Aerosol synthesis and characterization of semiconducting nanoparticles from the elements Si and Ge for the application in printable electronics: = Aerosolsynthese und Charakterisierung halbleitender Nanopartikeln aus den Elementen Si und Ge zur Anwendung in der druckbaren Elektronik
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1. Verfasser: | |
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Format: | Abschlussarbeit Buch |
Sprache: | English |
Veröffentlicht: |
Erlangen ; Nürnberg
[2018]
|
Schlagworte: | |
Online-Zugang: | Inhaltsverzeichnis Inhaltsverzeichnis |
Beschreibung: | 180 Seiten Illustrationen, Diagramme 21 cm |
Internformat
MARC
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245 | 1 | 0 | |a Aerosol synthesis and characterization of semiconducting nanoparticles from the elements Si and Ge for the application in printable electronics |b = Aerosolsynthese und Charakterisierung halbleitender Nanopartikeln aus den Elementen Si und Ge zur Anwendung in der druckbaren Elektronik |c vorgelegt von Christian Mehringer |
246 | 1 | 3 | |a Aerosolsynthese und Charakterisierung halbleitender Nanopartikeln aus den Elementen Si und Ge zur Anwendung in der druckbaren Elektronik |
246 | 1 | 1 | |a Aerosolsynthese und Charakterisierung halbleitender Nanopartikeln aus den Elementen Si und Ge zur Anwendung in der druckbaren Elektronik |
264 | 1 | |a Erlangen ; Nürnberg |c [2018] | |
300 | |a 180 Seiten |b Illustrationen, Diagramme |c 21 cm | ||
336 | |b txt |2 rdacontent | ||
337 | |b n |2 rdamedia | ||
338 | |b nc |2 rdacarrier | ||
502 | |b Dissertation |c Friedrich-Alexander-Universität Erlangen-Nürnberg |d 2018 | ||
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999 | |a oai:aleph.bib-bvb.de:BVB01-030589281 |
Datensatz im Suchindex
_version_ | 1804178904187928576 |
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adam_text | CONTENTS
1
INTRODUCTION..............................................................................................1
2
THEORY.....................................................................................................
3
2.1 PARTICLE SYNTHESIS IN THE GAS
PHASE...................................................................................3
2.1.1
PYROLYSIS..........................................................................................................................5
2.1.1.1 PYROLYSIS OF
MONOSILANE..............................................................................................
5
2.1.1.2 PYROLYSIS O F
MONOGERMANE.........................................................................................
6
2.1.1.3 PYROLYSIS OF
PHOSPHANE...............................................................................................
7
2.1.1.4 PYROLYSIS OF
DIBORANE...................................................................................................8
2.1.2
NUCLEATION.........................................................................................................................9
2.1.2.1 HOMOGENEOUS
NUCLEATION............................................................................................
9
2.1.2.2 HETEROGENEOUS
NUCLEATION..........................................................................................11
2.1.3
GROWTH............................................................................................................................
12
2.1.3.1 ADSORPTION LAYER
THEORIES...........................................................................................13
2.1.3.2 DIFFUSION
MODEL.........................................................................................................13
2.1.3.3 AGGLOMERATION AND SINTERING
.....................................................................................
15
2.2 THE SEMICONDUCTORS GE AND S
I.....................................................................................16
2.3 IMPURITY
DOPING.............................................................................................................19
2.3.1 DIFFUSION OF
IMPURITIES.................................................................................................21
2.3.2 SOLUBILITY OF
DOPANTS.....................................................................................................25
2.3.3 ADDITIONAL INFLUENCES ON DOPANT
LOCALIZATION..............................................................26
2.4 THIN FILM FIELD EFFECT
TRANSISTORS....................................................................................27
3
EXPERIMENTAL..........................................................................................31
3.1 EXPERIMENTAL REACTOR AND SAMPLE PREPARATION
..............................................................
31
3.1.1 CONCEPT AND
SET-UP.......................................................................................................
32
3.1.2 GAS SUPPLY AND SAFETY PRECAUTIONS
...............................................................................
34
3.1.3 LOW PRESSURE
IMPACTOR...................................................................................................37
3.1.4
MINI-FILTER.....................................................................................................................
38
3.1.5 FABRICATION OF DISPERSIONS, THIN FILMS AND
DEVICES......................................................40
3.2 CHARACTERIZATION
METHODS..............................................................................................
41
3.2.1
SEM...............................................................................................................................41
3.2.2
TEM...............................................................................................................................42
3.2.3 RAMAN
SPECTROSCOPY.....................................................................................................43
3.2.4
XRD...............................................................................................................................45
3.2.5 GAS ADSORPTION MEASUREMENTS
.....................................................................................
45
3.2.6
DR-UV/VIS...................................................................................................................
46
3.2.7
DLS................................................................................................................................46
3.2.8
ICP-OES.......................................................................................................................
47
3.2.9 CONTACT ANGLE
MEASUREMENTS.........................................................................................48
3.2.10 DEVICE CHARACTERIZATION BY ELECTRONIC MEASUREMENTS
...................................................
