Chiral nanomaterials: preparation, properties and applications
Saved in:
| Other Authors: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Weinheim
Wiley-VCH
[2018]
|
| Subjects: | |
| Online Access: | http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-33757-6/ Inhaltsverzeichnis |
| Physical Description: | ix, 289 Seiten Illustrationen, Diagramme (überwiegend farbig) |
| ISBN: | 9783527337576 3527337571 |
Staff View
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| 245 | 1 | 0 | |a Chiral nanomaterials |b preparation, properties and applications |c edited by Zhiyong Tang |
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| 264 | 4 | |c © 2018 | |
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| 653 | |a Chemie | ||
| 653 | |a Chemistry | ||
| 653 | |a Nanomaterialien | ||
| 653 | |a Nanomaterials | ||
| 653 | |a Nanotechnologie | ||
| 653 | |a Nanotechnology | ||
| 653 | |a Oberflächen- u. Kolloidchemie | ||
| 653 | |a Polymer Science & Technology | ||
| 653 | |a Polymerwissenschaft u. -technologie | ||
| 653 | |a Surface & Colloid Chemistry | ||
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Record in the Search Index
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| adam_text | CONTENTS
1 AN INTRODUCTION TO CHIRAL NANOMATERIALS: ORIGIN, CONSTRUCTION,
AND OPTICAL APPLICATION 1
ZHENGTAO LIF LIN SHI
,
AND ZHIYONG TANG
1.1 INTRODUCTION 1
1.2 CHIRAL NOBLE METAL CLUSTERS 3
1.2.1 ORIGIN OF CHIRAL NOBLE METAL CLUSTERS 3
1.2.2 CONSTRUCTION OF CHIRAL NOBLE METAL CLUSTERS WITH OPTICAL ACTIVITY
4
1.3 CHIRAL PLASMONIC NANOSTRUCTURES 5
1.3.1 ORIGIN OF CHIRAL PLASMONIC NANOSTRUCTURES 6
1.3.2 CONSTRUCTION OF CHIRAL PLASMONIC NANOPARTICLES WITH OPTICAL
ACTIVITY 10
1.3.3 CONSTRUCTION OF CHIRAL PLASMONIC ASSEMBLY WITH OPTICAL ACTIVITY 12
1.3.3.1 SOFT-TEMPLATE-INDUCED CHIRAL PLASMONIC ASSEMBLY 12
1.3.3.2 DNA-INDUCED CHIRAL PLASMONIC ASSEMBLY 14
1.3.3.3 INORGANIC-CHANNEL-INDUCED CHIRAL PLASMONIC ASSEMBLY 17
1.4 OPTICAL APPLICATION OF CHIRAL NOBLE METAL NANOSTRUCTURES 20
1.5 PERSPECTIVES 22
REFERENCES 24
2 CHIRALITY AT NANOSCALE - THEORY AND MECHANISM 29
WEI ZHANG
2.1 INTRODUCTION 29
2.2 BRIEF INTRODUCTION TO THE THEORETICAL BACKGROUND 32
2.2.1 QUANTUM DOTS, MOLECULES 32
2.2.2 METALLIC NANOSTRUCTURES 33
2.3 THE TWIST ROD MODEL 34
2.3.1 THE CD SPECTRA OF MIRROR SYSTEMS 34
2.3.2 DEPENDENCE ON THE SHAPE/ASPECT RATIO 34
2.3.3 DEPENDENCE ON THE GEOMETRIC STRUCTURE (6) - THE EXTENT OF
SYMMETRIC BREAKING 35
2.3.4 DEPENDENCE ON THE ELECTROMAGNETIC INTERACTION 36
2.3.5 INDUCED CHIRALITY 37
2.4 INDUCED CHIRALITY IN HYBRID NANOSTRUCTURES MADE OF CHIRAL MOLECULES
AND QDS 37
2.5 INDUCED CHIRALITY IN HYBRID NANOSTRUCTURES MADE OF CHIRAL MOLECULES
AND METAL NANOPARTICLES 39
2.6 INDUCED CHIRALITY IN HYBRID NANOSTRUCTURES MADE OF CHIRAL QUANTUM
DOTS AND METAL NANOPARTICLES 43
REFERENCES 47
3 PLASMONIC CHIRAL MATERIALS 51
CHENGYI SONG, CHEN ZHANG
,
AND PENG TAO
3.1 INTRODUCTION 51
3.2 FABRICATION OF PLASMONIC CHIRAL NANOMATERIALS 52
3.2.1 TOP-DOWN FABRICATION METHOD 52
3.2.2 BOTTOM-UP FABRICATION METHOD 53
3.2.2.1 TEMPLATE-BASED METHOD 53
