Verfügbarkeit: Solid state materials chemistry

Solid state materials chemistry:

Gespeichert in:

Bibliographische Detailangaben
Hauptverfasser:	Woodward, Patrick M. (VerfasserIn), Karen, Pavel 1951- (VerfasserIn), Evans, John S. O. (VerfasserIn), Vogt, Thomas (VerfasserIn)
Format:	Buch
Sprache:	English
Veröffentlicht:	Cambridge Cambridge University Press 2021
Schlagworte:	Festkörperphysik Festkörperchemie Solid state chemistry Materials science
Online-Zugang:	Inhaltsverzeichnis
Beschreibung:	Literaturangaben
Beschreibung:	xix, 687 Seiten Illustrationen, Diagramme
ISBN:	9780521873253

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Datensatz im Suchindex

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adam_text	Contents Preface Acknowledgments 1 Structures of Crystalline Materials Ll Symmetry 111 Translational Symmetry 112 Rotational Symmetry 113 Crystallographic Point Groups and Crystal Systems 114 Bravais Lattices 115 Introduction to Space Groups 116 Symmetry Elements That Combine Rotation and Translation 117 Space-Group Symbols 118 Description of a Crystal Structure Databases Composition 131 Coordination, Stoichiometry, and Connectivity 132 The Generalized 8—N Rule Structural Principles 141 Packing of Spheres 142 Filling Holes 143 Network Structures 144 Polyhedral Structures Structures of Selected Materials 151 The Spinel Structure 152 The Garnet Structure 153 Perovskite Structures 154 Silicates 155 Zeolites 156 Zintl Phases Problems Further Reading References page xvii xix vi Contents 2 Defects and More Complex Structures Point Defects in Crystalline Elemental Solids Intrinsic Point Defects in Compounds Thermodynamics of Vacancy Formation Extrinsic Defects Solid Solutions and Vegard’s Law Kröger-Vink Notation Line Defects in Metals 271 Edge Dislocations 272 Screw Dislocations Planar Defects in Materials 281 Stacking Faults 282 Twinning 283 Antiphase Boundaries 284 Crystallographic Shear Structures Gross Nonstoichiometry and Defect Ordering Incommensurate Structures Infinitely Adaptive Structures Problems Further Reading References 3 Defect Chemistry and Nonstoichiometry 3 1 Narrow Nonstoichiometry in Oxides 311 Point Defects in a Pure Stoichiometric Oxide 312 Point Defects upon Oxidation/Reduction of the Stoichiometric Oxide 313 Equilibrium Equations for Oxidative and Reductive Nonstoichiometry 314 Defect Equilibria for Schottky-Type Redox Compensation 315 Acceptor-Doped Oxides 316 Donor-Doped Oxides 317 Solid Solubility of Dopants 318 Cautionary Note on Defect Models in Pure Oxides 3 2 Wide Nonstoichiometry in Oxides 3 3 Point Defects and Diffusion 331 Point-Defect Movements 332 Random Hopping 333 Hopping Under a Driving Force Contents 334 Hopping Under a Concentration Gradient 335 Hopping Under an Electric Field 336 Relationship between Conductivity and Diffusivity 337 Ambipolar Diffusion 338 Temperature Dependence of Diffusivity 339 Diffusivity and Redox Defect Equilibria 3 3 10 Outline of Non-Steady-State Diffusion 3 3 11 Cautionary Note on Diffusion in Real Materials 3 4 Problems 3 5 Further Reading 3 6 References Phase Diagrams and Phase Transitions 4 1 Phase Diagrams 4 2 Two-Component Phase Diagrams 421 Without Compound Formation 422 With Compound Formation 423 Solid-Solution Formation 4 3 Three-Component Phase Diagrams 4 4 Structural Phase Transitions 441 Classification of Phase Transitions 442 Symmetry and Order Parameters 443 Introduction to Landau Theory 444 Second-Order Transitions 445 First-Order and Tricritical Transitions 446 Phonons, Soft Modes, and Displacive Transitions 4 5 Problems 4 6 Further Reading 4 7 References Chemical Bonding 5 1 Ionic Bonding 511 Coulombic