Multicomponent polymers: principles, structures and properties
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| Main Authors: | , |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Berlin ; Boston
De Gruyter
[2020]
Shanghai Tongji University Press |
| Series: | De Gruyter STEM
|
| Subjects: | |
| Online Access: | https://www.degruyter.com/books/9783110596328 Inhaltsverzeichnis Inhaltsverzeichnis |
| Physical Description: | XXVI, 379 Seiten Illustrationen, Diagramme 24 cm, 687 g |
| ISBN: | 9783110596328 3110596326 |
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MARC
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| 100 | 1 | |a Wang, Guojian |e Verfasser |0 (DE-588)1225704758 |4 aut | |
| 245 | 1 | 0 | |a Multicomponent polymers |b principles, structures and properties |c Guojian Wang, Junjie Yuan |
| 264 | 1 | |a Berlin ; Boston |b De Gruyter |c [2020] | |
| 264 | 1 | |a Shanghai |b Tongji University Press | |
| 300 | |a XXVI, 379 Seiten |b Illustrationen, Diagramme |c 24 cm, 687 g | ||
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| _version_ | 1804182264120082432 |
|---|---|
| adam_text | CONTENTS
PREFACE
*
V
ACKNOWLEDGEMENTS
*
VII
LIST
OF
FIGURES
-----
XV
LIST
OF
TABLES
*
XXIII
CHAPTER
1
INTRODUCTION
*
1
1.1
1.2
1.3
ABSTRACT
*
1
BASIC
CONCEPTS
*
3
MAIN
TYPES
AND
REPRESENTATION
METHODS
OF
MULTICOMPONENT
POLYMERS
*
5
1.3.1
1.3.2
1.4
1.4.1
1.4.2
1.4.3
1.4.4
1.5
MAIN
TYPES
OF
MULTICOMPONENT
POLYMERS
*
5
REPRESENTATION
OF
MULTICOMPONENT
POLYMERS
*
8
PREPARATION
OF
MULTICOMPONENT
POLYMERS
*
9
PHYSICAL
BLEND
METHODS
-----
9
COPOLYMERIZATION
BLENDING
METHOD
*
10
INTERPENETRATING
POLYMER
NETWORK
*
11
BLOCK
COPOLYMER
AND
GRAFT
COPOLYMER
*
12
DEVELOPMENT
OF
BLENDING
MODIFICATION
OF
POLYMERS
*
13
EXERCISES
*
15
CHAPTER
2
PHYSICAL
AND
CHEMICAL
PRINCIPLES
OF
MULTICOMPONENT
POLYMERS
*
16
2.1
2.2
2.3
2.4
THE
CONCEPT
OF
COMPATIBILITY
BETWEEN
POLYMERS
*
16
THERMODYNAMIC
ANALYSIS
OF
MISCIBILITY
OF
POLYMERS
*
18
CRITICAL
CONDITIONS
FOR
PHASE
SEPARATION
*
20
MISCIBILITY
OF
POLYMER
AND
PHASE
DIAGRAM
OF
TWO
COMPONENT
BLENDS
----
23
2.5
2.6
2.7
2.7.1
2.7.2
2.8
PHASE
SEPARATION
MECHANISM
*
25
APPLICATION
OF
SOLUBILITY
PARAMETER
THEORY
IN
BLENDS
*
29
METHODOLOGY
FOR
THE
COMPATIBILITY
BETWEEN
POLYMERS
*
32
GLASS
TRANSITION
TEMPERATURE
METHOD
*
33
OTHER
METHODS
-----36
METHODS
FOR
IMPROVING
THE
COMPATIBILITY
BETWEEN
POLYMER
BLENDS
-----
38
X
*
CONTENTS
2.8.1
THE
SIGNIFICANCE
OF
IMPROVING
THE
COMPATIBILITY
OF
POLYMER
BLENDS
*
38
2.8.2
2.8.3
2.8.4
2.8.5
STRUCTURAL
CHARACTERISTICS
OF
COMPATIBLE
POLYMERS
*
38
COMPATIBILIZATION
AND
ITS
METHODS
*
40
IMPROVING
COMPATIBILITY
BY
CHANGING
CHAIN
STRUCTURE
*
42
THE
APPLICATION
OF COMPATIBILIZER
*
45
EXERCISES
*
50
CHAPTER
3
PHASE
STRUCTURE
OF
MULTICOMPONENT
POLYMERS
*
52
3.1
3.2
3.2.1
3.2.2
INTRODUCTION
-----
52
BASIC
TYPES
OF
PHASE
STRUCTURE
OF
POLYMER
BLENDS
*
53
PHASE
STRUCTURES
OF
AMORPHOUS
POLYMER
BLENDS
*
53
MORPHOLOGICAL
CHARACTERISTICS
OF
BLENDS
CONTAINING
CRYSTALLINE
POLYMERS
*
61
3.3
3.3.1
3.3.2
3.3.3
FACTORS
AFFECTING
PHASE
STRUCTURE
OF
POLYMER
BLENDS
*
65
FACTORS
AFFECTING
CONTINUITY
*
65
FACTORS
AFFECTING
THE
MORPHOLOGY
AND
SIZE
OF
