Trends and applications in advanced polymeric materials:
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| Format: | Book |
| Language: | English |
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Hoboken, NJ
Wiley
2017
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| Subjects: | |
| Online Access: | Inhaltsverzeichnis Klappentext |
| Item Description: | Includes index |
| Physical Description: | xvii, 310 pages Illustrationen |
| ISBN: | 9781119363637 |
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| 245 | 1 | 0 | |a Trends and applications in advanced polymeric materials |c edited by Sanjay K. Nayak, Smita Mohanty and Lakshmi Unnikrishnan |
| 264 | 1 | |a Hoboken, NJ |b Wiley |c 2017 | |
| 264 | 4 | |c © 2018 | |
| 300 | |a xvii, 310 pages |b Illustrationen | ||
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| 700 | 1 | |a Mohanty, Smita |4 edt | |
| 700 | 1 | |a Unnikrishnan, Lakshmi |4 edt | |
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| adam_text | Contents
Preface xv
1 Polymer Nanocomposites and Coatings: The Game Changers 1
Gaurav Verma
1.1 Introduction 1
1.2 Polymer Nanocomposites 4
1.2.1 Types of Polymer Nanocomposites: Processing 4
1.2.1.1 Equipment and Processing 7
1.2.2 Polymer Property Enhancements 9
1.2.3 Polymer Nanocomposite Structure
an d Morphology 10
1.2.4 Characterization of Polymer Nanocomposites 11
1.2.4.1 Morphological Testing 12
1.2.4.2 Spectral Testing 14
1.2.4.3 Testing 15
1.2.5 Applications 16
1.2.5.1 Nanocomposite Coatings:
Focus PU-Clay Coatings 17
1.3 Conclusions 18
Acknowledgments 19
References 19
2 DGEBA Epoxy/CaC03 Nanocomposites for Improved
Chemical Resistance and Mechanical Properties for
Coating Applications 23
Manoj Kumar Shukla, Archana Mishra, Kavita Srivastava,
A K Rathore and Deepak Srivastava
2.1 Introduction 24
2.2 Experimental 26
2.2.1 Preparation of Epoxy/CaCO, Nanocomposites 26
2.2.2 Preparation of Panels 27
2.2.3 Preparation of Reagents for Chemical Resistance 27
27
28
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35
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57
58
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60
61
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62
63
Contents
2.2.3.1 Artificial Seawater (ASW)
2.2.4 Preparation of Films
2.3 Characterization of Epoxy/CaCOa Nanocomposite
2.3.1 Fourier Transform Infrared (FTIR) Spectra
2.3.2 Mechanical Properties
2.3.2.1 Impact Resistance
2.3.2.2 Scratch Hardness
2.3.2.3 Adhesion and Flexibility Test
2.3.2.4 Chemical Resistance Test
2.3.2.5 Morphological Properties
2.4 Results and Discussion
2.4.1 FTIR Spectroscopic Analysis
2.4.2 Studies on Mechenical Properties
2.4.2.1 Impact Resistance
2.4.2.2 Studies of Scratch Hardness
2.4.2.3 Adhesion and Flexibility Test
(Mandrel Bend Test)
2.4.3 Studies on Chemical Resistance
2.4.4 Morphological Studies
2.5 Conclusion
References
An Industrial Approach to FRLS (Fire Retardant Low Smoke)
Compliance in Epoxy Resin-Based Polymeric Products
Hari R and Sukumar Roy
3.1 Introduction
3.1.1 Incorporation of Additives
3.2 Experimental
3.3 Characterization, Results and Discussion
3.4 Conclusion
Acknowledgments
References
Polymer-Based Organic Solar Cell: An Overview
Neha Patni, Pranjal Sharma, Mythilypriya Suresh,
Birendrakumar Tiwari and Shibu G. Pillai
4.1 Introduction
4.2 Polymer Solar Cells: An Insight
4.2.1 Why Polymer Solar Cells are Preferable
4.3 Layer Stack Construction of Polymer Solar Cells
4.4 Simple Working of a Polymer Solar Cell
Contents vii
4.5 Life-Cycle Analysis (LCA) 63
