Survival guide to general chemistry:
Gespeichert in:
Hauptverfasser: | , , |
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Format: | Buch |
Sprache: | English |
Veröffentlicht: |
Boca Raton ; London ; New York
CRC Press
[2019]
|
Schlagworte: | |
Online-Zugang: | Inhaltsverzeichnis |
Beschreibung: | xix, 512 Seiten |
ISBN: | 9781138333727 |
Internformat
MARC
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100 | 1 | |a McMahon, Patrick E. |e Verfasser |4 aut | |
245 | 1 | 0 | |a Survival guide to general chemistry |c Patrick E. McMahon, Rosemary F. McMahon, Bohdan Khomtchouk |
246 | 1 | 3 | |a General chemistry |
264 | 1 | |a Boca Raton ; London ; New York |b CRC Press |c [2019] | |
264 | 4 | |c © 2019 | |
300 | |a xix, 512 Seiten | ||
336 | |b txt |2 rdacontent | ||
337 | |b n |2 rdamedia | ||
338 | |b nc |2 rdacarrier | ||
650 | 4 | |a Chemistry |v Textbooks | |
700 | 1 | |a McMahon, Rosemary Fischer |e Verfasser |4 aut | |
700 | 1 | |a Khomtchouk, Bohdan B. |e Verfasser |4 aut | |
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999 | |a oai:aleph.bib-bvb.de:BVB01-031565136 |
Datensatz im Suchindex
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adam_text | Contents
Preface xvii
Authors xix
Chapter 1 Unit Conversion and Density: An Introduction to Problem-Solving Methods 1
I General Techniques for Performing Unit Conversions 1
II General Procedures for Solving Density Problems 3
Process for Density Problems 3
III General Examples for Density with Unit Conversions 3
IV Practice Problems 6
V Answers to Practice Problems 7
Chapter 2 Atomic Particles, Isotopes, and Ions: An Initial Look at Atomic Structure 11
I General Concepts 11
II Atomic Symbols and Isotopes 13
Isotopes: Atoms with the Same Value of Z But with a Different Value for A 14
III Atomic Symbols and Ion Symbols 15
Additional Practice Examples 16
IV Practice Problems 17
V Answers to Practice Problems 17
Chapter 3 Working with Atomic Mass and Nuclear Mass 19
I General Concepts 19
II Potential Energy, Kinetic Energy, and Forces 19
III Energy, Mass Loss, and the Strong Nuclear Force 20
IV Calculating Mass Using the Atomic Mass Unit 22
V Calculating the Approximate Mass of an Atom in amu, kg, or g 23
Process for Calculating Atomic Masses 23
VI Average Atomic Mass for an Element 25
VII Practice Problems 26
VUI Answers to Practice Problems 27
Chapter 4 Procedures for Writing Formulas and Naming Compounds 31
I General Concepts 31
II Elemental Ions for Ionic Compounds 32
IB Writing Formulas for Binary Ionic Compounds 33
IV Naming Binary Ionic Compounds 36
Procedure for Naming a Binary Ionic Compound 36
Additional Concepts 37
Additional Practice Examples 38
V Writing Formulas for Ionic Compounds with Polyatomic Ions 39
Procedure for Writing Formulas for Ionic Compounds with
Polyatomic Ions 39
vii
Contents
VIII
VI
vn
vrn
ix
x
Naming Ionic Compounds with Polyatomic Ions
Procedure for Naming Ionic Compounds Containing Polyatomic Ions
Naming Binary Covalent Compounds
Covalent System for Naming Binary Covalent Compoun s
Additional Combination Practice Examples
Practice Problems
Answers to Practice Problems
40
41
41
42
43
46
46
Chapter 5 An Introduction to Moles and Molar Mass 49
I General Concepts 49
Counting Numbers 49
II Mass/Mole/Atom Conversions for Elements 51
Procedure for Solving Mole Problems (Elements) 51
III Mass/Mole/Molecule Conversions for Compounds 53
Procedure for Solving Mole Problems (Compounds) 54
IV Concepts for Using Ratios in Formulas 55
V Mass Percent of an Element in a Compound 58
VI Practice Problems 60
Vn Answers to Practice Problems 61
Chapter 6 Procedures for Calculating Empirical and Molecular Formulas 69
I General Concept 69
Concepts of Empirical or Molecular Formulas 69
II Procedure for Calculation of Simplest (Empirical) Formula of
Any Compound 69
HI Determination of the Simplest Formula from Element Mass Percent 71
IV Determination of the True Molecular Formula for Molecules 72
Determining and Using the Multiple 72
Procedure for Finding the Simplest Formula and True Molecular Formula 73
V Experimental Determination of Compound Formulas 73