48
3.3
CHEMICALS.................................................................................................
....................
49
3.3.1 GAS PHASE
SYNTHESIS..............................................................
49
3.3.2 DISPERSION
FORMATION.....................................................................................................49
4 ANISOTROPIC GE-SI HYBRID NANOPARTICLES
................................................
53
4.1 SI CARRIER PARTICLE
SYNTHESIS............................................................................................55
4.2 GE DEPOSITION ON SI CARRIER NANOPARTICLES
........... .
........................................................55
4.2.1 PATCHY PARTICLE
SYNTHESIS................................................................................................56
4.2.2 JANUS-LIKE NANOPARTICLE
SYNTHESIS..................................................................................
58
4.3 GROWTH REGIMES IN PATCHY AND JANUS-LIKE NANOPARTICLE SYNTHESIS
..............................
60
4.4 DEFECT STRUCTURE
ANALYSIS................................................................................................61
4.5 RAMAN
SPECTROSCOPY......................................................................................................66
5 GE AND GE-SI ALLOY/CORE-SHELL NANOPARTICLE SYNTHESIS
.
..........................67
5.1 SYNTHESIS OF GE N P
S.......................................................................................................68
5.1.1 SYNTHESIS IN HW
R1.......................................................................................................68
5.1.2 SEEDED SYNTHESIS IN HWR II
......
..................................................................................71
5.2 GE-SI GROWTH MODE DIAGRAM
.....
...............................................................................
76
5.2.1
MORPHOLOGY...................................................................................................................
79
5.2.2 RAMAN
ANALYSIS..............................................................................................................
79
5.3 GE-SI ALLOY NP
SYNTHESIS...............................................................................................82
5.3.1 COMPOSITION, MORPHOLOGY AND OPTICAL BAND
GAP..........................................................82
5.3.2 GE-SI ALLOY FORMATION
MECHANISM................................................................................
87
5.4 GE-SI CORE-SHELL NC
SYNTHESIS......................................................................................
88
5.4.1 MORPHOLOGY AND
ARCHITECTURE..........................................................................................88
5.4.2 GE-SI CORE-SHELL NP FORMATION
MECHANISM..................................................................92
6 DOPED
NANOPARTICLES..............................................................................95
6.1 SEEDED SYNTHESIS OF SI
NPS...............................................................................
96
6.2 PHOSPHORUS DOPING (N-DOPING) OF SI
NPS...................................................................100
6.2.1 EXPERIMENTAL
OBSERVATIONS..........................................................................................100
6.2.2
DISCUSSION.....................................................................................................................103
6.3 BORON DOPING (P-DOPING) OF SI
NPS..............................................................................107
7 FABRICATION OF DISPERSIONS, THIN FILMS AND DEVICES
.............................
109
7.1 GERMANIUM N P
S..........................................................................................................
109
7.1.1 GENP
DISPERSIONS.......................................................................................................
110
7.1.2 GE THIN FILM
FORMATION..................................................................................................
112
7.1.3 GE DEVICE
CHARACTERISTICS.............................................................................................118
7.2 GE-SI ALLOY N P
S.............................................................................................................121
7.2.1 GE-SI ALLOY NP
DISPERSIONS..........................................................................................121
7.2.2 GE-SI ALLOY THIN FILM FORMATION
..................................................................................
126
7.2.3 LASER POST PROCESSING AND GE-SI ALLOY DEVICE
CHARACTERISTICS....................................128
8 SUMMARY AND OUTLOOK
.........................................................................
135
9 LIST OF ABBREVIATIONS AND SYMBOLS
......................................................
137
10 LIST OF
FIGURES.......................................................................................141
11 LIST OF
TABLES........................................................................................153
12 LIST OF
REFERENCES.................................................................................155
A
APPENDICES..........................................................................................
167
A.L
XRD..............................................................................................................................
167
A.2
GESI..............................................................................................................................
174
A.2.1
SEEDING.........................................................................................................................
174
A.2.2
RAMAN...........................................................................................................................
177
A.2.3 COMPOSITIONAL OPTIMIZATION FOR ALLOY NP POWDER PRODUCTION
..................................
178
A.2.4 PSDS DERIVED FROM HRTEM
........................................................................................
