In situ characterization of plasmonic catalysis using surface-enhanced Raman scattering:
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1. Verfasser: | |
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Format: | Abschlussarbeit Buch |
Sprache: | English |
Veröffentlicht: |
Berlin
2018
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Schlagworte: | |
Online-Zugang: | Inhaltsverzeichnis Inhaltsverzeichnis |
Beschreibung: | XIII, 140 Seiten Illustrationen, Diagramme (farbig) |
Internformat
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245 | 1 | 0 | |a In situ characterization of plasmonic catalysis using surface-enhanced Raman scattering |c von M.S. Zhiyang Zhang |
264 | 1 | |a Berlin |c 2018 | |
300 | |a XIII, 140 Seiten |b Illustrationen, Diagramme (farbig) | ||
336 | |b txt |2 rdacontent | ||
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502 | |b Dissertation |c Humboldt-Universität zu Berlin |d 2018 | ||
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Datensatz im Suchindex
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adam_text | TABLE OF CONTENTS
ACKNOWLEDGMENTS................................................................................................................................V
ZUSAMMENFASSUNG.............................................................................................................................VII
ABSTRACT.............................................................................................................................................VIII
TABLE O F
CONTENTS...............................................................................................................................
IX
1. MOTIVATION AND GOALS O F THE
THESIS..............................................................................................
1
2. RESEARCH BACKGROUND
.
...................................................................................................................5
2.1 LOCALIZED SURFACE PLASMON
RESONANCE.....................................................................................
5
2.1.1 LSPR ON NOBLE METAL
NANOPARTICLES..................................................................................5
2.1.2 LSPR
DECAY..........................................................................................................................
6
2.2 PLASMONIC
CATALYSIS.....................................................................................................................7
2.2.1 BRIEF
INTRODUCTION................................................................................................................
7
2.2.2 MECHANISMS OF PLASMONIC
CATALYSIS..................................................................................8
2.2.3 CHALLENGES IN STUDYING PLASMONIC
CATALYSIS...................................................................10
2.3 SURFACE-ENHANCED RAMAN SCATTERING
(SERS).......................................................................
10
2.3.1 RAMAN SCATTERING AND
SERS............................................................................................10
2.3.2 SERS ENHANCEMENT
MECHANISM......................................................................................
12
2.4 SERS FOR STUDYING PLASMONIC CATALYSIS
.......................
15
2.4.1 BRIEF
INTRODUCTION..............................................................................................................
15
2.4.2 PHOTO-OXIDATION OF PATP
..........................................................................
15
2.4.2 PHOTO-REDUCTION O F
PNTP.................................................................................................
19
2.5 SERS MICROFLUIDICS FOR REACTION
MONITORING..................................................................
21
3. THE ROLE O F METAL IONS IN PLASMON-CATALYZED OXIDATION: A CASE STUDY
OF P ATP
DIMERIZATION.........................................................................................................................................
23
3.1 MAIN CONTENT O F THE
CHAPTER....................................................................................................
23
3.2
INTRODUCTION..............................................................................................................................
24
3.3 MATERIALS AND METHODS
25
3.3.1 MATERIALS.
25
3.3.2 SYNTHESIS O F GOLD NANOPARTICLES
.......................................................................................
25
3.3.3 SAMPLE PREPARATION USING GOLD NANOPARTICLES IN
SOLUTION.............................................25
3.3.4 SAMPLE PREPARATION USING IMMOBILIZED GOLD NANOPARTICLES
.........................................
25
3.3.5 RAMAN
EXPERIMENTS...........................................................................................................
25
3.3.6 XPS
EXPERIMENTS................................................................................................................26
3.4 AG+,
A
U
3+,
PT4+ AND HG2+ IONS INDUCE THE DIMERIZATION O F PATP TO
DMAB...................27
3.5 AG+ INDUCED FORMATION O F DMAB DEPENDS ON LASER INTENSITY AND
WAVELENGTH
............
.
31
3.6 AG+ INDUCED FORMATION O F DMAB IS FAVORED AT HIGH P H
....................................................33
3.7 FORMATION OF METAL OXIDE ON GOLD NANOPARTICLES
................................................................
35
3.8
CONCLUSIONS...............................................................................................................................
