Fundamentals of soft matter science:
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| Main Author: | |
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| Format: | Book |
| Language: | English |
| Published: |
Boca Raton
CRC Press, Taylor & Francis Group
[2020]
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| Edition: | Second edition |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis Klappentext |
| Physical Description: | xix, 283 Seiten Illustrationen, Diagramme (farbig) |
| ISBN: | 9781138724440 9781138724785 |
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| adam_text | Contents Preface...................................................................................................................xiii Acknowledgments................................................................................................ xv About the Author................................................................................................xvii About the Illustrator............................................................................................. xix Chapter 1. Introduction.......................................................................................1 1.1 What Is Soft Matter?................................................................ 1 1.2 Basic Thermal Physics..............................................................3 1.2.1 1.3 Equilibrium..................................................................4 1.2.2 Phase Transitions......................................................... 5 1.2.3 Solids, Liquids, and Gases............................................7 1.2.4 The Ideal Gas.............................................................. 9 Phase Diagrams....................................................................11 1.4 Diffusion and Random Walks................................................13 Questions....................................................................................... 17 References..................................................................................... 18 Further Reading.............................................................................19 Chapter 2. Self-assemblyand
Structure in Soft Matter................................... 21 2.1 2.2 Self-assembly.........................................................................22 Intermolecular Forces.......................................................... 26 2.2.1 Van der Waals Attraction.......................................... 26 2.2.2 Hard Sphere Repulsion............................................ 27 2.2.3 Electrostatic Forces................................................... 28 2.2.4 Hydrophobic Effects and the Hydrogen Bond.... 28 vii
viii Contents 2.3 Aggregation and Assembly................................................. 30 2.3.1 Power Laws and Fractals.......................................... 32 2.3.2 Amorphous Materials and Short-range Order....... 36 2.4 Active Matter: Beyond Equilibrium Assembly..................... 36 2.5 Mechanical Properties of Soft Matter..................................37 2.5.1 Viscosity and Elasticity.............................................. 37 Questions...................................................................................... 42 References.................................................................................... 43 Chapter 3. Liquid Crystals............................................................................... 45 3.1 Introduction to Liquid Crystals............................................46 3.1.1 What Is a Liquid Crystal?.......................................... 46 3.2 Anisotropy in Liquid Crystals............................................... 46 3.3 The Order Parameter............................................................48 3.4 Thermotropic and Lyotropic Liquid Crystals.......................49 3.5 Birefringence in Liquid Crystals............................................ 49 3.6 Topological Defects and Defect Textures.......................... 52 3.7 Thermotropic Liquid Crystal Phases................................... 54 3.6.1 3.8 Introduction to Topological Defects....................... 53 3.7.1 The Nematic Phase................................................... 55 3.7.2 The Smectic
Phases..................................................58 3.7.3 Chirality in Liquid Crystals.........................................60 3.7.4 The Cholesteric Phase.............................................. 61 3.7.5 The Chiral Smectic Phases.......................................63 3.7.6 Other Chiral Smectic Phases................................... 65 3.7.7 The Bent-Core (Banana) Phases................................66 3.7.8 Discotic Phases........................................................ 68 Experimental Techniques..................................................... 69 3.8.1 Deforming Liquid Crystals....................................... 69 3.8.2 Polarized Optical Microscopy....................................71 3.8.3 Electro-optical Measurements................................ 74 3.8.4 The Dielectric Properties of Liquid Crystals.............74 3.8.5 The Frèedericksz Transition and Measurement of the Elastic Constants............................................ 75 3.9 3.8.6 X-ray Diffraction....................................................... 78 3.8.7 Differential Scanning Calorimetry............................ 80 Applications of Liquid Crystals............................................ 83 3.9.1 Liquid Crystal Displays.............................................. 83 3.9.2 The Twisted Nematic Display................................... 85 3.9.3 Spatial Light Modulators.......................................... 86 3.9.4 Liquid Crystal Temperature Sensors........................ 86
Questions.......................................................................................89