Potential Energy 512 Lattice Energy and the Born-Mayer Equation 513 Experimental versus Calculated Lattice-Formation Energies 5 2 Atomic Orbitals 521 Energies of Atomic Orbitals 522 Sizes of Atomic Orbitals 5 3 Molecular-Orbital Theory 531 Homonuclear Diatomics: H,* and H, 532 The Heteronuclear Diatomic Case: HHe vü viii Contents 533 Orbital Overlap and Symmetry 534 Combination of o and w Bonding: O, 535 Symmetry-Adapted Linear Combinations (SALCs) 536 Simple Polyatomic Molecules: BeH, and CH, 537 Conjugated 7 Bonding: CgH, 538 Transition-Metal Complexes: [CrCl ] ~ and [CoCl,]?- 539 High- and Low-Spin Configurations 5 3 10 Jahn-Teller Distortions Bond Valences Problems Further Reading References 6 Electronic Band Structure The Band Structure of a Hydrogen-Atom Chain 611 The Electronic Structures of Cyclic Hy Molecules 612 Translational Symmetry and the Bloch Function 613 The Quantum Number k 614 Visualizing Crystal Orbitals 615 Band-Structure Diagrams 616 Density-of-States (DOS) Plots The Band Structure of a Chain of Hz Molecules Electrical and Optical Properties 631 Metals, Semiconductors, and Insulators 632 Direct- versus Indirect-Gap Semiconductors Representing Band Structures in Higher Dimensions 641 Crystal Orbitals in Two Dimensions 642 Crystal Orbitals in Three Dimensions Band Structures of Two-Dimensional Materials 651 Graphene 652 CuO,?” Square Lattice Band Structures of Three-Dimensional Materials 661 a-Polonium 662 Diamond 663 Elemental Semiconductors 664 Rhenium Trioxide 665 Perovskites Problems Further Reading References Contents ix 7 Optical Materials 243 7 1 Light, Color, and Electronic Excitations 243 7 2 Pigments, Dyes, and Gemstones 245 7 3 Transitions between d Orbitals (d-to-d Excitations) 246 731 Ligand- and Crystal-Field Theory 246 732 Absorption Spectra and Spectroscopic Terms 248 7 3 3, Correlation Diagrams 252 734 Selection Rules and Absorption Intensity 255 7 4 Charge-Transfer Excitations 258 741 Ligand-to-Metal Charge Transfer 259 742 Metal-to-Metal Charge Transfer 260 7 5 Compound Semiconductors 261 751 Optical Absorbance, Band Gap, and Color 262 752 Electronegativity, Orbital Overlap, and Band Gap 263 7 6 Conjugated Organic Molecules 265 7 7 Luminescence 267 7 3 Photoluminescence 268 781 Components ofa Phosphor 268 782 Radiative Return to the Ground State 270 733 Thermal Quenching 272 784 Lanthanoid Activators 274 785 Non-Lanthanoid Activators 279 786 Energy Transfer 281 737 Sensitizers 283 788 Concentration Quenching and Cross Relaxation 284 789 Up-Conversion Photoluminescence 285 7 9 Electroluminescence 287 791 Inorganic Light-Emitting Diodes (LEDs) 287 792 Organic Light-Emitting Diodes (OLEDs) 289 7 10 Materials for Lighting 291 7 10 1 Fluorescent Lamp Phosphors 292 7 10 2 Phosphor-Converted LEDs for White Light 293 7 11 Problems 294 7 12 Further Reading 298 7 13 References 299 8 Dielectrics and Nonlinear Optical Materials 301 8 1 Dielectric Properties 301 811 Dielectric Permittivity and Susceptibility 302 Contents 812 Polarization and the Clausius-Mossotti Equation 303 813 Microscopic Mechanisms of Polarizability 305 814 Frequency Dependence of the Dielectric Response 306 815 Dielectric Loss 308 8 2 Dielectric Polarizabilities and the Additivity Rule 309 8 3 Crystallographic Symmetry and Dielectric Properties 313 8 4 Pyroelectricity and Ferroelectricity 314 841 Ferroelectricity in BaTiO; 314 842 Antiferroelectricity 319 8 5 Piezoelectricity 321 8 6 Local Bonding Considerations in Non-Centrosymmetric Materials 324 861 Second-Order Jahn-Teller Distortions with d° Cations 325 862 Second-Order Jahn-Teller Distortions with s”p° Cations 327 8 7 Nonlinear Optical Materials 