3.2.2.2 STIMULI-RESPONSE FABRICATION METHOD 64
3.2.2.3 DYNAMIC SHADOWING GROWTH 66
3.3 PROPERTIES OF PLASMONIC CHIRAL NANOMATERIALS 68
3.3.1 OPTICAL PROPERTY 68
3.3.1.1 CIRCULAR DICHROISM 68
3.3.1.2 METAMATERIAL EFFECT 73
3.3.2 MAGNETIC PROPERTY 74
3.4 APPLICATIONS OF PLASMONIC CHIRAL NANOMATERIALS 77
3.4.1 CHIRAL DETECTION 77
3.4.2 SERS SENSOR 79
3.4.3 CHIRAL POLARIZER 79
3.5 CONCLUSIONS 79
ACKNOWLEDGMENTS 80
REFERENCES 80
4 OPTICALLY ACTIVE AND CHIRAL SEMICONDUCTOR NANOCRYSTALS 85
ASSAF BEN MOSHE AND GIL MARKOVICH
4.1 INTRODUCTION 85
4.2 CHIROPTICALLY ACTIVE EXCITONIC NANOCRYSTALS 86
4.3 EFFECTS THAT EMERGE FROM CHIRAL ARRANGEMENT OF NANOCRYSTALS 92
4.4 NANOCRYSTALS WITH CHIRAL CRYSTAL SYMMETRY (CHIRAL ATOMIC
ARRANGEMENT) 92
4.5 NANOSTRUCTURES WITH CHIRAL SHAPE 95
4.6 SUMMARY AND OUTLOOK 96
REFERENCES 97
5 CHIRALITY IN GOLD NANOCLUSTERS 99
CHENJIE ZENG, ZHIKUN WU, AND RONGCHAO JIN
5.1 INTRODUCTION 99
5.2 THE ORIGIN OF CHIRALITY IN AUW(SR)W NANOCLUSTERS
100
5.3 X-RAY STRUCTURES OF CHIRAL AUW(SR)M NANOCLUSTERS 101
5.3.1 A
U
20(SR)16 102
5.3.2 A
U
28(SR)20 102
5.3.3 A
U
38(SR)24 10S
5.3.4 A
U
102(SR)44 105
5.3.5 A
U
133(SR)52 106
5.3.6 SUMMARY OF SYMMETRY OF CHIRAL AND ACHIRAL AUW(SR)M
NANOCLUSTERS 109
5.4 SEPARATION OF RACEMIC GOLD NANOCLUSTERS AND THEIR CHIROPTICAL
PROPERTIES 110
5.4.1 A
U
38(SR)24 110
5.4.2 A
U
28(SR)20 111
5.5 OTHER CHIRALITY ORIGINS IN GOLD NANOCLUSTERS 111
5.5.1 CHIRALITY INDUCED BY CHIRAL CARBON CENTER IN THE THIOLATE
LIGAND 111
5.5.2 CHIRALITY IN PHOSPHINE-PROTECTED GOLD NANOCLUSTERS 114
5.6 CONCLUSION 115
ACKNOWLEDGMENT 115
REFERENCES 116
6 CHIRAL MESOPOROUS SILICA MATERIALS 121
YUANYUAN CAO AND SHUNAI CHE
6.1 INTRODUCTION 121
6.2 CHIRAL MESOPOROUS MATERIALS TEMPLATED BY ARTIFICIAL
AMPHIPHILES 123
6.2.1 CHIRAL MESOPOROUS SILICAS (CMSS) 123
6.2.1.1 SYNTHESIS AND FORMATION MECHANISM 123
6.2.1.2 SYNTHETIC CONTROL 135
6.2.1.3 FEATURES 144
6.2.2 OTHER INORGANIC MESOPOROUS MATERIALS 147
6.2.2.1 NONSILICEOUS MATERIALS 148
6.2.2.2 ELECTRON TRANSITION-BASED OPTICAL ACTIVITY (ETOA) 148
6.3 CHIRAL MESOPOROUS MATERIALS TEMPLATE BY DNA 152
6.3.1 ONE-DIMENSIONAL MULTIHELICAL SILICA FIBERS 153
6.3.2 THREE-DIMENSIONAL DNA-SILICA CHIRAL IMPELLER 154
6.3.2.1 MECHANISM OF HANDEDNESS INVERSION 155
6.3.2.2 HIERARCHICAL CHIRALITY: WATER-INDEPENDENT OPTICAL ACTIVITY 157
6.3.3 CHIRAL DNA-SILICA FILMS 157
6.4 CHIRAL MESOPOROUS MATERIALS TEMPLATED BY PEPTIDES 158
6.4.1 CHIRAL PEPTIDE MINERALIZATION OF SS-SHEET 159
6.4.2 CHIRAL POLYPEPTIDE MINERALIZATION OF A-HELICES 161
6.5 CHIRAL MESOPOROUS MATERIALS TEMPLATED BY POLYSACCHARIDES 162
6.5.1 CHIRAL MESOPOROUS CELLULOSE-SILICA FREESTANDING FILM 164
6.5.2 CHIRAL MESOPOROUS CHITIN-SILICA FREESTANDING FILM 164
6.6 SUMMARY AND OUTLOOK 164
REFERENCES 167
7 DNA-BASED CHIRAL NANOSTRUCTURES 179
HUA KUANG AND CHUANLAI XU
7.1 INTRODUCTION 179
7.2 PREPARATION OF DNA-DIRECTED CHIRAL NANOSTRUCTURES 180
7.2.1 NPS/DNA CONJUGATES 180
7.2.2 CHIRAL ASSEMBLY OF NPS 182
7.2.2.1 DIRECT HYBRIDIZATION FROM WATSON-CRICK BASE PAIRING 182
122.2 DNA TEMPLATE ENGINEERING 182
7 2 2 3 NANOASSEMBLY BY PCR 183
7.3 TYPICAL CHIRAL NANOCRYSTALS AND NANOASSEMBLIES 185