Contents ix References..................................................................................... 91 Further Reading............................................................................ 91 Chapter 4. Surfactants...................................................................................... 93 4.1 Introduction.......................................................................... 93 4.2 Types of Surfactants..............................................................94 4.3 Surface Tension and Surfactants........................................ 96 4.4 Self-assembly and Phase Behavior..................................... 100 4.4.1 The Micellar Phase and the Critical Micelle Concentration.........................................................100 4.5 4.4.2 Other Surfactant Phases.........................................103 4.4.3 The Packing Parameter.......................................... 105 Membrane Elasticity and Curvature................................. 107 4.5.1 4.6 4.7 Bicontinuous Phases.............................................. 110 Applications of Surfactants................................................ 111 4.6.1 Detergents.............................................................. 111 4.6.2 Detergent Foams and Bubbles.............................. 112 4.6.3 Emulsifiers and Emulsions....................................... 114 4.6.4 Commercial Paints and Inks....................................117 4.6.5 Surfactants and Gel Electrophoresis..................... 117 4.6.6 Surfactants In the
Lungs......................................... 118 Experimental Methods.......................................................120 4.7.1 The LangmuirTrough............................................ 120 4.7.2 Measuring Surface Tension..................................... 121 Questions..................................................................................... 123 References................................................................................... 124 Further Reading.......................................................................... 124 Chapter 5. Polymers....................................................................................... 125 5.1 Introduction.........................................................................126 5.2 Early Polymers..................................................................... 126 5.3 Polymer Structure................................................................128 5.4 Polymer Solutions.............................................................. 134 5.4.1 The Ideal Chain....................................................... 135 5.4.2 The Radius of Gyration............................................ 137 5.4.3 Excluded Volume and Solvent Effects................... 138 5.4.4 Increasing the Concentration of a Polymer Solution................................................................... 139 5.4.5 Stretching a Polymer Chain: The Entropie Chain.......................................................................141 5.4.6 Polyelectrolytes.......................................................143
x Contents 5.4.7 Polymer Gels.......................................................144 5.4.8 Hydrogels............................................................ 146 5.5 The Glassy and Polymer Melt Phases.............................. 147 5.6 The Mechanical Properties of Polymers...........................150 5.7 Liquid Crystal Polymers....................................................153 5.8 Experimental Techniques..................................................155 5.8.1 Scattering Techniques......................................... 155 5.8.2 Polymer Spectroscopy....................................... 158 5.8.2.1 Fourier Transform Infrared Spectroscopy..................................... 158 5.82.2 Raman Spectroscopy..........................160 5.8.2.3 Nuclear Magnetic Resonance........... 160 Questions.....................................................................................163 References................................................................................... 165 Further Reading.......................................................................... 165 Chapterő. Colloidal Materials.........................................................................167 6.1 Introduction.......................................................................168 6.2 Characteristics of Colloidal Systems................................ 170 6.3 Colloids in Suspension......................................................171 6.4 Competing Forces In Colloidal Dispersions..................... 173 6.5 Interparticle
Interactions.................................................. 174 6.6 6.5.1 Van der Waals Attraction ....................................175 6.5.2 Electrostatic Forces.............................................. 175 6.5.3 DLVO Theory....................................................... 176 6.5.4 Depletion Forces..................................................177 6.5.5 Steric Repulsion....................................................179 Colloidal Aggregation....................................................... 182 6.7 Colloidal Crystals.............................................................. 186 6.8 6.9 Granular Materials............................................................ 188 Foams............................................................................... 189 6.10 6.9.1 Why Do Some Liquids Foam?............................ 190 6.9.2 Soap Foams......................................................... 191 6.9.3 Foam Stability..................................................... 192 Experimental Techniques..................................................194 6.10.1 Light Scattering....................................................194 6.10.1.1 Light-Scattering Experiments............ 196 6.10.1.2 Static Light Scattering.......................196 6.10.1.3 Dynamic Light Scattering..................196 6.10.2 Zeta Potential and the Electric Double Layer....199 6.10.3 Rheology Measurements................................... 202 6.10.3.1 Common Rheometer Designs...........203
