Diffusion and electrophoretic NMR:
Gespeichert in:
| 1. Verfasser: | |
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| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Berlin ; Boston
De Gruyter
[2019]
|
| Schriftenreihe: | De Gruyter STEM
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| Beschreibung: | XVII, 332 Seiten Illustrationen, Diagramme 24 cm, 600 g |
| ISBN: | 9783110551525 3110551527 |
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| 100 | 1 | |a Stilbs, Peter |e Verfasser |0 (DE-588)1193497353 |4 aut | |
| 245 | 1 | 0 | |a Diffusion and electrophoretic NMR |c Peter Stilbs |
| 264 | 1 | |a Berlin ; Boston |b De Gruyter |c [2019] | |
| 264 | 4 | |c © 2019 | |
| 300 | |a XVII, 332 Seiten |b Illustrationen, Diagramme |c 24 cm, 600 g | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
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| 653 | |a NMR-Spektroskopie | ||
| 653 | |a Analytische Chemie | ||
| 653 | |a Chemische Analyse | ||
| 689 | 0 | 0 | |a NMR-Spektroskopie |0 (DE-588)4075421-2 |D s |
| 689 | 0 | 1 | |a Elektrophorese |0 (DE-588)4014373-9 |D s |
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Datensatz im Suchindex
| _version_ | 1804180510222581760 |
|---|---|
| adam_text | CONTENTS
PREFACE
*
V
ABOUT
THE
AUTHOR
*
XVIII
1
1.1
HISTORICAL
PERSPECTIVES
AND
BASIC
PULSED
NMR
CONCEPTS
*
1
EARLY
NMR
WORK
WAS
FIELD
SWEEP
BASED
-
HAHN
CONCEIVED
AND
DEVELOPED
PULSED
NMR
EXCITATION
AND
DETECTION
*
1
1.2
1.3
HAHN
DISCOVERED
SPIN
ECHO
FORMATION
IN
PULSED
NMR
*
2
THE
INTRODUCTION
OF
FT-NMR
LED
TO
A
TRANSITION
FROM
SWEEP
TO
PREDOMINANTLY
PULSED
NMR
DETECTION
*
3
1.4
THE
SOMEWHAT
DORMANT
TECHNIQUE
OF
MAGNETIC
FIELD
GRADIENT
SPIN
ECHO
NMR
DIFFUSOMETRY
GRADUALLY
ACHIEVES
GREATER
POPULARITY
IN
THE
1970S
*
5
1.5
PULSED
FIELD
GRADIENT
SPIN
ECHO
NMR
OPENS
DOORS
FOR
DIFFUSOMETRY
AND
MAKES
MAGNETIC
FIELD
GRADIENT-BASED
IMAGING
POSSIBLE
*
8
1.6
FREQUENCY-RESOLVED
MULTICOMPONENT
NMR
DIFFUSOMETRY
EMERGED
IN
THE
1970S
*
9
1.7
COMPUTER
AND
NMR
SPECTROMETER
DEVELOPMENTS
MAKE
FT-PGSE
EASIER
AND
A
MORE
POWERFUL
TECHNIQUE
*
9
1.8
NMR
IMAGING
(MRI
AND
NMR
MICROSCOPY)
TECHNIQUES
EMERGED
IN
THE
EARLY
1970S
*
10
1.8.1
1.9
FURTHER
READING
*
13
ELECTROPHORETIC
NMR
EMERGES
AS
A
COMPONENT-
RESOLVED
TECHNIQUE
*
13
1.10
1.10.1
1.11
OUTLINE,
SCOPE
AND
REQUIRED
BACKGROUND
FOR
THE
PRESENT
BOOK
*
13
FURTHER
READING
*
14
BASIC
PULSED
NMR
CONCEPTS
-
A
PICTORIAL
VECTOR
MODEL
CRASH
COURSE
*
15