7.3.1 INDIVIDUAL CHIRAL NANOPARTICLES 185
7.3.2 CHIRAL DIMERS 188
732.1 PREPARATION AND PROPERTIES 188
7 3 2 2 CHIRAL SENSING BASED ON DIMERS 190
7.3.3 CHIRAL CHAIN AND LADDER ASSEMBLIES 193
7.3.3.1 AU NP CHIRAL CHAINS 193
7 3 3 2 AU NR CHIRAL LADDER 194
7.3.4 TETRAHEDRON NANOARCHITECTURES 197
7.3.4.1 CHIRAL PYRAMID FABRICATION 197
7.3.42 DETECTIONS BASED ON PYRAMID NANOSTRUCTURE 201
7.3.5 CHIRAL HELICAL NANOPARTICLE ASSEMBLIES 202
7.3.6 OTHER NOVEL CHIRAL NANOSTRUCTURES 202
7.3.6.1 CORE-SATELLITES ASSEMBLIES 202
73.6.2 CHIRAL PLASMONIC OLIGOMERS 205
7.4 ORIGIN OF CHIROPLASMONIC ACTIVITIES 206
7.4.1 PLASMONIC CHIROGENESIS IN GOLD NANOPARTICLES ASSEMBLIES 206
7.4.2 UNDERSTANDING OF CHIROGENESIS IN GOLD NANOROD ASSEMBLIES 212
7.5 CONCLUSIONS 215
REFERENCES 217
8 APPLICATIONS IN CATALYSIS 223
TOMOHIRO YASUKAWA, HIROYUKI MIYAMURA, AND SHQ KOBAYASHI
8.1 INTRODUCTION 223
8.2 ASYMMETRIC HYDROGENATION REACTIONS CATALYZED BY CHIRAL METAL
NANOPARTICLES 225
8.2.1 ORITO-TYPE ASYMMETRIC HYDROGENATION 225
8.2.2 ASYMMETRIC HYDROGENATION OF ELECTRON-DEFICIENT OLEFINS 229
8.2.3 ASYMMETRIC HYDROGENATION OF UNACTIVATED KETONES 232
8.2.4 ASYMMETRIC HYDROSILYLATION 236
8.3 ASYMMETRIC C -C BOND-FORMING REACTIONS CATALYZED BY CHIRAL METAL
NANOPARTICLES 239
8.3.1 BACKGROUND 239
8.3.2 ASYMMETRIC ALLYLIC ALKYLATION CATALYZED BY PALLADIUM
NANOPARTICLES 239
8.3.3 ASYMMETRIC CROSS-COUPLING REACTION CATALYZED BY PD
NANOPARTICLES 243
8.3.4 HYDROFORMYLATION CATALYZED BY RHODIUM NANOPARTICLES 245
8.3.5 PAUSON-KHAND REACTION CATALYZED BY RH NANOPARTICLES
247
8.3.6 RH NANOPARTICLE-CATALYZED 1,4-ADDITION REACTION
248
8.3.7 ASYMMETRIE REACTIONS CATALYZED BY NANOCRYSTALLINE MAGNESIUM
OXIDE
249
8.3.8 ASYMMETRIC REACTIONS CATALYZED BY COPPER NANOPARTICLES
250
8.3.9 ASYMMETRIC REACTIONS CATALYZED BY GOLD NANOPARTICLES
251
8.4 SUMMARY
252
REFERENCES
252
9
APPLICATIONS IN POLYMER SCIENCE
259
YI LI, BAOZONG LI, AND YONGGANG YANG
9.1 INTRODUCTION
259
9.2 PREPARATION OF CHIRAL POLYBISSILSESQUIOXANES
260
9.2.1 PREPARATION THROUGH A SELF-TEMPLATING APPROACH
261
9.2.2 PREPARATION THROUGH AN EXTERNAL TEMPLATING APPROACH
262
9.2.2.1 PREPARATION USING CHIRAL CATIONIC LMWAS
263
9.2.2.2 PREPARATION USING CHIRAL ANIONIC LMWAS
267
9.3 CHARACTERIZATION OF CHIRAL POLYBISSILSESQUIOXANES
271
9.3.1 X-RAY DIFFRACTION CHARACTERIZATION
271
9.3.2 TEM CHARACTERIZATION
272
9.3.3 CHARACTERIZATION OF OPTICAL ACTIVITY
272
9.4 APPLICATIONS OF CHIRAL POLYBISSILSESQUIOXANES
276
9.5 CONCLUSION
276
REFERENCES
277
INDEX
281
|
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| dewey-full | 540 |
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| dewey-ones | 540 - Chemistry and allied sciences |
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| dewey-search | 540 |
| dewey-sort | 3540 |
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| discipline | Chemie / Pharmazie Werkstoffwissenschaften / Fertigungstechnik |
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| id | DE-604.BV044675038 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T07:59:00Z |
| institution | BVB |
| institution_GND | (DE-588)16179388-5 |