VI Practice Problems 76
VII Answers to Practice Problems 77
Chapter 7
Writing Chemical Equations
I General Concepts
Conservation Laws
II Writing Balanced Equations
Process for Writing Balanced Equations from Descriptions
IH Practice Problems
IV Answers to Practice Problems
83
83
83
83
84
86
86
Chapter 8
Techniques for Performing Stoichiometric Calculations
I General Concepts
n General Process for Stoichiometric Calculations Based on Balanced
Equations
Diagram Form
Viewing Each Step
89
- 89
- 90
- 91
-92
Contents ix
HI Percent Yield 93
IV Limiting Reagent 94
V Calculation of All Products and Reactants in a Limiting Reagent Problem 96
VI Practice Problems 100
VII Answers to Practice Problems 102
Chapter 9 Precipitation and Acid/Base Aqueous Reactions: Concepts and Methods to
Design Complete Balanced Equations 109
I General Concepts 109
II Solubility Equations and Aqueous Solution Formats 109
Solution Formation Equations 110
Formula Format 110
Ionic Format 111
Equation Formats for Complete Aqueous Solution Reactions 111
Formula Format Equation 111
Total Ionic Format Equation Ill
Net Ionic Equation 112
III Precipitation Reactions 113
Determining Ionic Compound Solubility 113
General Solubility Guideline Rules 114
Examples from the Previous Reactions 114
Predicting Products for Precipitation Reactions and Writing Equations 114
Process for Completing and Writing Precipitation Reaction Equations 114
IV Acid/Base Reactions: General Concepts 118
Properties of Acids 119
Properties of Bases 120
V Aqueous Acid/Base Reactions 121
Acid Ionization Reaction and Acid Strength 121
Aqueous Base Reactions 122
Completing Acid/Base Reactions and Equations 122
Examination of Reaction Requirements 123
A Specific Process for Completing and Writing Acid/Base
Reaction Equations 124
VI Practice Problems 127
VII Answers to Practice Problems 128
Chapter 10 Oxidation Numbers: A First Look at Redox Reactions 131
I General Concepts 131
II Oxidation Numbers 133
General Rules for Oxidation Numbers 133
III Process for the Analysis of Redox Reactions Using Oxidation Numbers 135
IV Practice Problems 138
V Answers to Practice Problems 138
Chapter 11 Solution Concentration, Molarity, and Solution Stoichiometry 141
I General Concepts 141
II Concentration Calculations Based on Molarity 142
General Procedure for Solving Molarity Problems 142
X
Contents
HI Solution Stoichiometry
Process for Solution Stoichiometry
IV Practice Problems
V Answers to Practice Problems
145
145
148
149
Chapter 12 Light, Matter, and Spectroscopy
I General Properties of Light
Wave Properties
The Wave Nature of Light
n Energy and the Quantum Theory of Light
Energy and Light Calculations
PH Electrons and Atoms —
IV Energy States, Light Interaction, and Electron Transitions
V Spectroscopy Calculations
VI Spectra Calculations Using [E (Final Level) - E (Initial Level)]
VH Practice Problems
Vni Answers to Practice Problems
153
153
153
153
154
155
156
157
157
159
161
162
Chapter 13
Atomic Orbitals and the Electronic Structure of the Atom
I Quantum Theory and Electron Orbitals
Orbital Architecture and Electron Spin
II Determining Electron Configurations of Elements
Rules for Ground State Electron Configurations
Closed Shells and the Noble Gas Electron Configuration
in Electron Configurations and Organization of the Periodic Table
Process to Read the Electron Configuration Directly from the
Periodic Table
Valence Shell Electrons
IV Ionization Energy and Electron Configuration Relationship
V Determination of Electron Configuration for Ions
Electron Configuration for Negative Ions
Electron Configuration for Most Fixed-Charge Positive Ions
Ion Formation for Metals in Groups 4A and 5A
Ion Formation for Transition Metals (B Groups)
VI Practice Problems
VII Answers to Practice Problems
167
167
169
170
171
173
175
176
177
178
180
180
181
182
182
183
183
Chapter 14 Alternate Methods for Visualizing and Constructing: Lewis Structures of
Covalent Molecules
I Introduction to Interpretation of Lewis Structures
II Common Bonding Behavior for Non-Metals in Covalent Molecules
General Concept of Normal Bonding in Covalent Molecules