38
4. THE ROLE O F LIGANDS IN HOT ELECTRON REDUCTION: A CASE STUDY O F
P-NITROTHIOPHENOL
REDUCTION...............................................................................................................................................
39
4.1 MAIN CONTENT O F THE
CHAPTER.....................................................................................................39
4.2
INTRODUCTION...............................................................................................................................40
4.3 MATERIALS AND
METHODS.............................................................................................................
41
4.3.1
MATERIALS.............................................................................................................................41
4.3.2 PREPARATION O F GOLD, SILVER AND COPPER NANOPARTICLES
...................................................
41
4.3.3 PREPARATION O F IMMOBILIZED METAL
NANOPARTICLES..........................................................
41
4.3.4 RAMAN
EXPERIMENTS...........................................................................................................
41
4.4 CHARACTERIZATION O F THE METAL
NANOSTRUCTURES.......................................................................
42
4.5 SIX-ELECTRON REDUCTION O F PNTP ON GOLD, SILVER AND COPPER
NANOPARTICLES
.....................
44
4.6 SIX-ELECTRON REDUCTION IS FAVORED UNDER HIGH LASER INTENSITY
..............................................
46
4.7 LIGANDS ENHANCE HOT ELECTRON
REDUCTION................................................................................
50
4.8 THE PROPOSED MECHANISM O F HOT-ELECTRON INDUCED REDUCTION O F PN TP
..........................
53
4.9 HOT ELECTRON REDUCTION O F NITROBENZENE DERIVATIVES
.............................................................
55
4.10
CONCLUSIONS.............................................................................................................................56
5. THE PH-REVERSIBLE RESPONSE O F THE SERS SPECTRUM OF PATP ON SILVER
NANOPARTICLES: CL
IONS ENHANCE THE REDUCTION O F DMAB BY HOT ELECTRONS
...............................................................
57
5.1 MAIN CONTENT OF THE
CHAPTER...................................................................................................
57
5.2
INTRODUCTION...............................................................................................................................58
5.3 MATERIALS AND
METHODS.............................................................................................................
59
5.3.1
MATERIALS............................................................................................................................
59
5.3.2 PREPARATION O F SILVER AND GOLD NANOPARTICLES
.................................................................
59
5.3.3 DMAB FORMATION AND PHOTO-REDUCTION ON SILVER
NANOPARTICLES................................60
5.3.4 PNTP ASSAYS USING SILVER AND GOLD
NANOPARTICLES........................................................60
5.3.5 RAMAN
EXPERIMENTS...........................................................................................................60
5.4 THE DEPENDENCE O F THE PH-RELATED REVERSIBILITY O F THE SERS
SPECTRUM O F
PATP ON THE ACID
SPECIES..............................................................................................................
60
5.5 DMAB FORMATION ON SILVER DURING THE INCUBATION PROCESS
...............................................
62
5.6 THE ROLE O F LIGANDS IN THE PH-RELATED REVERSIBILITY O F THE PATP
SPECTRUM ON SILVER
......
64
5.7 PH IRREVERSIBILITY O F THE SERS SPECTRUM O F PATP ON GOLD
NANOPARTICLE
........................
65
5.8
CONCLUSIONS..............................................................................................................................
66
6. CATALYSIS BY METAL NANOPARTICLES WITH A PLUG-IN SERS MICROFLUIDIC
PLATFORM
.................
67
6.1 MAIN CONTENT O F THE
CHAPTER....................................................................................................
67
6.2
INTRODUCTION..............................................................................................................................
68
6.3 MATERIALS AND
METHODS.............................................................................................................
69
6.3.1 SYNTHESIS O F GOLD
NANOPARTICLES......................................................................................
69
6.3.2 PREPARATION O F IMMOBILIZED GOLD NANOPARTICLES ON GLASS ROD AND
PDMS BLOCK......69
6.3.3 FABRICATION OF THE PLUG-IN SERS MICROFLUIDICS
PLATFORM.............................................69
6.3.4 MODIFICATION IMMOBILIZED GOLD NANOPARTICLES WITH SERS
PROBES..............................70
6.3.5 RAMAN
EXPERIMENTS...........................................................................................................71
6.3.6 ESTIMATION O F SERS ENHANCEMENT
FACTOR.......................................................................