4.6 Current Condition of Polymer Solar Cells 64
4.7 Materials Used for Developing PSC 65
4.7.1 Synthesis of Polymer Materials 65
4.7.1.1 Stille Cross-Coupling 66
4.7.1.2 Suzuki Cross-Coupling 66
4.7.1.3 Direct Arylation Polymerization 66
4.7.1.4 Polymerization Rates 67
4.7.2 Conjugated Polymers 67
4.7.3 Side-Chain Influence in Polymers 68
4.7.4 Purification 69
4.8 Degradation and Stability of a PSC 69
4.8.1 Physical Degradation 69
4.8.1.1 Morphological Stability 69
4.8.1.2 Flexibility and Delamination 70
4.8.2 Chemical Degradation 70
4.8.2.1 Polymer Instability 70
4.8.2.2 Photochemical Degradation 71
4.9 Dyes 72
4.9.1 Natural Dyes Used for Polymer Solar Cells 73
4.10 Performed Experiments 75
4.10.1 Experimental Setup 1 75
4.10.2 Experimental Setup 2 77
4.11 Summary 78
References 79
5 A Simple Route to Synthesize Nanostructures of Bismuth
Oxyiodide and Bismuth Oxychloride (BiOI/BiOCl)
Composite for Solar Energy Harvesting 83
I. D. Sharma, Chander Kant, A. K. Sharma,
Ravi Ranjan Pandey and K. K. Saini
5.1 Introduction 83
5.1.1 Bismuth Oxyhalide [BiOX (X = Cl, Br, I)]:
General Remarks 87
5.1.2 Synthesis of Bismuth Oxyhalide 89
5.2 Photocatalytic Activity Measurements 91
5.3 Results and Discussion 91
5.4 Conclusion 96
Acknowledgments 97
References 98
viii Contents
6 Investigation of DC Conductivity, Conduction Mechanism
and CH4 Gas Sensor of Chemically Synthesized Polyaniline
Nanofiber Deposited on DL-PLA Substrate 101
Muktikanta Panigrahi, Debabrat Pradhan,
Subhasis Basu Majumdar and Basudam Adhikari
6.1 Introduction 102
6.2 Experimental Details 104
6.2.1 Preparation of Desired Materials 104
6.2.2 Characterization of DL-PLA Films and
DL-PLA/PANI-ES Composites 105
6.3 Results and Discussion 106
6.3.1 Scanning Electron Microscopic (SEM) Analysis 106
6.3.2 Attenuated Total Reflectance Fourier
Transformation Infrared (ATR-FTIR)
Spectroscopic Analysis 107
6.3.3 Ultraviolet Visible (UV-Vis) Absorption
Spectroscopic Analysis 109
6.3.4 DC Electrical Analysis 111
6.4 Conclusion 120
Acknowledgments 121
References 121
Electrical Properties of Conducting Polymer-MWCNT
Binary and Hybrid Nanocomposites 127
B.T.S. Ramanujam and S. Radhakrishnan
7.1 Introduction 128
7.1.1 Theoretical Background of Electrical
Conductivity in CPCs 129
7.1.2 Factors Affecting Electrical Percolation
Threshold 129
7.1.3 Processing Methods of CPCs 130
7.1.4 Conduction Mechanism in CPCs 130
7.1.5 Multiwalled Carbon Nanotube
(MWCNT) - Potential Conducting Filler 131
7.1.5.1 Synthesis Methods of
Carbon Nanotubes 132
7.1.6 Electrical Properties of Polymer-MWCNT
Composites 134
7.2 AC/DC Properties of Polyethersulfone (PES)-MWCNT,
PES-Graphite-MWCNT Nanocomposites 135
7.2.1 Material Properties 135
Contents ix
7.2.2 Composite Preparation 135
7.3 Discussion of Results 136
7.3.1 Electrical Behavior of Polyethersulfone
(PES)-MWCNT Binary and PES-Graphite-
MWCNT Hybrid Composites 136
7.3.2 Transmission Electron Microscopy
(TEM) Analysis 138
7.4 Conclusion and Future Perspectives 139
Acknowledgment 141
References 141
8 Polyaniline-Based Sensors for Monitoring and
Detection of Ammonia and Carbon Monoxide Gases 145
Neha Patni, Neha Jain and Shibu G. Pillai
8.1 Introduction 145
8.2 Conducting Polymers 146
8.2.1 Polyaniline 147
8.2.1.1 Structure of Polyaniline 148
8.2.1.2 Properties of Polyaniline 148
8.3 Ammonia Detection 149
8.3.1 Sources of Ammonia 149
8.3.2 Experiment: Ammonia Sensor 153
8.4 Carbon Monoxide (CO) Detection 154
8.4.1 Common Sources of CO 154
8.4.2 Sensors Used for Detection of CO 155
8.5 Conclusion 158
References 159
