Heterogeneous photochemical electron transfer:
Saved in:
| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Boca Raton ; London ; New York
CRC Press
2018
|
| Edition: | Reissued |
| Series: | CRC revivals
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | 159 Seiten Diagramme |
| ISBN: | 9781315894102 0849359686 |
Staff View
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Record in the Search Index
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| adam_text | TABLE OF CONTENTS
Chapter 1
Theoretical Aspects of Electron-Transfer Reactions
I. General Features of Electron-Transfer Reactions........................
II. Adiabatic Outer Sphere Electron-Transfer Reactions in Solutions: Marcus
Theory.................................................................
III. Nonadiabatic Electron-Transfer Reactions...............................
A. Classical Description of Nonadiabatic Electron-Transfer
Reactions.......................................................
B. Semiclassical Description of Nonadiabatic Electron-Transfer
Reactions.......................................................
C. Quantum Mechanical Treatment of Nonadiabatic Electron-Transfer
Reactions.......................................................
IV. Heterogeneous Electron-Transfer Reaction...............................
A. Energetics of Interfacial Electron-Transfer Reactions, Fermi Level,
and Redox Potential of a Solution...............................
B. Distribution of Electronic Energy Levels in Solid Conductors and
Electrolytes....................................................
1. Metals...................................................
2. Semiconductors...........................................
3. Electronic Energy Levels in Solution.....................
C. Interfacial Electron-Transfer Kinetics, Empirical Rate Laws for
Electrochemical Reactions, and Comparison with Theory...........
1. Conducting Electrodes....................................
2. Semiconducting Electrodes................................
D. Interpretation of the Preexponential Factor in Electrochemical
Reactions.......................................................
E. Heterogeneous vs. Homogeneous Reorganization Energies...........
References....................................................................
A
. l
. 5
10
12
14
18
21
22
26
26
27
30
32
32
36
39
41
41
Chapter 2
Light Energy Harvesting and Photoinduced Electron Transfer in Organized Molecular
Assemblies
I. Introduction...................................................................43
II. Transfer of Electronic Excitation Energy in Micellar Assemblies................43
A. Intramicellar Triplet Energy Transfer...................................44
B. Triplet-Triplet Annihilation in Confined Reaction Space.................49
C. Excitation Energy Conduction Along a Micellar Surface to a
Reaction Trap..........................................................52
D. Long-Range Intramicellar Singlet Energy Transfer........................54
III. Photoinduced Electron Transfer in Micellar Assemblies.........................59
A. Electrical Potential of a Solution in the Vicinity of a Charged Molecular
Assembly...............................................................59
B. Photoionization.........................................................62
C. Intramicellar Electron Transfer.........................................64
D. Photoinduced Electron Transfer in Functionalized Micellar
Assemblies........................................................... 67
E. Light-Induced Charge Separation Through Hydrophobic Electron
Storage in Micellar Aggregates.........................................69
F. Micellar Model Systems for Photosynthesis............................. 70
IV. Light-Induced Electron Transfer in Inverted Micelles and Microemulsions........71
V. Photoinduced Electron Transfer and Transmembrane Redox Reactions in
Vesicles......................................................................
