Catalysis for fine chemicals:
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| Main Authors: | , , , |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Berlin ; Boston
De Gruyter
[2021]
|
| Series: | De Gruyter STEM
|
| Subjects: | |
| Online Access: | https://www.degruyter.com/books/9783110571158 Inhaltsverzeichnis |
| Physical Description: | XI, 392 Seiten Illustrationen, Diagramme |
| ISBN: | 9783110571158 |
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MARC
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| 100 | 1 | |a Bonrath, Werner |d 1959- |e Verfasser |0 (DE-588)133407810 |4 aut | |
| 245 | 1 | 0 | |a Catalysis for fine chemicals |c Werner Bonrath, Jonathan Medlock, Marc-André Müller, Jan Schütz |
| 264 | 1 | |a Berlin ; Boston |b De Gruyter |c [2021] | |
| 264 | 4 | |c © 2021 | |
| 300 | |a XI, 392 Seiten |b Illustrationen, Diagramme | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
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Record in the Search Index
| _version_ | 1809766085724995584 |
|---|---|
| adam_text |
CONTENTS
PREFACE
-
VII
1
1.1
1.1.1
1.1.2
1.1.3
1.1.4
1.1.5
1.2
1.3
1.4
INTRODUCTION
AND
FUNDAMENTAL
ASPECTS
-
1
GENERAL
CONCEPTS
OF
CATALYSIS
-
3
BASICS
OF
THERMODYNAMICS
AND
KINETICS
FOR
CHEMICAL
REACTIONS
----
3
GENERAL
PRINCIPLES
OF
HETEROGENEOUS
CATALYSIS
-
9
MECHANISMS
AND
KINETICS
ON
CATALYST
SURFACES
----
11
CHARACTERISATION
OF
SOLID
CATALYSTS
-
15
TERMS
AND
DEFINITIONS
-
19
CATALYST
PREPARATION
----
28
CHEMICAL
REACTORS
FOR
CATALYTIC
PROCESSES
-
30
OUTLOOK
----
33
REFERENCES
----
34
2
2.1
2.2
2.2.1
2.2.2
2.2.3
2.2.4
2.3
2.3.1
2.3.2
2.3.3
2.4
2.5
HETEROGENEOUS
HYDROGENATIONS
-
37
INTRODUCTION
----
37
NICKEL
CATALYSTS
----
43
HYDROGENATION
OF
NITRILES
----
43
HYDROGENATION
OF
CARBONYL
GROUPS
----
50
HYDROGENATION
OF
OTHER
FUNCTIONAL
GROUPS
----
51
REDUCTION
OF
MULTIPLE
FUNCTIONAL
GROUPS
IN
THE
SAME
REACTION
-
54
PLATINUM
GROUP
METAL
(PGM)
BASED
CATALYSTS
----
55
PALLADIUM
CATALYSTS
-
58
PLATINUM
CATALYSTS
-
78
OTHER
PGM
CATALYSTS
----
83
OTHER
METAL
CATALYSTS
----
85
SUMMARY
----
86
REFERENCES
----
86
3
3.1
3.2
3.2.1
3.2.2
3.2.3
3.2.4
3.2.5
3.2.6
3.2.7
3.2.8
HOMOGENEOUS
HYDROGENATIONS
-
91
INTRODUCTION
-
91
RH-CATALYSED
HYDROGENATIONS
----
92
(S)-3-(3,4-DIHYDROXYPHENYL)ALANINE,
1-DOPA
----
92
MENTHOL
(BASF
PROCESS)
----
99
METHYLENE
SUCCINAMIC
ACID
-
102
AUSKIREN
----
103
PREGABALIN
-
107
(+)
-
BIOTIN
----
107
SITAGLIPTIN
----
109
PANTOLACTONE
-
111
X
-
CONTENTS
3.3 RU-CATALYSED
HYDROGENATIONS
--------
112
3.3.1
HYDROGENATION
OF
ALLYLIC
ALCOHOLS
----
112
3.3.2
PIVOTAL
GLUTARATE
INTERMEDIATE
FOR
CANDOXATRIL
-
114
3.3.3
ARTEMISININ
----
115
3.3.4
KETONE
REDUCTIONS
----
116
3.3.5
DYNAMIC
KINETIC
