Organometallic Catalysts and Olefin Polymerization: Catalysts for a New Millennium
"Catalysis is more art than science", probably all of you have heard and even used this expression. Whether it is true or not, it alludes to the experience that new catalysts are hard to find, and near impossible to predict. Hard work and a lifetime of experience is invaluable. However, a...
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| Other Authors: | , , , |
|---|---|
| Format: | Electronic eBook |
| Language: | English |
| Published: |
Berlin, Heidelberg
Springer Berlin Heidelberg
2001
|
| Subjects: | |
| Online Access: | UBT01 Volltext |
| Summary: | "Catalysis is more art than science", probably all of you have heard and even used this expression. Whether it is true or not, it alludes to the experience that new catalysts are hard to find, and near impossible to predict. Hard work and a lifetime of experience is invaluable. However, a keen mind might give insight into where to search, but not necessarily about where to find the answers. Historically, "quantum leaps" have often arisen from serendipity - we all know the story about the nickel-contaminated reactor that triggered further research towards the first coordination catalyst for ethene polymerization. Taking advan tage of this event, Karl Ziegler became the first chemist to earn both a Nobel prize and a fortune for the same invention. A broken NMR tube helped Walter Kaminsky discover the effect of high concentrations of methylaluminoxanes as co catalysts for metallocenes. When air reacted with the concentrated trim ethyl aluminum solution, sufficient amounts of methylaluminoxanes were formed, and the lazy catalyst dormant in the NMR tube suddenly became sensationally active. Ziegler and Kaminsky were lucky and had the genius needed to take advantage of their luck |
| Physical Description: | 1 Online-Ressource (XII, 443 p) |
| ISBN: | 9783642594656 |
| DOI: | 10.1007/978-3-642-59465-6 |
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| spelling | Organometallic Catalysts and Olefin Polymerization Catalysts for a New Millennium edited by Richard Blom, Arild Follestad, Erling Rytter, Mats Tilset, Martin Ystenes Berlin, Heidelberg Springer Berlin Heidelberg 2001 1 Online-Ressource (XII, 443 p) txt rdacontent c rdamedia cr rdacarrier "Catalysis is more art than science", probably all of you have heard and even used this expression. Whether it is true or not, it alludes to the experience that new catalysts are hard to find, and near impossible to predict. Hard work and a lifetime of experience is invaluable. However, a keen mind might give insight into where to search, but not necessarily about where to find the answers. Historically, "quantum leaps" have often arisen from serendipity - we all know the story about the nickel-contaminated reactor that triggered further research towards the first coordination catalyst for ethene polymerization. Taking advan tage of this event, Karl Ziegler became the first chemist to earn both a Nobel prize and a fortune for the same invention. A broken NMR tube helped Walter Kaminsky discover the effect of high concentrations of methylaluminoxanes as co catalysts for metallocenes. When air reacted with the concentrated trim ethyl aluminum solution, sufficient amounts of methylaluminoxanes were formed, and the lazy catalyst dormant in the NMR tube suddenly became sensationally active. Ziegler and Kaminsky were lucky and had the genius needed to take advantage of their luck Chemistry Polymer Sciences Industrial Chemistry/Chemical Engineering Organic Chemistry Inorganic Chemistry Condensed Matter Physics Inorganic chemistry Organic chemistry Polymers Chemical engineering Condensed matter Metallorganische Verbindungen (DE-588)4038906-6 gnd rswk-swf Polymerisation (DE-588)4046704-1 gnd rswk-swf Katalysator (DE-588)4029919-3 gnd rswk-swf Alkene (DE-588)4001207-4 gnd rswk-swf 1\p (DE-588)1071861417 Konferenzschrift 2000 Oslo gnd-content Alkene (DE-588)4001207-4 s Polymerisation (DE-588)4046704-1 s Katalysator (DE-588)4029919-3 s Metallorganische Verbindungen (DE-588)4038906-6 s 2\p DE-604 Blom, Richard edt Follestad, Arild edt Rytter, Erling edt Tilset, Mats edt Erscheint auch als Druck-Ausgabe 9783642639876 https://doi.org/10.1007/978-3-642-59465-6 Verlag URL des Erstveröffentlichers Volltext 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Organometallic Catalysts and Olefin Polymerization Catalysts for a New Millennium Chemistry Polymer Sciences Industrial Chemistry/Chemical Engineering Organic Chemistry Inorganic Chemistry Condensed Matter Physics Inorganic chemistry Organic chemistry Polymers Chemical engineering Condensed matter Metallorganische Verbindungen (DE-588)4038906-6 gnd Polymerisation (DE-588)4046704-1 gnd Katalysator (DE-588)4029919-3 gnd Alkene (DE-588)4001207-4 gnd |
| subject_GND | (DE-588)4038906-6 (DE-588)4046704-1 (DE-588)4029919-3 (DE-588)4001207-4 (DE-588)1071861417 |
| title | Organometallic Catalysts and Olefin Polymerization Catalysts for a New Millennium |
| title_auth | Organometallic Catalysts and Olefin Polymerization Catalysts for a New Millennium |
| title_exact_search | Organometallic Catalysts and Olefin Polymerization Catalysts for a New Millennium |
| title_full | Organometallic Catalysts and Olefin Polymerization Catalysts for a New Millennium edited by Richard Blom, Arild Follestad, Erling Rytter, Mats Tilset, Martin Ystenes |
| title_fullStr | Organometallic Catalysts and Olefin Polymerization Catalysts for a New Millennium edited by Richard Blom, Arild Follestad, Erling Rytter, Mats Tilset, Martin Ystenes |
| title_full_unstemmed | Organometallic Catalysts and Olefin Polymerization Catalysts for a New Millennium edited by Richard Blom, Arild Follestad, Erling Rytter, Mats Tilset, Martin Ystenes |
| title_short | Organometallic Catalysts and Olefin Polymerization |
| title_sort | organometallic catalysts and olefin polymerization catalysts for a new millennium |
| title_sub | Catalysts for a New Millennium |
| topic | Chemistry Polymer Sciences Industrial Chemistry/Chemical Engineering Organic Chemistry Inorganic Chemistry Condensed Matter Physics Inorganic chemistry Organic chemistry Polymers Chemical engineering Condensed matter Metallorganische Verbindungen (DE-588)4038906-6 gnd Polymerisation (DE-588)4046704-1 gnd Katalysator (DE-588)4029919-3 gnd Alkene (DE-588)4001207-4 gnd |
| topic_facet | Chemistry Polymer Sciences Industrial Chemistry/Chemical Engineering Organic Chemistry Inorganic Chemistry Condensed Matter Physics Inorganic chemistry Organic chemistry Polymers Chemical engineering Condensed matter Metallorganische Verbindungen Polymerisation Katalysator Alkene Konferenzschrift 2000 Oslo |
| url | https://doi.org/10.1007/978-3-642-59465-6 |
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