| isbn | 9783527337576 3527337571 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-030072333 |
| oclc_num | 1020767645 |
| open_access_boolean | |
| owner | DE-703 DE-11 DE-29T DE-19 DE-BY-UBM |
| owner_facet | DE-703 DE-11 DE-29T DE-19 DE-BY-UBM |
| physical | ix, 289 Seiten Illustrationen, Diagramme (überwiegend farbig) |
| publishDate | 2018 |
| publishDateSearch | 2018 |
| publishDateSort | 2018 |
| publisher | Wiley-VCH |
| record_format | marc |
| spelling | Chiral nanomaterials preparation, properties and applications edited by Zhiyong Tang Weinheim Wiley-VCH [2018] © 2018 ix, 289 Seiten Illustrationen, Diagramme (überwiegend farbig) txt rdacontent n rdamedia nc rdacarrier Chiralität Chemie (DE-588)4147732-7 gnd rswk-swf Nanostrukturiertes Material (DE-588)4342626-8 gnd rswk-swf Biopolymere Biopolymers Chemie Chemistry Nanomaterialien Nanomaterials Nanotechnologie Nanotechnology Oberflächen- u. Kolloidchemie Polymer Science & Technology Polymerwissenschaft u. -technologie Surface & Colloid Chemistry (DE-588)4143413-4 Aufsatzsammlung gnd-content Nanostrukturiertes Material (DE-588)4342626-8 s Chiralität Chemie (DE-588)4147732-7 s DE-604 Tang, Zhiyong edt Wiley-VCH (DE-588)16179388-5 pbl Erscheint auch als Online-Ausgabe, ePDF 978-3-527-68433-5 Erscheint auch als Online-Ausgabe, ePub 978-3-527-68430-4 Erscheint auch als Online-Ausgabe, Mobi 978-3-527-68432-8 Erscheint auch als Online-Ausgabe, oBook 978-3-527-68278-2 X:MVB http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-33757-6/ DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030072333&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Chiral nanomaterials preparation, properties and applications Chiralität Chemie (DE-588)4147732-7 gnd Nanostrukturiertes Material (DE-588)4342626-8 gnd |
| subject_GND | (DE-588)4147732-7 (DE-588)4342626-8 (DE-588)4143413-4 |
| title | Chiral nanomaterials preparation, properties and applications |
| title_auth | Chiral nanomaterials preparation, properties and applications |
| title_exact_search | Chiral nanomaterials preparation, properties and applications |
| title_full | Chiral nanomaterials preparation, properties and applications edited by Zhiyong Tang |
| title_fullStr | Chiral nanomaterials preparation, properties and applications edited by Zhiyong Tang |
| title_full_unstemmed | Chiral nanomaterials preparation, properties and applications edited by Zhiyong Tang |
| title_short | Chiral nanomaterials |
| title_sort | chiral nanomaterials preparation properties and applications |
| title_sub | preparation, properties and applications |
| topic | Chiralität Chemie (DE-588)4147732-7 gnd Nanostrukturiertes Material (DE-588)4342626-8 gnd |
| topic_facet | Chiralität Chemie Nanostrukturiertes Material Aufsatzsammlung |
| url | http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-33757-6/ http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030072333&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT tangzhiyong chiralnanomaterialspreparationpropertiesandapplications AT wileyvch chiralnanomaterialspreparationpropertiesandapplications |