330 8 8 Nonlinear Susceptibility and Phase Matching 331 8 9 Important SHG Materials 334 891 KH PO, 336 892 KTiOPO, 336 893 Niobates and Tantalates 338 894 Organic and Polymer NLO Materials 339 895 Borates 340 8 10 Problems 343 8 11 Further Reading 346 8 12 References 346 9 Magnetic Materials 349 9 1 Magnetic Materials and Their Applications 349 9 2 Physics of Magnetism 349 921 Bar Magnets and Atomic Magnets 349 922 Magnetic Intensity, Induction, Energy, Susceptibility, and Permeability 352 923 Unit Systems in Magnetism 355 9 3 Types of Magnetic Materials 356 9 4 Atomic Origins of Magnetism 357 941 Electron Movements Contributing to Magnetism and Their Quantization 357 942 Atomic Magnetic Moments 359 943 Magnetic Moments for 3d Ions in Compounds 363 944 Magnetic Moments for 4fTons in Compounds 366 945 Note on Magnetic Moments of 4d and 5d Metals in Compounds 366 Contents xi 9 5 Diamagnetism 367 9 6 Paramagnetism 367 961 Curie and Curie-Weiss Paramagnetism 368 962 Pauli Paramagnetism 371 9 7 Antiferromagnetism 372 9 8 Superexchange Interactions 374 9 9 Ferromagnetism 377 991 Ferromagnetic Insulators and Half-Metals 381 992 Ferromagnetic Metals 382 993 Superferromagnets 384 9 10 Ferrimagnetism 385 9 11 Frustrated Systems and Spin Glasses 387 9 12 Magnetoelectric Multiferroics 388 9 13 Molecular and Organic Magnets 389 9 14 Problems 391 9 15 Further Reading 394 9 16 References 394 10 Conducting Materials 396 10 1 Conducting Materials 396 10 2 Metals 398 10 2 1 Drude Model 398 10 2 2 Free-Electron Model 402 10 2 3 Fermi-Dirac Distribution 403 10 2 4 Carrier Concentration 405 10 2 5 Carrier Mobility and Effective Mass 406 10 2 6 Fermi Velocity 407 10 2 7 Scattering Mechanisms 409 10 2 3 Band Structure and Conductivity of Aluminum 411 10 2 9 Band Structures and Conductivity of Transition Metals 412 10 3 Semiconductors 414 10 3 1 Carrier Concentrations in Intrinsic Semiconductors 414 10 3 2 Doping 416 10 3 3 Carrier Concentrations and Fermi Energies in Doped Semiconductors 419 10 3 4 Conductivity 421 10 3 5 p-n Junctions 422 10 3 6 Light-Emitting Diodes and Photovoltaic Cells 425 10 3 7 Transistors 426 xii Contents Transition-Metal Compounds 10 4 1 Electron Repulsion: The Hubbard Model 10 4 2 Transition-Metal Compounds with the NaCl-Type Structure 10 4 3 Transition-Metal Compounds with the Perovskite Structure Organic Conductors 10 5 1 Conducting Polymers 10 5 2 Polycyclic Aromatic Hydrocarbons 10 5 3 Charge-Transfer Salts Carbon 10 6 1 Graphene 10 6 2 Carbon Nanotubes Problems Further Reading References 11 Magnetotransport Materials Magnetotransport and Its Applications Charge, Orbital, and Spin Ordering in Iron Oxides 11 2 1 The Verwey Transition in Magnetite, Fe3O4 11 2 2 Double-Cell Perovskite, YBaFe;0; 11 2 3 CaFeO; and SrFeO; Charge and Orbital Ordering in Perovskite-Type Manganites 11 3 1 Spin and Orbital Ordering in CaMnO; and LaMnO; 11 3 2 The La,;_,Ca,MnO; Phase Diagram 11 3 3 Tuning the Colossal Magnetoresistance Half-Metals and Spin-Polarized Transport 11 4 1 Magnetoresistant Properties of Half-Metals 11 4 2 CrO, 11 4 3 Heusler Alloys 11 4 4 Half-Metals with Valence-Mixing Itinerant Electrons Problems Further Reading References 12 Superconductivity 12 1 Overview of Superconductivity 12 2 Properties of Superconductors 12 3 Origins of Superconductivity and BCS Theory 12 4 C¢o-Derived Superconductors 12 5 Molecular Superconductors 12 6 Contents BaBiO; Perovskite Superconductors Cuprate Superconductors 12 7 1 LazCuO, “214” Materials 12 7 2 YBazCu307-5 “YBCO” or “123” Materials 12 7 3 Other Cuprates 12 7 4 Electronic Properties of Cuprates Iron Pnictides and Related Superconductors Problems Further