71
6.4 SCHEME FOR THE *PLUG-IN* OPTOFLUIDIC PLATFORM 71
6.5 GOLD-CATALYZED THE REDUCTION OF PNTP BY NABPL UNDER CONTROLLED
AQUEOUS CONDITION 74
6.5.1 OPTIMIZATION OF LASER INTENSITY TO AVOID SIDE PHOTOREACTION O F
PNTP
......................
74
6.5.2 SERS MONITORING O F REDUCTION O F PNTP TO PATP ON GOLD BY NABPL
.....................
75
6.5.3 ANALYSIS O F THE REACTION
KINETICS....................................................................................
77
6.5.4 PROPOSED MECHANISM FOR THE GOLD-CATALYZED REDUCTION O F PNTP BY
NABPU
...........
79
6.6 DIMERIZATION OF PATP UNDER CONTROLLED GAS ATMOSPHERE
..................................................
80
6.7
CONCLUSIONS...............................................................................................................................
82
7. MAPPING THE INHOMOGENEITY IN PLASMONIC CATALYSIS WITH SERS
MICROSPECTROSCOPY
.......
85
7.1 MAIN CONTENT O F THE
CHAPTER....................................................................................................85
7.2
INTRODUCTION...............................................................................................................................
86
7.3 MATERIALS AND
METHODS..............................................................................................................87
7.3.1
MATERIALS.............................................................................................................................
87
7.3.2 SYNTHESIS O F GOLD
NANOPARTICLES.......................................................................................87
7.3.3 PREPARATION O F IMMOBILIZED GOLD NANOPARTICLES WITH
PATP........................................87
7.3.4 RAMAN
MEASUREMENTS.......................................................................................................
88
7.3.5 LAMP EMISSION
SPECTRUM..................................................................................................88
7.3.6 ESTIMATION O F SERS ENHANCEMENT FACTOR
.......................................................................
88
7.4 CHARACTERIZATION O F METAL
NANOSTRUCTURES..............................................................................
88
7.5 PATP DIMERIZATION UNDER HIGH LASER INTENSITY
......................................................................
89
7.6 SERS MAPPING O F DMAB FORMATION DURING THE INCUBATION O F PATP WITH
THE CATALYST 92
7.6.1 EFFICIENT FORMATION O F DMAB IN AIR DURING THE INCUBATION
.......................................
92
7.6.2 EFFECTS O F INCUBATION TIME, O
2
IN AIR, ROOM LIGHT AND MOLECULAR COVERAGE................95
7.7
CONCLUSIONS...............................................................................................................................
99
8. APPLICATION O F PLASMONIC CATALYSIS IN SURFACE MOLECULAR PATTERNING
ON SUPPORTED METAL
NANOPARTICLES.......................................................................................................................................
101
8.1 MAIN CONTENT O F THE
CHAPTER...................................................................................................
101
8.2
INTRODUCTION.............................................................................................................................
102
8.3 MATERIALS AND METHODS
103
8.3.1
MATERIALS..........................................................................................................................
103
8.3.2 FABRICATION O F
NANOPARTICLES...........................................................................................103
8.3.3 FUNCTIONALIZATION O F MONOLAYER ORGANIC MOLECULES ON IMMOBILIZED
NANOPARTICLES..............................................................................................................................103
8.3.4 RAMAN
MEASUREMENTS.....................................................................................................103
8.4 CHARACTERIZATION O F IMMOBILIZED GOLD NANOPARTICLES
.........................................................
104
8.5 PASSIVATION PATTERNING O F PATP VIA PLASMON-CATALYZED OXIDATION
................
104
8.6 ACTIVATION PATTERNING O F PATP VIA PLASMON-CATALYZED REDUCTION
...................................
106
8.7 SERS IMAGING OF DM AB PATTERNS O F DIFFERENT SHAPES FOR INFORMATION
STORAGE
...........
107
8.8 REWRITING OF THE
PATTERN.........................................................................................................
109
8.9
CONCLUSIONS.............................................................................................................................110
9. SUMMARY AND
OUTLOOK............................................................................................................I
L L
BIBLIOGRAPHY.....................................................................................................................................115
LIST O F
FIGURES...................................................................................................................................
