 194 44.2.12 VITAMIN E OR TOCOPHEROLS - 194 44.2.13 VITAMIN K OR PHYLLOQUINONE ---- 195 44.3 CATALYST PRODUCTION - 195 REFERENCES - 196 INDEX - 197
adam_txt	CONTENTS CHAPTER 1 INTRODUCTION - 1 1.1 1.2 1.3 1.4 CATALYSIS - 1 REACTION CHEMISTRY ---- 2 CATALYST PRODUCTION ---- 2 CATALYST FATE ---- 3 REFERENCES ---- 4 CHAPTER 2 HOMOGENEOUS CATALYSIS - 7 2.1 2.2 2.2.1 2.2.2 2.3 INTRODUCTION ---- 7 ADVANTAGES OF A HOMOGENEOUS SYSTEM ---- 8 REACTION CHEMISTRY ---- 8 CATALYST PRODUCTION --- 8 CATALYST FATE - 9 CHAPTER 3 HETEROGENEOUS CATALYSIS - 11 3.1 3.2 3.3 3.4 INTRODUCTION ---- 11 REACTION CHEMISTRY ---- 11 CATALYST PRODUCTION --- 12 CATALYST FATE - 13 REFERENCES ---- 13 CHAPTER 4 ACRYLICS---- 15 4.1 4.2 4.3 4.3.1 4.3.2 4.4 INTRODUCTION ---- 15 REACTION CHEMISTRY ---- 15 CATALYST PRODUCTION ---- 16 POTASSIUM PERSULFATE ---- 16 IRON (II) SULFATE PENTAHYDRATE ---- 16 CATALYST FATE ---- 17 REFERENCES ---- 17 CHAPTER 5 ADIPIC ACID ---- 19 5.1 5.2 5.3 INTRODUCTION ---- 19 CATALYST PRODUCTION ---- 19 CATALYST FATE ---- 20 REFERENCES---- 21 VI CONTENTS CHAPTER 6 AMMONIA ---- 23 6.1 6.2 6.3 6.4 INTRODUCTION ---- 23 REACTION CHEMISTRY ---- 23 CATALYST PRODUCTION -----24 CATALYST FATE ---- 25 REFERENCES ---- 25 CHAPTER 7 AMMONIUM SULFATE ---- 27 7.1 7.2 7.3 7.4 INTRODUCTION ---- 27 REACTION CHEMISTRY ---- 27 CATALYST PRODUCTION ---- 27 CATALYST FATE -----28 REFERENCES ---- 28 CHAPTER 8 BENZENE, TOLUENE, XYLENE (BTX) -----29 8.1 8.2 8.3 8.3.1 8.4 INTRODUCTION ---- 29 REACTION CHEMISTRY ---- 30 CATALYST PRODUCTION --- 30 ALUMINUM OXIDE, AKA ALUMINA, AKA ALUMINUM (III) OXIDE ---- 31 CATALYST FATE - 31 REFERENCES ---- 32 CHAPTER 9 BUTADIENE ---- 33 9.1 9.2 9.3 9.3.1 9.3.2 9.4 INTRODUCTION ---- 33 REACTION CHEMISTRY ---- 33 CATALYST PRODUCTION --- 34 CHROMIUM (III) OXIDE, AKA CHROMIA ---- 34 ALUMINUM OXIDE, AKA ALUMINA, OR ALUMINUM (III) OXIDE -----34 CATALYST FATE ---- 35 REFERENCES ---- 35 CHAPTER 10 CAPROLACTAM - 37 10.1 10.2 10.3 10.4 INTRODUCTION ---- 37 REACTION CHEMISTRY ---- 38 CATALYST PRODUCTION --- 38 CATALYST FATE -----38 REFERENCE ---- 38 CONTENTS VII CHAPTER 11 CHLORINE ---- 39 11.1 INTRODUCTION - 39 11.2 REACTION CHEMISTRY ----- 39 11.3 CATALYST PRODUCTION ----- 40 11.4 CATALYST FATE - 40 REFERENCES ---- 41 CHAPTER 12 CUMENE - 43 12.1 INTRODUCTION ---- 43 12.2 REACTION CHEMISTRY - 43 12.3 CATALYST PRODUCTION -44 12.3.1 ALUMINUM CHLORIDE ---- 44 12.3.2 PHOSPHORIC ACID ----- 44 12.4 CATALYST FATE ---- 45 REFERENCES ---- 45 CHAPTER 13 CYCLOHEXANE - - 47 