RESOLUTION
VIA
ASYMMETRIC
HYDROGENATION
----
119
3.4
IR-CATALYSED
HYDROGENATION
----
121
3.4.1
HYDROGENATION
OF
IMINES
----
121
3.4.2
HYDROGENATION
OF
KETONES
WITH
IRIDIUM
CATALYSTS
----
124
3.4.3
HYDROGENATION
OF
UNFUNCTIONALISED
DOUBLED
BONDS
-----
125
3.5
ASYMMETRIC
TRANSFER
HYDROGENATION
OF
C=O
AND
C=N
----
128
3.5.1
DORZOLAMIDE
----
130
3.5.2
STYRENE
OXIDE
----
131
3.5.3
(/?,/?)-TRANS-ACTINOL
FOR
ZEAXANTHIN
-
131
3.5.4
ALMOREXANT
----
132
REFERENCES
----
133
4
OXIDATIONS
----
142
4.1
INTRODUCTION
----
142
4.2
OXIDATION
OF
ALCOHOLS
----
143
4.3
OXIDATION
OF
PHENOLS
AND
AROMATIC
COMPOUNDS
-----
144
4.4
OXIDATION
OF
VARIOUS
C-C
BONDS
---
150
4.5
OXIDATION
FOR
SILANE
PRODUCTION
----
162
REFERENCES
-
164
5
GAS-PHASE
REACTIONS
-
170
REFERENCES
----
180
6
C-C-BOND
AND
C-N-BOND
FORMING
REACTIONS
(METAL-CATALYSED)
-
184
6.1
INTRODUCTION
AND
MIZOROKI-HECK
REACTIONS
----
184
6.2
OTHER
PALLADIUM
CATALYSED
C-C
BOND
FORMING
REACTIONS
-
189
6.2.1
SONOGASHIRA-HAGIHARA
REACTION
-
189
6.2.2
SUZUKI-MIYAURA-COUPLING
----
192
6.2.3
KUMADA-CORRIU
COUPLING
----
198
6.3
CARBONYLATION
REACTIONS
-
199
6.4
HYDROFORMYLATION
REACTIONS
-
201
6.5
SHOP
PROCESS
----
205
6.6
1,3-DIENE
FUNCTIONALISATION
----
207
6.7
TELOMERISATION
----
208
6.8
METATHESIS
----
217
6.9
FORMATION
OF
C-N
BONDS
(BUCHWALD-HARTWIG
COUPLING)
----
222
REFERENCES
----
226
CONTENTS
-
XI
7
REARRANGEMENT
REACTIONS
-
235
7.1
7.2
7.3
7.4
7.5
INTRODUCTION
----
235
WAGNER-MEERWEIN
REARRANGEMENTS
----
235
BECKMANN
REARRANGEMENT
----
237
[3,3]-SIGMATROPIC-TYPE
REARRANGEMENTS
----
237
THE
MEYER-SCHUSTER,
RUPE-KAMBLI
AND
PAULING
REARRANGEMENTS
-
246
7.6
ALLYLIC
REARRANGEMENTS
----
249
REFERENCES
----
254
8
ACID-BASE-CATALYSED
REACTIONS
-
257
8.1
8.2
8.3
8.4
8.5
8.6
8.7
REPLACEMENT
OF
BRPNSTED
ACIDS
----
257
ZEOLITE-BASED
CATALYSIS
-
263
HETEROPOLY
ACIDS
(HPAS)----
267
LEWIS
ACIDS
----
273
BASE
CATALYSIS
----
280
ETHYNYLATION
----
286
MANNICH
REACTIONS
----
288
REFERENCES
----
289
9
PHASE
TRANSFER
CATALYSIS
(PTC)
-
296
REFERENCES
-
308
10
10.1
10.2
10.2.1
10.2.2
10.2.3
10.2.4
10.2.5
10.2.6
10.2.7
10.2.8
10.2.9
BIOCATALYSIS
-
311
INTRODUCTION
TO
BIOCATALYSIS
-
311
INDUSTRIAL
APPLICATIONS
-
322
SAUERKRAUT
AND
ETHANOL:
APPLICATIONS
WITH
A
LONG
HISTORY
----
322
SUGARS
AND
OLIGOSACCHARIDES
-
325
ORGANIC
ACIDS
----
329
AMINO
ACIDS
----
335
VITAMINS
AND
CAROTENOIDS
----
341
ACTIVE
PHARMACEUTICAL
INGREDIENTS
----
353
FLAVOUR
COMPOUNDS
----
363
PESTICIDES
----
365
PLATFORM
CHEMICALS
----
366
REFERENCES
----
370
11
NEW
TRENDS
----
378
REFERENCES
----
383
INDEX
----
385 |
| adam_txt |
CONTENTS
PREFACE
-
VII
1
1.1
1.1.1
1.1.2
1.1.3
1.1.4
1.1.5
1.2
1.3
1.4
INTRODUCTION
AND
FUNDAMENTAL
ASPECTS
-
1
GENERAL
CONCEPTS
OF
CATALYSIS
-