MICROREGIONS
*
69
INFLUENCING
FACTORS
ON
PHASE
STRUCTURE
OF
BLENDS
CONTAINING
CRYSTALLINE
POLYMERS
*
72
3.4
3.4.1
3.4.2
3.4.3
3.4.4
3.4.5
INTERFACIAL
LAYER
OF
POLYMER
BLENDS
*
74
CONCEPT
OF
INTERFACE
LAYER
*
74
FORMATION
OF
INTERFACE
LAYER
*
75
INTERFACE
LAYER
THICKNESS
*
76
PROPERTIES
OF
INTERFACE
LAYER
*
77
FACTORS
AFFECTING
INTERFACE
LAYER
STRUCTURE
OF
POLYMER
BLENDS
*
79
EXERCISES
-----
81
CHAPTER
4
TOUGHENING
MECHANISM
OF
MULTICOMPONENT
POLYMERS
*
82
4.1
4.2
4.2.1
4.2.2
4.2.3
4.2.4
INTRODUCTION
-----
82
TOUGHENING
MECHANISM
OF
ELASTOMER-TOUGHENED
PLASTICS
*
83
EARLY
TOUGHENING
THEORY
*
84
CRAZE-SHEAR
BAND
THEORY
*
87
WU
*
S
PERCOLATION
THEORY
*
94
FACTORS
AFFECTING
IMPACT
STRENGTH
OF
ELASTOMER-TOUGHENED
PLASTICS
*
99
4.3
4.3.1
4.3.2
MECHANISM
OF
TOUGHENING
PLASTICS
WITH
NONELASTOMERS
*
103
TOUGHENING
BY
RIGID
ORGANIC
PARTICLES
*
103
TOUGHENING
OF
INORGANIC
RIGID
PARTICLES
*
110
EXERCISES
-----
111
CONTENTS
*
XI
CHAPTER
5
MECHANICAL
PROPERTIES
OF
MULTICOMPONENT
POLYMERS
*
113
5.1
5.2
INTRODUCTION
*
113
RELATIONSHIP
BETWEEN
PROPERTIES
OF
POLYMER
BLENDS
AND
THEIR
COMPONENTS
*
113
5.2.1
THE
*
MIXING
RULE
*
FOR
THE
PROPERTIES
OF
BICOMPONENT
POLYMERS
*
113
5.2.2
RELATIONSHIP
BETWEEN
PROPERTIES
AND
COMPONENT
PROPERTIES
OF
HOMOGENEOUS
BLENDS
*
114
5.2.3
RELATIONSHIP
BETWEEN
PROPERTIES
AND
COMPONENT
PROPERTIES
OF
SINGLE
CONTINUOUS
STRUCTURE
BLENDS
*
115
5.2.4
RELATIONSHIP
BETWEEN
PROPERTIES
OF
TWO-PHASE
CONTINUOUS
STRUCTURE
BLENDS
AND
THEIR
COMPONENTS
*
117
5.3
5.3.1
5.3.2
5.3.3
5.4
5.4.1
GLASS
TRANSITION
OF
MULTICOMPONENT
POLYMERS
*
118
GLASS
TRANSITION
OF
POLYMERS
*
118
FACTORS
AFFECTING
GLASS
TRANSITION
OF
POLYMERS
*
119
GLASS
TRANSITION
OF
MULTICOMPONENT
POLYMERS
*
123
ELASTIC
MODULUS
OF
POLYMER
ALLOYS
*
128
MODULUS
OF
ELASTICITY
AND
POISSON
*
S
RATIO
OF
POLYMER
MATERIALS
*
128
5.4.2
5.4.3
5.5
5.5.1
5.5.2
5.6
5.6.1
ESTIMATION
OF
ELASTIC
MODULUS
OF
POLYMER
ALLOYS
*
129
MECHANICAL
MODEL
OF
POLYMER
BLENDS
*
131
STRESS
RELAXATION
OF
POLYMER
ALLOYS
*
135
STRESS
RELAXATION
PROPERTIES
OF
BLENDS
*
135
STRESS
RELAXATION
PROPERTIES
OF
GRAFTED
AND
BLOCK
COPOLYMERS
*
138
DEFORMATION
OF
POLYMER
ALLOYS
*
141
MECHANICAL
STRENGTH
AND
LARGE
DEFORMATION
OF
POLYMER
MATERIALS
*
141
5.6.2
LARGE
DEFORMATION
OF
POLYMER
ALLOYS
*
145
EXERCISES
-----
156
CHAPTER
6
RHEOLOGICAL
PROPERTIES
OF
MULTICOMPONENT
POLYMERS
*
158
6.1
6.1.1
6.1.2
6.1.3
6.2
6.2.1
6.2.2
6.3
6.3.1
VISCOUS
FLOW
OF
POLYMER
MELTS
*
158
CHARACTERISTICS
OF
SHEAR
FLOW
IN
POLYMER
MELTS
*
158
APPARENT
VISCOSITY
OF
POLYMER
MELTS
*
160
FACTORS
AFFECTING
THE
APPARENT
VISCOSITY
OF
POLYMER
MELTS
*
161
VISCOUS
FLOW
OF
MULTICOMPONENT
POLYMERS
*
166
DISPERSION
OF
MULTICOMPONENT
POLYMER
MELTS
*
166
VISCOSITY
OF
MULTICOMPONENT
POLYMER
MELTS
*
167
ELASTIC
EFFECT
OF
MULTICOMPONENT
POLYMER
MELTS
*
176
PARAMETERS
FOR
CHARACTERIZATION
OF
POLYMER
MELT
ELASTICITY
*
176
XII
*
CONTENTS
6.3.2
RELATIONSHIP
BETWEEN
ELASTICITY
AND
COMPOSITION
OF
MULTICOMPONENT
POLYMER
MELTS
*
177
6.3.3
RELATIONSHIP
BETWEEN
ELASTICITY
AND
SHEAR
OF
MULTICOMPONENT
POLYMER
MELTS
*
178
6.3.4
6.3.5
ELASTICITY
OF
ELASTOMER
TOUGHENED
PLASTIC
MELT
*
179
INFLUENCE
OF
ELASTIC
EFFECT
OF
MULTICOMPONENT
POLYMER
