Elastic behavior of polymer melts: rheology and processing
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| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Munich
Hanser Publishers
[2019]
Cincinnati Hanser Publications |
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| Beschreibung: | XX, 274 Seiten Illustrationen, Diagramme 25 cm Enthält: Online-Ressource |
| ISBN: | 9781569907542 1569907544 |
Internformat
MARC
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| 100 | 1 | |a Münstedt, Helmut |d 1941- |e Verfasser |0 (DE-588)108019659 |4 aut | |
| 245 | 1 | 0 | |a Elastic behavior of polymer melts |b rheology and processing |c Helmut Münstedt |
| 264 | 1 | |a Munich |b Hanser Publishers |c [2019] | |
| 264 | 1 | |a Cincinnati |b Hanser Publications | |
| 300 | |a XX, 274 Seiten |b Illustrationen, Diagramme |c 25 cm |e Enthält: Online-Ressource | ||
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Datensatz im Suchindex
| _version_ | 1804180341723758592 |
|---|---|
| adam_text | CONTENTS
PREFACE
............................................................................................
V
ABOUT
THE
AUTHOR
.............................................................................
VII
LIST
OF
SYMBOLS
USED
IN
THE
BOOK
.................................................
IX
1
INTRODUCTION
.............................................................................
1
1.1
REFERENCES
...................................................................................................
2
2
PHENOMENOLOGICAL
EVIDENCE
OF
ELASTICITY
...............................
3
2.1
EFFECTS
DUE
TO
NORMAL
STRESSES
...................................................................
3
2.2
EXTRUDATE
SWELL
............................................................................................
4
2.3
CONTRACTION
FLOW
.........................................................................................
4
2.4
TIME
DEPENDENCE
.........................................................................................
5
2.5
REFERENCES
...................................................................................................
6
3
PRINCIPLES
OF
THE
DETERMINATION
OF
ELASTIC
PROPERTIES
.............
7
3.1
CREEP
RECOVERY
EXPERIMENT
AND
RETARDATION
SPECTRUM
.........................
7
3.2
RELAXATION
EXPERIMENT
AND
RELAXATION
SPECTRUM
..................................
11
3.3
DYNAMIC-MECHANICAL
EXPERIMENT
.............................................................
12
3.4
STRESSING
EXPERIMENT
.................................................................................
15
3.5
CAPILLARY
RHEOMETRY
...................................................................................
16
3.6
RECOVERABLE
ELONGATION
...............................................................................
18
3.7
REFERENCES
...................................................................................................
19
4
EXPERIMENTAL
BASICS
OF
VARIOUS
METHODS
FOR
MEASURING
THE
ELASTIC
BEHAVIOR
.................................................................
21
4.1
THERMAL
STABILITY
.........................................................................................
21
4.2
LINEARITY
AND
STATIONARITY
..........................................................................
23
4.2.1
CREEP
RECOVERY
EXPERIMENT
............................................................
23
4.2.2
RELAXATION
EXPERIMENT
.....................................................................
27
4.2.3
DYNAMIC-MECHANICAL
EXPERIMENTS
.................................................
27
4.2.4
STRESSING
EXPERIMENTS
.....................................................................
28
4.2.5
EXTRUDATE
SWELL
................................................................................
29
4.2.6
RECOVERABLE
ELONGATION
...................................................................
31
4.3
REFERENCES
....................................................................................................
34
5
DEPENDENCE
OF
ELASTIC
QUANTITIES
ON
EXPERIMENTAL
PARAMETERS
37
5.1
RECOVERABLE
COMPLIANCE
..............................................................................
37
5.1.1
STRESS
DEPENDENCE
..........................................................................
37
5.1.2
TEMPERATURE
DEPENDENCE
................................................................
38
5.2
RELAXATION
MODULUS
.....................................................................................
41
5.3
STORAGE
MODULUS
...........................................................................................
44
5.4
NORMAL
STRESS
DIFFERENCE
............................................................................
45
5.5
RECOVERABLE
ELONGATION
................................................................................
48
5.6
EXTRUDATE
SWELL
.............................................................................................
50
5.6.1
GENERAL
FEATURES
OF
EXTRUDATE
SWELL
.............................................
50
5.6.2
DETAILED
ANALYSIS
OF
EXTRUDATE
SWELL
.............................................
52
5.6.3
EXTRUDATE
SWELL
FOR
VARIOUS
DIE
GEOMETRIES
.................................
53
5.7
REFERENCES
....................................................................................................