3
BASICS
OF
THERMODYNAMICS
AND
KINETICS
FOR
CHEMICAL
REACTIONS
----
3
GENERAL
PRINCIPLES
OF
HETEROGENEOUS
CATALYSIS
-
9
MECHANISMS
AND
KINETICS
ON
CATALYST
SURFACES
----
11
CHARACTERISATION
OF
SOLID
CATALYSTS
-
15
TERMS
AND
DEFINITIONS
-
19
CATALYST
PREPARATION
----
28
CHEMICAL
REACTORS
FOR
CATALYTIC
PROCESSES
-
30
OUTLOOK
----
33
REFERENCES
----
34
2
2.1
2.2
2.2.1
2.2.2
2.2.3
2.2.4
2.3
2.3.1
2.3.2
2.3.3
2.4
2.5
HETEROGENEOUS
HYDROGENATIONS
-
37
INTRODUCTION
----
37
NICKEL
CATALYSTS
----
43
HYDROGENATION
OF
NITRILES
----
43
HYDROGENATION
OF
CARBONYL
GROUPS
----
50
HYDROGENATION
OF
OTHER
FUNCTIONAL
GROUPS
----
51
REDUCTION
OF
MULTIPLE
FUNCTIONAL
GROUPS
IN
THE
SAME
REACTION
-
54
PLATINUM
GROUP
METAL
(PGM)
BASED
CATALYSTS
----
55
PALLADIUM
CATALYSTS
-
58
PLATINUM
CATALYSTS
-
78
OTHER
PGM
CATALYSTS
----
83
OTHER
METAL
CATALYSTS
----
85
SUMMARY
----
86
REFERENCES
----
86
3
3.1
3.2
3.2.1
3.2.2
3.2.3
3.2.4
3.2.5
3.2.6
3.2.7
3.2.8
HOMOGENEOUS
HYDROGENATIONS
-
91
INTRODUCTION
-
91
RH-CATALYSED
HYDROGENATIONS
----
92
(S)-3-(3,4-DIHYDROXYPHENYL)ALANINE,
1-DOPA
----
92
MENTHOL
(BASF
PROCESS)
----
99
METHYLENE
SUCCINAMIC
ACID
-
102
AUSKIREN
----
103
PREGABALIN
-
107
(+)
-
BIOTIN
----
107
SITAGLIPTIN
----
109
PANTOLACTONE
-
111
X
-
CONTENTS
3.3 RU-CATALYSED
HYDROGENATIONS
--------
112
3.3.1
HYDROGENATION
OF
ALLYLIC
ALCOHOLS
----
112
3.3.2
PIVOTAL
GLUTARATE
INTERMEDIATE
FOR
CANDOXATRIL
-
114
3.3.3
ARTEMISININ
----
115
3.3.4
KETONE
REDUCTIONS
----
116
3.3.5
DYNAMIC
KINETIC
RESOLUTION
VIA
ASYMMETRIC
HYDROGENATION
----
119
3.4
IR-CATALYSED
HYDROGENATION
----
121
3.4.1
HYDROGENATION
OF
IMINES
----
121
3.4.2
HYDROGENATION
OF
KETONES
WITH
IRIDIUM
CATALYSTS
----
124
3.4.3
HYDROGENATION
OF
UNFUNCTIONALISED
DOUBLED
BONDS
-----
125
3.5
ASYMMETRIC
TRANSFER
HYDROGENATION
OF
C=O
AND
C=N
----
128
3.5.1
DORZOLAMIDE
----
130
3.5.2
STYRENE
OXIDE
----
131
3.5.3
(/?,/?)-TRANS-ACTINOL
FOR
ZEAXANTHIN
-
131
3.5.4
ALMOREXANT
----
132
REFERENCES
----
133
4
OXIDATIONS
----
142
4.1
INTRODUCTION
----
142
4.2
OXIDATION
OF
ALCOHOLS
----
143
4.3
OXIDATION
OF
PHENOLS
AND
AROMATIC
COMPOUNDS
-----
144
4.4
OXIDATION
OF
VARIOUS
C-C
BONDS
---
150
4.5
OXIDATION
FOR
SILANE
PRODUCTION
----
162
REFERENCES
-
164
5
GAS-PHASE
REACTIONS
-
170
REFERENCES
----
180
6
C-C-BOND
AND
C-N-BOND
FORMING
REACTIONS
(METAL-CATALYSED)
-
184
6.1
INTRODUCTION
AND
MIZOROKI-HECK
REACTIONS
----
184
6.2
OTHER
PALLADIUM
CATALYSED
C-C
BOND
FORMING
REACTIONS
-
189
6.2.1
SONOGASHIRA-HAGIHARA
REACTION
-
189
6.2.2
SUZUKI-MIYAURA-COUPLING
----
192
6.2.3
KUMADA-CORRIU
COUPLING
----
198
6.3
CARBONYLATION
REACTIONS
-
199
6.4
HYDROFORMYLATION
REACTIONS
-
201
6.5
SHOP
PROCESS
----
205
6.6
1,3-DIENE
FUNCTIONALISATION
----
207
6.7
TELOMERISATION
