Lewis acidic alkali metal and aluminium complexes: synthesis, reactivity and homogeneous catalysis:
Saved in:
| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Aachen
Mainz, G
2018
|
| Series: | Aachener Beiträge zur Chemie
129 |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | 130 Seiten Graphiken, Diagramme 21 cm x 14.8 cm, 191 g |
| ISBN: | 9783958862432 3958862438 |
Staff View
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Record in the Search Index
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| adam_text | TABLE OF CONTENTS
A. INTRODUCTION
A. 1 MOLECULAR ALKALI METAL COMPLEXES 1
A. 1.1 ORGANOMETALLIC SUPERBASES 3
A. 1.2 BOROHYDRIDES OF ALKALI METALS 4
A. 1.3 ALKALI METAL ORGANOPEROXIDES 6
A. 1.4 CATALYTIC APPLICATION OF ALKALI METAL COMPLEXES 7
A. 2 RING-OPENING OF CYCLIC ETHERS 9
A. 3 TITANIUM CARBENE COMPLEXES 10
A.4 AIMS AND SCOPE OF THIS THESIS 12
A. 5 REFERENCES AND NOTES 13
B. RESULTS AND DISCUSSION 18
B. L ALKALI METAL HYDRIDOTRIPHENYLBORATES [(L)M][HBPH3] (M = LI, NA, K)
18
B. 1.1 INTRODUCTION 18
B. 1.2 RESULTS AND DISCUSSION 18
B .L.2.1 HYDROBORATION CATALYSIS BY [(L)M][HBPH3] (M = LI, NA, K) 18
B.1.2.2 LIGAND INFLUENCE ON THE HYDROBORATION OF BENZOPHENONE 25
B .L.2.3 MECHANISTIC INVESTIGATION 33
B .L.3 CONCLUSION 44
B.L.4 EXPERIMENTAL SECTION 45
B.1.5 REFERENCES AND NOTES 61
B.2 MONONUCLEAR ALKALI METAL ORGANOPEROXIDES 65
B.2.1 INTRODUCTION 65
B.2.2 RESULTS AND DISCUSSION 65
B.2.2.1 SYNTHESIS AND CHARACTERIZATION 65
B.2.3 CONCLUSION 71
B.2.4 EXPERIMENTAL SECTION 71
B.2.5 REFERENCES AND NOTES 75
B.3 RING-OPENING OF THE BY LITHIUM AMIDE WITH A PENDANT SIH BOND 77
B.3.1 INTRODUCTION 77
B.3.2 RESULTS AND DISCUSSION 77
B.3.2.1 SYNTHESIS AND CHARACTERIZATION 77
B.3.2.2 RING-OPENING OF THE 80
B.3.3 CONCLUSION 83
B.3.4 EXPERIMENTAL SECTION 84
B.3.5 REFERENCES AND NOTES 90
B.4 RING-OPENING OF THE BY AN ALUMINUM HYDRIDOTRIPHENYLBORATE 92
B.4.1 INTRODUCTION 92
B.4.2 RESULTS AND DISCUSSION 92
B.4.2.1 SYNTHESIS AND CHARACTERIZATION 92
B.4.2.2 CATALYTIC RING-OPENING OF THE AND THP 98
B.4.3 CONCLUSION 98
B.4.4 EXPERIMENTAL SECTION 99
B.4.5 REFERENCES AND NOTES 101
B.5 TITANIUM CARBENE COMPLEXES STABILIZED BY [MESTACDM] (M - LI, NA, K)
104
B.5.1 INTRODUCTION 104
B.5.2 RESULTS AND DISCUSSION 104
B.5.2.1 SYNTHESIS AND CHARACTERIZATION 104
B.5.2.2 REACTIVITY STUDIES 110
B.5.3 CONCLUSION 113
B.5.4 EXPERIMENTAL SECTION 114
B.5.5 REFERENCES AND NOTES 118
C. SUMMARY 121
D. APPENDIX 124
D. 1 GENERAL EXPERIMENTAL DETAILS 124
D.1.1 REFERENCES AND NOTES 125
D.2 LIST OF ABBREVIATIONS 125
D.3 LIST OF COMPOUNDS 126
D.4 CURRICULUM VITAE 128
D.5 PUBLICATIONS 129
D.5.1 PUBLICATION IN PEER-REVIEWED JOURNALS 129
D.5.2 CONFERENCE CONTRIBUTIONS 130
|
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| illustrated | Not Illustrated |
| indexdate | 2024-07-10T08:13:16Z |
| institution | BVB |
| institution_GND | (DE-588)1065499698 |
| isbn | 9783958862432 3958862438 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-030652168 |
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| owner | DE-83 |