9 Synthesis and Characterization of Luminescent
La2Zr207/Sm3+ Polymer Nanocomposites 163
Pramod Halappa and C. Shivakumara
9.1 Introduction 164
9.1.1 Luminescence 165
9.1.2 Photoluminescence 165
9.1.2.1 Fluorescence 165
9.1.2.2 Delayed Fluorescence or
Phosphorescence 167
9.1.2.3 Jablonski Diagram 167
9.1.2.4 Phosphors 169
9.1.2.5 Photoluminescence of Samarium
Ion (Sm3+) 173
Scope and Objectives of the Present Study 173
9.1.3
x Contents
9.2 Experimental 175
9.2.1 Synthesis of Sm3+-Doped La2Zr207 175
9.2.2 Preparation of PVA Polymer Thin Films 176
9.2.3 Preparation of Sm3+-Doped La2Zr207 with
PVA-Polymer Composite Films 177
9.2.4 Characterization 177
9.3 Results and Discussion 178
9.3.1 Structural Analysis by X-Ray Diffraction 178
9.3.2 SEM Analysis 181
9.3.3 UV-Vis Spectroscopy 181
9.3.4 Thermogravimetric Analysis (TGA) 181
9.3.5 Photoluminescence Properties 182
9.3.6 Chromaticity Color Coordinates 184
9.4 Conclusion 186
Aknowledgment 186
References 186
10 Study of Gas Transport Phenomenon in Layered
Polymer Nanocomposite Membranes 191
A.K. Patel and N.K. Acharya
10.1 Introduction 192
10.1.1 Transport Phenomenon 193
10.1.2 Metal Coating 196
10.2 Experimental 196
10.2.1 Fabrication of Nanocomposite Membrane 196
10.2.2 Gas Permeability Test 197
10.3 Results and Discussion 199
10.4 Conclusion 203
Acknowledgment 203
References 204
11 Synthesis and Ion Transport Studies of K+ Ion
Conducting Nanocomposite Polymer Electrolytes 207
Angesh Chandra, Alok Bhatt and Archana Chandra
11.1 Introduction 208
11.2 Experimental 209
11.3 Results and Discussion 210
11.4 Conclusion 216
Acknowledgment 217
References 217
Contents xi
12 Recent Studies in Polyurethane-Based Drug Delivery Systems 219
Archana Solanki and Sonal Thako
12.1 Introduction 219
12.1.1 Polyurethane Chemistry: A Brief Overview 219
12.1.2 Carbohydrate Cross-Linked Polyurethanes 227
12.1.3 Biomedical Applications of PUs 229
12.2 Experimental 232
12.2.1 Impact of PU Chemistry on Drug
Delivery Profiles 232
12.2.2 Drug Loading and Release Kinetics 235
12.2.3 Waterborne pH-Responsive Polyurethanes 236
12.3 Conclusion 240
References 240
13 Synthesis and Characterization of Polymeric Hydrogels
for Drug Release Formulation and Its Comparative Study 245
NisargK. Prajapati, Nirmal K. Patel and
Vijay Kumar Sinha
13.1 Introduction 246
13.2 Materials and Method 246
13.2.1 Preparation of Sodium Salt of Partly
Carboxylic Propyl Starch (Na-PCPS) 246
13.2.2 Preparation of 2-Hydroxy-3-
((2-hydroxypropanoyl)oxy)propyl acrylate 247
13.2.3 Graft Copolymerization with PCPS-g-2-
hydroxy- 3 - ((2 - hydroxyprop anoyl) oxy)
propyl acrylate (HPA) 247
13.2.4 Drug Loading in Polymeric Binder 248
13.2.5 Preparation of Matrix Tablets 249
13.2.6 In-Vitro Dissolution Studies of Tablet 250
13.3 Result and Discussion 250
13.3.1 UC-NMR Spectra Analysis of 2-Hydroxy-3-
((2-hydroxypropanoyl)oxy) propyl acrylate 250
13.3.2 XRD Analysis of Starch, CPS, PCPS-g-2-
hydr oxy- 3 - ((2 - hydroxyprop anoyl) oxy)
propyl acrylate (HPA) 250
13.3.3 In-Vitro Study 251
13.4 Conclusion 253
Acknowledgment 253
References 253
xii Contents
14 Enhancement in Gas Diffusion Barrier Property of
Polyethylene by Plasma Deposited SiOx Films for Food
Packaging Applications 255
Purvi Dave, Nisha Chandwani, S. K. Nema and S. Mukherji 255
14.1 Introduction 256
14.2 Transport of Gas Molecules Through Packaging
Polymers 258
14.2.1 Packaging Polymer Struture 258
14.2.2 Transport of Gas Molecules Through
Semicrystalline Polymer Films 258
14.2.3 Measurement of Gas Transmission
Rate Through a Packaging Film 260
14.3 Experimental 261