54
6
DEPENDENCE
OF
ELASTIC
PROPERTIES
ON
MOLECULAR
STRUCTURE
....
57
6.1
ANALYSIS
OF
MOLECULAR
STRUCTURE
.................................................................
57
6.1.1
MOLAR
MASS
DISTRIBUTION
AND
ITS
CHARACTERISTIC
QUANTITIES
.........
57
6.1.2
BRANCHES
AND
THEIR
ANALYSIS
..........................................................
60
6.2
INFLUENCE
OF
MOLAR
MASS
..............................................................................
64
6.2.1
LINEAR
ELASTIC
PROPERTIES
.................................................................
64
6.2.2
NONLINEAR
ELASTIC
PROPERTIES
............................................................
66
6.3
INFLUENCE
OF
MOLAR
MASS
DISTRIBUTION
........................................................
68
6.3.1
LINEAR
ELASTIC
PROPERTIES
.................................................................
68
6.3.1.1
DEPENDENCE
ON
THE
POLYDISPERSITY
INDEX
.........................
69
6.3.1.2
EFFECT
OF
HIGH
MOLAR
MASS
COMPONENTS
...........................
73
6.3.2
NONLINEAR
ELASTIC
PROPERTIES
............................................................
77
6.4
INFLUENCE
OF
LONG-CHAIN
BRANCHING
............................................................
83
6.4.1
LINEAR
ELASTIC
PROPERTIES
.................................................................
83
6.4.1.1
LONG-CHAIN
BRANCHED
POLYSTYRENES
..................................
83
6.4.1.2
LONG-CHAIN
BRANCHED
POLYOLEFINS
......................................
84
6.4.1.3
TEMPERATURE
DEPENDENCE
OF
LINEAR
ELASTIC
COMPLIANCES
86
6.4.1.4
RETARDATION
SPECTRA
............................................................
88
6.4.1.5
RELAXATION
SPECTRA
..............................................................
92
6.4.2
NONLINEAR
ELASTIC
PROPERTIES
............................................................
94
6.4.2.1
RECOVERABLE
COMPLIANCE
.....................................................
94
6.4.2.2
DAMPING
FUNCTION
..............................................................
95
6.4.2.3
EXTRUDATE
SWELL
...................................................................
96
6.4.2.4
RECOVERABLE
ELONGATION
......................................................
99
6.5
INFLUENCE
OF
MECHANICAL
PRETREATMENTS
ON
ELASTIC
PROPERTIES
................
101
6.5.1
EXTRUDATE
SWELL
OF
LONG-CHAIN
BRANCHED
POLYETHYLENES
.............
101
6.5.2
ELASTIC
PROPERTIES
OF
A
LONG-CHAIN
BRANCHED
AND
A
LINEAR
POLYPROPYLENE
...................................................................................
104
6.6
REFERENCES
...................................................................................................
106
7
MODELS
FOR
THE
DESCRIPTION
OF
ELASTIC
EFFECTS
.........................
ILL
7.1
SPRING-DASHPOT
MODELS
................................................................................
ILL
7.2
ENTANGLEMENTS
............................................................................................
114
7.3
DOI-EDWARDS
THEORY
...................................................................................
116
7.4
THEORY
FOR
LONG-CHAIN
BRANCHED
POLYMERS
.............................................
117
7.5
MIXING
RULE
FOR
THE
LINEAR
STEADY-STATE
RECOVERABLE
COMPLIANCE
OF
BLENDS
.......................................................................................................
119
7.6
NUMERICAL
DESCRIPTION
OF
THE
NONLINEAR
BEHAVIOR
OF
THE
STEADY-STATE
RECOVERABLE
COMPLIANCE
..............................................................................
123
7.7
NUMERICAL
DESCRIPTIONS
OF
EXTRUDATE
SWELL
.............................................
125
7.7.1
ENTRY
REGION
.....................................................................................
125
7.7.2
FLOW
WITHIN
THE
CAPILLARY
...............................................................
126
7.8
REFERENCES
...................................................................................................
128
8
ELASTIC
BEHAVIOR
AND
ITS
RELEVANCE
FOR
VARIOUS
APPLICATIONS
..
131
8.1
CREEP
RECOVERY
EXPERIMENTS
AS
A
CONTRIBUTION
TO
MOLECULAR
ANALYSIS
.
131
8.1.1
CREEP
RECOVERY
COMPLIANCE
............................................................
131
8.1.2
RETARDATION
SPECTRA
..........................................................................
133
8.1.3
CALCULATION
OF
DYNAMIC-MECHANICAL
QUANTITIES
FROM
RETARDATION
SPECTRA
..........................................................................
