Catalytic oxidations with nitrous oxide:
Saved in:
| Main Author: | |
|---|---|
| Format: | Thesis Book |
| Language: | English |
| Published: |
Köln
2018
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | IV, 176 Seiten Illustrationen 21 cm |
Staff View
MARC
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| 100 | 1 | |a Gianolio, Eleonora |d 1986- |e Verfasser |0 (DE-588)1154412091 |4 aut | |
| 245 | 1 | 0 | |a Catalytic oxidations with nitrous oxide |c vorgelegt von Eleonora Gianolio |
| 264 | 1 | |a Köln |c 2018 | |
| 300 | |a IV, 176 Seiten |b Illustrationen |c 21 cm | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 502 | |b Dissertation |c Universität zu Köln |d 2017 | ||
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| 650 | 0 | 7 | |a Stickstoffmonoxid |0 (DE-588)4183282-6 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Oxidans |0 (DE-588)4202009-8 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Alkohole |0 (DE-588)4141899-2 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Rutheniumoxide |0 (DE-588)4178772-9 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Distickstoffmonoxid |0 (DE-588)4150244-9 |2 gnd |9 rswk-swf |
| 655 | 7 | |0 (DE-588)4113937-9 |a Hochschulschrift |2 gnd-content | |
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Record in the Search Index
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|---|---|
| adam_text | 1
SUMMARY........................................................................
1
2 INTRODUCTION
..................................................................
6
3 BACKGROUND
..................................................................
8
3.1 ELECTRONIC STRUCTURE OF NITROUS OXIDE
....................................
8
3.2 THE REACTIVITY OF NITROUS
OXIDE............................................10
3.3 ACTIVATION OF NITROUS OXIDE BY NATURE
...............................
15
3.4 VARIOUS ACTIVATION MODES OF NITROUS OXIDE
......................
16
3.5 NITROUS OXIDE-MEDIATED CROSS COUPLING REACTIONS
.........
25
3.6 HETEROGENEOUS DECOMPOSITION OF NITROUS OXIDE
............
28
3.7 ELECTROCATALYTIC DECOMPOSITION OF NITROUS O XIDE
............
30
3.8 PERRUTHENATE CATALYSED OXIDATION OF ALCOHOLS
................
31
3.9 TPAP-CATALYSED OXIDATIVE TRANSFORMATIONS.....................42
4
CONCEPT........................................................................
53
5 RESULTS AND DISCUSSION
............................................
57
5.1 VANADYL COMPLEXES
.............................................................
57
5.2 ATTEMPTS IN THE CLEAVAGE OF THE N 20-N H C ADDUCT
.......
59
5.3 COPPER-BASED OXIDATION OF ALCOHOLS
................................
61
5.4 ATTEMPTS IN PD-CATALYSED OXIDATIONS
...............................
62
5.4.1 THE SAEGUSA-LTO
OXIDATION...................................................64
5.5 RUTHENIUM-CATALYSED OXIDATION OF ALCOHOLS....................66
5.6 SCOPE OF THE
OXIDATION........................................................72
5.7 ASYMMETRIE SHARPLESS DIHYDROXYLATION
84
6
DISCUSSION..................................................................
86
6.1 VANADIUM COMPLEXES IN THE EPOXIDATION OF
NORBORNENE............................................................................88
6.1.1 ATTEMPTS IN THE CLEAVAGE OF NITROUS OXIDE-NHC ADDUCT
PROMOTED BY METAL PORPHYRINS
.........................................
92
6.1.2 PALLADIUM-CATALYSED OXIDATIONS
.......................................
94
6.1.3 SAEGUSA-LTO OXIDATION
........................................................
95
6.2 ATTEMPTS IN THE COPPER-CATALYSED OXIDATION OF
ALCOHOLS.................................................................................
97
6.3 RUTHENIUM-CATALYSED OXIDATION OF ALCOHOLS
...................