1.11.1
1.11.2
ENERGY
LEVELS
AND
FREQUENCIES
IN
NMR
SPECTROSCOPY
*
15
THE
COMPARABLY
VERY
LOW
FREQUENCY
OF
NMR
SPECTROSCOPY
HAS
SEVERAL
CONSEQUENCES
*
15
1.11.3
THE
*
ROTATING
FRAME
*
DESCRIPTION
OF
EXCITATION
AND
EMISSION
IN
NMR
*
17
1.11.4
SPIN
MAGNETIZATION
DEPHASES
WITH
TIME
IN
THEX -Y -PLANE
AND
CONSTITUTES
THE
TIME-DOMAIN
NMR
SIGNAL
-
THE
*
FREE
INDUCTION
DECAY
*
*
18
1.11.5
RESTORATION
OF
THERMAL
EQUILIBRIUM
AND
LOSS
OF
PHASE
COHERENCE
IN
THEX -Y
PLANE
ARE
TWO
TYPES
OF
SPIN
RELAXATION
PROCESSES
*
20
X
CONTENTS
1.11.6
DETECTION
OF
TRANSVERSE
MAGNETIZATION
IS
MADE
IN
A
PHASE
SENSITIVE
MANNER,
FOLLOWED
BY
DISCRETE
DIGITIZATION
*
20
1.11.7
ROTATING
FRAME
MAGNETIZATION
IS
MONITORED
THROUGH
QUADRATURE
DETECTION
AND
COMPLEX
FOURIER
TRANSFORMATION
*
21
1.11.8
ACTUAL
PULSED
NMR
HARDWARE
AND
DETECTION
PROCEDURES
*
25
1.11.8.1
FURTHER
READING
*
26
1.11.9
CORRECTING
BASIC
NON-IDEALITIES
OF
PULSE
GENERATION
AND
DATA
ACQUISITION
*
27
1.12
REFERENCES
*
28
2
BASIC
CONCEPTS
*
30
2.1
MOLECULAR
TRANSPORT
PROCESSES
AND
THE
NMR
TIME
WINDOW
*
30
2.2
ROTATIONAL
DIFFUSION
*
32
2.3
SELF-DIFFUSION
AND
OTHER
MODES
OF
TRANSLATIONAL
MOTION
*
36
2.3.1
ESTIMATING
SELF-DIFFUSION
COEFFICIENTS
FROM
A
MACROSCOPIC
PERSPECTIVE
*
38
2.3.2
ESTIMATING
SELF-DIFFUSION
COEFFICIENTS
FROM
A
MOLECULAR
PERSPECTIVE
*
40
2.3.3
GENERAL
AND
EXPERIMENTAL
METHODOLOGICAL
HISTORICAL
CONSIDERATIONS
*
41
2.3.4
FLOW
AND
RELATED
MODES
OF
NON-BROWNIAN
MOTION
*
42
2.3.5
INFLUENCE
OF
BARRIERS
TO
MOLECULAR
TRANSPORT
*
42
2.3.6
FURTHER
READING
*
44
2.4
MUTUAL
DIFFUSION
*
44
2.4.1
FURTHER
READING
*
46
2.5
WHY
STUDY
SELF-DIFFUSION
AND
OTHER
TRANSPORT
PROCESSES
BY
NMR?
-----
47
2.5.1
MAIN
OBJECTIVES
*
47
2.5.2
WHAT
CAN
FAVORABLY
BE
STUDIED
AND
BY
WHICH
APPROACH?
*
47
2.5.3
THE
MOST
BASIC
EXPERIMENTAL
STRATEGY
BASED
ON
SELF-DIFFUSION
DATA
*
48
2.6
SPIN-ECHO
FORMATION
UNDER
THE
INFLUENCE
OF
A
STEADY
MAGNETIC
FIELD
GRADIENT:
THE
KEY
TO
NMR
DIFFUSOMETRY
*
49
2.6.1
LABELING
NUCLEI
WITH
POSITIONAL
INFORMATION
*
50
2.6.2
THE
INTRINSIC
*
TIME-REVERSAL
EFFECT
OF
SPIN-ECHO
FORMATION
*
50
2.6.3
ILLUSTRATING
SPIN-ECHO
FORMATION
*
52
2.6.3.1
THE
BASIC
90-90
HAHN
ECHO
*
52
2.6.3.2
A
90-180
PULSE
PAIR
------
54
2.6.3
3
A
90-90-90
SEQUENCE
-
THE
STIMULATED
ECHO
AND
OTHERS
*
55
2.6.3.4
SPIN
PHASE
GRAPHING,
MAGNETIZATION
HELICES
AND
DIFFRACTION
ANALOGIES
*
59
2.6.4
EFFECTS
OF
J-MODULATION
ON
SPIN-ECHO
FORMATION
*
61
CONTENTS
XI
2.6.5
QUANTIFYING
SELF-DIFFUSION
USING
SPIN
