Polyethylene-based biocomposites and bionanocomposites:
Gespeichert in:
Weitere Verfasser: | , |
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Format: | Buch |
Sprache: | English |
Veröffentlicht: |
Beverly, MA
Scrivener Publishing
[2016]
Hoboken, New Jersey Wiley [2016] |
Schriftenreihe: | Thermoplastic bionanocomposites series
|
Schlagworte: | |
Online-Zugang: | Inhaltsverzeichnis Klappentext |
Beschreibung: | xvii, 453 Seiten Illustrationen, Diagramme |
ISBN: | 9781119038450 |
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Datensatz im Suchindex
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adam_text | Contents
Preface fi
XV
1 Polyethylene-based Biocomposites and Bionanocomposites:
State-of-the-Art, New Challenges and Opportunities 1
Sigrid Liiftl and Visakh. P. M.
1.1 Introduction 2
1.2 History of the Synthesis of Polyethylene: From Fossil
Fuels to Renewable Chemicals 5
1.3 Commercial Significance of PE and Bio(nano)Composites 8
1.4 State-of-the-Art 10
1.4.1 Graphene 11
1.4.2 Carbon Nanotubes 13
1.4.3 Clays and Layered Silicates 15
1.4.4 Alumium Oxide 16
1.4.5 Hydroxyapatite 16
1.4.6 Starch 18
1.4.7 Nanocrystalline Cellulose 19
1.4.8 Rice Husk 20
1.4.9 Plant Fibers 20
1.4.9.1 Flax Fibers 21
1.4.9.2 Hemp Fibers 21
1.4.9.3 Rape Fibers 23
1.4.9.4 Sisal Fibers 23
1.4.10 Distillers Grains 24
1.4.11 Date Palm Wood Flour 24
1.4.12 Chitin and Chitosan 25
1.4.13 Keratin Fibers 26
1.4.14 Eggshell 26
1.4.15 Conch Shell 27
1.4.16 Metal Nanoparticles 27
1.4.17 PE as Additive for Other Biopolymers 28
V
vi Contents
1.5 Preparation Methods for Nanocomposites and
Bionanocomposites 28
1.5.1 Melt Mixing 28
1.5.2 Solution Mixing 29
1.5.3 In-SituPolymerization 29
1.5.4 Other Methods 29
1.6 Environmental Concerns with Regard
to Nanoparticles 29
1.7 Challenges and Opportunities 30
References 31
2 Polyethylene/Chitin-based Biocomposites
and Bionanocomposites 43
Meriem Fardioui, Abou El Kacem Qaiss and Rachid Bouhfid
2.1 Introduction 43
2.2 Preparation of Biocomposites and Bionanocomposites 45
2.2.1 Chitin Preparation 46
2.2.1.1 Demineralization 46
2.2.1.2 Deproteinization 46
2.2.1.3 Bleaching 47
2.2.2 Nanochitin Preparation 48
2.2.3 Composites/Nanocomposites Preparation 48
2.3 Characterization of Biocomposites and
Bionanocomposites 50
2.3.1 Infrared Analysis of Chitin 50
2.3.2 Mechanical Properties 51
2.3.2.1 Biocomposite 51
2.3.2.2 Bionanocomposite 53
2.3.3 Dynamic Mechanical Analysis 55
2.3.4 Dynamic Mechanical Thermal Analysis
(Frequency Sweep) 57
2.4 Applications 62
2.4.1 Biomedical Application 62
2.4.2 Packaging and Coating Application 62
2.4.3 Water Treatment 63
2.4.4 Fire Retardant Application 64
2.4.5 Recycling and Lifetime Studies 64
2.5 Conclusions and Perspectives 64
References 65
Contents vii
3 Polyethylene/Starch-based Biocomposites
and Bionanocomposites 69
Yasamatt Ganji
3.1 Introduction 69
3.2 Polyethylene/Starch-based Composite 70
3.2.1 Preparation 72
3.2.1.1 Plasticizers 72
3.2.1.2 Extrusion 73
3.2.1.3 Solid-state Shear Pulverization (SSSP) 74
3.2.1.4 Mill Processing 75
3.2.1.5 Melt Blending 76
3.2.1.6 Solution Casting 76