98
6.3.1
PRESSURE...............................................................................102
6.3.2 SUBSTRATE
SCOPE.................................................................102
6.3.3 THE IN SITU
PROCEDURE........................................................103
6.3.4 SCOPE OF THE IN SITU PROCEDURE
........................................
109
6.3.5 PRELIMINARY INSIGHTS INTO THE REACTION MECHANISM
......
110
6.4 SHARPLESS ASYMMETRIC DIHYDROXYLATION
...........................
114
7
OUTLOOK
......................................................................
115
8 EXPERIMENTAL SECTION..............................................
117
8.1 GENERAL EXPERIMENTAL
CONDITIONS......................................117
8.2 PROCEDURES FOR THE OXIDATION OF ALCOHOLS WITH TPAP AS
CATALYST AND NITROUS OXIDE AS TERMINAL OXIDANT
...........
121
8.2.1 OXIDATION OF HMF
1............................................................ 121
8.2.2 OXIDATION OF HMF 1 - IN SITU PROCEDURE
.........................
123
8.2.3 OXIDATION OF 3-METHYL-2-BUTENOL 2 1 2
..............................124
8.2.4 OXIDATION OF 3-METHOXYBENZYL ALCOHOL 213 ....................125
8.2.5 OXIDATION OF 3-HYDROXYBENZYL ALCOHOL 214.....................127
8.2.6 OXIDATION OF 9-ANTHRACENEMETHANOL 2 1 5
.......................
128
8.2.7 OXIDATION OF 2,2-DIMETHYM-PHENYPROPANOL 2 1 6
.........
130
8.2.8 OXIDATION OF FURFURYL ALCOHOL 2 1 7
......................................131
8.2.9 OXIDATION OF 2-THIOPHENEMETHANOL 2 1 8
.........................
133
8.2.10 OXIDATION OF 4-CHLOROBENZYL ALCOHOL 2 1 9
.......................
134
8.2.11 OXIDATION OF 3-NITROBENZYL ALCOHOL 2 2 0
..........................
135
8.2.12 OXIDATION OF 1,2-BENZENEDIMETHANOL 184
......................
137
8.2.13 OXIDATION OF BENZYL ALCOHOL 1 6 3
......................................138
8.2.14 OXIDATION OF 4-HYDROXY-3-METHOXYBENZYL ALCOHOL
2 2 1
........................................................................................140
8.2.15 OXIDATION OF 1,4-PENTANEDIOL 1 8
.....................................
141
8.2.16 OXIDATION OF N-OCTANOL 222
...............................................
143
8.2.17 OXIDATION OF 2-OCTANOL 223
...............................................
144
8.2.18 OXIDATION OF 2-OCTANOL 22
.................................................
146
8.2.19 OXIDATION OF (+)-FENCHOL 2 2 4
............................................147
8.2.20 OXIDATION OF (-)-MENTHOL 2 2 5
............................................149
8.2.21 OXIDATION OF (-)-CARVEOL 2 2 6
.............................................151
III
8.2.22 OXIDATION OF GERANIOL 113
.............................
8.2.23 OXIDATION OF 4-TERT-BUTYLCYCLOHEXANOL 2 2 7
....................154
8.2.24 OXIDATION OF CITRONELLOL
115...............................................155
8.2.25 OXIDATION OF A-CYCLOPROPYLBENZYL ALCOHOL 1 8
...............
157
8.2.26 OXIDATION OF 1 -PHENYLETHANOL 2 0 8
..................................
158
9 REFERENCES
................................................................
160
9.1
ABBREVIATIONS......................................................................169
9.2 ABSTRACT-KURZZUSAMMENFASSUNG....................................172
ERKLAERUNG........................................................................
174
CURRICULUM
VITAE...........................................................