MELTS
ON
MOLDING
PROCESS
-----
180
EXERCISES
-----
182
CHAPTER
7
OTHER
CHARACTERISTICS
OF
MULTICOMPONENT
POLYMERS
*
184
7.1
7.1.1
7.1.2
7.1.3
7.2
7.2.1
7.2.2
7.2.3
7.3
7.3.1
7.3.2
7.3.3
7.4
7.4.1
PERMEABILITY
OF
MULTICOMPONENT
POLYMERS
*
184
INTRODUCTION
-----
184
AIR
PERMEABILITY
OF
MULTICOMPONENT
POLYMERS
-----
185
PERMEABILITY
OF
MULTICOMPONENT
POLYMERS
*
187
BARRIER
PROPERTIES
OF
MULTICOMPONENT
POLYMERS
*
188
BARRIER
PROPERTIES
OF
POLYMERS
*
188
BARRIER
PROPERTIES
OF
BLENDED
POLYMERS
*
190
INFLUENCING
FACTORS
OF
BARRIER
PROPERTY
OF
BLEND
POLYMER
*
191
TRANSPARENCY
OF
MULTICOMPONENT
POLYMERS
*
194
TRANSPARENCY
OF
POLYMER
BLENDS
*
194
TRANSPARENCY
OF
RUBBER
TOUGHENED
PLASTIC
BLENDS
*
195
REFRACTIVE
INDEX
AND
TRANSMITTANCE
OF
COPOLYMERS
*
199
DIELECTRIC
PROPERTIES
OF
MULTICOMPONENT
POLYMERS
*
201
RELATIONSHIP
BETWEEN
DIELECTRIC
PROPERTIES
AND
COMPOSITION
OF
MULTICOMPONENT
POLYMERS
*
201
7.4.2
THE
RELATIONSHIP
BETWEEN
DIELECTRIC
PROPERTIES
OF
MULTICOMPONENT
POLYMERS
AND
COMPATIBILIZERS
*
205
7.3.3
RELATIONSHIP
BETWEEN
DIELECTRIC
PROPERTIES
AND
PROCESSING
CONDITIONS
OF
MULTICOMPONENT
POLYMERS
*
207
CHAPTER
8
GRAFT
COPOLYMERS
*
212
8.1
8.1.1
8.1.2
8.2
8.2.1
8.2.2
8.2.3
8.2.4
CONCEPTS
OF
GRAFT
COPOLYMERS
*
212
DEFINITION
AND
DEVELOPMENT
OF
GRAFT
COPOLYMERS
*
212
REPRESENTATION
OF
GRAFT
COPOLYMERS
*
213
SYNTHESIS
OF
GRAFT
COPOLYMERS
*
214
BASIC
METHODS
FOR
PREPARING
GRAFT
COPOLYMERS
-----
214
CHAIN
TRANSFER
METHOD
*
215
ACTIVE
GROUP
METHOD
-----
217
RADIATION
METHODS
-----
218
CONTENTS
*
*
XIII
8.2.5
ADDITIVE
POLYMERIZATION
AND
RING-OPENING
POLYMERIZATION
*
219
8.2.6
IONIC
POLYMERIZATION
-----
220
8.2.7
MACROMER
METHOD
-----
221
8.3
PROPERTIES
OF
GRAFT
COPOLYMERS
*
225
8.3.1
CHEMICAL
PROPERTIES
OF
GRAFT
COPOLYMERS
*
225
8.3.2
SOLUTION
PROPERTIES
OF
GRAFT
COPOLYMERS
*
226
8.3.3
MECHANICAL
PROPERTIES
OF
GRAFT
COPOLYMERS
*
228
8.3.4
GAS
PERMEABILITY
OF
GRAFT
COPOLYMER
*
234
8.3.5
LIQUID
PERMEABILITY
OF
GRAFT
COPOLYMERS
*
240
8.3.6
VISCOELASTICITY
OF
GRAFT
COPOLYMERS
-----
242
8.3.7
MELTING
AND
CRYSTALLIZATION
OF
GRAFT
COPOLYMERS
*
244
8.4
APPLICATION
OF
GRAFT
COPOLYMER
*
245
8.5
GRAFT
MODIFICATION
OF
PS
PLASTICS
*
247
8.5.1
HIGH
IMPACT
POLYSTYRENE
*
248
8.5.2
ABS
RESIN
AND
ITS
MODIFICATION
*
253
8.6
GRAFTING
MODIFICATION
OF
POLYVINYL
CHLORIDE
PLASTICS
*
259
8.6.1
SUMMARY
-----
259
8.6.2
GRAFT
COPOLYMER
OF
VINYL
CHLORIDE
ON
SOFT
POLYMER
SKELETON
*
260
8.6.3
GRAFT
COPOLYMER
WITH
VINYL
CHLORIDE
AS
FRAMEWORK
*
267
8.7
GRAFT
COPOLYMERS
OF
INORGANIC
MATERIALS
*
275
8.7.1
SUMMARY
*
275
8.7.2
PREPARATION
OF
INORGANIC
MATERIAL
GRAFT
COPOLYMER
*
276
8.7.3
STRUCTURE
OF
INORGANIC
MATERIAL
GRAFT
COPOLYMER
*
281
8.7.4
PROPERTIES
AND
APPLICATIONS
OF
INORGANIC
MATERIAL
GRAFT
COPOLYMERS
*
282
8.8
GRAFT
COPOLYMER
OF
CARBON
NANOMATERIALS
*
283
8.8.1
TYPES,
STRUCTURES
AND
CHARACTERISTICS
OF
CARBON
NANOMATERIALS
*
283
8.8.2
GRAFT
MODIFICATION
OF
CARBON
NANOTUBES
*
286
8.8.3
APPLICATION
OF
POLYMER
GRAFTED
CARBON
NANOTUBES
*
290
EXERCISES
*
294
CHAPTER
9
BLOCK
COPOLYMERS
*
298
9.1
BASIC
CONCEPTS
OF
BLOCK
COPOLYMERS
*
298
9.2
SYNTHESIS
METHOD
OF
BLOCK
COPOLYMER
*
300
9.2.1
PREPARATION
OF
BLOCK
COPOLYMERS
BY
LIVING
ANION