3.2.1.7 Injection Molding 77
3.2.1.8 In-SituPolymerization 77
3.2.1.9 Electron Beam Irradiation 78
3.2.2 Characterization 78
3.2.2.1 Mechanical Properties 78
3.2.2.2 Thermal Properties 81
3.2.2.3 Fourier Transform Infrared
Spectroscopy (FTIR) 82
3.2.2.4 Viscoelastic Properties 84
3.2.2.5 Morphology 84
3.2.2.6 Degradation 85
3.2.2.7 Water Absorption 87
3.2.2.8 Water Vapor Transmission
Rate (WVTR) 88
3.2.2.9 Gas Permeability (GP) 88
3.2.2.10 Optical Properties 89
3.2.3 Application 89
3.2.3.1 Biomedical 89
3.2.3.2 Packaging 90
3.3 Conclusion 91
Abbreviations 92
References 93
4 Polyethylene/Soy Protein-based Biocomposites:
Properties, Applications, Challenges and Opportunities 99
H. Ismail, S. T. Sam and K. M. Chin
4.1 Introduction 99
4.2 Processing of Soy Protein 101
viii Contents
4.3 Effect of Different Compatibilizers on
Polyethylene/Soy Protein-based Biocomposites 102
4.3.1 Effect of Polyethylene Grafted
Maleic Anhydride 102
4.3.1.1 Rheological Characterization 102
4.3.1.2 Tensile Characterization 104
4.3.1.3 Thermal Characterization 107
4.3.1.4 Morphological Characterization 111
4.3.1.5 Biodegradation 112
4.3.2 Effect of Epoxidized Natural Rubber 135
4.3.2.1 Rheological Characterization 136
4.3.2.2 Tensile Characterization 137
4.3.2.3 Thermal Characterization 142
4.3.2.4 Morphological Characterization 146
4.3.2.5 Biodegradation 146
4.4 Opportunity and Challenges 161
References 163
5 Polyethylene/Hemicellulose-based Biocomposites and
Bionanocomposites 167
K. Sudhakar,N. Naryana Reddy, K. Rao,
S. J. Moloi, A. Babul Reddy and E. Rotimi Sadiku
5.1 Introduction 167
5.2 Hemicellulose Structure 170
5.2.1 Hardwood Hemicellulose 170
5.2.1.1 Glucuronoxylan (GX) 170
5.2.1.2 Glucomannan (GM) 171
5.2.1.3 Xyloglucan (XG) 171
5.2.2 Softwood Hemicellulose 171
5.2.2.1 Galactoglucomannans (GGM) 171
5.2.2.2 Arabinoglucuronoxylan (AGX) 172
5.3 Hemicellulose Properties 176
5.4 Hemicellulose-based Biocomposites 177
5.4.1 Xylan-based Biocomposites 177
5.4.2 Manam-based Biocomposites 179
5.5 Hemicellulose-based Bionanocomposites 186
5.5.1 Xylan-based Bionanocomposites 186
5.5.2 Manam-based Bionanocomposites 188
5.6 Hemicellulose Applications 190
5.7 Conclusion 191
Acknowledgment 192
References 192
Contents ix
6 Polyethylene/Polyhydroxyalkanoates-based
Biocomposites and Bionanocomposites 201
Oluranti Agboola, Rotimi Sadiku, Touhami Mokrani,
Ismael Amer, Mapula Lucey Moropeng and
Munyadziwa Mercy Ramakokovhti
6.1 Introduction 202
6.2 Polyethylene/Polyhydroxyalkanoates-based
Biocomposites and Bionanocomposites 202
6.2.1 Preparation 204
6.2.1.1 Milling Processes 204
6.2.1.2 Intermix and Brabender Mixing 208
6.2.1.3 Melt Blending 209
6.2.1.4 Extrusion 211
6.2.1.5 Injection Molding 212
6.2.1.6 In-SituPolymerization 215
6.2.2 Characterizations 216
6.2.2.1 Tensile Characterizations 217
6.2.2.2 Thermal Characterizations 217
6.2.2.3 Morphological Characterizations 221
6.2.2.4 X-ray Diffraction 223
6.2.2.5 Spectroscopic Characterizations 224
6.2.2.6 Rheological Characterization 226
6.2.2.7 Viscoelastic Characterizations 228
6.2.2.8 Electrical Characterizations 231