175
|
| any_adam_object | 1 |
| author | Gianolio, Eleonora 1986- |
| author_GND | (DE-588)1154412091 |
| author_facet | Gianolio, Eleonora 1986- |
| author_role | aut |
| author_sort | Gianolio, Eleonora 1986- |
| author_variant | e g eg |
| building | Verbundindex |
| bvnumber | BV045144924 |
| ctrlnum | (OCoLC)1041707271 (DE-599)DNB1158697120 |
| discipline | Chemie / Pharmazie |
| format | Thesis Book |
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| genre_facet | Hochschulschrift |
| id | DE-604.BV045144924 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T08:09:55Z |
| institution | BVB |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-030534701 |
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| owner_facet | DE-355 DE-BY-UBR DE-29T DE-83 |
| physical | IV, 176 Seiten Illustrationen 21 cm |
| publishDate | 2018 |
| publishDateSearch | 2018 |
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| spelling | Gianolio, Eleonora 1986- Verfasser (DE-588)1154412091 aut Catalytic oxidations with nitrous oxide vorgelegt von Eleonora Gianolio Köln 2018 IV, 176 Seiten Illustrationen 21 cm txt rdacontent n rdamedia nc rdacarrier Dissertation Universität zu Köln 2017 Katalytische Oxidation (DE-588)4163425-1 gnd rswk-swf Oxidation (DE-588)4137187-2 gnd rswk-swf Stickstoffmonoxid (DE-588)4183282-6 gnd rswk-swf Oxidans (DE-588)4202009-8 gnd rswk-swf Alkohole (DE-588)4141899-2 gnd rswk-swf Rutheniumoxide (DE-588)4178772-9 gnd rswk-swf Distickstoffmonoxid (DE-588)4150244-9 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Katalytische Oxidation (DE-588)4163425-1 s Oxidans (DE-588)4202009-8 s Stickstoffmonoxid (DE-588)4183282-6 s Oxidation (DE-588)4137187-2 s Alkohole (DE-588)4141899-2 s Rutheniumoxide (DE-588)4178772-9 s Distickstoffmonoxid (DE-588)4150244-9 s DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030534701&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Gianolio, Eleonora 1986- Catalytic oxidations with nitrous oxide Katalytische Oxidation (DE-588)4163425-1 gnd Oxidation (DE-588)4137187-2 gnd Stickstoffmonoxid (DE-588)4183282-6 gnd Oxidans (DE-588)4202009-8 gnd Alkohole (DE-588)4141899-2 gnd Rutheniumoxide (DE-588)4178772-9 gnd Distickstoffmonoxid (DE-588)4150244-9 gnd |
| subject_GND | (DE-588)4163425-1 (DE-588)4137187-2 (DE-588)4183282-6 (DE-588)4202009-8 (DE-588)4141899-2 (DE-588)4178772-9 (DE-588)4150244-9 (DE-588)4113937-9 |
| title | Catalytic oxidations with nitrous oxide |
| title_auth | Catalytic oxidations with nitrous oxide |
| title_exact_search | Catalytic oxidations with nitrous oxide |
| title_full | Catalytic oxidations with nitrous oxide vorgelegt von Eleonora Gianolio |
| title_fullStr | Catalytic oxidations with nitrous oxide vorgelegt von Eleonora Gianolio |
| title_full_unstemmed | Catalytic oxidations with nitrous oxide vorgelegt von Eleonora Gianolio |
| title_short | Catalytic oxidations with nitrous oxide |
| title_sort | catalytic oxidations with nitrous oxide |
| topic | Katalytische Oxidation (DE-588)4163425-1 gnd Oxidation (DE-588)4137187-2 gnd Stickstoffmonoxid (DE-588)4183282-6 gnd Oxidans (DE-588)4202009-8 gnd Alkohole (DE-588)4141899-2 gnd Rutheniumoxide (DE-588)4178772-9 gnd Distickstoffmonoxid (DE-588)4150244-9 gnd |
| topic_facet | Katalytische Oxidation Oxidation Stickstoffmonoxid Oxidans Alkohole Rutheniumoxide Distickstoffmonoxid Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030534701&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT gianolioeleonora catalyticoxidationswithnitrousoxide |