Normal Neutral Bonding Rules
Summary of Normal Neutral Bond Numbers for H, Be, B, C, N, O, F
Summary of Normal Neutral Bond Numbers for Elements in Rows 3-5
185
185
- 186
- 186
187
188
- 190
Contents
XI
HI Constructing Lewis Structures for Covalent Molecules from H and the
Row-2 Elements: Bonding That Follows Normal Neutral Bonding Rules 190
Lewis Structure Concepts 190
Process for Molecules Containing H, Be, B, C, N, O, F 191
IV Constructing Lewis Structures for Covalent Molecules Using Elements
from Rows 3-5: Bonding Patterns That Follow Normal Neutral
Bonding Rules 195
V Constructing Molecules That Require Exceptions to Normal Neutral
Bonding Rules 198
Bonding Patterns through Exception Rules 199
Exception Rule #1 200
Exception Rule #2 200
Exception Rule #3 200
Working with Exception Rule #1 200
Lewis Structures for Polyatomic Ions 201
Using Exception Rule #3 203
Other Uses for Exception Rules 204
Resonance Structures 204
VI Practice Problems 205
VII Answers to Practice Problems 206
Chapter 15 Additional Techniques for Designing and Representing Structures of
Large Molecules 209
I Techniques for Understanding and Designing Isomers of
Large Molecules 209
General Rule #1 for the Number of Multiple Bonds (or Rings) 209
II Using Condensed Structural Formulas 213
Guidelines for Converting a Full Structure to a Condensed
Structural Formula 213
Guidelines for Expanding Condensed Formulas: Reconstructing the
Complete Molecule 216
III Concept of Ring Structures and Line Drawings 217
Structural Notation: Guidelines for Producing Line Drawings 218
Converting Line Drawings to Structural Formulas 219
IV Practice Problems 219
V Answers to Practice Problems 220
Chapter 16 Determining and Drawing Molecular Geometry and Polarity 223
I Concepts of Molecular Geometry 223
Types of Geometry Analysis for Central Atoms 223
Counting Electron Regions 223
Summary of E R Count 224
H Process for Complete Determination of Molecular Geometry and Polarity 224
Descriptions of Geometric Figures for 2 to 4 Electron Regions 225
Descriptions of Geometric Figures for 5 and 6 Electron Regions 225
Contents
XII
_ m„,rv Determination from Electron Region Geometry 228
m SSI“— D—•- a
Tri80°
and Octahedral
IV Molecular Polarity ’
V Practice Problems
VI Answers to Practice Problems 48
Chapter 17 Summary Analysis of Central Atom Bonding, Hybridization, and Geometry 243
I Concept of Sigma Bonds and Pi Bonds 243
II Concept of Hybridization 244
Electron Configuration and Hybridization of Carbon in CH4 245
III Summary Tables 248
IV Practice Problems 2-^
V Answers to Practice Problems 251
Chapter 18 Concepts of Potential Energy, Enthalpy, and Bond Energy Calculations 253
I Concept of Energy 253
II Chemical Bond Energetics 254
Bond Strengths and Bond Dissociation Energy (BDE) 255
HI Energy and Chemical Reactions 256
Potential Energy Changes and Enthalpy 256
IV Potential Energy Diagrams 257
Activation Energy 258
V Calculating Reaction Enthalpy Values 260
Process for Calculation of AH (Reaction) for a Balanced Equation 260
VI Reading an Energy Diagram 264
VII Practice Problems 265
VIH Answers to Practice Problems 266
Chapter 19 Thermochemistry Calculations: Heat Capacity and Enthalpy 269
I General Concepts of Thermodynamics 269
The First Law of Thermodynamics 270
II Heat Capacity and Heat Transfer between Substances 271
Simple Heat Transfer for One Substance 273
Simple Heat Transfer between Two Substances 274
III Energy and Enthalpy in Chemical Reactions 278
IV Calorimetry 279
Determining AH and AE from Calorimetry 280
General Procedures for Solving Calorimetry Problems 280
V Enthalpy and Hess’s Law 284
Process for Applying Hess’s Law Calculations 285
VI Calculation of AH (Reaction) from Enthalpies of Formation 287
VII Enthalpy and Stoichiometric Calculations 291
VIII Practice Problems 294
IX Answers to Practice Problems 297
Contents
xiii
Chapter 20 Working with Gas Laws 307
I Kinetic Theory of Gases 307
Kinetic Energy, Temperature, and Graham’s Law for Diffusion 307
II The Ideal Gas Law 310
Measurements of Gas Pressure 310
Solving Ideal Gas Law Problems 311
