Nuclear and radiochemistry:
Saved in:
| Main Authors: | , |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Amsterdam, Netherlands ; Oxford, United Kingdom; Cambridge, MA, United States
Elsevier
[2018]
|
| Edition: | Second edition |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis Inhaltsverzeichnis |
| Physical Description: | xvi, 464 Seiten Illustrationen, Diagramme |
| ISBN: | 9780128136430 |
Staff View
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| 245 | 1 | 0 | |a Nuclear and radiochemistry |c József Kónya and Noémi M. Nagy (Imre Lajos Isotope Laboratory, Department of Physical Chemistry, University of Debrecen, Hungary) |
| 250 | |a Second edition | ||
| 264 | 1 | |a Amsterdam, Netherlands ; Oxford, United Kingdom; Cambridge, MA, United States |b Elsevier |c [2018] | |
| 264 | 4 | |c © 2018 | |
| 300 | |a xvi, 464 Seiten |b Illustrationen, Diagramme | ||
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Record in the Search Index
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| adam_text | Contents
Preface xv
Chapter 1: Introduction 1
Further Reading 9
Chapter 2: Basic Concepts 11
2 1 Atomic Nuclei 11
211 Components of Nuclei 11
2 2 Forces in the Nucleus 13
2 3 Other Properties of Nuclei 17
2 4 Elementary or Composite Particles 19
2 5 Models of Nuclei 21
251 The Liquid-Drop Model 21
252 The Shell Model 23
253 Unified and Collective Models 24
Further Reading 24
Chapter 3: Isotopes 25
3 1 Isotopic Effects 27
311 Physical Isotope Effects 30
312 Spectroscopic Isotope Effects 31
313 Phase Equilibrium Isotope Effects 32
314 Isotope Effects in the Kinetics of Chemical Reactions 32
315 The Isotope Effect in a Chemical Equilibrium 36
316 Biological Isotope Effects 37
3 2 Separation of Isotopes 38
3 3 Isotope Composition in Nature 39
3 4 Study of Geological Formations and Processes by Stable Isotope Ratios 41
341 Study of the Temperature and Age of Geological Formations 42
342 Study of the Hydrological Process by Measuring the Ratio
of Oxygen and Hydrogen Isotopes 43
343 Changes in the Isotope Ratio of Nitrogen 44
344 Isotope Ratios of Carbon 45
345 Stable Isotope Ratios in Ecological Studies 46
Further Reading 46
Chapter 4: Radioactive Decay 49
4 1 Kinetics of Radioactive Decay 49
411 Statistics of Simple Radioactive Decay 49
412 Activity and Intensity 51
413 Decay of Independent (Mixed) Nuclei 51
414 Branching Decay 52
415 Kinetics of Successive Decay 54
416 Radioactive Equilibria 57
4 2 Radioactive Decay Series 61
4 3 Radioactive Dating 62
431 Radioactive Dating by Lead Isotope Ratios 63
432 Dating of Sediments by 210Pb Radioactivity 66
433 Radioactive Dating by Helium Concentration 66
434 Radioactive Dating by Fission of Uranium 67
435 Radioactive Dating by Argon Concentration 67
436 Radioactive Dating by 87Rb-87Sr, Parent-Daughter Pairs 67
437 Radiocarbon Dating 68
4 4 Mechanism of Radioactive Decay 69
441 Alpha Decay 69
442 Beta Decays 75
443 Electron Capture 79
444 Proton and Neutron Decay 80
445 Spontaneous Fission 82
446 Isomeric Transition (IT) 82
447 Exotic Decay 83
Further Reading 84
Chapter 5: Interaction of Radiation With Matter 85
5 1 Basic Concepts 85
5 2 Interaction of Alpha Particles With Matter 87
521 Energy Loss of Alpha Particles 87
522 Backscattering of Alpha Particles 93
Contents vii
5 3 Interaction of Beta Radiation With Matter 97
531 Interaction of Beta Particles With Orbital Electrons and the Nuclear
Field 98
532 Cherenkov Radiation 100
533 Annihilation of Positrons 101
534 Absorption of Beta Radiation 102
535 Self-Absorption of Beta Radiation 105
536 Backscattering of Beta Radiation 108
5 4 Interaction of Gamma Radiation With Matter 112
541 Rayleigh Scattering 112
542 Thomson Scattering 113
543 Compton Scattering 114
544 The Photoelectric Effect 116
545 Pair Formation 117
546 Total Absorption of Gamma Radiation 119
547 Resonance Absorption of Nuclei and the Mössbauer Effect 120