POLYMERIZATION
*
300
9.2.2
PREPARATION
OF
STAR
BLOCK
COPOLYMERS
BY
LIVING
ANION
POLYMERIZATION
*
306
9.2.3
PREPARATION
OF
POLYURETHANE
BLOCK
COPOLYMER
*
307
9.3
STRUCTURE
AND
PROPERTIES
OF
STYRENE
BLOCK
COPOLYMERS
*
312
XIV
*
CONTENTS
9.3.1
9.3.2
MORPHOLOGICAL
STRUCTURE
OF
STYRENE
BLOCK
COPOLYMERS
*
312
CONDITIONS
FOR
PHASE
DOMAIN
FORMATION
OF
STYRENE
BLOCK
COPOLYMERS
*
315
9.3.3
9.3.4
9.4
9.4.1
9.4.2
9.4.3
PROPERTIES
OF
STYRENE
BLOCK
COPOLYMERS
*
316
OTHER
STYRENE
BLOCK
COPOLYMERS
*
322
STRUCTURE
AND
PROPERTIES
OF
TPPU
-----
322
MORPHOLOGICAL
STRUCTURE
OF
TPPU
-----
322
PROPERTIES
OF
TPPU
-----
328
BLENDING
OF
TPPU
WITH
OTHER
POLYMERS
-----332
CHAPTER
10
INTERPENETRATING
POLYMER
NETWORKS
*
336
10.1
SUMMARY
-----
336
10.2
HISTORY
OF
IPNS
-----
337
10.3
TYPES
AND
REPRESENTATION
OF
IPNS
*
340
10.3.1
TYPES
OF
IPNS
-----
340
10.3.2
REPRESENTATION
OF
IPN
-----
342
10.4
PREPARATION
OF
IPNS
*
345
10.4.1
PREPARATION
OF
STEP-BY-STEP
POLYMER
NETWORKS
*
345
10.4.2
PREPARATION
OF
SYNCHRONIZED
POLYMER
NETWORKS
*
348
10.4.3
PREPARATION
OF
LATEX
POLYMER
NETWORK
*
349
10.4.4
PREPARATION
OF
THERMOPLASTIC
POLYMER
NETWORKS
*
351
10.5
PERFORMANCE
OF
IPNS
*
353
10.5.1
ENHANCEMENT
PERFORMANCE
*
353
10.5.2
TOUGHENING
PROPERTIES
-----
354
10.5.3
DAMPING
PERFORMANCE
-----
354
10.5.4
ADHESIVE
PROPERTY
-----
355
10.5.5
MACHINABILITY
-----
356
10.6
APPLICATION
OF
IPNS
-----
357
10.6.1
ELASTOMER
REINFORCEMENT
------
357
10.6.2
TOUGHENED
PLASTICS
-----
359
10.6.3
THERMOPLASTIC
IPN
-----
360
10.6.4
DYNAMIC
VULCANIZATION
THERMOPLASTIC
IPN
*
361
10.6.5 COMPOUND
MATERIAL
-----
363
10.6.6
FUNCTIONAL
MATERIALS
*
364
10.6.7
ADHESIVES
AND
COATINGS
*
367
EXERCISES
-----
369
INDEX
*
371
|
| adam_txt |
CONTENTS
PREFACE
*
V
ACKNOWLEDGEMENTS
*
VII
LIST
OF
FIGURES
-----
XV
LIST
OF
TABLES
*
XXIII
CHAPTER
1
INTRODUCTION
*
1
1.1
1.2
1.3
ABSTRACT
*
1
BASIC
CONCEPTS
*
3
MAIN
TYPES
AND
REPRESENTATION
METHODS
OF
MULTICOMPONENT
POLYMERS
*
5
1.3.1
1.3.2
1.4
1.4.1
1.4.2
1.4.3
1.4.4
1.5
MAIN
TYPES
OF
MULTICOMPONENT
POLYMERS
*
5
REPRESENTATION
OF
MULTICOMPONENT
POLYMERS
*
8
PREPARATION
OF
MULTICOMPONENT
POLYMERS
*
9
PHYSICAL
BLEND
METHODS
-----
9
COPOLYMERIZATION
BLENDING
METHOD
*
10
INTERPENETRATING
POLYMER
NETWORK
*
11
BLOCK
COPOLYMER
AND
GRAFT
COPOLYMER
*
12
DEVELOPMENT
OF
BLENDING
MODIFICATION
OF
POLYMERS
*
13
EXERCISES
*
15
CHAPTER
2
PHYSICAL
AND
CHEMICAL
PRINCIPLES
OF
MULTICOMPONENT
POLYMERS
*
16
2.1
2.2
2.3
2.4
THE
CONCEPT
OF
COMPATIBILITY
BETWEEN
POLYMERS
*
16
THERMODYNAMIC
ANALYSIS
OF
MISCIBILITY
OF
POLYMERS
*
18
CRITICAL
CONDITIONS
FOR
PHASE
SEPARATION
*
20
MISCIBILITY
OF
POLYMER
AND
PHASE
DIAGRAM
OF
TWO
COMPONENT
BLENDS
----
23
2.5
2.6
2.7
2.7.1
2.7.2
2.8
PHASE
SEPARATION
MECHANISM
*
25
APPLICATION
OF
SOLUBILITY
PARAMETER
THEORY
IN
BLENDS
*
29
METHODOLOGY
FOR
THE
COMPATIBILITY
BETWEEN
POLYMERS
*
32
GLASS
TRANSITION
TEMPERATURE
METHOD
*
33
OTHER
METHODS
-----36
METHODS
FOR
IMPROVING
THE
COMPATIBILITY
BETWEEN
POLYMER
BLENDS
-----
38
X
*
CONTENTS
2.8.1
THE
SIGNIFICANCE
OF
IMPROVING
THE
COMPATIBILITY
OF
POLYMER
BLENDS
*
38
2.8.2
2.8.3
2.8.4
2.8.5
STRUCTURAL
CHARACTERISTICS
OF
COMPATIBLE
POLYMERS
*
38
COMPATIBILIZATION
AND
ITS
METHODS
*
40
IMPROVING
