Highlights in Solute-Solvent Interactions:
Most organic molecules retain their integrity when dissolved, and even though in such cases the effects exerted by solvents are, in the language of the coordination chemist, of the "outer sphere" kind, the choice of solvent can be critical to the successful outcome of an operation or prepa...
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| Format: | Elektronisch E-Book |
| Sprache: | English |
| Veröffentlicht: |
Vienna
Springer Vienna
2002
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| Schlagworte: | |
| Online-Zugang: | UBT01 Volltext |
| Zusammenfassung: | Most organic molecules retain their integrity when dissolved, and even though in such cases the effects exerted by solvents are, in the language of the coordination chemist, of the "outer sphere" kind, the choice of solvent can be critical to the successful outcome of an operation or preparation. Solubilities of reactants and products must be taken into account, and even if the organic principals in the reactions retain their integrity, many of the reagents are electrolytes, and their state of aggregation will affect their reactivity. In testifying to the importance of understanding solute-solvent interactions I draw attention to a large class of inorganic species for which the involvement in the chemical and physical properties by the solvent is even more deeply seated. It is comprised by the large body of metal atoms in low oxidation states for which solvent molecules intervene as reagents. At the same time, because the ions carry charges, the effects arising from outer sphere interactions are usually greater than they are for neutral molecules. To cite an example: when FeCb(s) is dissolved in water to form a dilute - say O. OlO- solution there is a complete reorganization of the coordination sphere of the cation. Whereas in the solid each cation is surrounded by six chloride ions, in the solution the dominant form is [Fe(H20)6]3+ followed by [Fe(H20)sCI]2+, [Fe(H20)4CI2]+, etc. in rapidly decreasing abundance |
| Beschreibung: | 1 Online-Ressource (IX, 222 p. 11 illus) |
| ISBN: | 9783709161517 |
| DOI: | 10.1007/978-3-7091-6151-7 |
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| 520 | |a Most organic molecules retain their integrity when dissolved, and even though in such cases the effects exerted by solvents are, in the language of the coordination chemist, of the "outer sphere" kind, the choice of solvent can be critical to the successful outcome of an operation or preparation. Solubilities of reactants and products must be taken into account, and even if the organic principals in the reactions retain their integrity, many of the reagents are electrolytes, and their state of aggregation will affect their reactivity. In testifying to the importance of understanding solute-solvent interactions I draw attention to a large class of inorganic species for which the involvement in the chemical and physical properties by the solvent is even more deeply seated. It is comprised by the large body of metal atoms in low oxidation states for which solvent molecules intervene as reagents. At the same time, because the ions carry charges, the effects arising from outer sphere interactions are usually greater than they are for neutral molecules. To cite an example: when FeCb(s) is dissolved in water to form a dilute - say O. OlO- solution there is a complete reorganization of the coordination sphere of the cation. Whereas in the solid each cation is surrounded by six chloride ions, in the solution the dominant form is [Fe(H20)6]3+ followed by [Fe(H20)sCI]2+, [Fe(H20)4CI2]+, etc. in rapidly decreasing abundance | ||
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| spelling | Highlights in Solute-Solvent Interactions edited by Wolfgang Linert Vienna Springer Vienna 2002 1 Online-Ressource (IX, 222 p. 11 illus) txt rdacontent c rdamedia cr rdacarrier Most organic molecules retain their integrity when dissolved, and even though in such cases the effects exerted by solvents are, in the language of the coordination chemist, of the "outer sphere" kind, the choice of solvent can be critical to the successful outcome of an operation or preparation. Solubilities of reactants and products must be taken into account, and even if the organic principals in the reactions retain their integrity, many of the reagents are electrolytes, and their state of aggregation will affect their reactivity. In testifying to the importance of understanding solute-solvent interactions I draw attention to a large class of inorganic species for which the involvement in the chemical and physical properties by the solvent is even more deeply seated. It is comprised by the large body of metal atoms in low oxidation states for which solvent molecules intervene as reagents. At the same time, because the ions carry charges, the effects arising from outer sphere interactions are usually greater than they are for neutral molecules. To cite an example: when FeCb(s) is dissolved in water to form a dilute - say O. OlO- solution there is a complete reorganization of the coordination sphere of the cation. Whereas in the solid each cation is surrounded by six chloride ions, in the solution the dominant form is [Fe(H20)6]3+ followed by [Fe(H20)sCI]2+, [Fe(H20)4CI2]+, etc. in rapidly decreasing abundance Chemistry Analytical Chemistry Organic Chemistry Inorganic Chemistry Characterization and Evaluation of Materials Analytical chemistry Inorganic chemistry Organic chemistry Materials science Wechselwirkung (DE-588)4064937-4 gnd rswk-swf Lösung Chemie (DE-588)4036159-7 gnd rswk-swf Lösungsmittel (DE-588)4036160-3 gnd rswk-swf Lösung Chemie (DE-588)4036159-7 s Lösungsmittel (DE-588)4036160-3 s Wechselwirkung (DE-588)4064937-4 s 1\p DE-604 Linert, Wolfgang edt Erscheint auch als Druck-Ausgabe 9783709172810 https://doi.org/10.1007/978-3-7091-6151-7 Verlag URL des Erstveröffentlichers Volltext 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Highlights in Solute-Solvent Interactions Chemistry Analytical Chemistry Organic Chemistry Inorganic Chemistry Characterization and Evaluation of Materials Analytical chemistry Inorganic chemistry Organic chemistry Materials science Wechselwirkung (DE-588)4064937-4 gnd Lösung Chemie (DE-588)4036159-7 gnd Lösungsmittel (DE-588)4036160-3 gnd |
| subject_GND | (DE-588)4064937-4 (DE-588)4036159-7 (DE-588)4036160-3 |
| title | Highlights in Solute-Solvent Interactions |
| title_auth | Highlights in Solute-Solvent Interactions |
| title_exact_search | Highlights in Solute-Solvent Interactions |
| title_full | Highlights in Solute-Solvent Interactions edited by Wolfgang Linert |
| title_fullStr | Highlights in Solute-Solvent Interactions edited by Wolfgang Linert |
| title_full_unstemmed | Highlights in Solute-Solvent Interactions edited by Wolfgang Linert |
| title_short | Highlights in Solute-Solvent Interactions |
| title_sort | highlights in solute solvent interactions |
| topic | Chemistry Analytical Chemistry Organic Chemistry Inorganic Chemistry Characterization and Evaluation of Materials Analytical chemistry Inorganic chemistry Organic chemistry Materials science Wechselwirkung (DE-588)4064937-4 gnd Lösung Chemie (DE-588)4036159-7 gnd Lösungsmittel (DE-588)4036160-3 gnd |
| topic_facet | Chemistry Analytical Chemistry Organic Chemistry Inorganic Chemistry Characterization and Evaluation of Materials Analytical chemistry Inorganic chemistry Organic chemistry Materials science Wechselwirkung Lösung Chemie Lösungsmittel |
| url | https://doi.org/10.1007/978-3-7091-6151-7 |
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