5 5 Interaction of Neutrons With Matter 124
551 Discovery of Neutrons 125
552 Production of Neutrons 126
553 Interaction of Neutrons With Matter 128
Further Reading 130
Chapter 6: Nuclear Reactions 133
6 1 Kinetics of Nuclear Reactions 135
6 2 Classification of Nuclear Reactions 137
621 Nuclear Reactions With Neutrons 137
622 Nuclear Reactions With Gamma Photons 142
623 Nuclear Reactions With Charged Particles 143
624 Thermonuclear Reactions 145
625 Nucleogenesis: The Production of Elements in the Universe 146
626 Production of Transuranium Elements 151
6 3 General Scheme of Radionuclide Production by Nuclear Reactions and
Radioactive Decay 155
6 4 Chemical Effects of Nuclear Reactions 155
Further Reading 158
Chapter 7: Nuclear Energy Production 159
7 1 Nuclear Power Plants 160
711 The Main Parts of Nuclear Reactors 162
712 Natural Nuclear Reactors 169
713 The First Artificial Nuclear Reactor 170
714 Types of Nuclear Reactors 170
715 Environmental Impacts of Nuclear Reactors 171
7 2 Accidents in Nuclear Power Plants 173
7 3 Storage and Treatment of Spent Fuel and Other Radioactive Waste 176
731 Storage of Low- and Intermediate-Level Nuclear Waste 178
732 Treatment and Storage of High-Level Nuclear Waste 180
7 4 New Trends in Nuclear Energy Production 181
741 Improvement of the Fission in Nuclear Power Plants 181
742 Experiments with Fusion Energy Production 183
7 5 Nuclear Weapons 184
Further Reading 185
Chapter 8: Radioactive Tracer Methods 187
8 1 History of Radioactive Tracer Methods 187
8 2 Basic Concepts 188
8 3 Selection of Tracers 194
8 4 Position of the Labeling Atom in a Molecule 198
8 5 General Methods for the Preparation of Radioactive Tracers 201
851 Tracers Received From Radioactive Decay Series 201
852 Artificial Radioactive Tracers 206
8 6 Radioactive Isotopes in Tracer Methods 210
861 Tritium 210
862 Carbon-14 210
863 Isotopes Used in Medical PET 212
864 Sodium Isotopes 212
865 Magnesium-28 213
866 Aluminum-28 213
867 Phosphorus-32 213
868 Sulfur-35 213
869 Chlorine-36 214
8 6 10 Potassium Isotopes 214
8 6 11 Calcium-45 214
8 6 12 Chromium-51 214
8 6 13 Manganese-54 214
8 6 14 Iron Isotopes 214
8 6 15 Cobalt-60 215
8 6 16 Nickel-63 215
8 6 17 Copper Isotopes 215
8 6 18 Zinc-65 215
Contents ix
8 6 19 Gallium and Germanium Isotopes 216
8 6 20 Arsenic isotopes 216
8 6 21 Radioactive Isotopes of Selenium, Bromine, and Rare
Earth Elements 216
8 6 22 Bromine Isotopes 216
8 6 23 Krypton-85 217
8 6 24 Rubidium-86 217
8 6 25 Strontium Isotopes 217
8 6 26 Yttrium-90 217
8 6 27 Technetium-99m 217
8 6 28 Rutenium, Rhodium, and Palladium Isotopes 217
8 6 29 Silver Isotopes 218
8 6 30 Cadmium-115m 218
8 6 31 Indium Isotopes 218
8 6 32 Iodine Isotopes 218
8 6 33 Xenon Isotopes 219
8 6 34 Cesium Isotopes 219
8 6 35 Renium-186 219
8 6 36 Iridium-192 219
8 6 37 Gold-198 219
8 6 38 Mercury-203 220
8 6 39 Isotopes of Elements Heavier than Mercury 220
8 6 40 Transuranium Elements 220
8 7 The Main Steps of the Production of Unsealed Radioactive Preparations
(Lajos Baranyai) 220
871 Unsealed Radioactive Preparations Using Reactor Irradiation 221
872 Unsealed Radioisotope Preparations Based on Cyclotron Irradiation 236
873 Quality Control of Unsealed Radioactive Preparations 239
8 8 Production of Encapsulated Radioactive Preparations (Sealed Sources)
(Lajos Baranyai) 239
881 The Main Steps of the Production of Sealed Radioactive Sources 240
882 Quality Control of Sealed Radioactive Sources 241
8 9 Facilities, Equipment, and Tools Serving for Production of Radioactive
Substances (Lajos Baranyai) 241
Further Reading 244
Chapter 9: Physicochemical Application of Radiotracer Methods 247
9 1 The Thermodynamic Concept of Classification (Distribution
of Radioactive and Stable Isotopes) 247
9 2 Classification of Tracer Methods 250
9 3 Physicochemical Applications of Tracer Methods 253
931 Solubility Measurements 253