135
8.2
ELASTIC
PROPERTIES
AND
ENTRANCE
FLOW
PATTERNS
........................................
137
8.3
ELASTIC
BEHAVIOR
OF
REFINED
POLYETHYLENES
AND
THEIR
RELATION
TO
END-USE
PROPERTIES
.....................................................................................
140
8.3.1
APPLICATION-RELATED
PROPERTIES
OF
IUPAC
C
IN
COMPARISON
WITH
IUPAC
A
....................................................................................
141
8.3.2
OPTICAL
PROPERTIES
OF
VARIOUS
POLYETHYLENES
AFTER
MECHANICAL
PRETREATMENTS
................................................................
141
8.4
EXTRUDATE
SWELL
AS
A
QUANTITY
FOR
QUALITATIVE
MATERIAL
SPECIFICATIONS
..
142
8.5
REFERENCES
....................................................................................................
144
9
POLYMERIC
MATERIALS
WITH
MICROPARTICLES
.................................
147
9.1
GENERAL
EXPERIMENTAL
FEATURES
.................................................................
147
9.1.1
SLIP
AND
EDGE
FRACTURE
.....................................................................
147
9.1.2
YIELDING
.............................................................................................
148
9.2
GLASS
BEADS
AS
FILLERS
..................................................................................
150
9.2.1
DETERMINATION
OF
YIELD
STRESSES
......................................................
150
9.2.2
RECOVERABLE
STRAIN
............................................................................
153
9.2.3
COLLOIDAL
GLASSES
..............................................................................
155
9.2.4
MODEL
FOR
SUSPENDED
GLASS
BEADS
OF
MICROSIZE
...........................
155
9.2.5
DYNAMIC-MECHANICAL
MEASUREMENTS
.............................................
157
9.3
NORMAL
STRESS
DIFFERENCES
AND
RECOVERABLE
STRAIN
..................................
159
9.4
EXTRUDATE
SWELL
.............................................................................................
163
9.5
VARIOUS
MICROFILLERS
.....................................................................................
165
9.6
REFERENCES
....................................................................................................
165
10
POLYMERIC
MATERIALS
WITH
NANOPARTICLES
.................................
167
10.1
NANOPARTICLES
INVESTIGATED
.........................................................................
168
10.2
DYNAMIC-MECHANICAL
EXPERIMENTS
............................................................
171
10.2.1
DETERMINATION
OF
LINEAR
BEHAVIOR
...................................................
171
10.2.2
MELTS
WITH
VARIOUS
CONCENTRATIONS
OF
NANOPARTICLES
..................
172
10.3
CREEP
AND
CREEP
RECOVERY
EXPERIMENTS
...................................................
176
10.3.1
INFLUENCE
OF
A
PARTICLE
NETWORK
......................................................
176
10.3.2
NANOSILICA-FILLED
PMMA
AS
A
MODEL
SYSTEM
.................................
177
10.3.3
RETARDATION
SPECTRA
..........................................................................
179
10.4
MODEL
.............................................................................................................
180
10.4.1
EXPERIMENTAL
RESULTS
SUPPORTING
THE
MODEL
.................................
182
10.4.1.1
DEPENDENCE
OF
THE
RECOVERABLE
COMPLIANCE
ON
FILLER
SIZE
............................................................................
182
10.4.1.2
STRESS
DEPENDENCE
OF
THE
RECOVERABLE
COMPLIANCE
.......
182
10.5
TEMPERATURE
DEPENDENCE
OF
CREEP
AND
CREEP
RECOVERY
.......................
185
10.6
INFLUENCE
OF
THE
POLYMER
MATRIX
ON
THE
LINEAR
STEADY-STATE
RECOVERABLE
COMPLIANCE
..............................................................................
188
10.7
LINEAR
ELASTIC
PROPERTIES
OF
MELTS
WITH
VARIOUS
NANOFILLERS
....................
190
10.7.1
POLYMETHYLMETHACRYLATE
WITH
NANOCLAY
........................................
191
10.7.2
POLYMETHYLMETHACRYLATE
WITH
GRAPHITE
..........................................
192
10.7.3
POLYMETHYLMETHACRYLATE,
POLYCARBONATE,
AND
POLYPROPYLENE
WITH
CARBON
NANOTUBES
...................................................................
193
10.8
NONLINEAR
ELASTIC
PROPERTIES
.......................................................................
195
10.8.1
EXTRUDATE
SWELL
................................................................................