Reading References 13 Energy Materials: lonic Conductors, Mixed Conductors, and Intercalation Chemistry Electrochemical Cells and Batteries Fuel Cells Conductivity in lonic Compounds Superionic Conductors 13 4 1 Agl: A Cation Superionic Conductor 13 4 2 PbF2: An Anionic Superionic Conductor Cation Conductors 13 5 1 Sodium B-alumina 13 5 2 Other Ceramic Cation Conductors 13 5 3 Polymeric Cation Conductors Proton Conductors 13 6 1 Water-Containing Proton Conductors 13 6 2 Acid Salts 13 6 3 Perovskite Proton Conductors Oxide-Ion Conductors 13 7 1 Fluorite-Type Oxide-Ion Conductors 13 7 2 Perovskite, Aurivillius, Brownmillerite, and Other Oxide Conductors 13 7 3 SOFC Electrode Materials and Mixed Conductors Intercalation Chemistry and Its Applications 13 8 1 Graphite Intercalation Chemistry 13 8 2 Lithium Intercalation Chemistry and Battery Electrodes 13 8 3 Lithium-Ion Batteries with Oxide Cathodes 13 8 4 Electrochemical Characteristics of Lithium Batteries 13 8 5 Other Lithium Battery Electrode Materials Problems Further Reading References xiii xiv Contents 14 Zeolites and Other Porous Materials Zeolites 14 1 1 Representative Structures of Zeolites 14 1 2 Roles of Template Molecules in Zeolite Synthesis 14 1 3 Zeolites in Catalysis 14 1 4 Ion-Exchange Properties 14 1 5 Drying Agents, Molecular Sieving, and Sorption 14 1 6 AIPOs and Related Materials Mesoporous Aluminosilicates Other Porous Oxide Materials Metal-Organic Frameworks (MOFs) 14 4 1 MOF Structures 14 4 2 Some Applications of MOFs Problems Further Reading References 15 Amorphous and Disordered Materials The Atomic Structure of Glasses Topology and the Structure of Glasses Oxide Glasses Optical Properties and Refractive Index Optical Fibers Nucleation and Growth The Glass Transition Strong and Fragile Behavior of Liquids and Melts Low-Temperature Dynamics of Amorphous Materials Electronic Properties: Anderson Localization Metallic Glasses Problems Further Reading References Appendix A: Crystallographic Point Groups in Schénflies Symbolism Appendix B: International Tables for Crystallography Appendix C: Nomenclature of Silicates Appendix D: Bond-Valence Parameters in Solids Appendix E: The Effect of a Magnetic Field on a Moving Charge Appendix F: Coupling j/ Appendix G: Appendix H: Appendix I: Appendix J: The Langevin Function The Brillouin Function Measuring and Analyzing Magnetic Properties Fundamental Constants of Exact Value References for Appendices Index Contents XV
adam_txt	Contents Preface Acknowledgments 1 Structures of Crystalline Materials Ll Symmetry 111 Translational Symmetry 112 Rotational Symmetry 113 Crystallographic Point Groups and Crystal Systems 114 Bravais Lattices 115 Introduction to Space Groups 116 Symmetry Elements That Combine Rotation and Translation 117 Space-Group Symbols 118 Description of a Crystal Structure Databases Composition 131 Coordination, Stoichiometry, and Connectivity 132 The Generalized 8—N Rule Structural Principles 141 Packing of Spheres 142 Filling Holes 143 Network Structures 144 Polyhedral Structures Structures of Selected Materials 151 The Spinel Structure 152 The Garnet Structure 153 Perovskite Structures 154 Silicates 155 Zeolites 156 Zintl Phases Problems Further Reading References page xvii xix vi Contents 2 Defects and More Complex Structures Point Defects in Crystalline Elemental Solids Intrinsic Point Defects in Compounds Thermodynamics of Vacancy Formation Extrinsic Defects Solid Solutions and Vegard’s Law Kröger-Vink Notation Line Defects in Metals 271 Edge Dislocations 272 Screw Dislocations Planar Defects in Materials 281 Stacking Faults 282 Twinning 283 Antiphase Boundaries 284 