Cover -- Title Page -- Copyright Page -- Contents -- Preface -- Part I: General Concepts and Photoelectrochemical Systems -- 1 Photoelectrochemical Reaction Engineering for Solar Fuels Production -- 1.1 Introduction -- 1.1.1 Undeveloped Power of Renewables -- 1.1.2 Comparison Solar Hydrogen from Dif...

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Bibliographische Detailangaben

1. Verfasser:	Demirci Sankir, Nurdan (VerfasserIn)
Format:	Elektronisch E-Book
Sprache:	English
Veröffentlicht:	Newark John Wiley & Sons, Incorporated 2019
Schriftenreihe:	Advances in Solar Cell Materials and Storage (ASCMS)
Online-Zugang:	TUM01 Volltext
Zusammenfassung:	Cover -- Title Page -- Copyright Page -- Contents -- Preface -- Part I: General Concepts and Photoelectrochemical Systems -- 1 Photoelectrochemical Reaction Engineering for Solar Fuels Production -- 1.1 Introduction -- 1.1.1 Undeveloped Power of Renewables -- 1.1.2 Comparison Solar Hydrogen from Different Sources -- 1.1.3 Economic Targets for Hydrogen Production and PEC Systems -- 1.1.4 Goals of Using Hydrogen -- 1.2 Theory and Classification of PEC Systems -- 1.2.1 Classification Framework for PEC Cell Conceptual Design -- 1.2.2 Classification Framework for Design of PEC Devices -- 1.2.3 Integrated Device vs PV + Electrolysis -- 1.3 Scaling Up of PEC Reactors -- 1.4 Reactor Designs -- 1.5 System-Level Design -- 1.6 Outlook -- 1.6.1 Future Reactor Designs -- 1.6.1.1 Perforated Designs -- 1.6.1.2 Membrane-Less and Microfluidic Designs -- 1.6.1.3 Redox-Mediated Systems -- 1.6.2 Avenues for Future Research -- 1.6.2.1 Intensification and Waste Heat Utilization -- 1.6.2.2 Usefulness of Oxidation and Coupled Process with Hydrogen Generation -- 1.7 Summary and Conclusions -- References -- 2 The Measurements and Efficiency Definition Protocols in Photoelectrochemical Solar Hydrogen Generation -- 2.1 Introduction -- 2.2 PEC Measurement -- 2.2.1 Measurements of Optical Properties -- 2.2.2 Polarization Curve Measurements -- 2.2.3 Photocurrent Transients Measurements -- 2.2.4 IPCE and APCE Measurements -- 2.2.5 Mott-Schottky Measurements -- 2.2.6 Measurement (Calculation) of Charge Separation Efficiency -- 2.2.7 Measurements of Charge Injection Efficiency -- 2.2.8 Gas Evolution Measurements -- 2.3 The Efficiency Definition Protocols in PEC Water Splitting -- 2.3.1 Solar-to-Hydrogen Conversion Efficiency -- 2.3.2 Applied Bias Photon-to-Current Efficiency -- 2.3.3 IPCE and APCE -- 2.4 Summary -- References 3 Photoelectrochemical Cell: A Versatile Device for Sustainable Hydrogen Production -- 3.1 Introduction -- 3.2 Photoelctrochemical (PEC) Cells -- 3.2.1 Solar-to-Hydrogen (STH) Conversion Efficiency -- 3.2.2 Applied Bias Photon-to-Current Efficiency (ABPE) -- 3.2.3 External Quantum Efficiency (EQE) or Incident Photon-to-Current Efficiency (IPCE) -- 3.2.4 Internal Quantum Efficiency (IQE) or a Absorbed Photon-to-Current Efficiency (APCE) -- 3.3 Monometal Oxide Systems for PEC H2 Generation -- 3.3.1 Titanium Dioxide (TiO2) -- 3.3.2 Zinc Oxide (ZnO) -- 3.3.3 Tungsten Oxide (WO3) -- 3.3.4 Iron Oxide (Fe2O3) -- 3.3.5 Bismuth Vandate (BiVO4) -- 