ECHOES
-
A
SIMPLIFIED
MODEL
*
63
2.6.6
INFLUENCE
OF
FLOW
OR
ON
SPIN-ECHO
FORMATION
*
65
2.6.7
SELF-DIFFUSION
EFFECTS
ALONGSIDE
OTHER
NMR
PARAMETERS
IN
SPIN-ECHO
EXPERIMENTS
*
66
2.6.8
SPIN
ECHOES
AND
STEADY-GRADIENT
DIFFUSIONS^
EFFECTS
IN
MULTIPULSE
NMR
EXPERIMENTS
*
67
2.6.9
QUANTIFYING
SELF-DIFFUSION
USING
SPIN
ECHOES
-
DERIVING
ECHO
ATTENUATION
EXPRESSIONS
MORE
RIGOROUSLY
*
69
2.7
SPIN-ECHO
FORMATION
UNDER
THE
INFLUENCE
OF
PULSED
MAGNETIC
FIELD
GRADIENTS
*
70
2.7.1
THE
BASIC
PGSE
EXPERIMENT
*
71
2.7.2
THE
STIMULATED
ECHO
(PGSTE)
VARIANT
OF
THE
PGSE
EXPERIMENT
*
74
2.7.3
BASIC
ADVANTAGES
IN
USING
PGSTE
RATHER
THAN
PGSE
*
75
2.7.4
MULTIPULSE
CPMG-BASED
PGSE
-----
76
2.7.5
BACKGROUND
MAGNETIC
FIELD
GRADIENT
INFLUENCE
ON
PGSE
EXPERIMENTS
*
77
2.7.6
FURTHER
READING
*
78
2.8
OPTIMIZATION
AND
EVALUATION
OF
BASIC
PGSE
AND
PGSTE
EXPERIMENTS
*
79
2.8.1
DEALING
WITH
INTRINSIC
NUCLEAR
SPIN
FACTORS
*
79
2.8.2
DEALING
WITH
QUADRUPOLAR
NUCLEI
*
80
2.8.3
PGSE,
AS
APPLIED
TO
CARBON-13
NUCLEI
*
81
2.8.4
DEALING
WITH
INSTRUMENTAL
FACTORS
AND
OTHER
NONIDEALITIES
*
82
2.8.5
BRIEF
SUMMARY
OF
COMMON
COMPLICATIONS
IN
PGSE
STUDIES
*
83
2.8.5.1
CONVECTION
*
83
2.5.5.2
EDDY
CURRENTS
AND
SAMPLE
VIBRATION
*
84
2.8.53
RADIATION
DAMPING
*
85
2.8.5.4
CHEMICAL
EXCHANGE
AND
CROSS-RELAXATION
*
85
2.8.5.5
GENERAL
ADVICE
ON
SAMPLE
SIZE
AND
LENGTH
IN
PGSE
STUDIES
*
86
2.9
PHASE
CYCLING
*
86
2.9.1
SOFTWARE
DESIGN
OF
SELECTIVE
PHASE
CYCLES
*
90
2.9.2
SEPARATING
OUT
A
THREE-PULSE
GENERATED
STIMULATED
ECHO
*
91
2.9.3
USING
*
CRUSHER
*
MAGNETIC
FIELD
GRADIENT
PULSES
TO
DESTROY
TRANSVERSE
MAGNETIZATION
WITHIN
A
PULSE
SEQUENCE
*
93
2.9.4
*
MULTIPLEXED
*
NMR
EXPERIMENTS
*
94
2.9.5
FURTHER
READING
*
94
2.10
REFERENCES
*
94
3
PGSE
NMR
DIFFUSOMETRY
EXAMPLE
APPLICATIONS
*
100
3.1
FURTHER
READING
*
100
3.2
STRATEGIES
AND
CONSTRAINTS
*
100
XII
CONTENTS
3.3
3.4
3.4.1
3.4.1.1
3.4.1.2
3.4.1.3
3.5
3.5.1
3.5.2
3.5.2.1
3.5.2.2
3.5.3
3.5.3.1
3.5.3.2
3.5.4
3.5.4.1
3.5.4.2
3.5.43
3.5.5
3.5.5.1
3.5.5.2
3.5.6
3.5.6.1
3.5.6.2
3.5.7
3.5.7.1
3.5.7.2
3.5.7.3
3.6
3.6.1
3.6.1.1
3.6.2
3.6.2.1
3.6.2.2
3.6.2.3
3.6.3
3.6.3.1
3.63.2
3.6.4
3.6.4.1
SYSTEMS
SUITABLE
FOR
DIFFUSION-RELATED
INVESTIGATION
BY
NMR
*
101
DIFFUSION
IN
SINGLE
OR
BINARY
LIQUIDS
*
103
MONITORING
SELF-DIFFUSION
OF
GASES
DISSOLVED
IN
WATER
*
104
OBJECTIVES
*
104
EXPERIMENTAL
ASPECTS
*
104
FURTHER
READING
*
105
DIFFUSION-BASED
NMR
SIGNAL
DETECTION
AND
MONITORING
OF
MISCELLANEOUS
AGGREGATION
PROCESSES