| owner_facet | DE-83 |
| physical | 130 Seiten Graphiken, Diagramme 21 cm x 14.8 cm, 191 g |
| publishDate | 2018 |
| publishDateSearch | 2018 |
| publishDateSort | 2018 |
| publisher | Mainz, G |
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| series | Aachener Beiträge zur Chemie |
| series2 | Aachener Beiträge zur Chemie |
| spelling | Osseili, Hassan 1986- Verfasser (DE-588)1167960971 aut Lewis acidic alkali metal and aluminium complexes: synthesis, reactivity and homogeneous catalysis Hassan Osseili 201809 Aachen Mainz, G 2018 130 Seiten Graphiken, Diagramme 21 cm x 14.8 cm, 191 g txt rdacontent n rdamedia nc rdacarrier Aachener Beiträge zur Chemie 129 Homogene Katalyse (DE-588)4160579-2 gnd rswk-swf Alkalimetallkomplexe (DE-588)4226069-3 gnd rswk-swf Aluminiumkomplexe (DE-588)4325724-0 gnd rswk-swf Anorganische Chemie Chemisches Institut Lewis-Säure-Base-Konzept RWTH Aachen molecular catalysis (DE-588)4113937-9 Hochschulschrift gnd-content Homogene Katalyse (DE-588)4160579-2 s Alkalimetallkomplexe (DE-588)4226069-3 s Aluminiumkomplexe (DE-588)4325724-0 s DE-604 Verlag Mainz (DE-588)1065499698 pbl Aachener Beiträge zur Chemie 129 (DE-604)BV012745008 129 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030652168&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Osseili, Hassan 1986- Lewis acidic alkali metal and aluminium complexes: synthesis, reactivity and homogeneous catalysis Aachener Beiträge zur Chemie Homogene Katalyse (DE-588)4160579-2 gnd Alkalimetallkomplexe (DE-588)4226069-3 gnd Aluminiumkomplexe (DE-588)4325724-0 gnd |
| subject_GND | (DE-588)4160579-2 (DE-588)4226069-3 (DE-588)4325724-0 (DE-588)4113937-9 |
| title | Lewis acidic alkali metal and aluminium complexes: synthesis, reactivity and homogeneous catalysis |
| title_auth | Lewis acidic alkali metal and aluminium complexes: synthesis, reactivity and homogeneous catalysis |
| title_exact_search | Lewis acidic alkali metal and aluminium complexes: synthesis, reactivity and homogeneous catalysis |
| title_full | Lewis acidic alkali metal and aluminium complexes: synthesis, reactivity and homogeneous catalysis Hassan Osseili |
| title_fullStr | Lewis acidic alkali metal and aluminium complexes: synthesis, reactivity and homogeneous catalysis Hassan Osseili |
| title_full_unstemmed | Lewis acidic alkali metal and aluminium complexes: synthesis, reactivity and homogeneous catalysis Hassan Osseili |
| title_short | Lewis acidic alkali metal and aluminium complexes: synthesis, reactivity and homogeneous catalysis |
| title_sort | lewis acidic alkali metal and aluminium complexes synthesis reactivity and homogeneous catalysis |
| topic | Homogene Katalyse (DE-588)4160579-2 gnd Alkalimetallkomplexe (DE-588)4226069-3 gnd Aluminiumkomplexe (DE-588)4325724-0 gnd |
| topic_facet | Homogene Katalyse Alkalimetallkomplexe Aluminiumkomplexe Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030652168&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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