3.4 Complex Nanostructures for PEC Splitting of Water -- 3.4.1 Plasmonic Metal Semiconductor Composite Photoelectrodes -- 3.4.2 Semiconductor Heterojunctions -- 3.4.3 Quantum Dots Sensitized Semiconductor Photoelectrodes -- 3.4.4 Synergistic Effect in Semiconductor Photoelectrodes -- 3.4.5 Biosensitized Semiconductor Photoelectrodes -- 3.4.6 Tandem Stand-Alone PEC Water-Splitting Device -- 3.5 Conclusion and Outlook -- Acknowledgments -- References -- 4 Hydrogen Generation from Photoelectrochemical Water Splitting -- 4.1 Introduction -- 4.2 Principle of Photoelectrochemical (PEC) Hydrogen Generation -- 4.3 Photoeletrode Materials -- 4.3.1 Photoanode Materials -- 4.3.1.1 TiO2-Based Photoelectrode -- 4.3.1.2 BiVO4-Based Photoelectrode -- 4.3.1.3 α-Fe2O3-Based Photoelectrode -- 4.3.2 Photocathode Materials -- 4.3.2.1 Copper-Based Chalcogenides-Based Photoelectrode -- 4.3.2.2 Silicon-Based Photoelectrode -- 4.3.2.3 Cu2O-Based Photoelectrode -- 4.3.2.4 III-V Group Materials -- 4.3.2.5 CdS-Based Photoelectrode -- 4.4 Advances in Photoelectrochemical (PEC) Hydrogen Generation -- 4.4.1 Monocomponent Catalyst -- 4.4.2 Functional Cocatalyst -- 4.4.3 Z-Scheme Catalyst -- 4.5 Pros and cons of photoelectrodes and photocatalysts 4.6 Conclusion and Outlook -- Acknowledgments -- References -- Part II: Photoactive Materials for Solar Hydrogen Generation -- 5 Hematite Materials for Solar-Driven Photoelectrochemical Cells -- 5.1 Introduction -- 5.2 Physical Properties of Hematite -- 5.2.1 Crystal Structure -- 5.2.2 Optical Properties -- 5.2.3 Electronic Properties -- 5.2.4 Band Structure -- 5.2.5 Overview of Hematite Bottlenecks and Corresponding Strategies -- 5.2.5.1 Addressing Poor Light Absorption Efficiency -- 5.2.5.2 Addressing Fast Charge Carrier Recombination -- 5.2.5.3 Addressing Sluggish Water Oxidation Kinetics -- 5.3 Experimental Strategies to Enhance the Photoactivity of Hematite -- 5.3.1 Nanostructuring -- 5.3.1.1 Direct Synthesis -- 5.3.1.2 In Situ Structural Transformation -- 5.3.1.3 "Locking" Nanostructures -- 5.3.2 Doping -- 5.3.2.1 Oxygen Vacancies -- 5.3.2.2 Foreign Ion Doping -- 5.3.3 Construction of Heterojunctions -- 5.3.3.1 Semiconducting Overlayers -- 5.3.3.2 Sensitization and Tandem Cells -- 5.3.3.3 OER Catalysts -- 5.3.3.4 Engineering of Current Collectors -- 5.4 Fundamental Characteristics of the PEC Behaviors of Hematite -- 5.4.1 Transient Absorption Spectroscopy -- 5.4.2 Effects of Morphology -- 5.4.3 Effect of Doping -- 5.4.3.1 Oxygen (O) Vacancies -- 5.4.3.2 n-type Dopants -- 5.4.3.3 p-type Dopants -- 5.4.3.4 Isovalent Dopants -- 5.4.3.5 Multiple Dopants -- 5.4.4 Effect of Water Oxidation Catalysts -- 5.4.4.1 Mechanism of Uncatalyzed Water Oxidation -- 5.4.4.2 Mechanism of Catalyzed Water Oxidation -- 5.4.5 Effect of Heterojunctions -- 5.4.5.1 Facilitating Charge Separation and Transfer -- 5.4.5.2 Surface Passivation -- 5.4.5.3 Back-Contact Engineering -- 5.5 Summary -- References -- 6 Design of Bismuth Vanadate-Based Materials: New Advanced Photoanodes for Solar Hydrogen Generation -- 6.1 Introduction
Beschreibung:	1 Online-Ressource
ISBN:	9781119460008