IN
AQUEOUS
SOLUTION
*
105
GENERAL
OBJECTIVES
*
107
RHODAMINE
66
SELF-AGGREGATION
IN
AQUEOUS
SOLUTION
*
107
OBJECTIVES
*
107
EXPERIMENTAL
ASPECTS
*
107
DISSOLVED
ORGANIC
MATTER
IN
NATURAL WATERS
*
108
OBJECTIVES
*
108
EXPERIMENTAL
ASPECTS
*
109
SUBSTRATE
BINDING
TO
SUPRAMOLECULAR
STRUCTURES
IN
AQUEOUS
SOLUTION
*
110
OBJECTIVES
*
110
EXPERIMENTAL
ASPECTS
*
111
FURTHER
READING
*
111
NUCLEOTIDE
AGGREGATION
IN
AQUEOUS
SOLUTION
*
112
OBJECTIVE
*
112
EXPERIMENTAL
ASPECTS
*
113
PROTEIN
AGGREGATION
IN
AQUEOUS
SOLUTION
*
114
OBJECTIVES
*
114
EXPERIMENTAL
ASPECTS
*
115
PGSE
IN
ORGANOMETALLIC
CHEMISTRY
*
116
OBJECTIVES
*
116
EXPERIMENTAL
ASPECTS
*
117
FURTHER
READING
*
117
SURFACTANT
SYSTEMS
*
117
PHYSICOCHEMICAL
CHARACTERISTICS
*
117
FURTHER
READING
*
122
SURFACTANT
AGGREGATION
*
123
OBJECTIVES
*
123
EXPERIMENTAL
ASPECTS
*
123
FURTHER
READING
*
125
MICELLAR
SOLUBILIZATION
*
125
OBJECTIVES
*
126
EXPERIMENTAL
AND
EVALUATIONS
ASPECTS
*
126
MIXED
MICELLIZATION
*
129
OBJECTIVES
*
129
CONTENTS
*
XIII
3.6.A.2
EXPERIMENTAL
ASPECTS
*
129
3.6.4.3
FURTHER
READING
*
131
3.6.5
*
MICROEMULSIONS
*
AND
MICROEMULSION
STRUCTURE
*
132
3.6.5.1
OBJECTIVES
*
132
3.6.5.2
EXPERIMENTAL
ASPECTS
*
132
3.6
5.3
FURTHER
READING
*
134
3.6.6
SURFACTANT
ADSORPTION
FROM
AQUEOUS
SOLUTION
ONTO
SURFACES
AND
LARGE
PARTICLES
*
134
3.6.6.1
OBJECTIVES
*
135
3.6.6.2
EXPERIMENTAL
ASPECTS
*
135
3.6.7
SURFACTANT
AND
POLYMER
BINDING
TO
SUSPENDED
CARBON
NANOTUBES
IN
AQUEOUS
SOLUTION
*
138
3.6.7.1
OBJECTIVES
*
139
3.6.7.2
EXPERIMENTAL
ASPECTS
*
139
3.6.8
FURTHER
READING
*
140
3.7
POLYMER
SYSTEMS
IN
SOLUTION;
GENERAL
*
140
3.7.1
FURTHER
READING
*
144
3.7.2
DIFFUSION
IN
MIXED
POLYMER
SYSTEMS
IN
SOLUTION
*
144
3.7.2.1
OBJECTIVE
-----
144
3.7.2.2
EXPERIMENTAL
ASPECTS
*
145
3.7.3
COUNTERION
DIFFUSION
IN
POLYELECTROLYTE
SYSTEMS
IN
SOLUTION
*
145
3.7.3.1
OBJECTIVES
*
145
3.73.2
EXPERIMENTAL
ASPECTS
*
146
3.7.3.3 FURTHER
READING
*
147
3.7.4
BLOCK
COPOLYMER
AND
POLYMER-SURFACTANT
INTERACTION
IN
AQUEOUS
SOLUTION
-
ASSOCIATIVE
THICKENERS
*
147
3.7.4.1
OBJECTIVES
*
148
3.7.4.2
EXPERIMENTAL
ASPECTS
*
148
3.7.4.3
FURTHER
READING
*
150
3.8
REFERENCES
*
150
4
GETTING
STARTED
*
155
4.1
THE
EXPERIMENTAL
ENVIRONMENT
TO
AIM
FOR
*
155
4.1.1
FURTHER
READING
*
159
4.2
PGSE
ON
A
CONVENTIONAL
NMR
SUPERCON
SPECTROMETER
WITH
A
COMMERCIAL
FIELD
GRADIENT
PROBE
AND
GRADIENT
CURRENT
DRIVER
*
159
4.2.1
FURTHER
READING
*
161
4.3
PGSE
ON
A
NEWER
GENERATION
PERMANENT
MAGNET
BENCH-TOP