Crystallographic Shear Structures Gross Nonstoichiometry and Defect Ordering Incommensurate Structures Infinitely Adaptive Structures Problems Further Reading References 3 Defect Chemistry and Nonstoichiometry 3 1 Narrow Nonstoichiometry in Oxides 311 Point Defects in a Pure Stoichiometric Oxide 312 Point Defects upon Oxidation/Reduction of the Stoichiometric Oxide 313 Equilibrium Equations for Oxidative and Reductive Nonstoichiometry 314 Defect Equilibria for Schottky-Type Redox Compensation 315 Acceptor-Doped Oxides 316 Donor-Doped Oxides 317 Solid Solubility of Dopants 318 Cautionary Note on Defect Models in Pure Oxides 3 2 Wide Nonstoichiometry in Oxides 3 3 Point Defects and Diffusion 331 Point-Defect Movements 332 Random Hopping 333 Hopping Under a Driving Force Contents 334 Hopping Under a Concentration Gradient 335 Hopping Under an Electric Field 336 Relationship between Conductivity and Diffusivity 337 Ambipolar Diffusion 338 Temperature Dependence of Diffusivity 339 Diffusivity and Redox Defect Equilibria 3 3 10 Outline of Non-Steady-State Diffusion 3 3 11 Cautionary Note on Diffusion in Real Materials 3 4 Problems 3 5 Further Reading 3 6 References Phase Diagrams and Phase Transitions 4 1 Phase Diagrams 4 2 Two-Component Phase Diagrams 421 Without Compound Formation 422 With Compound Formation 423 Solid-Solution Formation 4 3 Three-Component Phase Diagrams 4 4 Structural Phase Transitions 441 Classification of Phase Transitions 442 Symmetry and Order Parameters 443 Introduction to Landau Theory 444 Second-Order Transitions 445 First-Order and Tricritical Transitions 446 Phonons, Soft Modes, and Displacive Transitions 4 5 Problems 4 6 Further Reading 4 7 References Chemical Bonding 5 1 Ionic Bonding 511 Coulombic Potential Energy 512 Lattice Energy and the Born-Mayer Equation 513 Experimental versus Calculated Lattice-Formation Energies 5 2 Atomic Orbitals 521 Energies of Atomic Orbitals 522 Sizes of Atomic Orbitals 5 3 Molecular-Orbital Theory 531 Homonuclear Diatomics: H,* and H, 532 The Heteronuclear Diatomic Case: HHe vü viii Contents 533 Orbital Overlap and Symmetry 534 Combination of o and w Bonding: O, 535 Symmetry-Adapted Linear Combinations (SALCs) 536 Simple Polyatomic Molecules: BeH, and CH, 537 Conjugated 7 Bonding: CgH, 538 Transition-Metal Complexes: [CrCl ] ~ and [CoCl,]?- 539 High- and Low-Spin Configurations 5 3 10 Jahn-Teller Distortions Bond Valences Problems Further Reading References 6 Electronic Band Structure The Band Structure of a Hydrogen-Atom Chain 611 The Electronic Structures of Cyclic Hy Molecules 612 Translational Symmetry and the Bloch Function 613 The Quantum Number k 614 Visualizing Crystal Orbitals 615 Band-Structure Diagrams 616 Density-of-States (DOS) Plots The Band Structure of a Chain of Hz Molecules Electrical and Optical Properties 631 Metals, Semiconductors, and Insulators 632 Direct- versus Indirect-Gap Semiconductors Representing Band Structures in Higher Dimensions 641 Crystal Orbitals in Two Dimensions 642 Crystal Orbitals in Three Dimensions Band Structures of Two-Dimensional Materials 651 Graphene 652 CuO,?” Square Lattice Band Structures of Three-Dimensional Materials 661 a-Polonium 662 Diamond 663 Elemental Semiconductors 664 Rhenium Trioxide 665 Perovskites Problems Further Reading References Contents ix 7 Optical Materials 243 7 1 Light, Color, and Electronic Excitations 243 7 2 Pigments, Dyes, and Gemstones 245 7 3 Transitions between d Orbitals (d-to-d Excitations) 246 731 Ligand- and Crystal-Field Theory 246 732 Absorption Spectra and Spectroscopic Terms 248 7 3 3, Correlation Diagrams 252 734 Selection Rules and Absorption Intensity 255 7 4 