13.1 INTRODUCTION ---- 47 13.2 REACTION CHEMISTRY ----- 48 13.3 CATALYST PRODUCTION - 48 13.4 CATALYST FATE ---- 49 REFERENCES ---- 50 CHAPTER 14 ETHANOL ---- 51 14.1 INTRODUCTION ---- 51 14.2 REACTION CHEMISTRY ----- 51 14.2.1 FROM STARCHES - 51 14.2.2 FROM ETHYLENE ---- 52 14.3 CATALYST PRODUCTION ----- 53 14.3.1 YEASTS ---- 53 14.3.2 PHOSPHORIC ACID - 53 14.3.3 SILICA ---- 54 14.3.4 DIATOMACEOUS EARTH ----- 54 14.4 CATALYST FATE ---- 55 REFERENCES ---- 55 VIII - CONTENTS CHAPTER 15 ETHYLENE ---- 57 15.1 15.2 15.3 15.3.1 15.4 INTRODUCTION ---- 57 REACTION CHEMISTRY ---- 57 CATALYST PRODUCTION --- 57 ALUMINUM OXIDE ---- 57 CATALYST FATE - 58 REFERENCES - 58 CHAPTER 16 ETHYLENE DICHLORIDE - 59 16.1 16.2 16.3 16.3.1 16.3.2 16.4 INTRODUCTION ---- 59 REACTION CHEMISTRY - 59 CATALYST PRODUCTION - 60 IRON (III) CHLORIDE - FECI 3 , AKA FERRIC CHLORIDE - 60 COPPER (II) CHLORIDE - CUCL 2 ---- 61 CATALYST FATE - 61 REFERENCES - 62 CHAPTER 17 ETHYLENE GLYCOL - 63 17.1 17.2 17.3 17.3.1 17.4 INTRODUCTION ---- 63 REACTION CHEMISTRY ---- 64 CATALYST PRODUCTION - 64 SILVER (1) OXIDE - 64 CATALYST FATE - 64 REFERENCES - 65 CHAPTER 18 ETHYLENE OXIDE ---- 67 18.1 18.2 18.3 18.3.1 18.4 INTRODUCTION ---- 67 REACTION CHEMISTRY - 67 CATALYST PRODUCTION - 68 SILVER (1) OXIDE - 68 CATALYST FATE - 68 REFERENCES -----69 CHAPTER 19 FORMALDEHYDE - 71 19.1 19.2 19.3 INTRODUCTION ---- 71 REACTION CHEMISTRY ---- 72 CATALYST PRODUCTION ---- 72 CONTENTS - IX 19.3.1 SILVER ---- 72 19.3.2 IRON OXIDE WITH MOLYBDENUM AND/OR VANADIUM - 74 19.4 CATALYST FATE ----- 74 REFERENCES ---- 75 CHAPTER 20 HYDROGEN ---- 77 20.1 INTRODUCTION ---- 77 20.2 REACTION CHEMISTRY ----- 77 20.3 CATALYST PRODUCTION ----- 78 20.4 CATALYST FATE ---- 78 REFERENCES - 78 CHAPTER 21 HYDROGEN PEROXIDE - 79 21.1 INTRODUCTION ---- 79 21.2 REACTION CHEMISTRY - 80 21.3 CATALYST PRODUCTION - 81 21.4 CATALYST FATE ---- 82 REFERENCES - 82 CHAPTER 22 ISOPROPANOL - 83 22.1 INTRODUCTION -----83 22.2 REACTION CHEMISTRY ------83 22.3 CATALYST PRODUCTION - 84 22.3.1 PHOSPHORIC ACID ----- 84 22.3.2 TUNGSTEN CATALYST ----- 84 22.3.3 RANEY NICKEL ---- 85 22.4 CATALYST FATE ----- 85 REFERENCES - 85 CHAPTER 23 LINEAR ALPHA OLEFINS - 87 23.1 INTRODUCTION -----87 23.2 REACTION CHEMISTRY - 87 23.3 CATALYST PRODUCTION - 88 23.3.1 THE INEOS PROCESS ---- 88 23.3.2 THE GULF PROCESS ----- 89 23.3.3 SHOP ---- 89 23.3.4 CHEVRON PHILLIPS ----- 89 23.3.5 IDEMITSU ---- 89 X CONTENTS 23.3.6 23.3.7 23.3.8 23.4 EXXON RESEARCH AND ENGINEERING ---- 90 DUPONT -----90 IHS -----90 CATALYST FATE - 91 REFERENCES ---- 91 CHAPTER 24 METHANOL ---- 93 24.1 24.2 24.3 24.4 INTRODUCTION ---- 93 REACTION CHEMISTRY ---- 93 CATALYST PRODUCTION ---- 94 CATALYST FATE - 94 REFERENCES -----94 CHAPTER 25 NITRIC ACID ---- 95 25.1 25.2 25.3 25.4 INTRODUCTION ---- 95 REACTION CHEMISTRY ---- 95 CATALYST PRODUCTION -----96 CATALYST FATE - 97 REFERENCES ---- 97 CHAPTER 26 NYLON -----99 26.1 26.1.1 26.2 26.3 26.3.1 26.3.2 26.4 INTRODUCTION -----99 TYPES OF NYLON -----99 REACTION CHEMISTRY ---- 100 CATALYST PRODUCTION - 100 WITH DINITRILES ---- 100 OTHER ACIDS ---- 101 CATALYST FATE - 101 REFERENCES ---- 101 CHAPTER 27 PHENOL ---- 103 27.1 27.2 27.2.1 27.2.2 INTRODUCTION ---- 103 REACTION CHEMISTRY ---- 103 THE CUMENE PROCESS ---- 104 OTHER METHODS OF PHENOL PRODUCTION ---- 104 CONTENTS - - XI 27.3 27.4 CATALYST PRODUCTION - 104 CATALYST FATE - 105 REFERENCES ---- 105 CHAPTER 28 PHOSGENE - 107 28.1 28.2 28.3 28.4 INTRODUCTION ---- 107 REACTION CHEMISTRY ---- 108 CATALYST PRODUCTION --- 108 CATALYST FATE - 108 REFERENCES - 109 CHAPTER 29 POLYCARBONATE - 111 29.1 29.2 29.3 29.3.1 29.3.2 29.4 INTRODUCTION ---- 111 REACTION CHEMISTRY ---- 112 CATALYST PRODUCTION --- 112 TITANIUM CATALYST - 112 ZINC GLUTARATE ---- 112 CATALYST FATE - 113 REFERENCES - 113 CHAPTER 30 POLYESTER, POLYETHYLENE TEREPHTHALATE (PETE) - 115 30.1 30.2 30.3 30.3.1 30.3.2 30.3.3 30.3.4 30.4 INTRODUCTION ---- 115 REACTION CHEMISTRY ---- 116 CATALYST PRODUCTION - 117 ANTIMONY TRIOXIDE (SB 2 0 3 , AKA ANTIMONY (III) OXIDE) ---- 117 ANTIMONY TRIACETATE (SB(C 2 H 3 O 2 )3) ---- 118 TITANIUM DIOXIDE (TIO 2 ) - 118 GERMANIUM DIOXIDE (GEO 2 ) ---- 118 CATALYST FATE - 119 REFERENCES---- 119 CHAPTER 31 POLYETHYLENE - 121 31.1 31.2 31.3 31.3.1 31.3.2 31.3.3 INTRODUCTION ---- 121 REACTION CHEMISTRY ---- 122 CATALYST PRODUCTION - 123 SI0 2 -SILICA - 123 ZIEGLER-NATTA CATALYSTS ---- 123 TITANIUM TETRACHLORIDE ON A SUPPORT OF MAGNESIUM CHLORIDE ---- 123 XII ----- CONTENTS 31.3.4 31.3.5 31.4 METALLOCENES ---- 124 METHYLALUMINOXANE COCATALYST (MAO) ---- 126 CATALYST FATE ---- 126 REFERENCES ---- 127 CHAPTER 32 POLYPROPYLENE - 129 32.1 32.2 32.3 32.3.1 32.3.2 32.4 INTRODUCTION ---- 129 REACTION CHEMISTRY ---- 130 CATALYST PRODUCTION --- 130 DIETHYLALUMINUM HALIDE, (CH 3 CH 2 ) 2 AIX 3 ---- 131 METALLOCENES ---- 131 CATALYST FATE ---- 132 REFERENCES ---- 132 CHAPTER 33 POLYSTYRENE---- 135 33.1 33.2 33.3 33.3.1 33.3.2 33.4 INTRODUCTION ---- 135 REACTION CHEMISTRY ---- 136 CATALYST PRODUCTION ---- 138 FOR STYRENE ---- 138 FOR POLYSTYRENE ---- 138 CATALYST FATE - 139 REFERENCES ---- 139 CHAPTER 34 POLYTETRAFLUOROETHYLENE - 141 34.1 34.2 34.3 34.3.1 34.3.2 34.3.3 34.3.4 INTRODUCTION ---- 141 REACTION CHEMISTRY ---- 141 CATALYST PRODUCTION ---- 142 ZINC (II) CHLORIDE, ZNCL 2 ---- 142 SILVER (1) NITRATE, AGN0 3 ---- 142 METHANOL, CH 3 OH ---- 142 AMMONIUM PERSULFATE, NH 4 S 2 0 8 ---- 142 REFERENCES ---- 143 CHAPTER 35 POLYVINYL CHLORIDE (PVC) ---- 145 35.1 35.2 35.3 INTRODUCTION ---- 145 REACTION CHEMISTRY ---- 146 CATALYST PRODUCTION --- 146 CONTENTS - - XIII 35.4 CATALYST FATE ---- 147 REFERENCES ---- 147 CHAPTER 36 PROPYLENE---- 149 36.1 INTRODUCTION ---- 149 36.2 REACTION CHEMISTRY ---- 149 36.3 CATALYST PRODUCTION ---- 150 36.3.1 RHENIUM OXIDE (AKA, DIRHENIUM HEPTOXIDE) ---- 150 36.3.2 MOLYBDENUM OXIDE (MOO 3 ) ---- 151 36.4 CATALYST FATE ---- 151 REFERENCES - 151 CHAPTER 37 PROPYLENE OXIDE AND PROPYLENE GLYCOL - 153 37.1 INTRODUCTION ---- 153 37.2 REACTION CHEMISTRY ---- 153 37.3 CATALYST PRODUCTION ---- 155 37.3.1 TS-1, TITANIUM SILICATE ---- 155 37.3.2 SULFURIC ACID, CATALYTICALLY ----- 156 37.3.3 ALKALI, FOR PROPYLENE GLYCOL PRODUCTION ---- 156 37.4 CATALYST FATE ----- 156 REFERENCES ---- 157 CHAPTER 38 RUBBER---- 159 38.1 INTRODUCTION ---- 159 38.2 SYNTHETIC RUBBERS AND USE IN TIRES ---- 160 38.2.1 POLYISOPRENE ---- 161 38.2.2 POLYBUTADIENE ---- 162 38.2.3 ETHYLENE-PROPYLENE-DIENE RUBBERS ----- 164 38.2.4 OTHERS - 165 38.3 TIRE CONSTRUCTION AND COMPOUNDING ------ 167 REFERENCES ---- 167 CHAPTER 39 STYRENE ---- 169 39.1 INTRODUCTION - 169 39.2 REACTION CHEMISTRY ----- 169 39.3 CATALYST PRODUCTION ----- 170 39.3.1 FE 2 O 3 ---- 170 XIV - CONTENTS 39.4 CATALYST FATE ---- 170 REFERENCES - 170 CHAPTER 40 SULFURIC ACID - 171 40.1 INTRODUCTION ---- 171 40.2 REACTION CHEMISTRY - 171 40.3 CATALYST PRODUCTION ----- 172 40.4 CATALYST FATE ---- 172 REFERENCES - 173 CHAPTER 41 TOLUENE DIISOCYANATE - 175 41.1 INTRODUCTION ---- 175 41.2 REACTION CHEMISTRY ----- 175 41.3 CATALYST PRODUCTION ----- 176 41.4 CATALYST FATE ---- 176 REFERENCES - 177 CHAPTER 42 VINYL ACETATE - 179 42.1 INTRODUCTION ---- 179 42.2 REACTION CHEMISTRY ----- 179 42.3 CATALYST PRODUCTION - 179 42.3.1 CATALYST FORM ---- 181 42.4 CATALYST FATE ---- 181 REFERENCES - 181 CHAPTER 43 VINYL CHLORIDE MONOMER - 183 43.1 INTRODUCTION ---- 183 43.2 REACTION CHEMISTRY ------ 184 43.3 CATALYST PRODUCTION ----- 185 43.3.1 MERCURY (II) CHLORIDE, HGCI 2 185 