SPECTROMETERS
*
162
4.4
PGSE
ON
A
SINGLE-SIDED
OR
OTHERWISE
COMPACT
*
NMR-MOUSE
*
TYPE
OF
INSTRUMENTATION
*
165
4.4.1
FURTHER
READING
*
166
XIV
*
CONTENTS
4.5
5
5.1
5.2
5.3
5.3.1
5.4
5.4.1
5.4.2
5.5
5.6
5.6.1
5.6.2
5.6.3
5.6.4
5.7
5.7.1
5.7.1.1
5.7.2
5.7.3
5.7.4
6
6.1
6.2
6.3
6.3.1
6.4
6.5
BASIC
PREOPERATION
CHECKLIST
ON
*
NONCOMPACT
*
SPECTROMETER
TYPES
*
166
REFERENCES
*
173
NONOBVIOUS
PITFALLS
AND
OTHER
POTENTIALLY
CONFUSING
ELEMENTS
IN
PGSE
STUDIES
*
175
NONLINEARITY
BETWEEN
RELATIVE
ECHO
AMPLITUDES
AND
COMPONENT
CONCENTRATIONS
*
175
EDDY
CURRENT
AND
SAMPLE
VIBRATION
DISTURBANCES
*
176
DEALING
WITH
CONCENTRATED
SAMPLES
IN
PROTON
PGSE
EXPERIMENTS
*
179
RADIATION
DAMPING
EFFECTS
*
179
CONVECTIVE
TRANSPORT
IN
THE
SAMPLE
*
179
SPECIAL
WAYS
OF
SUPPRESSING
MACROSCOPIC
CONVECTION
PHYSICALLY
*
182
SUPPRESSING
CONVECTION
EFFECTS
IN
PGSE
BY
USING
MORE
COMPLEX
PULSE
SEQUENCES
*
182
EFFECTS
OF
CHEMICAL
EXCHANGE
DURING
THE
PGSE
SEQUENCE
*
184
INFLUENCE
FROM
RESTRICTED
DIFFUSION
AND
INHERENT
APPROXIMATIONS
IN
THE
STEJSKAL-TANNER
RELATION
*
185
RESTRICTED
DIFFUSION
IN
GENERAL
*
185
THE
GPD
APPROXIMATION
*
187
THE
SGP
APPROXIMATION
*
187
FURTHER
READING
*
188
LESS
OBVIOUS
OR
WIDELY
MISCONCEIVED
CONCEPTS
IN
THE
CONTEXT
OF
NMR
DIFFUSOMETRY
*
188
*
AFFINITY
NMR
*
-----
188
FURTHER
READING
*
189
*
DOSY
*
AND
*
DOSY
MAPS
*
*
189
*
NMR
CHROMATOGRAPHY
*
AND
*
MATRIX-ASSISTED
NMR
*
*
190
FURTHER
READING
*
191
REFERENCES
*
191
DATA
PREPARATION,
EVALUATION
AND
PRESENTATION
*
195
FURTHER
READING
*
199
THE
ACTUAL
FITTING
PROBLEM
IN
THE
CONTEXT
OF
PGSE
DATA
SETS
*
199
SOME
EXISTING
DATA
PROCESSING
STRATEGIES
IN
SIMILAR
CONTEXT
*
200
FURTHER
READING
*
205
PRIOR
KNOWLEDGE
IN
PGSE
EXPERIMENTAL
ANALYSIS
*
206
EXPONENTIAL-TYPE
FITTING
OF
PGSE
BANDSHAPE
DATA
-
SOME
BASIC
EXAMPLES
*
207
CONTENTS
*
*
XV
6.6
STEP-WISE
UNRAVELING
OF
MORE
COMPLEX
SPECTRAL
OVERLAP
IN
PGSEDATA
*
211
6.6.1
ACHIEVING
PGSE
SIGNAL
SEPARATION
BY
INCREASING
EXPERIMENTAL
DIMENSIONALITY
*
215
6.7
AUTOMATED
OVERVIEW
SCANNING
PGSE
DATA
-
*
HR-DOSY,
*
*
RECORD
*
PROCESSING
AND
SIMILAR
*
215
6.8
ANALYZING
PGSE
DATA
SETS
BY
APPLYING
DISTRIBUTIONS
OF
SELF-DIFFUSION
COEFFICIENTS
*
219
6.8.1 FURTHER
READING
*
223
6.8.2
STRETCHED
EXPONENTIALS
OF
KOHLRAUSCH-WILLIAMS-WATTS
TYPE
*
223
6.8.3
GAMMA
FUNCTION
MODELING
OF
POLYDISPERSITY
IN
PGSE
DATA
*
224
6.8.4
INVERSE
LAPLACE
TRANSFORM
MODELING
*
226
6.9
WHICH
DATA
ANALYSIS
PROCEDURE
TO
CHOOSE
FOR
ANALYZING
PGSE
DATA
SETS?