6.2.3 Applications of PE/PHAs-based Biocomposites
and Bionanocomposites 233
6.2.3.1 PE/PHAs-based Biocomposites
and Bionanocomposites in Biomedical
Applications 234
6.2.3.2 PE/PHAs-based Biocomposites
and Bionanocomposites in Packaging
Applications 237
6.2.3.3 PE/PHAs-based Biocomposites
and Bionanocomposites in Structural
Applications 240
6.2.3.4 PE/PHAs-based Biocomposites and
Bionanocomposites in Military
Applications 242
6.2.3.5 PE/PHAs-based Biocomposites and
Bionanocomposites in Coating
Applications 245
x Contents
6.2.3.6 PE/PHAs-based Biocomposites and
Bionanocomposites in Fire-Retardant
Applications 248
6.2.3.7 PE/PHAs-based Biocomposites and
Bionanocomposites in Aerospace
Applications 249
6.2.3.8 PE/PHAs-based Biocomposites and
Bionanocomposites in Optical
Applications 251
6.2.3.9 Recycling and Lifetime Studies on
PE/PHAs-based Biocomposites and
Bionanocomposites 253
6.3 Conclusions 255
Abbreviations 256
References 257
7 Polyethylene/Other Biomaterials-based Biocomposites and
Bionanocomposites 279
A. Babul Reddy, B. Manjula, K. Sudhakar, V. Sivatijineyulu,
T. Jayaramudu and E. R. Sadiku
7.1 Introduction 279
7.2 Polyethylene/Lignin-based Biocomposites and
Bionanocomposites 284
7.2.1 Preparation 286
7.2.1.1 Twin-screw Extruder 286
7.2.1.2 Single-screw Extruder 286
7.2.1.3 Brabender Mixer 286
7.2.1.4 Compression Molding 287
7.2.1.5 Haake Buchler Internal Batch Mixer 287
7.2.1.6 Melt Blending 287
7.2.1.7 Solvent/Solution Casting Method 288
7.2.2 Characterization 288
7.2.2.1 Mechanical Properties 288
7.2.2.2 Thermogravimetric Analysis of
Lignin Containing Biocomposites 290
7.2.2.3 Characterization of Biodegraded
PE/Lignin Biocomposites 292
7.2.2.4 Morphology of Lignin and LDPE/
Lignin Biocomposites 294
7.2.3 Applications 294
Contents xi
7.3 Polyethylene/Alginate-based Biocomposites
and Bionanocomposites 296
7.3.1 Preparation 298
7.3.1.1 Compression Molding 298
7.3.2 Characterization 299
7.3.2.1 Mechanical Properties of the
Biocomposites 299
7.3.2.2 Thermal Properties of the Matrix
and the Biocomposites 299
7.3.2.3 Biodegradation of Alginate-based
Polyethylene Composites 301
7.3.3 Applications 302
7.4 Polyethylene/Casein-based Biocomposites and
Bionanocomposites 302
7.4.1 Preparation 304
7.4.1.1 Twin-screw Extruder 304
7.4.1.2 Brabender Plasti-corder 304
7.4.1.3 Injection Molded 305
7.4.2 Characterization 305
7.4.2.1 Mechanical Properties 305
7.4.2.2 Thermal Properties 306
7.4.2.3 Confocal Scanning Laser Microscopy 306
7.4.3 Applications 306
7.5 Conclusions 307
References 308
Studies of Polyethylene-based Biocomposites,
Bionanocomposites and Other Non-Biobased
Nano composites 315
Norshahida Sarifuddin and Hanafi Ismail
8.1 Introduction 316
8.2 Studies of Polyethylene-based Biocomposites 317
8.2.1 Polyethylene/Starch-based Biocomposites 317
8.2.1.1 Preparation and Characterization 318
8.2.2 Polyethylene/Starch/Cellulose Fiber
Biocomposites 322
8.2.2.1 Preparation and Characterization 322
8.3 Studies of Polyethylene-based Bionanocomposites 327
8.3.1 Nanofillers for Bionanocomposites 327
xii Contents