43.4 CATALYST FATE ---- 185 REFERENCES - 186 CHAPTER 44 VITAMINS - 187 44.1 INTRODUCTION ---- 187 44.2 REACTION CHEMISTRY AND SYNTHESES ---- 187 44.2.1 VITAMIN A ---- 187 CONTENTS ----- XV 44.2.2 VITAMIN BJ OR THIAMINE ---- 188 44.2.3 VITAMIN B 2 OR RIBOFLAVIN - 188 44.2.4 VITAMIN B 3 , OFTEN NIACIN ---- 189 44.2.5 VITAMIN B 5 OR PANTOTHENIC ACID - 189 44.2.6 VITAMIN B 6 OR PYRIDOXINE - 190 44.2.7 VITAMIN B 7 OR BIOTIN - 190 44.2.8 VITAMIN B 9 OR FOLIC ACID ---- 191 44.2.9 VITAMIN B 12 OR CYANOCOBALAMIN ---- 191 44.2.10 VITAMIN C OR ASCORBIC ACID - 193 44.2.11 VITAMIN D OR CHOLECALCIFEROL - 194 44.2.12 VITAMIN E OR TOCOPHEROLS - 194 44.2.13 VITAMIN K OR PHYLLOQUINONE ---- 195 44.3 CATALYST PRODUCTION - 195 REFERENCES - 196 INDEX - 197
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spelling	Benvenuto, Mark Anthony Verfasser (DE-588)1047943697 aut Industrial catalysis Mark Anthony Benvenuto, Heinz Plaumann Berlin ; Boston De Gruyter [2021] © 2021 XV, 200 Seiten Illustrationen, Diagramme txt rdacontent n rdamedia nc rdacarrier De Gruyter STEM Technische Chemie (DE-588)4078178-1 gnd rswk-swf Katalyse (DE-588)4029921-1 gnd rswk-swf Technische Chemie (DE-588)4078178-1 s Katalyse (DE-588)4029921-1 s DE-604 Plaumann, Heinz Verfasser (DE-588)1242933867 aut Walter de Gruyter GmbH & Co. KG (DE-588)10095502-2 pbl Erscheint auch als Online-Ausgabe, PDF 978-3-11-054286-8 Erscheint auch als Online-Ausgabe, EPUB 978-3-11-054294-3 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=032822736&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis
spellingShingle	Benvenuto, Mark Anthony Plaumann, Heinz Industrial catalysis Technische Chemie (DE-588)4078178-1 gnd Katalyse (DE-588)4029921-1 gnd
subject_GND	(DE-588)4078178-1 (DE-588)4029921-1
title	Industrial catalysis
title_auth	Industrial catalysis
title_exact_search	Industrial catalysis
title_exact_search_txtP	Industrial catalysis
title_full	Industrial catalysis Mark Anthony Benvenuto, Heinz Plaumann
title_fullStr	Industrial catalysis Mark Anthony Benvenuto, Heinz Plaumann
title_full_unstemmed	Industrial catalysis Mark Anthony Benvenuto, Heinz Plaumann
title_short	Industrial catalysis
title_sort	industrial catalysis
topic	Technische Chemie (DE-588)4078178-1 gnd Katalyse (DE-588)4029921-1 gnd
topic_facet	Technische Chemie Katalyse
url	http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=032822736&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
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