*
227
6.9.1
EXISTING
SOFTWARE
FOR
OFF-LINE
PROCESSING
AND
DEEPER
ANALYSIS
OF
PGSE
DATA
-----
228
6.9.1.1
CORE,
DESCRIBED
TECHNICALLY
*
229
6.9.1.2
THE
SCORE
MODIFICATION
OF
CORE
*
230
6.9.1.3
COMPARING
THE
CORE
AND
SCORE
VARIANTS
*
230
6.9.2
SUMMARIZING
AND
PRESENTING
RESULTS
-
DOSY
DISPLAYS
AND
RELATED
*
231
6.10
ERROR
ESTIMATION
IN
PGSE
STUDIES
*
232
6.10.1
MONTE
CARLO
ESTIMATION
OF
PARAMETER CONFIDENCE
LIMITS
*
234
6.10.2
ERROR
ESTIMATION,
AS
GRAPHICALLY
OR
NUMERICALLY
IMPLIED
IN
HR-DOSY
OR
RECORD-TYPE
DATA
ANALYSIS
OUTCOMES
*
235
6.11
PGSE
AND
NMR
DATA
PROCESSING
IN
RETROSPECT
*
235
6.11.1
FURTHER
READING
*
239
6.12
NMR
DATA
PROCESSING
SOFTWARE
SOURCES
*
239
6.12.1
DEDICATED
*
PGSE
SOFTWARE
*
*
240
6.12.1.1
THE
DOSY
TOOLBOX
AND
GNAT
------
240
6.12.1.2
CORE
-----
240
6.12.2
OTHER
SOFTWARE
OF
GENERAL
INTEREST
IN
THE
CONTEXT
OF
PGSE
STUDIES
*
243
6.12.3
SUPPORTING
MATHEMATIC
AND
NUMERIC
SOFTWARE
*
244
REFERENCES
*
247
7
SPECIALIZED
MEASUREMENTS
AND
SYSTEMS
*
250
7.1
PULSED
RADIOFREQUENCY
(BJ
RATHER
THAN
B
O
FIELD
GRADIENT
DIFFUSOMETRY
*
250
7.2
STATIC
SUPERCONDUCTING
MAGNET
STRAY
FIELD
DIFFUSOMETRY
*
250
7.3
MODULATED
MAGNETIC
FIELD
GRADIENT
METHODS
*
252
7.3.1
FURTHER
READING
*
253
XVI
*
CONTENTS
7.4
7.5
7.5.1
7.5.2
7.5.3
7.5.4
7.6
7.6.1
8
8.1
8.2
8.3
8.4
8.5
8.6
8.6.1
8.6.2
8.6.3
8.6.4
8.6.5
8.7
8.7.1
8.8
8.8.1
8.8.2
8.8.3
8.9
8.9.1
8.9.2
8.9.3
8.10
8.11
8.11.1
HR-MAS
PGSE
DIFFUSOMETRY
STUDIES
ON
SEMISOLIDS
*
253
PGSE
NMR
DIFFUSOMETRY
IN
HETEROGENEOUS
OR
MICROHETEROGENEOUS
SYSTEMS
*
255
BIOLOGICAL
SYSTEMS
*
258
PROBING
PERIODIC
STRUCTURES
THROUGH
*
DIFFUSIVE
DIFFRACTION
*
EFFECTS
IN
PGSE
-----
258
SUPPRESSING
*
NATURAL
*
BACKGROUND
MAGNETIC
FIELD
GRADIENTS
IN
HETEROGENEOUS
SYSTEMS
*
260
FURTHER
READING
*
261
SPATIALLY
LOCALIZED
NMR
DIFFUSOMETRY
AND
NMR
MICROSCOPY
*
261
FURTHER
READING
*
263
REFERENCES
*
263
ELECTROPHORETIC
NMR
(ENMR)
*
266
FURTHER
READING
*
269
EVALUATING
ECHO
SIGNAL
PHASE
DATA
IN
ENMR
*
269
ENMR
REVIEWS
*
270
BASIC
EXPERIMENTAL
IMPLEMENTATION
OF
ENMR
*
271
BEGINNER
*
S
LESSONS
LEARNED
BY
USING
THE
ORIGINALLY
COMMON
U-TUBE
ENMR
SAMPLE
GEOMETRY
*
272
GENERAL
CONSIDERATIONS
IN
EXPERIMENTAL
ENMR
*
274
SAFETY
*
274
BASIC
PHYSICS
*
274
SAMPLE
HEATING
IN
ENMR
*
275
MAGNETIC
FIELD
GRADIENTS
AND
MOTION
INDUCED
BY
CURRENTS
IN
THE
SAMPLE
*
275
FURTHER
READING
*
276
WHY
STUDY
ELECTROPHORETIC
MOBILITY
RATHER
THAN
SELF-DIFFUSION?
*
276
TRANSFERENCE
NUMBERS
AND
ELECTROPHORETIC
MOBILITY
*
277
ELECTRO-OSMOSIS
AND
ELECTROPHORESIS
IN
A
HISTORICAL
PERSPECTIVE
*
278
ELECTRO-OSMOSIS