932 Measurements of the Rate of Migration, Diffusion, and
Self-Diffusion 254
933 Isotope Exchange Reactions 267
934 Study of Interfacial Reactions 280
935 Coprecipitation 283
936 Tracer Techniques in Electrochemistry 285
Further Reading 285
Chapter 10: Radio- and Nuclear Analysis 287
10 1 Radioactive Isotopes as Tracers 287
10 1 1 The Measurement of Concentration Using Natural Radioactive
Isotopes 287
10 1 2 Determination of Yield of Separation Reactions by Radioactive
Tracers 288
10 1 3 Solubility Measurements 290
10 1 4 Radiochromatography 290
10 1 5 Radiometric Titration 291
10 1 6 Isotope Dilution Methods 293
10 2 Radioanalytical Methods Using the Interaction of Radiation
with Matter 297
10 2 1 Basic Concepts 297
10 2 2 Analytical Methods Using Irradiations with Neutrons 303
10 2 3 Irradiation with X-Ray and Gamma Photons 318
10 2 4 Irradiation with Electron and Beta Radiation 325
10 2 5 Irradiation with Charged Particles 327
Further Reading 332
Chapter 11: Industrial Application of Radioisotopes 335
Lajos Baranyai
11 1 Introduction 335
11 2 Tracer Investigations With Open/Unsealed Radioisotopes 335
11 2 1 The Principle, Types, and Sensitivity of the Radiotracer Technique 336
11 2 2 Unsealed Radionuclides Used for Labeling in Industrial Tracer
Studies 337
11 2 3 Exploration of Leaks 339
11 2 4 Determination of Flow Rates 340
11 2 5 Measuring Volume and/or Mass of Large Quantities of Substances
in Closed Equipment 344
Contents xi
11 2 6 Investigation of Homogeneity of Mixtures 345
11 2 7 Characterization of Material Flow and Determination of Chemical
Engineering Parameters 347
11 2 8 Wear Studies 354
11 2 9 Groundwater Flow Studies 355
11 3 Absorption and Scattering Measurements With Sealed Radioactive
Sources 357
11 3 1 Principle of the Measurements 357
11 3 2 Sealed Radioactive Sources Used for Measurement 357
11 3 3 Level Indication of Materials in Tanks 358
11 3 4 Material Thickness Determination 359
11 3 5 Material Density Determination 362
11 3 6 Moisture Content Determination 362
11 3 7 Industrial Radiography 364
11 3 8 Geological Borehole Logging With Nuclear Methods 366
Further Reading 367
Chapter 12: An Introduction to Nuclear Medicine 369
Jo zsef Varga
12 1 Fields of Nuclear Medicine 369
12 1 1 In Vitro Diagnostics 369
12 1 2 In Vivo Diagnostics 370
12 1 3 Therapy with Unsealed Radioactive Preparations 370
12 2 The Role and Aspects of Applying Radiotracers in Medicine 371
12 2 1 Comparison of Methods for In Vitro Measurement
of Concentrations 371
12 2 2 Measurement of Tracers and Contrast Materials Inside the Organism
by External Detectors 371
12 2 3 Production of Artificial Radionuclides 372
12 2 4 How Do You Choose Radiotracers for Medical Applications? 372
12 2 5 Types of Electromagnetic Radiation 375
12 2 6 Most Common Radionuclides in Nuclear Medicine 376
12 2 7 Theranostics 378
12 3 In Vitro Diagnostics with Radioisotopes 378
12 3 1 Basic Reaction of Immunoassays 379
12 3 2 Immunometric (“Sandwich”) Assay 379
12 4 Radionuclide Imaging 380
12 4 1 Parts of a Gamma Camera 382
12 4 2 Digital Gamma Cameras 383
12 4 3 Methods for Emission Imaging 383
12 4 4 Computer-Aided Processing of Nuclear Medical Images 384
12 5 Some Examples of Gamma Camera Imaging Procedures 387
12 5 1 Thyroid Scintigraphy 388
12 5 2 Tumor Imaging 388
12 5 3 Myocardial Perfusion Scintigraphy 390
12 5 4 SPECT Imaging of Epilepsy 391
12 6 Positron Emission Tomography 392
12 6 1 The PET Camera 392
12 6 2 18F-FDG PET Studies with PET-CT 393
12 6 3 Research Studies Using PET 394
12 6 4 Imaging Myocardial Metabolism 396
Further Reading 397
Chapter 13: Environmental Radioactivity 399
13 1 Natural Radioactive Isotopes 399
13 2 Radioactive Isotopes of Anthropogenic Origin 400
13 3 Occurrence of Radioactive Isotopes in the Environment 402
13 3 1 Radioactivity in the Atmosphere 403
13 3 2 Radioactivity in the Hydrosphere 405