195
10.8.2
RECOVERABLE
ELONGATION
...................................................................
196
10.9
COMPARISON
OF
NONLINEAR
AND
LINEAR
ELASTIC
PROPERTIES
.........................
198
10.10
REFERENCES
...................................................................................................
198
11
IMMISCIBLE
POLYMER
BLENDS
.....................................................
201
11.1
LINEAR
ELASTIC
BEHAVIOR
...............................................................................
202
11.1.1
DYNAMIC-MECHANICAL
EXPERIMENTS
.................................................
202
11.1.2
RECOVERABLE
SHEAR
............................................................................
208
11.2
NONLINEAR
ELASTIC
BEHAVIOR
........................................................................
211
11.2.1
RECOVERABLE
ELONGATION
...................................................................
212
11.2.2
EXTRUDATE
SWELL
...............................................................................
215
11.3
REFERENCES
...................................................................................................
217
12
INFLUENCE
OF
ELASTIC
PROPERTIES
ON
PROCESSING
........................
219
12.1
MEASUREMENT
OF
ELASTIC
QUANTITIES
AT
HIGH
SHEAR
RATES
.........................
219
12.2
THE
ROLE
OF
EXTRUDATE
SWELL
IN
THE
SHAPE
OF
EXTRUDED
PARTS
..................
222
12.3
THE
ROLE
OF
EXTRUDATE
SWELL
IN
PELLETIZING
..................................................
223
12.4
THE
ROLE
OF
EXTRUDATE
SWELL
IN
ADDITIVE
MANUFACTURING
BY
MATERIAL
EXTRUSION
.......................................................................................
224
12.5
EXTRUDATE
SWELL
AND
EXTRUSION
THROUGH
AN
ANNULAR
DIE
.......................
225
12.6
EXTRUDATE
SWELL
OF
RECTANGULAR
DIES
..........................................................
228
12.7
INFLUENCE
OF
TENSILE
STRESS
ON
EXTRUDATE
SWELL
........................................
231
12.8
ELASTIC
PROPERTIES
OF
POLYMER
MELTS
AND
THEIR
RELATION
WITH
FILM
DRAWING
................................................................................................
233
12.8.1
BASIC
FEATURES
OF
FILM
DRAWING
......................................................
233
12.8.2
MODELS
FOR
THE
DRAWING
PROCESS
....................................................
234
12.8.3
DRAWING
EXPERIMENTS
ON
THREE
POLYPROPYLENES
...........................
236
12.9
DRAW
RESONANCE
...........................................................................................
238
12.9.1
FILM
DRAWING
....................................................................................
238
12.9.2
FIBER
SPINNING
..................................................................................
242
12.9.3
COMPARISON
WITH
RESULTS
FROM
THE
LITERATURE
...............................
243
12.10
REFERENCES
....................................................................................................
244
13
INFLUENCES
OF
PROCESSING
ON
MOLECULAR
ORIENTATION
AND
RECOVERABLE
STRAIN
...................................................................
247
13.1
GENERAL
INFLUENCE
OF
PROCESSING
..................................................................
247
13.2
MOLECULAR
ORIENTATION
AND
RECOVERABLE
STRAIN
.........................................
249
13.3
INJECTION-MOLDED
PARTS
FROM
AMORPHOUS
POLYMERS
.................................
252
13.3.1
RECOVERABLE
STRAIN
WITHIN
AN
INJECTION-MOLDED
PART
.....................
252
13.3.2
MECHANICAL
PROPERTIES
OF
INJECTION-MOLDED
PARTS
.........................
254
13.4
FILMS
FROM
SEMI-CRYSTALLINE
POLYMERS
......................................................
257
13.4.1
STRETCH
FILMS
.....................................................................................
258
13.4.2
SHRINK
FILMS
.....................................................................................
261
13.4.2.1
THERMAL
SHRINKAGE
OF
UNIAXIALLY
STRETCHED
FILMS
...........
262
13.4.2.2
SHRINKAGE
OF
MAXIALLY
STRETCHED
FILMS
.............................
263
13.4.3
ROLE
OF
MOLECULAR
ORIENTATION
FOR
APPLICATIONS
.............................
265
13.4.3.1
APPLICATIONS
OF
STRETCH
FILMS
.............................................
265
13.4.3.2
APPLICATIONS
OF
SHRINK
FILMS
.............................................
266
13.5
REFERENCES
....................................................................................................
267
INDEX
.................................................................................................