Contents xi Questions.................................................................................... 205 References...................................................................................206 Further Reading..........................................................................207 Chapter 7. Soft Biological Materials............................................................. 209 7.1 Introduction...................................................................... 209 7.2 The Composition of theCell............................................. 211 7.3 The Cell Membrane.......................................................... 212 7.3.1 Lipid Phase Behavior............................................ 214 7.3.2 Lipid Domains and the Raft Hypothesis............218 7.3.3 Membrane Elasticity and Curvature in Biological Membranes........................................ 220 7.3.4 7.4 Other Fatty Biological Molecules...................... 221 Protein Structures and Assemblies................................. 222 7.4.1 Protein Filaments............................................... 224 7.4.2 The Cytoskeleton............................................... 225 7.4.3 Semi-flexibility and Persistence Length............227 7.4.4 Microtubules and Molecular Motors: An 7.4.5 The Nucleic Acids............................................... 231 7.4.6 The Structure of the Nucleic Acids.....................231 Example of a Biological Active Nematic............230 7.5 Experimental Techniques.................................................233 7.5.1 Studying Membrane
Behavior..........................233 7.5.1.1 Lipid Vesicles........................................ 233 7.5.1.2 Imaging Membranes Using Atomic Force Microscopy................. 235 7.5.2 Fluorescence Microscopy..................................236 7.5.3 Confocal Fluorescence Microscopy.................. 240 7.5.4 Other FluorescenceTechniques........................242 7.5.5 Transmission Electron Microscopy on Soft 7.5.6 X-ray Scattering from Biological Assemblies.. .244 7.5.7 Examples of X-ray Scattering on Soft Biological Structures..........................................244 Biological Structures..........................................246 7.5.7.1 Lipid Bilayers........................................246 7.57.2 Protein Filaments............................... 248
xii Contents 7.5.8 Nuclear Magnetic Resonance in Biology..............250 Questions.....................................................................................252 References...................................................................................253 Further Reading.......................................................................... 253 Glossary..................................................................................................... 255 Appendix A: The Fourier Transform.......................................................263 Appendix B: Physical Constants and Conversions............................... 265 Appendix C: Laue Scattering Theory..................................................... 267 Appendix D: Entropy and Thermodynamic Equilibrium..................... 271 Appendix E: The Amino Acids................................................................ 275 Index.......................................................................................................... 277
This revised edition continues to provide the most approachable introduction to the structure, characteristics, and everyday applications of soft matter. It begins with a substantially revised overview of the underlying physics and chemistry common to soft materials. Subsequent chapters comprehensively address the different classes of soft materials, from liquid crystals to surfac tants, polymers, colloids, and biomaterials, with vivid, full-color illustrations throughout. There are new worked examples throughout, new problems, some deeper mathematical treatment, and new sections on key topics such as diffusion, active matter, liquid crystal defects, surfactant phases and more. • Introduces the science of soft materials, experimental methods used in their study, and wide-ranging applications in everyday life • Provides brand new worked examples throughout, in addition to expanded chapter problem sets and an updated glossary • Includes expanded mathematical content and substantially revised introductory chapters This book will provide a comprehensive introductory resource to both un dergraduate and graduate students discovering soft materials for the first time and is aimed at students with an introductory college background in physics, chemistry or materials science. Linda Hirst is Professor of Physics at the University of California, Merced where she has been a faculty member since 2008 after spending three years on the faculty in the Physics Department at Florida State University. Born in Liverpool in the UK, she obtained her BSc and PhD in Physics from the University
of Manchester and spent time as a postdoctoral researcher in the Dept, of Materials Science and Engineering at the University of California, Santa Barbara. Professor Hirst s research interests cover a variety of topics in soft-condensed matter physics, with particular interests in soft biomaterials and liquid crystals. Prof. She has a strong interest in promoting study of soft matter and its importance to students, scientists and the public. Physics CRC Press Taylor Francis Croup an Informa business www.crcpress.com CRC Press titles are available as eBook editions in a range of digital formats 9781138724440
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| spelling | Hirst, Linda S. Verfasser (DE-588)1106874463 aut Fundamentals of soft matter science Linda S. Hirst Second edition Boca Raton CRC Press, Taylor & Francis Group [2020] © 2020 xix, 283 Seiten Illustrationen, Diagramme (farbig) txt rdacontent n rdamedia nc rdacarrier Chemie Soft condensed matter SCIENCE / Chemistry / General bisacsh SCIENCE / Solid State Physics bisacsh TECHNOLOGY & ENGINEERING / Material Science bisacsh Weiche Materie (DE-588)4609142-7 gnd rswk-swf Weiche Materie (DE-588)4609142-7 s DE-604 Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=031486530&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=031486530&sequence=000003&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
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