AND
THE
*
DOUBLE
LAYER
*
CONCEPT
*
278
ELECTROPHORESIS
*
279
FURTHER
READING
*
280
MORE
RECENT
METHODOLOGICAL
DEVELOPMENTS
IN
ENMR
*
281
PULSE
SEQUENCES
AND
SAMPLE
CELLS
*
282
HARDWARE
EVOLUTION
*
283
PARTIAL
PERFORMANCE
SPECIFICATIONS
FOR
THE
ENMR-1000
UNIT
*
286
ENMR
EQUIPMENT
USED
BY
OTHER
RESEARCHERS
*
286
GENERAL
CONSIDERATIONS
ON
SUITABILITY
OF
ENMR
APPLICATIONS
*
288
FURTHER
READING
*
289
CONTENTS
*
XVII
8.12
SOME
ENMR
EXAMPLE
STUDIES
*
289
8.12.1
ION
BINDING
TO
POLYETHYLENE
OXIDE)
POLYMER
CHAINS
IN
AQUEOUS
SOLUTION
*
290
8.12.1.1
OBJECTIVE
*
291
8.12.1.2
EXPERIMENTAL
ASPECTS
*
292
8.12.1.3
FURTHER
READING
-----
294
8.12.2
SURFACTANT/NONIONIC
POLYMER
INTERACTION
*
294
8.12.2.1
OBJECTIVES
*
294
8.12.2.2
EXPERIMENTAL
ASPECTS
*
294
8.12.2.3
FURTHER
READING
*
296
8.12.3
INVESTIGATING
IONIC
LIQUIDS
*
BY
ENMR
*
296
8.12.3.1
OBJECTIVES
*
297
8.12.3.2
EXPERIMENTAL
ASPECTS
*
297
8.12.3.3
FURTHER
READING
*
298
8.13
SPATIALLY
RESOLVED
NMR-BASED
MONITORING
OF
ELECTRICALLY
INDUCED
TRANSPORT
*
299
8.14
FURTHER
READING
*
299
REFERENCES
*
300
9
BUILDING
HOME-BREW
PGSE
AND
ENMR
INSTRUMENTATION
*
303
9.1
FURTHER
READING
*
303
9.2
PGSE
ON
OLDER-GENERATION
RESISTIVE
ELECTROMAGNET-TYPE
SPECTROMETERS
*
303
9.3
HOME-BREW
GRADIENT
COILS
FOR
SUPERCONDUCTING
MAGNET
GEOMETRIES
*
307
9.3.1
FURTHER
READING
*
308
9.4
GRADIENT
CURRENT
GENERATION
AND
SAFETY
CONSIDERATIONS
*
308
9.5
HOME-BREW
GRADIENT
CONTROL
*
309
9.6
ELECTROPHORETIC
NMR
(ENMR)
*
310
9.7
CONSIDERING
COMPLETE
HOME-BREW
NMR
SYSTEMS
*
311
9.8
FURTHER
READING
*
312
9.9
INTERNET
RESOURCES
*
312
REFERENCES
*
314
10
OTHER
MORE
RECENT
TEXTS
AND
REVIEWS
ON
NMR
DIFFUSOMETRY
*
315
REFERENCES
*
316
APPENDIX:
QUANTIFYING
SELF-DIFFUSION-RELATED
SPIN
ECHO
MAGNETIC
FIELD
GRADIENT-INDUCED
SPIN
ECHO
ATTENUATION
AND
DERIVING
THE
BASIC
PULSED-GRADIENT
STEJSKAL-TANNER
RELATION
*
318
INDEX
*
323
|
| any_adam_object | 1 |
| author | Stilbs, Peter |
| author_GND | (DE-588)1193497353 |
| author_facet | Stilbs, Peter |
| author_role | aut |
| author_sort | Stilbs, Peter |
| author_variant | p s ps |
| building | Verbundindex |
| bvnumber | BV046160495 |
| classification_rvk | VG 9500 |
| ctrlnum | (OCoLC)1121487201 (DE-599)DNB1177435551 |
| discipline | Chemie / Pharmazie |
| format | Book |
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| id | DE-604.BV046160495 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T08:36:54Z |
| institution | BVB |
| institution_GND | (DE-588)10095502-2 |
| isbn | 9783110551525 3110551527 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-031540420 |