8.3.2 Polyethylene/Starch/Cellulose Fiber/Halloysite
Bionanocomposites 330
8.3.2.1 Preparation and Characterization 330
8.4 Studies of Polyethylene and Other Non-biobased
Nano composites 334
8.4.1 Carbon Nanotubes 334
8.4.2 Polyethylene/Carbon Nanotubes Composites 336
8.4.2.1 Preparation and Characterization 336
8.5 Concluding Remarks 338
References 338
9 Biodegradation Study of Polyethylene-based
Biocomposites and Bionanocomposites 345
Sumana Ghosh
9.1 Introduction 345
9.2 Biopolymer-based Biocomposites 346
9.3 Biopolymer-based Bionanocomposites 347
9.4 Applications of Biopolymer-based Biocomposites
and Bionanocomposites 347
9.5 Biodegradation 349
9.6 Biodegradation Study of Cellulose-based
Biocomposites/Bionanocomposites 350
9.7 Biodegradation Study of Chitin-based
Biocomposites/Bionanocomposites 352
9.8 Biodegradation Study of Starch-based
Biocomposites/Bionanocomposites 353
9.9 Biodegradation Study of Hemicellulose-based
Biocomposites/Bionanocomposites 355
9.10 Biodegradation Study of Polylactic Acid-based
Biocomposites/Bionanocomposites 356
9.11 Biodegradation Study of Polyhydroxyalkanoates-based
Biocomposites/Bionanocomposites 357
9.12 Conclusions 360
Acknowledgments 360
References 360
Contents xiii
10 Polyethylene-based Bio- and Nanocomposites for
Packaging Applications 365
Paula A. Zapata and Humberto Palza
10.1 Introduction 366
10.2 Polyethylene-based Nanocomposites 369
10.2.1 Layered Silicates 371
10.2.2 Barrier Properties of Polymer Nanocomposites 374
10.2.3 Polyethylene/Clay Nanocomposites for
Packaging Applications 379
10.2.4 Polyethylene-based Nanocomposites for
Active Packaging 380
10.3 Polyethylene-based Biocomposites 383
10.3.1 Gas Permeation 385
10.3.2 Water Permeation 388
10.4 Polyethylene-based Bionanocomposites 393
10.5 Conclusions 397
References 398
11 Properties and Utilization of Plant Fibers and
Nanocellulose for Thermoplastic Composites 405
Nadir Ayrilmis, Alireza Ashori and Jin Heon Kwon
11.1 Introduction 406
11.2 Plant Fibers 407
11.2.1 Fiber Source 407
11.2.2 Plant-fiber Types 407
11.2.3 Plant-fiber Yield 407
11.2.4 Chemical Composition of Plant Fibers 409
11.2.5 Mechanical Properties of Plant Fibers 412
11.2.6 Modification of Plant Fibers 414
11.2.6.1 Physical Methods 414
11.2.6.2 Chemical Methods 415
11.2.6.3 Coupling Agents 415
11.2.6.4 Alkaline Treatment 416
11.2.6.5 Acetylation 417
11.2.6.6 Thermal Treatment 417
11.2.6.7 Other Chemical Treatments 418
11.3 Nanocellulose 418
11.3.1 Microfibrillated Cellulose 421
11.3.2 Nanocrystalline Cellulose 422
11.4 Conclusions 424
References 425
xiv Contents
12 Modification of Poly (lactic acid) Matrix by Chemically
Modified Flax Fiber Bundles and Poly(ethylene glycol)
Plasticizer 429
A. Arbelaiz, J. Trifol, C. PeHa-Rodriguez, f. Labidi
and A. Eceiza
12.1 Introduction 429
12.2 Experimental 431
12.2.1 Materials 431
12.2.2 Flax Fiber Surface Modification and
Characterization 431
12.2.3 Compounding, Processing and
Characterization of PLA/Flax Fiber
Composites and PLA/PEG Blends 432
12.3 Results and Discussion 433
12.3.1 PLA Matrix Modification with
Silane-treated Fibers 433