----
208
6.8
METATHESIS
----
217
6.9
FORMATION
OF
C-N
BONDS
(BUCHWALD-HARTWIG
COUPLING)
----
222
REFERENCES
----
226
CONTENTS
-
XI
7
REARRANGEMENT
REACTIONS
-
235
7.1
7.2
7.3
7.4
7.5
INTRODUCTION
----
235
WAGNER-MEERWEIN
REARRANGEMENTS
----
235
BECKMANN
REARRANGEMENT
----
237
[3,3]-SIGMATROPIC-TYPE
REARRANGEMENTS
----
237
THE
MEYER-SCHUSTER,
RUPE-KAMBLI
AND
PAULING
REARRANGEMENTS
-
246
7.6
ALLYLIC
REARRANGEMENTS
----
249
REFERENCES
----
254
8
ACID-BASE-CATALYSED
REACTIONS
-
257
8.1
8.2
8.3
8.4
8.5
8.6
8.7
REPLACEMENT
OF
BRPNSTED
ACIDS
----
257
ZEOLITE-BASED
CATALYSIS
-
263
HETEROPOLY
ACIDS
(HPAS)----
267
LEWIS
ACIDS
----
273
BASE
CATALYSIS
----
280
ETHYNYLATION
----
286
MANNICH
REACTIONS
----
288
REFERENCES
----
289
9
PHASE
TRANSFER
CATALYSIS
(PTC)
-
296
REFERENCES
-
308
10
10.1
10.2
10.2.1
10.2.2
10.2.3
10.2.4
10.2.5
10.2.6
10.2.7
10.2.8
10.2.9
BIOCATALYSIS
-
311
INTRODUCTION
TO
BIOCATALYSIS
-
311
INDUSTRIAL
APPLICATIONS
-
322
SAUERKRAUT
AND
ETHANOL:
APPLICATIONS
WITH
A
LONG
HISTORY
----
322
SUGARS
AND
OLIGOSACCHARIDES
-
325
ORGANIC
ACIDS
----
329
AMINO
ACIDS
----
335
VITAMINS
AND
CAROTENOIDS
----
341
ACTIVE
PHARMACEUTICAL
INGREDIENTS
----
353
FLAVOUR
COMPOUNDS
----
363
PESTICIDES
----
365
PLATFORM
CHEMICALS
----
366
REFERENCES
----
370
11
NEW
TRENDS
----
378
REFERENCES
----
383
INDEX
----
385 |
| any_adam_object | 1 |
| any_adam_object_boolean | 1 |
| author | Bonrath, Werner 1959- Medlock, Jonathan Müller, Marc-André 1985- Schütz, Jan |
| author_GND | (DE-588)133407810 (DE-588)1240619081 (DE-588)106047042X |
| author_facet | Bonrath, Werner 1959- Medlock, Jonathan Müller, Marc-André 1985- Schütz, Jan |
| author_role | aut aut aut aut |
| author_sort | Bonrath, Werner 1959- |
| author_variant | w b wb j m jm m a m mam j s js |
| building | Verbundindex |
| bvnumber | BV047215951 |
| classification_rvk | VN 7340 |
| ctrlnum | (OCoLC)1268197851 (DE-599)DNB1214751598 |
| discipline | Chemie / Pharmazie |
| discipline_str_mv | Chemie / Pharmazie |
| format | Book |
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| id | DE-604.BV047215951 |
| illustrated | Illustrated |
| index_date | 2024-07-03T16:55:50Z |
| indexdate | 2024-09-10T00:17:14Z |
| institution | BVB |
| institution_GND | (DE-588)10095502-2 |
| isbn | 9783110571158 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-032620670 |
| oclc_num | 1268197851 |
| open_access_boolean | |
| owner | DE-29T DE-11 |
| owner_facet | DE-29T DE-11 |
| physical | XI, 392 Seiten Illustrationen, Diagramme |
| publishDate | 2021 |
| publishDateSearch | 2021 |
| publishDateSort | 2021 |
| publisher | De Gruyter |
| record_format | marc |
| series2 | De Gruyter STEM |