130
LIST O F
SCHEMES.................................................................................................................................
133
LIST O F
ABBREVIATIONS........................................................................................................................
134
CURRICULUM
VITAE...............................................................................................................................135
PUBLICATIONS.......................................................................................................................................
137
DECLARATION.........................................................................................................................................140
|
any_adam_object | 1 |
author | Zhang, Zhiyang 1988- |
author_GND | (DE-588)1169414907 |
author_facet | Zhang, Zhiyang 1988- |
author_role | aut |
author_sort | Zhang, Zhiyang 1988- |
author_variant | z z zz |
building | Verbundindex |
bvnumber | BV045331378 |
classification_rvk | VK 5577 |
ctrlnum | (OCoLC)1090113721 (DE-599)DNB1169168116 |
discipline | Chemie / Pharmazie |
format | Thesis Book |
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indexdate | 2024-07-10T08:15:07Z |
institution | BVB |
language | English |
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physical | XIII, 140 Seiten Illustrationen, Diagramme (farbig) |
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spelling | Zhang, Zhiyang 1988- Verfasser (DE-588)1169414907 aut In situ characterization of plasmonic catalysis using surface-enhanced Raman scattering von M.S. Zhiyang Zhang Berlin 2018 XIII, 140 Seiten Illustrationen, Diagramme (farbig) txt rdacontent n rdamedia nc rdacarrier Dissertation Humboldt-Universität zu Berlin 2018 Aminothiophenol (DE-588)4502546-0 gnd rswk-swf Oberflächenverstärkter Raman-Effekt (DE-588)4172264-4 gnd rswk-swf Oberflächenplasmonresonanz (DE-588)4737046-4 gnd rswk-swf Heterogene Katalyse (DE-588)4123377-3 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Heterogene Katalyse (DE-588)4123377-3 s Oberflächenplasmonresonanz (DE-588)4737046-4 s Oberflächenverstärkter Raman-Effekt (DE-588)4172264-4 s Aminothiophenol (DE-588)4502546-0 s DE-604 B:DE-101 application/pdf http://d-nb.info/1169168116/04 Inhaltsverzeichnis DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030718229&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
spellingShingle | Zhang, Zhiyang 1988- In situ characterization of plasmonic catalysis using surface-enhanced Raman scattering Aminothiophenol (DE-588)4502546-0 gnd Oberflächenverstärkter Raman-Effekt (DE-588)4172264-4 gnd Oberflächenplasmonresonanz (DE-588)4737046-4 gnd Heterogene Katalyse (DE-588)4123377-3 gnd |
subject_GND | (DE-588)4502546-0 (DE-588)4172264-4 (DE-588)4737046-4 (DE-588)4123377-3 (DE-588)4113937-9 |
title | In situ characterization of plasmonic catalysis using surface-enhanced Raman scattering |
title_auth | In situ characterization of plasmonic catalysis using surface-enhanced Raman scattering |
title_exact_search | In situ characterization of plasmonic catalysis using surface-enhanced Raman scattering |
title_full | In situ characterization of plasmonic catalysis using surface-enhanced Raman scattering von M.S. Zhiyang Zhang |
title_fullStr | In situ characterization of plasmonic catalysis using surface-enhanced Raman scattering von M.S. Zhiyang Zhang |
title_full_unstemmed | In situ characterization of plasmonic catalysis using surface-enhanced Raman scattering von M.S. Zhiyang Zhang |
title_short | In situ characterization of plasmonic catalysis using surface-enhanced Raman scattering |
title_sort | in situ characterization of plasmonic catalysis using surface enhanced raman scattering |
topic | Aminothiophenol (DE-588)4502546-0 gnd Oberflächenverstärkter Raman-Effekt (DE-588)4172264-4 gnd Oberflächenplasmonresonanz (DE-588)4737046-4 gnd Heterogene Katalyse (DE-588)4123377-3 gnd |
topic_facet | Aminothiophenol Oberflächenverstärkter Raman-Effekt Oberflächenplasmonresonanz Heterogene Katalyse Hochschulschrift |
url | http://d-nb.info/1169168116/04 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030718229&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
work_keys_str_mv | AT zhangzhiyang insitucharacterizationofplasmoniccatalysisusingsurfaceenhancedramanscattering |
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