12.3.2 PLA Matrix Modification with PEG 436
12.4 Conclusions 442
Acknowledgments 443
References 443
Index
447
Serves as a “one-stop” reference resource for important research accomplishments in the area of
polyethylene-based biocomposites and bionanocomposites
Biodegradable polymers have experienced a growing interest in recent years for applications
in packaging, agriculture, automotive, medicine, and other areas. One of the drivers for this
development is the great quantity of synthetic plastic discarded improperly in the environment.
Therefore, R D in industry and in academic research centers seek out materials that are reprocessable
and biodegradable.
This unique book comprises 12 chapters written by subject specialists and is a state-of-the-art
look at all types of po!yethyIene(PE)-based biocomposites and bionanocomposites as well as their
preparation, characterization and applications.
The topics covered include:
• PE/chitin- and PE/starch-based biocomposites and bionanocomposites
• Properties, applications, challenges and opportunities regarding PE/soy protein-based
biocomposites and bionanocomposites
• PE/hemicellulose-, PE/polyhydroxyalkanoates- and other PE-based biocomposites and
biona nocomposites
• Biodegradation study of PE-based biocomposites and bionanocomposites
• PE-based bionanocomposites for packaging applications
• Properties and utilization of plant fibers and nanocellulose for thermoplastic composites
• Modification of poly(lactic acid) matrix by chemically modified flax fiber bundles and
poly(ethylene glycol) plasticizer.
Audience
This book will help researchers, scientists, engineers and students in the field of polyethylene-
based biocomposites and bionanocomposites who want to learn about preparation methods,
characterization techniques and applications. Interested industries include biotechnology, materials,
automotive, packaging, and agriculture.
Visakh P.M. is a prolific editor with more than 16 books to his name. He is working as a postdoc
researcher at the Department of Ecology and Basic Safety, Tomsk Polytechnic University (TPU),
Tomsk, Russia. He obtained his PhD, MPhil and MSc degrees from the School of Chemical Sciences,
Mahatma Gandhi University, Kerala, India. His research interests include: polymer nanocomposites,
bio-nanocomposites, rubber-based nanocomposites, fire retardant polymers, and liquid crystalline
polymers and silicon sensors.
Stgrid Liiftl worked for more than 13 years at the Vienna University of Technology as a research
associate after she gained her PhD. She was in charge of failure analyses and degradation studies of
polymers and gave courses in specialty polymers and biocompatible materials. In 2016 she founded
her own consultancy company 1WILL. This work also includes teaching such as helping students
with learning difficulties and how to write a scientific thesis. She is the author and co-author of several
scientific publications and editor of two books including “Polyoxymethylene Handbook: Structure,
Properties, Applications and Their Nanocomposites” (2014 Wiley-Scrivener).