| spelling | Bonrath, Werner 1959- Verfasser (DE-588)133407810 aut Catalysis for fine chemicals Werner Bonrath, Jonathan Medlock, Marc-André Müller, Jan Schütz Berlin ; Boston De Gruyter [2021] © 2021 XI, 392 Seiten Illustrationen, Diagramme txt rdacontent n rdamedia nc rdacarrier De Gruyter STEM Katalyse (DE-588)4029921-1 gnd rswk-swf Arzneimittel (DE-588)4003115-9 gnd rswk-swf Herstellung (DE-588)4159653-5 gnd rswk-swf Feinchemikalie (DE-588)4379906-1 gnd rswk-swf Feinchemikalie Heterogene Katalyse Homogene Katalyse Katalyse Feinchemikalie (DE-588)4379906-1 s Arzneimittel (DE-588)4003115-9 s Herstellung (DE-588)4159653-5 s Katalyse (DE-588)4029921-1 s DE-604 Medlock, Jonathan Verfasser (DE-588)1240619081 aut Müller, Marc-André 1985- Verfasser (DE-588)106047042X aut Schütz, Jan Verfasser aut Walter de Gruyter GmbH & Co. KG (DE-588)10095502-2 pbl Erscheint auch als Online-Ausgabe, PDF 978-3-11-057118-9 Erscheint auch als Online-Ausgabe, EPUB 978-3-11-057125-7 X:MVB https://www.degruyter.com/books/9783110571158 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=032620670&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Bonrath, Werner 1959- Medlock, Jonathan Müller, Marc-André 1985- Schütz, Jan Catalysis for fine chemicals Katalyse (DE-588)4029921-1 gnd Arzneimittel (DE-588)4003115-9 gnd Herstellung (DE-588)4159653-5 gnd Feinchemikalie (DE-588)4379906-1 gnd |
| subject_GND | (DE-588)4029921-1 (DE-588)4003115-9 (DE-588)4159653-5 (DE-588)4379906-1 |
| title | Catalysis for fine chemicals |
| title_auth | Catalysis for fine chemicals |
| title_exact_search | Catalysis for fine chemicals |
| title_exact_search_txtP | Catalysis for fine chemicals |
| title_full | Catalysis for fine chemicals Werner Bonrath, Jonathan Medlock, Marc-André Müller, Jan Schütz |
| title_fullStr | Catalysis for fine chemicals Werner Bonrath, Jonathan Medlock, Marc-André Müller, Jan Schütz |
| title_full_unstemmed | Catalysis for fine chemicals Werner Bonrath, Jonathan Medlock, Marc-André Müller, Jan Schütz |
| title_short | Catalysis for fine chemicals |
| title_sort | catalysis for fine chemicals |
| topic | Katalyse (DE-588)4029921-1 gnd Arzneimittel (DE-588)4003115-9 gnd Herstellung (DE-588)4159653-5 gnd Feinchemikalie (DE-588)4379906-1 gnd |
| topic_facet | Katalyse Arzneimittel Herstellung Feinchemikalie |
| url | https://www.degruyter.com/books/9783110571158 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=032620670&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT bonrathwerner catalysisforfinechemicals AT medlockjonathan catalysisforfinechemicals AT mullermarcandre catalysisforfinechemicals AT schutzjan catalysisforfinechemicals AT walterdegruytergmbhcokg catalysisforfinechemicals |