III Condition Changes for a Specific Gas Sample 313
IV Solving Additional Problems Using Gas Laws 315
Stoichiometric Calculations Using Gas Laws 316
V Gas Mixtures and Law of Partial Pressures 316
VI Practice Problems 319
VII Answers to Practice Problems 320
Chapter 21 Guideline for Analyzing Inlermolecular Forces and Calculating
Phase Change Enthalpies 325
I Overview of Inlerparticle and Inlermolecular Forces 325
Phase Changes and Temperature 325
Descriptions of Interparticle Forces 326
II A Guideline for Comparing Total Strength of Inlermolecular Forces
in Individual Compounds 328
Strengths of Interparticle Forces 328
Process for Comparing Total Inlermolecular Forces for Different
Compounds 328
III Enthalpy of Phase Changes 333
IV Interparticle and Inlermolecular Forces for Solutions 336
Solubility Requirements 336
Interparticle and Intermolecular Forces between Solutes and Solvents 337
Process for Comparing Total Intermolecular Forces for Solutions 337
V Enthalpies of Solutions 339
VI Practice Problems 340
VII Answers to Practice Problems 341
Chapter 22 Kinetics Part 1: Rate Laws, Rate Equations, and an Introduction to Reaction
Mechanisms 345
I General Concept of Kinetics 345
Additional Variables Affecting Reaction Rates 345
Information Relationships for Kinetics and Mechanisms 346
II Introduction to Reaction Mechanisms 346
III Description of Reactions by Mechanisms 347
Variability of Mechanisms 347
IV Experimental Kinetics: Determining Reactant Orders and Rate
Constants from Integrated Rate Equations 348
Zero-Order Reactants 349
First-Order Reactants 349
Second-Order Reactants 352
Experimental Determination of Reactant Orders in Multiple-
Concentration Rate Expressions 354
Contents
xiv
356
356
357
357
358
359
361
361
361
363
364
365
Chapter 23 General Techniques for Solving Equilibrium Problems 371
I Concentration Quotient and Equilibrium Expression 371
Equilibrium Types and Expressions 372
II Techniques for Performing Equilibrium Calculations: Calculating K 374
Process for Calculating the Numerical Value of the Equilibrium
Constant (K) from Concentrations 375
III Techniques for Performing Equilibrium Calculations 380
Process for Calculating Equilibrium Concentrations of All
Reactants and Products from the Numerical Value of the
Equilibrium Constant (K) 380
IV Techniques for Performing Equilibrium Calculations 384
Using the Quadratic Formula 384
V Techniques for Performing Equilibrium Calculations 388
Using the Simplification Technique 388
The Common Ion Effect 390
VI Shifts in Equilibrium 391
VII Practice Problems 393
VIII Answers to Practice Problems 395
Chapter 24 Kinetics Part 2: Application of Rate Laws and Rate Variables to Reaction
Mechanisms 407
I Predicting Rate Expressions from Mechanisms 407
II General Concepts for Rate Expression Comparison: Identification of
the Rate Determining Step 407
III Rules and Procedures for Predicting Rate Expressions 408
Rule 4 Procedure for Predicting Rate Expressions for Multi-Step
Reactions 409
IV Determining Rate Expressions from Mechanism Descriptions 409
Notation for Mechanisms Written in Equation Form 409
Comparison of Rate Expressions for Mechanisms #1, #2, #3 411
V General Construction of Potential Energy Diagrams ’ 414
VI Energy, Temperature, and Chemical Reactions 416
Bonding Changes and Activation Energy 416
Bonding Changes and Temperature 416
Relationship between Rate Constant, Temperature, and Ea 417
VI
VII
■ • pom Fxnressions from Initial Rate Data Calculations
------------
“7 b E,t*s“-
Reactant Order Determination by Simple Inspection
r,Orderby L08» h”*Ad»”
Determining ,1« Complete Rate Ertpms rons
Determining the Value for the Rate Constant
Determining the Value for Any Unknown Ram
Determining Reactant Orders from Limited Data Sets
Practice Problems
Answers to Practice Problems
Contents
xv
VII Reading Potential Energy Diagrams 418
VIII Rates and Catalysis 422
IX Practice Problems 423
X Answers to Practice Problems 426
Chapter 25 Thermodynamics: Entropy and Free Energy 433
I General Concepts of Entropy 433
Predicting Entropy Changes for a Chemical Process 433