Charge-Transfer Excitations 258 741 Ligand-to-Metal Charge Transfer 259 742 Metal-to-Metal Charge Transfer 260 7 5 Compound Semiconductors 261 751 Optical Absorbance, Band Gap, and Color 262 752 Electronegativity, Orbital Overlap, and Band Gap 263 7 6 Conjugated Organic Molecules 265 7 7 Luminescence 267 7 3 Photoluminescence 268 781 Components ofa Phosphor 268 782 Radiative Return to the Ground State 270 733 Thermal Quenching 272 784 Lanthanoid Activators 274 785 Non-Lanthanoid Activators 279 786 Energy Transfer 281 737 Sensitizers 283 788 Concentration Quenching and Cross Relaxation 284 789 Up-Conversion Photoluminescence 285 7 9 Electroluminescence 287 791 Inorganic Light-Emitting Diodes (LEDs) 287 792 Organic Light-Emitting Diodes (OLEDs) 289 7 10 Materials for Lighting 291 7 10 1 Fluorescent Lamp Phosphors 292 7 10 2 Phosphor-Converted LEDs for White Light 293 7 11 Problems 294 7 12 Further Reading 298 7 13 References 299 8 Dielectrics and Nonlinear Optical Materials 301 8 1 Dielectric Properties 301 811 Dielectric Permittivity and Susceptibility 302 Contents 812 Polarization and the Clausius-Mossotti Equation 303 813 Microscopic Mechanisms of Polarizability 305 814 Frequency Dependence of the Dielectric Response 306 815 Dielectric Loss 308 8 2 Dielectric Polarizabilities and the Additivity Rule 309 8 3 Crystallographic Symmetry and Dielectric Properties 313 8 4 Pyroelectricity and Ferroelectricity 314 841 Ferroelectricity in BaTiO; 314 842 Antiferroelectricity 319 8 5 Piezoelectricity 321 8 6 Local Bonding Considerations in Non-Centrosymmetric Materials 324 861 Second-Order Jahn-Teller Distortions with d° Cations 325 862 Second-Order Jahn-Teller Distortions with s”p° Cations 327 8 7 Nonlinear Optical Materials 330 8 8 Nonlinear Susceptibility and Phase Matching 331 8 9 Important SHG Materials 334 891 KH PO, 336 892 KTiOPO, 336 893 Niobates and Tantalates 338 894 Organic and Polymer NLO Materials 339 895 Borates 340 8 10 Problems 343 8 11 Further Reading 346 8 12 References 346 9 Magnetic Materials 349 9 1 Magnetic Materials and Their Applications 349 9 2 Physics of Magnetism 349 921 Bar Magnets and Atomic Magnets 349 922 Magnetic Intensity, Induction, Energy, Susceptibility, and Permeability 352 923 Unit Systems in Magnetism 355 9 3 Types of Magnetic Materials 356 9 4 Atomic Origins of Magnetism 357 941 Electron Movements Contributing to Magnetism and Their Quantization 357 942 Atomic Magnetic Moments 359 943 Magnetic Moments for 3d Ions in Compounds 363 944 Magnetic Moments for 4fTons in Compounds 366 945 Note on Magnetic Moments of 4d and 5d Metals in Compounds 366 Contents xi 9 5 Diamagnetism 367 9 6 Paramagnetism 367 961 Curie and Curie-Weiss Paramagnetism 368 962 Pauli Paramagnetism 371 9 7 Antiferromagnetism 372 9 8 Superexchange Interactions 374 9 9 Ferromagnetism 377 991 Ferromagnetic Insulators and Half-Metals 381 992 Ferromagnetic Metals 382 993 Superferromagnets 384 9 10 Ferrimagnetism 385 9 11 Frustrated Systems and Spin Glasses 387 9 12 Magnetoelectric Multiferroics 388 9 13 Molecular and Organic Magnets 389 9 14 Problems 391 9 15 Further Reading 394 9 16 References 394 10 Conducting Materials 396 10 1 Conducting Materials 396 10 2 Metals 398 10 2 1 Drude Model 398 10 2 2 Free-Electron Model 402 10 2 3 Fermi-Dirac Distribution 403 10 2 4 Carrier Concentration 405 10 2 5 Carrier Mobility and Effective Mass 406 10 2 6 Fermi Velocity 407 10 2 7 Scattering Mechanisms 409 10 2 3 Band Structure and Conductivity of Aluminum 411 10 2 9 Band Structures and Conductivity of Transition Metals 412 10 3 Semiconductors 414 10 3 1 Carrier Concentrations in Intrinsic Semiconductors 414 10 3 2 Doping 