| oclc_num | 1121487201 |
| open_access_boolean | |
| owner | DE-92 DE-19 DE-BY-UBM DE-83 DE-703 |
| owner_facet | DE-92 DE-19 DE-BY-UBM DE-83 DE-703 |
| physical | XVII, 332 Seiten Illustrationen, Diagramme 24 cm, 600 g |
| publishDate | 2019 |
| publishDateSearch | 2019 |
| publishDateSort | 2019 |
| publisher | De Gruyter |
| record_format | marc |
| series2 | De Gruyter STEM |
| spelling | Stilbs, Peter Verfasser (DE-588)1193497353 aut Diffusion and electrophoretic NMR Peter Stilbs Berlin ; Boston De Gruyter [2019] © 2019 XVII, 332 Seiten Illustrationen, Diagramme 24 cm, 600 g txt rdacontent n rdamedia nc rdacarrier De Gruyter STEM NMR-Spektroskopie (DE-588)4075421-2 gnd rswk-swf Elektrophorese (DE-588)4014373-9 gnd rswk-swf NMR-Spektroskopie Analytische Chemie Chemische Analyse NMR-Spektroskopie (DE-588)4075421-2 s Elektrophorese (DE-588)4014373-9 s DE-604 Walter de Gruyter GmbH & Co. KG (DE-588)10095502-2 pbl Erscheint auch als Online-Ausgabe, PDF 978-3-11-055153-2 Erscheint auch als Online-Ausgabe, EPUB 978-3-11-055165-5 X:MVB http://www.degruyter.com/search?f_0=isbnissn&q_0=9783110551525&searchTitles=true B:DE-101 application/pdf http://d-nb.info/1177435551/04 Inhaltsverzeichnis DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=031540420&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Stilbs, Peter Diffusion and electrophoretic NMR NMR-Spektroskopie (DE-588)4075421-2 gnd Elektrophorese (DE-588)4014373-9 gnd |
| subject_GND | (DE-588)4075421-2 (DE-588)4014373-9 |
| title | Diffusion and electrophoretic NMR |
| title_auth | Diffusion and electrophoretic NMR |
| title_exact_search | Diffusion and electrophoretic NMR |
| title_full | Diffusion and electrophoretic NMR Peter Stilbs |
| title_fullStr | Diffusion and electrophoretic NMR Peter Stilbs |
| title_full_unstemmed | Diffusion and electrophoretic NMR Peter Stilbs |
| title_short | Diffusion and electrophoretic NMR |
| title_sort | diffusion and electrophoretic nmr |
| topic | NMR-Spektroskopie (DE-588)4075421-2 gnd Elektrophorese (DE-588)4014373-9 gnd |
| topic_facet | NMR-Spektroskopie Elektrophorese |
| url | http://www.degruyter.com/search?f_0=isbnissn&q_0=9783110551525&searchTitles=true http://d-nb.info/1177435551/04 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=031540420&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT stilbspeter diffusionandelectrophoreticnmr AT walterdegruytergmbhcokg diffusionandelectrophoreticnmr |
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