COMPATIBILITY
BY
CHANGING
CHAIN
STRUCTURE
*
42
THE
APPLICATION
OF COMPATIBILIZER
*
45
EXERCISES
*
50
CHAPTER
3
PHASE
STRUCTURE
OF
MULTICOMPONENT
POLYMERS
*
52
3.1
3.2
3.2.1
3.2.2
INTRODUCTION
-----
52
BASIC
TYPES
OF
PHASE
STRUCTURE
OF
POLYMER
BLENDS
*
53
PHASE
STRUCTURES
OF
AMORPHOUS
POLYMER
BLENDS
*
53
MORPHOLOGICAL
CHARACTERISTICS
OF
BLENDS
CONTAINING
CRYSTALLINE
POLYMERS
*
61
3.3
3.3.1
3.3.2
3.3.3
FACTORS
AFFECTING
PHASE
STRUCTURE
OF
POLYMER
BLENDS
*
65
FACTORS
AFFECTING
CONTINUITY
*
65
FACTORS
AFFECTING
THE
MORPHOLOGY
AND
SIZE
OF
MICROREGIONS
*
69
INFLUENCING
FACTORS
ON
PHASE
STRUCTURE
OF
BLENDS
CONTAINING
CRYSTALLINE
POLYMERS
*
72
3.4
3.4.1
3.4.2
3.4.3
3.4.4
3.4.5
INTERFACIAL
LAYER
OF
POLYMER
BLENDS
*
74
CONCEPT
OF
INTERFACE
LAYER
*
74
FORMATION
OF
INTERFACE
LAYER
*
75
INTERFACE
LAYER
THICKNESS
*
76
PROPERTIES
OF
INTERFACE
LAYER
*
77
FACTORS
AFFECTING
INTERFACE
LAYER
STRUCTURE
OF
POLYMER
BLENDS
*
79
EXERCISES
-----
81
CHAPTER
4
TOUGHENING
MECHANISM
OF
MULTICOMPONENT
POLYMERS
*
82
4.1
4.2
4.2.1
4.2.2
4.2.3
4.2.4
INTRODUCTION
-----
82
TOUGHENING
MECHANISM
OF
ELASTOMER-TOUGHENED
PLASTICS
*
83
EARLY
TOUGHENING
THEORY
*
84
CRAZE-SHEAR
BAND
THEORY
*
87
WU
*
S
PERCOLATION
THEORY
*
94
FACTORS
AFFECTING
IMPACT
STRENGTH
OF
ELASTOMER-TOUGHENED
PLASTICS
*
99
4.3
4.3.1
4.3.2
MECHANISM
OF
TOUGHENING
PLASTICS
WITH
NONELASTOMERS
*
103
TOUGHENING
BY
RIGID
ORGANIC
PARTICLES
*
103
TOUGHENING
OF
INORGANIC
RIGID
PARTICLES
*
110
EXERCISES
-----
111
CONTENTS
*
XI
CHAPTER
5
MECHANICAL
PROPERTIES
OF
MULTICOMPONENT
POLYMERS
*
113
5.1
5.2
INTRODUCTION
*
113
RELATIONSHIP
BETWEEN
PROPERTIES
OF
POLYMER
BLENDS
AND
THEIR
COMPONENTS
*
113
5.2.1
THE
*
MIXING
RULE
*
FOR
THE
PROPERTIES
OF
BICOMPONENT
POLYMERS
*
113
5.2.2
RELATIONSHIP
BETWEEN
PROPERTIES
AND
COMPONENT
PROPERTIES
OF
HOMOGENEOUS
BLENDS
*
114
5.2.3
RELATIONSHIP
BETWEEN
PROPERTIES
AND
COMPONENT
PROPERTIES
OF
SINGLE
CONTINUOUS
STRUCTURE
BLENDS
*
115
5.2.4
RELATIONSHIP
BETWEEN
PROPERTIES
OF
TWO-PHASE
CONTINUOUS
STRUCTURE
BLENDS
AND
THEIR
COMPONENTS
*
117
5.3
5.3.1
5.3.2
5.3.3
5.4
5.4.1
GLASS
TRANSITION
OF
MULTICOMPONENT
POLYMERS
*
118
GLASS
TRANSITION
OF
POLYMERS
*
118
FACTORS
AFFECTING
GLASS
TRANSITION
OF
POLYMERS
*
119
GLASS
TRANSITION
OF
MULTICOMPONENT
POLYMERS
*
123
ELASTIC
MODULUS
OF
POLYMER
ALLOYS
*
128
MODULUS
OF
ELASTICITY
AND
POISSON
*
S
RATIO
OF
POLYMER
MATERIALS
*
128
5.4.2
5.4.3
5.5
5.5.1
5.5.2
5.6
5.6.1
ESTIMATION
OF
ELASTIC
MODULUS
OF
POLYMER
ALLOYS
*
129
MECHANICAL
MODEL
OF
POLYMER
BLENDS
*
131
STRESS
RELAXATION
OF
POLYMER
ALLOYS
*
135
STRESS
RELAXATION
PROPERTIES
OF
BLENDS
*
135
STRESS
RELAXATION
PROPERTIES
OF
GRAFTED
AND
BLOCK
COPOLYMERS
*
138
DEFORMATION
OF
POLYMER
ALLOYS
*
141
MECHANICAL
STRENGTH
AND
LARGE
DEFORMATION
OF
POLYMER
MATERIALS
*
141
5.6.2
LARGE
DEFORMATION
OF
POLYMER
ALLOYS
*
145
EXERCISES
-----
156
CHAPTER
6
RHEOLOGICAL
PROPERTIES
OF
MULTICOMPONENT
POLYMERS
*
158
6.1
6.1.1
6.1.2
6.1.3
6.2
6.2.1
6.2.2
6.3
6.3.1
VISCOUS
FLOW
OF
POLYMER
MELTS
*
158
CHARACTERISTICS
OF
SHEAR
FLOW
IN
POLYMER
MELTS
*
158
APPARENT
VISCOSITY
OF
POLYMER
MELTS
*
160
FACTORS
AFFECTING
THE
APPARENT
VISCOSITY
OF
POLYMER
MELTS
*
161
VISCOUS
FLOW
OF
MULTICOMPONENT