II Entropy and the Second Law of Thermodynamics 436
III Calculation of Entropy and the Third Law of Thermodynamics 438
IV Enthalpy, Entropy, and Chemical Spontaneity 441
Enthalpy and Chemical Spontaneity 442
Entropy and Chemical Spontaneity 442
Combining Enthalpy and Entropy as Spontaneity Measures 442
Spontaneity and Temperature 443
V Reaction Spontaneity and Free Energy 445
Definition of Free Energy (AG) 445
Enthalpy, Entropy, and Temperature Contributions to Free Energy 446
Standard Free Energy (AG°) 447
Calculation of AG° at Variable Temperatures 450
VI Non-Standard Free Energy (AG) and Concentrations 454
Calculating Non-Standard Free Energy (AGX) 455
VII Non-Standard Free Energy (AG) and Equilibrium Constants 457
VIII Comprehensive Examples 460
IX Practice Problems 463
X Answers to Practice Problems 465
Chapter 26 Acid/Base Equilibrium, pH, and Buffers 473
I Acid and Base Dissociation Reactions: Acid and Base Strength 473
Autoionization of Water 476
II Relationship between Acid (pka) and Conjugate Base Strength 476
III Process for Determining the Equilibrium Position for Acid/Base
Reactions 478
IV pH Calculations in Aqueous Solutions: General Concept of pH 481
V pH Calculations in Aqueous Solutions: Reactions of One Acid or
Base with Water 482
VI pH Calculations in Aqueous Solutions: Solving General Acid/Base
Reactions 488
VII The Common Ion Effect and Acid/Base Buffers 494
VIII The Hendersen-Hasselbach Equation 496
IX Practice Problems 497
X Answers to Practice Problems 498
Index
|
any_adam_object | 1 |
author | McMahon, Patrick E. McMahon, Rosemary Fischer Khomtchouk, Bohdan B. |
author_facet | McMahon, Patrick E. McMahon, Rosemary Fischer Khomtchouk, Bohdan B. |
author_role | aut aut aut |
author_sort | McMahon, Patrick E. |
author_variant | p e m pe pem r f m rf rfm b b k bb bbk |
building | Verbundindex |
bvnumber | BV046185688 |
callnumber-first | Q - Science |
callnumber-label | QD33 |
callnumber-raw | QD33.2 |
callnumber-search | QD33.2 |
callnumber-sort | QD 233.2 |
callnumber-subject | QD - Chemistry |
classification_rvk | VC 5010 |
ctrlnum | (OCoLC)1099552944 (DE-599)BVBBV046185688 |
dewey-full | 540 |
dewey-hundreds | 500 - Natural sciences and mathematics |
dewey-ones | 540 - Chemistry and allied sciences |
dewey-raw | 540 |
dewey-search | 540 |
dewey-sort | 3540 |
dewey-tens | 540 - Chemistry and allied sciences |
discipline | Chemie / Pharmazie |
format | Book |
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language | English |
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spelling | McMahon, Patrick E. Verfasser aut Survival guide to general chemistry Patrick E. McMahon, Rosemary F. McMahon, Bohdan Khomtchouk General chemistry Boca Raton ; London ; New York CRC Press [2019] © 2019 xix, 512 Seiten txt rdacontent n rdamedia nc rdacarrier Chemistry Textbooks McMahon, Rosemary Fischer Verfasser aut Khomtchouk, Bohdan B. Verfasser aut Erscheint auch als Druck-Ausgabe, Paperback 978-1-138-33362-8 HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=031565136&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
spellingShingle | McMahon, Patrick E. McMahon, Rosemary Fischer Khomtchouk, Bohdan B. Survival guide to general chemistry Chemistry Textbooks |
title | Survival guide to general chemistry |
title_alt | General chemistry |
title_auth | Survival guide to general chemistry |
title_exact_search | Survival guide to general chemistry |
title_full | Survival guide to general chemistry Patrick E. McMahon, Rosemary F. McMahon, Bohdan Khomtchouk |
title_fullStr | Survival guide to general chemistry Patrick E. McMahon, Rosemary F. McMahon, Bohdan Khomtchouk |
title_full_unstemmed | Survival guide to general chemistry Patrick E. McMahon, Rosemary F. McMahon, Bohdan Khomtchouk |
title_short | Survival guide to general chemistry |
title_sort | survival guide to general chemistry |
topic | Chemistry Textbooks |
topic_facet | Chemistry Textbooks |
url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=031565136&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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