14.3.1 Contact Angle Measurements to Determine
Film Wetting Properties 262
14.3.2 FTIR-ATR Study to Determine Film Chemistry 262
14.3.3 Film Thickness Measurement 262
14.3.4 High Resolution Scanning Electron
Microscopy to Determine Film Morphology 262
14.3.5 OTR Measurement to Determine
Oxygen Diffusion Barrier Property 263
14.4 Results 263
14.4.1 Observations 263
14.4.1.1 Wetting Behavior of SiOx Films 263
14.4.1.2 Chemistry of SiOx Film 264
14.4.1.3 Deposition Rate 264
14.4.1.4 High Resolution Scanning Electron
Microscopy 265
14.4.1.5 Oxygen Transmission Rate 267
14.4.2 Discussion 267
14.5 Conclusion 271
References 272
15 Synthesis and Characterization of Nanostructured
Olivine LiFeP04 Electrode Material for Lithium-Polymer
Rechargeable Battery 275
K. Rani, M. Abdul Kader and S. Palaniappan
15.1 Introduction 276
15.1.1 Energy Storage: Rechargeable Batteries 276
15.1.1.1 Lithium Battery 278
15.1.1.2 Comparison between Li-Polymer
Battery and Liquid Battery 279
Contents xiii
15.1.1.3 Commercial Production 280
15.1.1.4 Advantages of Lithium Polymer
Batteries 281
15.1.1.5 Limitations of Lithium-Polymer
Batteries 282
15.1.2 Cell Manufacturers Using Lithium
Iron Phosphate 282
15.1.3 Lithium Iron Phosphate (LiFeP04) 284
15.1.3.1 Synthesis of LiFeP04 286
15.1.3.2 Structure of LiFePO, 287
15.1.3.3 Work on LiFeP04 Cell Systems 290
15.2 Experimental 292
15.2.1 Synthesis 292
15.3 Characterization 292
15.4 Results and Discussion 293
15.4.1 Morphology 293
15.4.2 E-DAX 294
15.4.3 Charge-Discharge Characteristics 294
15.4.4 XRD Studies on LiFePO, 295
15.5 Conclusion 296
Acknowledgments 297
References 298
Index 305
This comprehensive compilation of contemporary research initiatives
in polymer science technology details the advancement in the fields
of coatings, sensors, energy harvesting and gas transport.
Polymers are the most versatile material and used in all industrial sectors because
of their light weight, ease of processing and manufacturing, the ability to mold
into intricate shapes, and its cost-effectiveness. They can easily be filled with a
range of reinforcing agents like fibers, particulates, flakes and spheres in micro/
nano sizes and compete with conventional materials in terms of performance,
properties and durability. Polymers continue to be discovered and the demand for
them is increasing.
The book comprises a series of chapters outlining recent developments in
various high performance applications of Advanced Polymeric Materials. The
topics covered encompass specialized applications of polymeric matrices, their
blends, composites and nanocomposites pertaining to smart high performance
coatings, high barrier packaging, solar energy harvesting, power generation using
polymers, polymer sensors, conducting polymers, gas transport membranes and
smart drug delivery systems.
Thus, the theme of the book embraces all the latest innovations and future
applications of polymers and related materials. What is novel about this book
is that it delineates the applications from a research point of view through
descriptions highlighting specific developmental criteria.
Audience
The book serves as a reference for all those industry polymer scientists and
academic researchers required or interested in updating themselves on recent
innovations. It will be exceedingly useful for engineers and students as the
book acts as a practical guide for forward-looking research. Industrialists
and entrepreneurs will also benefit by understanding the industrially viable
technology from the novel techniques presented in the book.