POLYMERS
*
166
DISPERSION
OF
MULTICOMPONENT
POLYMER
MELTS
*
166
VISCOSITY
OF
MULTICOMPONENT
POLYMER
MELTS
*
167
ELASTIC
EFFECT
OF
MULTICOMPONENT
POLYMER
MELTS
*
176
PARAMETERS
FOR
CHARACTERIZATION
OF
POLYMER
MELT
ELASTICITY
*
176
XII
*
CONTENTS
6.3.2
RELATIONSHIP
BETWEEN
ELASTICITY
AND
COMPOSITION
OF
MULTICOMPONENT
POLYMER
MELTS
*
177
6.3.3
RELATIONSHIP
BETWEEN
ELASTICITY
AND
SHEAR
OF
MULTICOMPONENT
POLYMER
MELTS
*
178
6.3.4
6.3.5
ELASTICITY
OF
ELASTOMER
TOUGHENED
PLASTIC
MELT
*
179
INFLUENCE
OF
ELASTIC
EFFECT
OF
MULTICOMPONENT
POLYMER
MELTS
ON
MOLDING
PROCESS
-----
180
EXERCISES
-----
182
CHAPTER
7
OTHER
CHARACTERISTICS
OF
MULTICOMPONENT
POLYMERS
*
184
7.1
7.1.1
7.1.2
7.1.3
7.2
7.2.1
7.2.2
7.2.3
7.3
7.3.1
7.3.2
7.3.3
7.4
7.4.1
PERMEABILITY
OF
MULTICOMPONENT
POLYMERS
*
184
INTRODUCTION
-----
184
AIR
PERMEABILITY
OF
MULTICOMPONENT
POLYMERS
-----
185
PERMEABILITY
OF
MULTICOMPONENT
POLYMERS
*
187
BARRIER
PROPERTIES
OF
MULTICOMPONENT
POLYMERS
*
188
BARRIER
PROPERTIES
OF
POLYMERS
*
188
BARRIER
PROPERTIES
OF
BLENDED
POLYMERS
*
190
INFLUENCING
FACTORS
OF
BARRIER
PROPERTY
OF
BLEND
POLYMER
*
191
TRANSPARENCY
OF
MULTICOMPONENT
POLYMERS
*
194
TRANSPARENCY
OF
POLYMER
BLENDS
*
194
TRANSPARENCY
OF
RUBBER
TOUGHENED
PLASTIC
BLENDS
*
195
REFRACTIVE
INDEX
AND
TRANSMITTANCE
OF
COPOLYMERS
*
199
DIELECTRIC
PROPERTIES
OF
MULTICOMPONENT
POLYMERS
*
201
RELATIONSHIP
BETWEEN
DIELECTRIC
PROPERTIES
AND
COMPOSITION
OF
MULTICOMPONENT
POLYMERS
*
201
7.4.2
THE
RELATIONSHIP
BETWEEN
DIELECTRIC
PROPERTIES
OF
MULTICOMPONENT
POLYMERS
AND
COMPATIBILIZERS
*
205
7.3.3
RELATIONSHIP
BETWEEN
DIELECTRIC
PROPERTIES
AND
PROCESSING
CONDITIONS
OF
MULTICOMPONENT
POLYMERS
*
207
CHAPTER
8
GRAFT
COPOLYMERS
*
212
8.1
8.1.1
8.1.2
8.2
8.2.1
8.2.2
8.2.3
8.2.4
CONCEPTS
OF
GRAFT
COPOLYMERS
*
212
DEFINITION
AND
DEVELOPMENT
OF
GRAFT
COPOLYMERS
*
212
REPRESENTATION
OF
GRAFT
COPOLYMERS
*
213
SYNTHESIS
OF
GRAFT
COPOLYMERS
*
214
BASIC
METHODS
FOR
PREPARING
GRAFT
COPOLYMERS
-----
214
CHAIN
TRANSFER
METHOD
*
215
ACTIVE
GROUP
METHOD
-----
217
RADIATION
METHODS
-----
218
CONTENTS
*
*
XIII
8.2.5
ADDITIVE
POLYMERIZATION
AND
RING-OPENING
POLYMERIZATION
*
219
8.2.6
IONIC
POLYMERIZATION
-----
220
8.2.7
MACROMER
METHOD
-----
221
8.3
PROPERTIES
OF
GRAFT
COPOLYMERS
*
225
8.3.1
CHEMICAL
PROPERTIES
OF
GRAFT
COPOLYMERS
*
225
8.3.2
SOLUTION
PROPERTIES
OF
GRAFT
COPOLYMERS
*
226
8.3.3
MECHANICAL
PROPERTIES
OF
GRAFT
COPOLYMERS
*
228
8.3.4
GAS
PERMEABILITY
OF
GRAFT
COPOLYMER
*
234
8.3.5
LIQUID
PERMEABILITY
OF
GRAFT
COPOLYMERS
*
240
8.3.6
VISCOELASTICITY
OF
GRAFT
COPOLYMERS
-----
242
8.3.7
MELTING
AND
CRYSTALLIZATION
OF
GRAFT
COPOLYMERS
*
244
8.4
APPLICATION
OF
GRAFT
COPOLYMER
*
245
8.5
GRAFT
MODIFICATION
OF
PS
PLASTICS
*
247
8.5.1
HIGH
IMPACT
POLYSTYRENE
*
248
8.5.2
ABS
RESIN
AND
ITS
MODIFICATION
*
253
8.6
GRAFTING
MODIFICATION
OF
POLYVINYL
CHLORIDE
PLASTICS
*
259
8.6.1
SUMMARY
-----
259
8.6.2
GRAFT
COPOLYMER
OF
VINYL
CHLORIDE
ON
SOFT
POLYMER
SKELETON
*
260
8.6.3
GRAFT
COPOLYMER
WITH
VINYL
CHLORIDE
AS
FRAMEWORK
*
267
8.7
GRAFT
COPOLYMERS
OF
INORGANIC
MATERIALS
*
275
8.7.1
SUMMARY
*
275
8.7.2
PREPARATION
OF
INORGANIC
MATERIAL
GRAFT
COPOLYMER
*
276
8.7.3
STRUCTURE
OF