416 10 3 3 Carrier Concentrations and Fermi Energies in Doped Semiconductors 419 10 3 4 Conductivity 421 10 3 5 p-n Junctions 422 10 3 6 Light-Emitting Diodes and Photovoltaic Cells 425 10 3 7 Transistors 426 xii Contents Transition-Metal Compounds 10 4 1 Electron Repulsion: The Hubbard Model 10 4 2 Transition-Metal Compounds with the NaCl-Type Structure 10 4 3 Transition-Metal Compounds with the Perovskite Structure Organic Conductors 10 5 1 Conducting Polymers 10 5 2 Polycyclic Aromatic Hydrocarbons 10 5 3 Charge-Transfer Salts Carbon 10 6 1 Graphene 10 6 2 Carbon Nanotubes Problems Further Reading References 11 Magnetotransport Materials Magnetotransport and Its Applications Charge, Orbital, and Spin Ordering in Iron Oxides 11 2 1 The Verwey Transition in Magnetite, Fe3O4 11 2 2 Double-Cell Perovskite, YBaFe;0; 11 2 3 CaFeO; and SrFeO; Charge and Orbital Ordering in Perovskite-Type Manganites 11 3 1 Spin and Orbital Ordering in CaMnO; and LaMnO; 11 3 2 The La,;_,Ca,MnO; Phase Diagram 11 3 3 Tuning the Colossal Magnetoresistance Half-Metals and Spin-Polarized Transport 11 4 1 Magnetoresistant Properties of Half-Metals 11 4 2 CrO, 11 4 3 Heusler Alloys 11 4 4 Half-Metals with Valence-Mixing Itinerant Electrons Problems Further Reading References 12 Superconductivity 12 1 Overview of Superconductivity 12 2 Properties of Superconductors 12 3 Origins of Superconductivity and BCS Theory 12 4 C¢o-Derived Superconductors 12 5 Molecular Superconductors 12 6 Contents BaBiO; Perovskite Superconductors Cuprate Superconductors 12 7 1 LazCuO, “214” Materials 12 7 2 YBazCu307-5 “YBCO” or “123” Materials 12 7 3 Other Cuprates 12 7 4 Electronic Properties of Cuprates Iron Pnictides and Related Superconductors Problems Further Reading References 13 Energy Materials: lonic Conductors, Mixed Conductors, and Intercalation Chemistry Electrochemical Cells and Batteries Fuel Cells Conductivity in lonic Compounds Superionic Conductors 13 4 1 Agl: A Cation Superionic Conductor 13 4 2 PbF2: An Anionic Superionic Conductor Cation Conductors 13 5 1 Sodium B-alumina 13 5 2 Other Ceramic Cation Conductors 13 5 3 Polymeric Cation Conductors Proton Conductors 13 6 1 Water-Containing Proton Conductors 13 6 2 Acid Salts 13 6 3 Perovskite Proton Conductors Oxide-Ion Conductors 13 7 1 Fluorite-Type Oxide-Ion Conductors 13 7 2 Perovskite, Aurivillius, Brownmillerite, and Other Oxide Conductors 13 7 3 SOFC Electrode Materials and Mixed Conductors Intercalation Chemistry and Its Applications 13 8 1 Graphite Intercalation Chemistry 13 8 2 Lithium Intercalation Chemistry and Battery Electrodes 13 8 3 Lithium-Ion Batteries with Oxide Cathodes 13 8 4 Electrochemical Characteristics of Lithium Batteries 13 8 5 Other Lithium Battery Electrode Materials Problems Further Reading References xiii xiv Contents 14 Zeolites and Other Porous Materials Zeolites 14 1 1 Representative Structures of Zeolites 14 1 2 Roles of Template Molecules in Zeolite Synthesis 14 1 3 Zeolites in Catalysis 14 1 4 Ion-Exchange Properties 14 1 5 Drying Agents, Molecular Sieving, and Sorption 14 1 6 AIPOs and Related Materials Mesoporous Aluminosilicates Other Porous Oxide Materials Metal-Organic Frameworks (MOFs) 14 4 1 MOF Structures 14 4 2 Some Applications of MOFs Problems Further Reading References 15 Amorphous and Disordered Materials The Atomic Structure of Glasses Topology and the Structure of Glasses Oxide Glasses Optical Properties and Refractive Index Optical Fibers Nucleation and Growth The Glass Transition Strong and Fragile Behavior of Liquids and Melts Low-Temperature Dynamics of Amorphous Materials Electronic Properties: Anderson Localization Metallic