Transition Metal and Rare Earth Compounds: Excited States, Transitions, Interactions II
There exists a large literature on the spectroscopic properties of copper(II) com- 9 pounds. This is due to the simplicity of the d electron configuration, the wide variety of stereochemistries that copper(II) compounds can adopt, and the f- xional geometric behavior that they sometimes exhibit [1]....
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| Format: | Elektronisch E-Book |
| Sprache: | English |
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Berlin, Heidelberg
Springer Berlin Heidelberg
2001
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| Schriftenreihe: | Topics in Current Chemistry
214 |
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| Online-Zugang: | UBT01 Volltext |
| Zusammenfassung: | There exists a large literature on the spectroscopic properties of copper(II) com- 9 pounds. This is due to the simplicity of the d electron configuration, the wide variety of stereochemistries that copper(II) compounds can adopt, and the f- xional geometric behavior that they sometimes exhibit [1]. The electronic and geometric properties of a molecule are inexorably linked and this is especially true with six-coordinate copper(II) compounds which are subject to a Jahn-T- ler effect.However,the spectral-structural correlations that are sometimes d- wn must often be viewed with caution as the information contained in a typical solution UV-Vis absorption spectrum of a copper(II) compound is limited. Meaningful spectral-structural correlations can be obtained in a related series of compounds where detailed spectroscopic data is available. In the fol- 4– lowing sections two such series are examined; the six-coordinate CuF and 6 2+ Cu(H O) ions doped as impurities in single crystal hosts.Using low tempera- 2 6 ture polarized optical spectroscopy and electron paramagnetic resonance, a very detailed picture can be drawn about the geometry of these ions in both their ground and excited electronic states. We then compare the spectrosco- cally determined structural data with that obtained from X-ray diffraction or EXAFS measurements |
| Beschreibung: | 1 Online-Ressource (X, 186 p) |
| ISBN: | 9783540444749 |
| DOI: | 10.1007/3-540-44474-2 |
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| 520 | |a There exists a large literature on the spectroscopic properties of copper(II) com- 9 pounds. This is due to the simplicity of the d electron configuration, the wide variety of stereochemistries that copper(II) compounds can adopt, and the f- xional geometric behavior that they sometimes exhibit [1]. The electronic and geometric properties of a molecule are inexorably linked and this is especially true with six-coordinate copper(II) compounds which are subject to a Jahn-T- ler effect.However,the spectral-structural correlations that are sometimes d- wn must often be viewed with caution as the information contained in a typical solution UV-Vis absorption spectrum of a copper(II) compound is limited. Meaningful spectral-structural correlations can be obtained in a related series of compounds where detailed spectroscopic data is available. In the fol- 4– lowing sections two such series are examined; the six-coordinate CuF and 6 2+ Cu(H O) ions doped as impurities in single crystal hosts.Using low tempera- 2 6 ture polarized optical spectroscopy and electron paramagnetic resonance, a very detailed picture can be drawn about the geometry of these ions in both their ground and excited electronic states. We then compare the spectrosco- cally determined structural data with that obtained from X-ray diffraction or EXAFS measurements | ||
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| id | DE-604.BV045151976 |
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| spelling | Transition Metal and Rare Earth Compounds Excited States, Transitions, Interactions II edited by Hartmut Yersin Berlin, Heidelberg Springer Berlin Heidelberg 2001 1 Online-Ressource (X, 186 p) txt rdacontent c rdamedia cr rdacarrier Topics in Current Chemistry 214 There exists a large literature on the spectroscopic properties of copper(II) com- 9 pounds. This is due to the simplicity of the d electron configuration, the wide variety of stereochemistries that copper(II) compounds can adopt, and the f- xional geometric behavior that they sometimes exhibit [1]. The electronic and geometric properties of a molecule are inexorably linked and this is especially true with six-coordinate copper(II) compounds which are subject to a Jahn-T- ler effect.However,the spectral-structural correlations that are sometimes d- wn must often be viewed with caution as the information contained in a typical solution UV-Vis absorption spectrum of a copper(II) compound is limited. Meaningful spectral-structural correlations can be obtained in a related series of compounds where detailed spectroscopic data is available. In the fol- 4– lowing sections two such series are examined; the six-coordinate CuF and 6 2+ Cu(H O) ions doped as impurities in single crystal hosts.Using low tempera- 2 6 ture polarized optical spectroscopy and electron paramagnetic resonance, a very detailed picture can be drawn about the geometry of these ions in both their ground and excited electronic states. We then compare the spectrosco- cally determined structural data with that obtained from X-ray diffraction or EXAFS measurements Chemistry Organic Chemistry Physical Chemistry Inorganic Chemistry Optics, Optoelectronics, Plasmonics and Optical Devices Inorganic chemistry Organic chemistry Physical chemistry Optics Optoelectronics Plasmons (Physics) Yersin, Hartmut edt Erscheint auch als Druck-Ausgabe 9783540679769 https://doi.org/10.1007/3-540-44474-2 Verlag URL des Erstveröffentlichers Volltext |
| spellingShingle | Transition Metal and Rare Earth Compounds Excited States, Transitions, Interactions II Chemistry Organic Chemistry Physical Chemistry Inorganic Chemistry Optics, Optoelectronics, Plasmonics and Optical Devices Inorganic chemistry Organic chemistry Physical chemistry Optics Optoelectronics Plasmons (Physics) |
| title | Transition Metal and Rare Earth Compounds Excited States, Transitions, Interactions II |
| title_auth | Transition Metal and Rare Earth Compounds Excited States, Transitions, Interactions II |
| title_exact_search | Transition Metal and Rare Earth Compounds Excited States, Transitions, Interactions II |
| title_full | Transition Metal and Rare Earth Compounds Excited States, Transitions, Interactions II edited by Hartmut Yersin |
| title_fullStr | Transition Metal and Rare Earth Compounds Excited States, Transitions, Interactions II edited by Hartmut Yersin |
| title_full_unstemmed | Transition Metal and Rare Earth Compounds Excited States, Transitions, Interactions II edited by Hartmut Yersin |
| title_short | Transition Metal and Rare Earth Compounds |
| title_sort | transition metal and rare earth compounds excited states transitions interactions ii |
| title_sub | Excited States, Transitions, Interactions II |
| topic | Chemistry Organic Chemistry Physical Chemistry Inorganic Chemistry Optics, Optoelectronics, Plasmonics and Optical Devices Inorganic chemistry Organic chemistry Physical chemistry Optics Optoelectronics Plasmons (Physics) |
| topic_facet | Chemistry Organic Chemistry Physical Chemistry Inorganic Chemistry Optics, Optoelectronics, Plasmonics and Optical Devices Inorganic chemistry Organic chemistry Physical chemistry Optics Optoelectronics Plasmons (Physics) |
| url | https://doi.org/10.1007/3-540-44474-2 |
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