269
|
| any_adam_object | 1 |
| author | Münstedt, Helmut 1941- |
| author_GND | (DE-588)108019659 |
| author_facet | Münstedt, Helmut 1941- |
| author_role | aut |
| author_sort | Münstedt, Helmut 1941- |
| author_variant | h m hm |
| building | Verbundindex |
| bvnumber | BV046063220 |
| classification_rvk | UV 4100 ZM 5100 |
| classification_tum | WER 659f CHE 712f PHY 216f |
| ctrlnum | (OCoLC)1111819674 (DE-599)DNB1184414432 |
| discipline | Chemie / Pharmazie Physik Werkstoffwissenschaften Chemie Werkstoffwissenschaften / Fertigungstechnik |
| format | Book |
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| id | DE-604.BV046063220 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T08:34:14Z |
| institution | BVB |
| institution_GND | (DE-588)1064064051 |
| isbn | 9781569907542 1569907544 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-031444526 |
| oclc_num | 1111819674 |
| open_access_boolean | |
| owner | DE-210 DE-29T DE-12 DE-703 DE-91G DE-BY-TUM DE-83 |
| owner_facet | DE-210 DE-29T DE-12 DE-703 DE-91G DE-BY-TUM DE-83 |
| physical | XX, 274 Seiten Illustrationen, Diagramme 25 cm Enthält: Online-Ressource |
| publishDate | 2019 |
| publishDateSearch | 2019 |
| publishDateSort | 2019 |
| publisher | Hanser Publishers Hanser Publications |
| record_format | marc |
| spelling | Münstedt, Helmut 1941- Verfasser (DE-588)108019659 aut Elastic behavior of polymer melts rheology and processing Helmut Münstedt Munich Hanser Publishers [2019] Cincinnati Hanser Publications XX, 274 Seiten Illustrationen, Diagramme 25 cm Enthält: Online-Ressource txt rdacontent n rdamedia nc rdacarrier Rheologische Eigenschaft (DE-588)4366895-1 gnd rswk-swf Polymerschmelze (DE-588)4175247-8 gnd rswk-swf Rheologie (DE-588)4049828-1 gnd rswk-swf Elastizität (DE-588)4014159-7 gnd rswk-swf Polymere (DE-588)4046699-1 gnd rswk-swf PLAS2019 Polymerschmelze (DE-588)4175247-8 s Rheologische Eigenschaft (DE-588)4366895-1 s DE-604 Polymere (DE-588)4046699-1 s Elastizität (DE-588)4014159-7 s Rheologie (DE-588)4049828-1 s Hanser Publications (DE-588)1064064051 pbl Erscheint auch als Online-Ausgabe 978-1-56990-755-9 B:DE-101 application/pdf http://d-nb.info/1184414432/04 Inhaltsverzeichnis DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=031444526&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Münstedt, Helmut 1941- Elastic behavior of polymer melts rheology and processing Rheologische Eigenschaft (DE-588)4366895-1 gnd Polymerschmelze (DE-588)4175247-8 gnd Rheologie (DE-588)4049828-1 gnd Elastizität (DE-588)4014159-7 gnd Polymere (DE-588)4046699-1 gnd |
| subject_GND | (DE-588)4366895-1 (DE-588)4175247-8 (DE-588)4049828-1 (DE-588)4014159-7 (DE-588)4046699-1 |
| title | Elastic behavior of polymer melts rheology and processing |
| title_auth | Elastic behavior of polymer melts rheology and processing |
| title_exact_search | Elastic behavior of polymer melts rheology and processing |
| title_full | Elastic behavior of polymer melts rheology and processing Helmut Münstedt |
| title_fullStr | Elastic behavior of polymer melts rheology and processing Helmut Münstedt |
| title_full_unstemmed | Elastic behavior of polymer melts rheology and processing Helmut Münstedt |
| title_short | Elastic behavior of polymer melts |
| title_sort | elastic behavior of polymer melts rheology and processing |
| title_sub | rheology and processing |
| topic | Rheologische Eigenschaft (DE-588)4366895-1 gnd Polymerschmelze (DE-588)4175247-8 gnd Rheologie (DE-588)4049828-1 gnd Elastizität (DE-588)4014159-7 gnd Polymere (DE-588)4046699-1 gnd |
| topic_facet | Rheologische Eigenschaft Polymerschmelze Rheologie Elastizität Polymere |
| url | http://d-nb.info/1184414432/04 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=031444526&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT munstedthelmut elasticbehaviorofpolymermeltsrheologyandprocessing AT hanserpublications elasticbehaviorofpolymermeltsrheologyandprocessing |
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