178
A.3
SEM...............................................................................................................................179
|
any_adam_object | 1 |
author | Mehringer, Christian 1985- |
author_GND | (DE-588)1166812510 |
author_facet | Mehringer, Christian 1985- |
author_role | aut |
author_sort | Mehringer, Christian 1985- |
author_variant | c m cm |
building | Verbundindex |
bvnumber | BV045200300 |
ctrlnum | (OCoLC)1099709579 (DE-599)DNB1166464946 |
format | Thesis Book |
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language | English |
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owner_facet | DE-29T DE-29 DE-83 |
physical | 180 Seiten Illustrationen, Diagramme 21 cm |
publishDate | 2018 |
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spelling | Mehringer, Christian 1985- Verfasser (DE-588)1166812510 aut Aerosol synthesis and characterization of semiconducting nanoparticles from the elements Si and Ge for the application in printable electronics = Aerosolsynthese und Charakterisierung halbleitender Nanopartikeln aus den Elementen Si und Ge zur Anwendung in der druckbaren Elektronik vorgelegt von Christian Mehringer Aerosolsynthese und Charakterisierung halbleitender Nanopartikeln aus den Elementen Si und Ge zur Anwendung in der druckbaren Elektronik Erlangen ; Nürnberg [2018] 180 Seiten Illustrationen, Diagramme 21 cm txt rdacontent n rdamedia nc rdacarrier Dissertation Friedrich-Alexander-Universität Erlangen-Nürnberg 2018 Nanopartikel (DE-588)4333369-2 gnd rswk-swf Germanium (DE-588)4135644-5 gnd rswk-swf Halbleiterschicht (DE-588)4158812-5 gnd rswk-swf Silicium (DE-588)4077445-4 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Nanopartikel (DE-588)4333369-2 s Germanium (DE-588)4135644-5 s Silicium (DE-588)4077445-4 s Halbleiterschicht (DE-588)4158812-5 s DE-604 B:DE-101 application/pdf http://d-nb.info/1166464946/04 Inhaltsverzeichnis DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030589281&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
spellingShingle | Mehringer, Christian 1985- Aerosol synthesis and characterization of semiconducting nanoparticles from the elements Si and Ge for the application in printable electronics = Aerosolsynthese und Charakterisierung halbleitender Nanopartikeln aus den Elementen Si und Ge zur Anwendung in der druckbaren Elektronik Nanopartikel (DE-588)4333369-2 gnd Germanium (DE-588)4135644-5 gnd Halbleiterschicht (DE-588)4158812-5 gnd Silicium (DE-588)4077445-4 gnd |
subject_GND | (DE-588)4333369-2 (DE-588)4135644-5 (DE-588)4158812-5 (DE-588)4077445-4 (DE-588)4113937-9 |
title | Aerosol synthesis and characterization of semiconducting nanoparticles from the elements Si and Ge for the application in printable electronics = Aerosolsynthese und Charakterisierung halbleitender Nanopartikeln aus den Elementen Si und Ge zur Anwendung in der druckbaren Elektronik |
title_alt | Aerosolsynthese und Charakterisierung halbleitender Nanopartikeln aus den Elementen Si und Ge zur Anwendung in der druckbaren Elektronik |
title_auth | Aerosol synthesis and characterization of semiconducting nanoparticles from the elements Si and Ge for the application in printable electronics = Aerosolsynthese und Charakterisierung halbleitender Nanopartikeln aus den Elementen Si und Ge zur Anwendung in der druckbaren Elektronik |
title_exact_search | Aerosol synthesis and characterization of semiconducting nanoparticles from the elements Si and Ge for the application in printable electronics = Aerosolsynthese und Charakterisierung halbleitender Nanopartikeln aus den Elementen Si und Ge zur Anwendung in der druckbaren Elektronik |
title_full | Aerosol synthesis and characterization of semiconducting nanoparticles from the elements Si and Ge for the application in printable electronics = Aerosolsynthese und Charakterisierung halbleitender Nanopartikeln aus den Elementen Si und Ge zur Anwendung in der druckbaren Elektronik vorgelegt von Christian Mehringer |
title_fullStr | Aerosol synthesis and characterization of semiconducting nanoparticles from the elements Si and Ge for the application in printable electronics = Aerosolsynthese und Charakterisierung halbleitender Nanopartikeln aus den Elementen Si und Ge zur Anwendung in der druckbaren Elektronik vorgelegt von Christian Mehringer |
title_full_unstemmed | Aerosol synthesis and characterization of semiconducting nanoparticles from the elements Si and Ge for the application in printable electronics = Aerosolsynthese und Charakterisierung halbleitender Nanopartikeln aus den Elementen Si und Ge zur Anwendung in der druckbaren Elektronik vorgelegt von Christian Mehringer |
title_short | Aerosol synthesis and characterization of semiconducting nanoparticles from the elements Si and Ge for the application in printable electronics |
title_sort | aerosol synthesis and characterization of semiconducting nanoparticles from the elements si and ge for the application in printable electronics aerosolsynthese und charakterisierung halbleitender nanopartikeln aus den elementen si und ge zur anwendung in der druckbaren elektronik |
title_sub | = Aerosolsynthese und Charakterisierung halbleitender Nanopartikeln aus den Elementen Si und Ge zur Anwendung in der druckbaren Elektronik |
topic | Nanopartikel (DE-588)4333369-2 gnd Germanium (DE-588)4135644-5 gnd Halbleiterschicht (DE-588)4158812-5 gnd Silicium (DE-588)4077445-4 gnd |
topic_facet | Nanopartikel Germanium Halbleiterschicht Silicium Hochschulschrift |
url | http://d-nb.info/1166464946/04 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030589281&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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