Glasses Problems Further Reading References Appendix A: Crystallographic Point Groups in Schénflies Symbolism Appendix B: International Tables for Crystallography Appendix C: Nomenclature of Silicates Appendix D: Bond-Valence Parameters in Solids Appendix E: The Effect of a Magnetic Field on a Moving Charge Appendix F: Coupling j/ Appendix G: Appendix H: Appendix I: Appendix J: The Langevin Function The Brillouin Function Measuring and Analyzing Magnetic Properties Fundamental Constants of Exact Value References for Appendices Index Contents XV
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id	DE-604.BV047137814
illustrated	Illustrated
index_date	2024-07-03T16:34:39Z
indexdate	2024-07-10T09:03:41Z
institution	BVB
isbn	9780521873253
language	English
oai_aleph_id	oai:aleph.bib-bvb.de:BVB01-032543793
oclc_num	1247378167
open_access_boolean
owner	DE-11 DE-703 DE-29T DE-83 DE-91G DE-BY-TUM
owner_facet	DE-11 DE-703 DE-29T DE-83 DE-91G DE-BY-TUM
physical	xix, 687 Seiten Illustrationen, Diagramme
publishDate	2021
publishDateSearch	2021
publishDateSort	2021
publisher	Cambridge University Press
record_format	marc
spelling	Woodward, Patrick M. Verfasser (DE-588)107792058X aut Solid state materials chemistry Patrick M. Woodward (Ohio State University), Pavel Karen (Universitetet i Oslo), John S. O. Evans (Durham University), Thomas Vogt (University of South Carolina) Cambridge Cambridge University Press 2021 xix, 687 Seiten Illustrationen, Diagramme txt rdacontent n rdamedia nc rdacarrier Literaturangaben Festkörperphysik (DE-588)4016921-2 gnd rswk-swf Festkörperchemie (DE-588)4129288-1 gnd rswk-swf Solid state chemistry Materials science Festkörperphysik (DE-588)4016921-2 s DE-604 Festkörperchemie (DE-588)4129288-1 s Karen, Pavel 1951- Verfasser (DE-588)1249281997 aut Evans, John S. O. Verfasser (DE-588)1175529109 aut Vogt, Thomas Verfasser (DE-588)1209704064 aut HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=032543793&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis
spellingShingle	Woodward, Patrick M. Karen, Pavel 1951- Evans, John S. O. Vogt, Thomas Solid state materials chemistry Festkörperphysik (DE-588)4016921-2 gnd Festkörperchemie (DE-588)4129288-1 gnd
subject_GND	(DE-588)4016921-2 (DE-588)4129288-1
title	Solid state materials chemistry
title_auth	Solid state materials chemistry
title_exact_search	Solid state materials chemistry
title_exact_search_txtP	Solid state materials chemistry
title_full	Solid state materials chemistry Patrick M. Woodward (Ohio State University), Pavel Karen (Universitetet i Oslo), John S. O. Evans (Durham University), Thomas Vogt (University of South Carolina)
title_fullStr	Solid state materials chemistry Patrick M. Woodward (Ohio State University), Pavel Karen (Universitetet i Oslo), John S. O. Evans (Durham University), Thomas Vogt (University of South Carolina)
title_full_unstemmed	Solid state materials chemistry Patrick M. Woodward (Ohio State University), Pavel Karen (Universitetet i Oslo), John S. O. Evans (Durham University), Thomas Vogt (University of South Carolina)
title_short	Solid state materials chemistry
title_sort	solid state materials chemistry
topic	Festkörperphysik (DE-588)4016921-2 gnd Festkörperchemie (DE-588)4129288-1 gnd
topic_facet	Festkörperphysik Festkörperchemie
url	http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=032543793&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
work_keys_str_mv	AT woodwardpatrickm solidstatematerialschemistry AT karenpavel solidstatematerialschemistry AT evansjohnso solidstatematerialschemistry AT vogtthomas solidstatematerialschemistry

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