S. K. Nayak holds the position of Director General, Central Institute of Plastics
Engineering Technology (CIPET) as well as Prof. Chair of R D wings of
Cl PET. He is an active researcher in the field of polymer science technology
and has authored several textbooks on novel technological developments and is
the Editor-in-Chief of International Journal of Plastics Technology (IJPT).
Smita Mohanty is the Senior Scientist and In-charge of the Laboratory for
Advanced Research in Polymeric Materials (the R D wing of CIPET), with more
than 12 years of research and teaching experience. She has published —150 papers
in major international journals and has 5 Indian patents to her credit.
Lakshmi (Jnnikrishnan is working as a Scientist at LARPM. She has published
15 papers in major international journals and her major area of research includes
polymer electrolyte membranes, piezoelectric membrane systems, membrane
separators, biosensors and conductive composites.
ISBN 978-1-119-36363-7
as an e-book
www.wiley.comwww.scrivenerpublishing.com
78
1119
363637
JSI
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| author_facet | Nayak, Sanjay K. Mohanty, Smita Unnikrishnan, Lakshmi |
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| bvnumber | BV044601456 |
| callnumber-first | T - Technology |
| callnumber-label | TA455 |
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| dewey-full | 620.1/92 |
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| dewey-ones | 620 - Engineering and allied operations |
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| discipline | Chemie / Pharmazie Physik Werkstoffwissenschaften / Fertigungstechnik |
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| id | DE-604.BV044601456 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T07:56:28Z |
| institution | BVB |
| isbn | 9781119363637 |
| language | English |
| lccn | 017036474 |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-029999884 |
| oclc_num | 1033649800 |
| open_access_boolean | |
| owner | DE-703 |
| owner_facet | DE-703 |
| physical | xvii, 310 pages Illustrationen |
| publishDate | 2017 |
| publishDateSearch | 2017 |
| publishDateSort | 2017 |
| publisher | Wiley |
| record_format | marc |
| spelling | Trends and applications in advanced polymeric materials edited by Sanjay K. Nayak, Smita Mohanty and Lakshmi Unnikrishnan Hoboken, NJ Wiley 2017 © 2018 xvii, 310 pages Illustrationen txt rdacontent n rdamedia nc rdacarrier Includes index Polymers Industrial applications Nanostructured materials Kunststoff (DE-588)4033676-1 gnd rswk-swf Hochleistungswerkstoff (DE-588)4312250-4 gnd rswk-swf Kunststoff (DE-588)4033676-1 s Hochleistungswerkstoff (DE-588)4312250-4 s DE-604 Nayak, Sanjay K. edt Mohanty, Smita edt Unnikrishnan, Lakshmi edt Erscheint auch als Online-Ausgabe Trends and applications in advanced polymeric materials Hoboken, NJ : John Wiley & Sons, 2017 9781119364788 Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029999884&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029999884&sequence=000002&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
| spellingShingle | Trends and applications in advanced polymeric materials Polymers Industrial applications Nanostructured materials Kunststoff (DE-588)4033676-1 gnd Hochleistungswerkstoff (DE-588)4312250-4 gnd |
| subject_GND | (DE-588)4033676-1 (DE-588)4312250-4 |
| title | Trends and applications in advanced polymeric materials |
| title_auth | Trends and applications in advanced polymeric materials |
| title_exact_search | Trends and applications in advanced polymeric materials |
| title_full | Trends and applications in advanced polymeric materials edited by Sanjay K. Nayak, Smita Mohanty and Lakshmi Unnikrishnan |
| title_fullStr | Trends and applications in advanced polymeric materials edited by Sanjay K. Nayak, Smita Mohanty and Lakshmi Unnikrishnan |
| title_full_unstemmed | Trends and applications in advanced polymeric materials edited by Sanjay K. Nayak, Smita Mohanty and Lakshmi Unnikrishnan |
| title_short | Trends and applications in advanced polymeric materials |
| title_sort | trends and applications in advanced polymeric materials |
| topic | Polymers Industrial applications Nanostructured materials Kunststoff (DE-588)4033676-1 gnd Hochleistungswerkstoff (DE-588)4312250-4 gnd |
| topic_facet | Polymers Industrial applications Nanostructured materials Kunststoff Hochleistungswerkstoff |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029999884&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029999884&sequence=000002&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT nayaksanjayk trendsandapplicationsinadvancedpolymericmaterials AT mohantysmita trendsandapplicationsinadvancedpolymericmaterials AT unnikrishnanlakshmi trendsandapplicationsinadvancedpolymericmaterials |