Cover design by Russell Richardson
Front cover image from BigStock.com
w A y __ Vk M m Also available
Wiley cii/
y
www.wiley.comwww.scrivenerpublishing.com
ISBN 978-1-119-03845-0
781119
038450
|
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id | DE-604.BV044517037 |
illustrated | Illustrated |
indexdate | 2024-07-10T07:54:45Z |
institution | BVB |
isbn | 9781119038450 |
language | English |
lccn | 016038237 |
oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-029916651 |
oclc_num | 962556924 |
open_access_boolean | |
owner | DE-703 |
owner_facet | DE-703 |
physical | xvii, 453 Seiten Illustrationen, Diagramme |
publishDate | 2016 |
publishDateSearch | 2016 |
publishDateSort | 2016 |
publisher | Scrivener Publishing Wiley |
record_format | marc |
series2 | Thermoplastic bionanocomposites series |
spelling | Polyethylene-based biocomposites and bionanocomposites edited by Visakh. P.M. and Sigrid Lüftl Beverly, MA Scrivener Publishing [2016] Hoboken, New Jersey Wiley [2016] xvii, 453 Seiten Illustrationen, Diagramme txt rdacontent n rdamedia nc rdacarrier Thermoplastic bionanocomposites series Biopolymers Materials Biodegradation Nanobiotechnology Biopolymere (DE-588)4006893-6 gnd rswk-swf Biomaterial (DE-588)4267769-5 gnd rswk-swf Polyethylene (DE-588)4076241-5 gnd rswk-swf Nanokomposit (DE-588)4768127-5 gnd rswk-swf Nanobiotechnologie (DE-588)7657744-2 gnd rswk-swf Biopolymere (DE-588)4006893-6 s Nanokomposit (DE-588)4768127-5 s DE-604 Nanobiotechnologie (DE-588)7657744-2 s Polyethylene (DE-588)4076241-5 s Biomaterial (DE-588)4267769-5 s P. M., Visakh 1984- (DE-588)1081104791 edt Lüftl, Sigrid edt Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029916651&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029916651&sequence=000002&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
spellingShingle | Polyethylene-based biocomposites and bionanocomposites Biopolymers Materials Biodegradation Nanobiotechnology Biopolymere (DE-588)4006893-6 gnd Biomaterial (DE-588)4267769-5 gnd Polyethylene (DE-588)4076241-5 gnd Nanokomposit (DE-588)4768127-5 gnd Nanobiotechnologie (DE-588)7657744-2 gnd |
subject_GND | (DE-588)4006893-6 (DE-588)4267769-5 (DE-588)4076241-5 (DE-588)4768127-5 (DE-588)7657744-2 |
title | Polyethylene-based biocomposites and bionanocomposites |
title_auth | Polyethylene-based biocomposites and bionanocomposites |
title_exact_search | Polyethylene-based biocomposites and bionanocomposites |
title_full | Polyethylene-based biocomposites and bionanocomposites edited by Visakh. P.M. and Sigrid Lüftl |
title_fullStr | Polyethylene-based biocomposites and bionanocomposites edited by Visakh. P.M. and Sigrid Lüftl |
title_full_unstemmed | Polyethylene-based biocomposites and bionanocomposites edited by Visakh. P.M. and Sigrid Lüftl |
title_short | Polyethylene-based biocomposites and bionanocomposites |
title_sort | polyethylene based biocomposites and bionanocomposites |
topic | Biopolymers Materials Biodegradation Nanobiotechnology Biopolymere (DE-588)4006893-6 gnd Biomaterial (DE-588)4267769-5 gnd Polyethylene (DE-588)4076241-5 gnd Nanokomposit (DE-588)4768127-5 gnd Nanobiotechnologie (DE-588)7657744-2 gnd |
topic_facet | Biopolymers Materials Biodegradation Nanobiotechnology Biopolymere Biomaterial Polyethylene Nanokomposit Nanobiotechnologie |
url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029916651&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029916651&sequence=000002&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
work_keys_str_mv | AT pmvisakh polyethylenebasedbiocompositesandbionanocomposites AT luftlsigrid polyethylenebasedbiocompositesandbionanocomposites |