INORGANIC
MATERIAL
GRAFT
COPOLYMER
*
281
8.7.4
PROPERTIES
AND
APPLICATIONS
OF
INORGANIC
MATERIAL
GRAFT
COPOLYMERS
*
282
8.8
GRAFT
COPOLYMER
OF
CARBON
NANOMATERIALS
*
283
8.8.1
TYPES,
STRUCTURES
AND
CHARACTERISTICS
OF
CARBON
NANOMATERIALS
*
283
8.8.2
GRAFT
MODIFICATION
OF
CARBON
NANOTUBES
*
286
8.8.3
APPLICATION
OF
POLYMER
GRAFTED
CARBON
NANOTUBES
*
290
EXERCISES
*
294
CHAPTER
9
BLOCK
COPOLYMERS
*
298
9.1
BASIC
CONCEPTS
OF
BLOCK
COPOLYMERS
*
298
9.2
SYNTHESIS
METHOD
OF
BLOCK
COPOLYMER
*
300
9.2.1
PREPARATION
OF
BLOCK
COPOLYMERS
BY
LIVING
ANION
POLYMERIZATION
*
300
9.2.2
PREPARATION
OF
STAR
BLOCK
COPOLYMERS
BY
LIVING
ANION
POLYMERIZATION
*
306
9.2.3
PREPARATION
OF
POLYURETHANE
BLOCK
COPOLYMER
*
307
9.3
STRUCTURE
AND
PROPERTIES
OF
STYRENE
BLOCK
COPOLYMERS
*
312
XIV
*
CONTENTS
9.3.1
9.3.2
MORPHOLOGICAL
STRUCTURE
OF
STYRENE
BLOCK
COPOLYMERS
*
312
CONDITIONS
FOR
PHASE
DOMAIN
FORMATION
OF
STYRENE
BLOCK
COPOLYMERS
*
315
9.3.3
9.3.4
9.4
9.4.1
9.4.2
9.4.3
PROPERTIES
OF
STYRENE
BLOCK
COPOLYMERS
*
316
OTHER
STYRENE
BLOCK
COPOLYMERS
*
322
STRUCTURE
AND
PROPERTIES
OF
TPPU
-----
322
MORPHOLOGICAL
STRUCTURE
OF
TPPU
-----
322
PROPERTIES
OF
TPPU
-----
328
BLENDING
OF
TPPU
WITH
OTHER
POLYMERS
-----332
CHAPTER
10
INTERPENETRATING
POLYMER
NETWORKS
*
336
10.1
SUMMARY
-----
336
10.2
HISTORY
OF
IPNS
-----
337
10.3
TYPES
AND
REPRESENTATION
OF
IPNS
*
340
10.3.1
TYPES
OF
IPNS
-----
340
10.3.2
REPRESENTATION
OF
IPN
-----
342
10.4
PREPARATION
OF
IPNS
*
345
10.4.1
PREPARATION
OF
STEP-BY-STEP
POLYMER
NETWORKS
*
345
10.4.2
PREPARATION
OF
SYNCHRONIZED
POLYMER
NETWORKS
*
348
10.4.3
PREPARATION
OF
LATEX
POLYMER
NETWORK
*
349
10.4.4
PREPARATION
OF
THERMOPLASTIC
POLYMER
NETWORKS
*
351
10.5
PERFORMANCE
OF
IPNS
*
353
10.5.1
ENHANCEMENT
PERFORMANCE
*
353
10.5.2
TOUGHENING
PROPERTIES
-----
354
10.5.3
DAMPING
PERFORMANCE
-----
354
10.5.4
ADHESIVE
PROPERTY
-----
355
10.5.5
MACHINABILITY
-----
356
10.6
APPLICATION
OF
IPNS
-----
357
10.6.1
ELASTOMER
REINFORCEMENT
------
357
10.6.2
TOUGHENED
PLASTICS
-----
359
10.6.3
THERMOPLASTIC
IPN
-----
360
10.6.4
DYNAMIC
VULCANIZATION
THERMOPLASTIC
IPN
*
361
10.6.5 COMPOUND
MATERIAL
-----
363
10.6.6
FUNCTIONAL
MATERIALS
*
364
10.6.7
ADHESIVES
AND
COATINGS
*
367
EXERCISES
-----
369
INDEX
*
371 |
| any_adam_object | 1 |
| any_adam_object_boolean | 1 |
| author | Wang, Guojian Yuan, Junjie |
| author_GND | (DE-588)1225704758 |
| author_facet | Wang, Guojian Yuan, Junjie |
| author_role | aut aut |
| author_sort | Wang, Guojian |
| author_variant | g w gw j y jy |
| building | Verbundindex |
| bvnumber | BV047177339 |
| classification_rvk | UV 9240 |
| ctrlnum | (OCoLC)1226308550 (DE-599)DNB1210656620 |
| dewey-full | 668.9 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 668 - Technology of other organic products |
| dewey-raw | 668.9 |
| dewey-search | 668.9 |
| dewey-sort | 3668.9 |
| dewey-tens | 660 - Chemical engineering |
| discipline | Chemie / Pharmazie Physik |
| discipline_str_mv | Chemie / Pharmazie Physik |
| format | Book |
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| id | DE-604.BV047177339 |
| illustrated | Illustrated |
| index_date | 2024-07-03T16:44:54Z |
| indexdate | 2024-07-10T09:04:47Z |