A. Structural Features of Vesicles and Bilayer Lipid Membranes..........73
B. Photoinduced Electron-Transfer Reactions in Vesicle
Dispersions...........................................................75
VI. Electron Transfer in Monolayer Assemblies....................................82
VII. Light-Induced Charge Separation in Aqueous Dispersions of Inorganic
Colloids and Polyelectrolytes...............................................83
References..........................................................................84
Chapter 3
Charge Transfer Reactions in Semiconductor Systems
I. Introduction.................................................................87
II. Properties of Semiconductor Particles........................................87
A. Structural Properties.................................................87
1. Size and Shape: Macroparticles, Colloids, and Particles........87
2. Lattice Defects................................................90
B. Optical Properties.................................................. 91
1. Optical Absorption of Bulk Semiconductors and Colloidal
Particles: Mie Theory........................................ 91
2. Optical Absorption of Very Small Particles: Quantum
Size Effects...................................................94
3. Photoluminescence of Semiconductor Particles and
Electrodes................................................... 97
4. Quantum Size Effects in the Photoluminescence of Colloidal
Semiconductors............................................... 99
C. Electronic Properties................................................100
1. Band Edge Positions...........................................100
2. Space Charge Layers and Band Bending..........................102
3. Space Charge Layers in Semiconductor Particles................106
4. Fermi Level Pinning...........................................108
5. Light-Induced Charge Separation...............................109
6. Trapped vs. Free Charge Carriers in Small Semiconductor
Particles.....................................................Ill
III. Experimental Methods........................................................113
IV. Dynamics of Charge Carrier Trapping and Recombination in Small
Semiconductor Particles....................................................114
V. Dynamics of Interfacial Charge Transfer Processes......................... 118
VI. Photosensitized Electron Injection in Colloidal Semiconductors..............126
VII. Applications: Photocatalysis................................................131
A. Photocleavage of Hydrogen Sulfide....................................132
B. Photodegradation of Organic Wastes and Pollutants....................133
C. Photodecomposition of Water: Solar Energy Conversion.................135
D. Incorporation of Colloidal Semiconductors in Supramolecular
Assemblies...........................................................144
VIII. Concluding Remarks..........................................................144
References.........................................................................145
Index
151
|
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| author_facet | Grätzel, Michael 1944- |
| author_role | aut |
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| bvnumber | BV045144653 |
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| discipline | Chemie / Pharmazie |
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| illustrated | Not Illustrated |
| indexdate | 2024-07-10T08:09:54Z |
| institution | BVB |
| isbn | 9781315894102 0849359686 |
| language | English |
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| owner_facet | DE-703 |
| physical | 159 Seiten Diagramme |
| publishDate | 2018 |
| publishDateSearch | 2018 |
| publishDateSort | 2018 |
| publisher | CRC Press |
| record_format | marc |
| series2 | CRC revivals |
| spelling | Grätzel, Michael 1944- Verfasser (DE-588)172106435 aut Heterogeneous photochemical electron transfer author Michael Grätzel Reissued Boca Raton ; London ; New York CRC Press 2018 159 Seiten Diagramme txt rdacontent n rdamedia nc rdacarrier CRC revivals Elektronentransfer (DE-588)4151907-3 gnd rswk-swf Fotochemie (DE-588)4045873-8 gnd rswk-swf Heterogenes System (DE-588)4159737-0 gnd rswk-swf Fotochemie (DE-588)4045873-8 s Elektronentransfer (DE-588)4151907-3 s DE-604 Heterogenes System (DE-588)4159737-0 s 1\p DE-604 Erscheint auch als Online-Ausgabe 978-1-351-07320-2 Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030534434&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Grätzel, Michael 1944- Heterogeneous photochemical electron transfer Elektronentransfer (DE-588)4151907-3 gnd Fotochemie (DE-588)4045873-8 gnd Heterogenes System (DE-588)4159737-0 gnd |
| subject_GND | (DE-588)4151907-3 (DE-588)4045873-8 (DE-588)4159737-0 |
| title | Heterogeneous photochemical electron transfer |
| title_auth | Heterogeneous photochemical electron transfer |
| title_exact_search | Heterogeneous photochemical electron transfer |
| title_full | Heterogeneous photochemical electron transfer author Michael Grätzel |
| title_fullStr | Heterogeneous photochemical electron transfer author Michael Grätzel |
| title_full_unstemmed | Heterogeneous photochemical electron transfer author Michael Grätzel |
| title_short | Heterogeneous photochemical electron transfer |
| title_sort | heterogeneous photochemical electron transfer |
| topic | Elektronentransfer (DE-588)4151907-3 gnd Fotochemie (DE-588)4045873-8 gnd Heterogenes System (DE-588)4159737-0 gnd |
| topic_facet | Elektronentransfer Fotochemie Heterogenes System |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030534434&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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