13 3 3 Radioactivity in the Lithosphere 405
13 3 4 Radioactive Isotopes in Living Organisms 407
13 4 Biological Effects of Radiation 409
13 4 1 Dose Units 409
13 4 2 Mechanism of Biological Effects 411
13 4 3 The Natural Background of Radiation 413
13 4 4 Effects of Radiation on Living Organisms 415
Further Reading 419
Chapter 14: Detection and Measurement of Radioactivity 421
14 1 Gas-Filled Tubes 423
14 2 Scintillation Detectors 426
14 2 1 Scintillator Materials 426
14 2 2 Photomultipliers 432
14 3 Semiconductor Detectors 433
14 4 Electric Circuits Connected to Detectors 435
14 5 Track and Other Detectors 436
14 5 1 Cloud Chambers and Bubble Chambers 436
14 5 2 Autoradiography 437
14 5 3 Solid-State Detectors 438
Contents xiii
14 5 4 Chemical Dosimeters 438
14 5 5 Detection of Neutrons by Nuclear Reactions 439
14 6 Absolute Measurement of Decomposition 440
14 7 Statistics of Radioactive Decay 441
14 7 1 Statistical Error of Radioactivity Measurement 441
14 7 2 Correction of Background Radioactivity 444
Further Reading 445
|
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| id | DE-604.BV044985290 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T08:06:23Z |
| institution | BVB |
| isbn | 9780128136430 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-030377605 |
| oclc_num | 1028013580 |
| open_access_boolean | |
| owner | DE-19 DE-BY-UBM DE-11 |
| owner_facet | DE-19 DE-BY-UBM DE-11 |
| physical | xvi, 464 Seiten Illustrationen, Diagramme |
| publishDate | 2018 |
| publishDateSearch | 2018 |
| publishDateSort | 2018 |
| publisher | Elsevier |
| record_format | marc |
| spelling | Kónya, József 1937- Verfasser (DE-588)1167868897 aut Nuclear and radiochemistry József Kónya and Noémi M. Nagy (Imre Lajos Isotope Laboratory, Department of Physical Chemistry, University of Debrecen, Hungary) Second edition Amsterdam, Netherlands ; Oxford, United Kingdom; Cambridge, MA, United States Elsevier [2018] © 2018 xvi, 464 Seiten Illustrationen, Diagramme txt rdacontent n rdamedia nc rdacarrier Kernchemie (DE-588)4138530-5 gnd rswk-swf Radiochemie (DE-588)4138529-9 gnd rswk-swf Kernchemie (DE-588)4138530-5 s Radiochemie (DE-588)4138529-9 s DE-604 Nagy, Noémi M. Verfasser (DE-588)1167875907 aut Erscheint auch als Online-Ausgabe 978-0-12-813644-7 V:DE-603;B:DE-17 application/pdf http://scans.hebis.de/HEBCGI/show.pl?42381487_toc.pdf Inhaltsverzeichnis HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030377605&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Kónya, József 1937- Nagy, Noémi M. Nuclear and radiochemistry Kernchemie (DE-588)4138530-5 gnd Radiochemie (DE-588)4138529-9 gnd |
| subject_GND | (DE-588)4138530-5 (DE-588)4138529-9 |
| title | Nuclear and radiochemistry |
| title_auth | Nuclear and radiochemistry |
| title_exact_search | Nuclear and radiochemistry |
| title_full | Nuclear and radiochemistry József Kónya and Noémi M. Nagy (Imre Lajos Isotope Laboratory, Department of Physical Chemistry, University of Debrecen, Hungary) |
| title_fullStr | Nuclear and radiochemistry József Kónya and Noémi M. Nagy (Imre Lajos Isotope Laboratory, Department of Physical Chemistry, University of Debrecen, Hungary) |
| title_full_unstemmed | Nuclear and radiochemistry József Kónya and Noémi M. Nagy (Imre Lajos Isotope Laboratory, Department of Physical Chemistry, University of Debrecen, Hungary) |
| title_short | Nuclear and radiochemistry |
| title_sort | nuclear and radiochemistry |
| topic | Kernchemie (DE-588)4138530-5 gnd Radiochemie (DE-588)4138529-9 gnd |
| topic_facet | Kernchemie Radiochemie |
| url | http://scans.hebis.de/HEBCGI/show.pl?42381487_toc.pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030377605&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT konyajozsef nuclearandradiochemistry AT nagynoemim nuclearandradiochemistry |
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