| institution | BVB |
| institution_GND | (DE-588)10095502-2 |
| isbn | 9783110596328 3110596326 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-032582694 |
| oclc_num | 1226308550 |
| open_access_boolean | |
| owner | DE-573 DE-703 |
| owner_facet | DE-573 DE-703 |
| physical | XXVI, 379 Seiten Illustrationen, Diagramme 24 cm, 687 g |
| publishDate | 2020 |
| publishDateSearch | 2020 |
| publishDateSort | 2020 |
| publisher | De Gruyter Tongji University Press |
| record_format | marc |
| series2 | De Gruyter STEM |
| spelling | Wang, Guojian Verfasser (DE-588)1225704758 aut Multicomponent polymers principles, structures and properties Guojian Wang, Junjie Yuan Berlin ; Boston De Gruyter [2020] Shanghai Tongji University Press XXVI, 379 Seiten Illustrationen, Diagramme 24 cm, 687 g txt rdacontent n rdamedia nc rdacarrier De Gruyter STEM Polymer-Blend (DE-588)4200547-4 gnd rswk-swf Polymergemisch (DE-588)4175243-0 gnd rswk-swf Polymergemisch (DE-588)4175243-0 s Polymer-Blend (DE-588)4200547-4 s DE-604 Yuan, Junjie Verfasser aut Walter de Gruyter GmbH & Co. KG (DE-588)10095502-2 pbl Erscheint auch als Online-Ausgabe, EPUB 978-3-11-059441-6 Erscheint auch als Online-Ausgabe, PDF 978-3-11-059633-5 X:MVB https://www.degruyter.com/books/9783110596328 B:DE-101 application/pdf https://d-nb.info/1210656620/04 Inhaltsverzeichnis DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=032582694&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Wang, Guojian Yuan, Junjie Multicomponent polymers principles, structures and properties Polymer-Blend (DE-588)4200547-4 gnd Polymergemisch (DE-588)4175243-0 gnd |
| subject_GND | (DE-588)4200547-4 (DE-588)4175243-0 |
| title | Multicomponent polymers principles, structures and properties |
| title_auth | Multicomponent polymers principles, structures and properties |
| title_exact_search | Multicomponent polymers principles, structures and properties |
| title_exact_search_txtP | Multicomponent polymers principles, structures and properties |
| title_full | Multicomponent polymers principles, structures and properties Guojian Wang, Junjie Yuan |
| title_fullStr | Multicomponent polymers principles, structures and properties Guojian Wang, Junjie Yuan |
| title_full_unstemmed | Multicomponent polymers principles, structures and properties Guojian Wang, Junjie Yuan |
| title_short | Multicomponent polymers |
| title_sort | multicomponent polymers principles structures and properties |
| title_sub | principles, structures and properties |
| topic | Polymer-Blend (DE-588)4200547-4 gnd Polymergemisch (DE-588)4175243-0 gnd |
| topic_facet | Polymer-Blend Polymergemisch |
| url | https://www.degruyter.com/books/9783110596328 https://d-nb.info/1210656620/04 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=032582694&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT wangguojian multicomponentpolymersprinciplesstructuresandproperties AT yuanjunjie multicomponentpolymersprinciplesstructuresandproperties AT walterdegruytergmbhcokg multicomponentpolymersprinciplesstructuresandproperties |
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