Mechanochemistry in materials:
Saved in:
| Other Authors: | , |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
London
Royal Society of Chemistry
[2018]
|
| Series: | Polymer chemistry series
26 |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | xiv, 196 Seiten Illustrationen, Diagramme (teilweise farbig) |
| ISBN: | 9781782621461 |
Staff View
MARC
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Record in the Search Index
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|---|---|
| adam_text | Contents
Chapter 1 Mechanochemistry: Inspiration from Biology 1
Tamuka Chidanguro, Wengui Weng and Yoan C Simon
1 1 Introduction and Historical Perspective 1
1 2 Biomimetism and Rationale for Emulating
Mechanotransduction Pathways 3
121 Principles of Biomimetism and Strategies
to Implement It 3
122 Introduction of the Importance of
Mechanotransduction Pathways for Living
Organisms 4
123 Adaptivity in Bones 6
1 3 Sensing 15
131 Via Protein Unfolding 15
132 Via Ion Channel Opening 21
1 4 Conclusion 30
References 31
Chapter 2 Mechanophores for Chemical Function 36
C E Diesendruck
2 1 Introduction 36
2 2 Creation of Reactive Species 37
221 Radicals 37
222 Carbon Cations 38
223 Reactive Organic Functional Groups 39
2 3 Catalyst Activation 42
Polymer Chemistry Series No 26
Mechanochemistry in Materials
Edited by Yoan C Simon and Stephen L Craig
© The Royal Society of Chemistry 2018
Published by the Royal Society of Chemistry, www rsc org
xi
Contents
xii
2 4 Spectral Change 44
2 5 Production of Small Molecules 47
2 6 Other 48
2 7 Conclusions and Perspectives 49
References 50
Chapter 3 Optical Sensing of Stress in Polymers 53
R Göstl, J M Clough and R R Sijbesma
3 1 Introduction 53
3 2 Bond-Isomerization Reactions 55
3 3 Covalent Bond Scission Reactions 58
3 4 Conjugated Polymers 63
3 5 Chromophore Rearrangement 64
3 6 Photonic Polymers and Cholesteric
Liquid Crystals 67
3 7 Conclusion 69
Acknowledgements 70
References 70
Chapter 4 Materials Design Principles for
Mechanochemical Transduction 76
M N Silberstein and M S Manivannan
4 1 Introduction 76
4 2 Mechanics Terminology 77
4 3 Mechanophore Kinetics 79
4 4 Experimental Techniques for MCR Polymers 82
4 5 Elastomers 87
4 6 Glassy Polymers 99
4 7 Composites and Coatings 107
4 8 Mechanochemically Modified Networks 108
4 9 Conclusions 113
Abbreviations 114
Acknowledgements 115
References 115
Chapter 5 Tailoring Mechanochemical Reactivity of
Covalent Bonds in Polymers by Non-covalent
Interactions 119
Huan Zhang, Linxing Zhang, Yinjun Chen, Yangju
Lin and Wengui Weng
5 1 Introduction 119
5 2 Theoretical Background of Polymer
Mechanochemistry and the Effects of
Supramolecular Interactions 120
Contents
xiii
521 Coil-to-stretch Transition and
Bead-rod Model 120
522 Intra-chain Non-covalent Interactions 121
523 Inter-chain Non-covalent Interactions 123
524 Non-covalent Interactions in the Bulk 125
5 3 Experimental Observations 125
531 Mechanical Cleavage of Covalent
Bonds in Dilute Solution 125
532 Effects of Strong Hydrogen Bonding
Interactions on the Activation of
Mechanophores in the Bulk 130
533 Effects of Van de Waals Interactions 136
534 Effect of Metallo-supramolecular
Interactions 140
5 4 Non-covalent Interactions in
Stress-responsive Materials 143
541 Activation of Mechanophores and
Irreversible Deformation of the Matrix 143
542 Successive Mechanochemical Activation
in Hydrogen-bonded Reinforced
Elastomers 143
5 5 Conclusions and Outlook 146
551 Conclusions 146
552 Outlook 147
Acknowledgements 147
References 148
Chapter 6 Mechanochemistry of Polymer Brushes 155
Nariye Cavusoglu Ataman, Jan Genzer and
Harm-Anton Klok
6 1 Introduction 155
6 2 Degrafting of Polymer Brushes 156
6 3 Summary and Conclusions 164
References 165
Chapter 7 Coupling Mechanics to Chemical Reactions
to Create “Materials that Compute” 167
Victor V Yashin, Steven P Levitan and Anna C Balazs
7 1 Introduction 167
7 2 Modeling Self-oscillating Gels 169
721 Kinetics of the BZ Reaction in a Polymer Gel 169
722 Gel Swelling in the Presence of an
External Force 171
723 Values of Parameters Used in the
Calculations 172
xiv
Contents
7 3 Modeling Force-controlled Entrainment of BZ Gels 173
731 Phase Dynamics Equations for
Mechanically Deformed BZ Gels 174
732 Entraining the Responsive BZ Gel 176
7 4 Self-oscillating Gels Coupled Through
Piezoelectric Films 181
7 5 Conclusions 191
Acknowledgement 192
References 192
Subject Index
|
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| illustrated | Illustrated |
| indexdate | 2024-07-10T07:52:26Z |
| institution | BVB |
| isbn | 9781782621461 |
| language | English |
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| physical | xiv, 196 Seiten Illustrationen, Diagramme (teilweise farbig) |
| publishDate | 2018 |
| publishDateSearch | 2018 |
| publishDateSort | 2018 |
| publisher | Royal Society of Chemistry |
| record_format | marc |
| series | Polymer chemistry series |
| series2 | Polymer chemistry series |
| spelling | Mechanochemistry in materials edited by Yoan C. Simon and Stephen L. Craig London Royal Society of Chemistry [2018] © 2018 xiv, 196 Seiten Illustrationen, Diagramme (teilweise farbig) txt rdacontent n rdamedia nc rdacarrier Polymer chemistry series 26 Mechanical chemistry Mechanical chemistry fast Mechanochemie (DE-588)4295813-1 gnd rswk-swf Werkstoffkunde (DE-588)4079184-1 gnd rswk-swf Mechanochemie (DE-588)4295813-1 s Werkstoffkunde (DE-588)4079184-1 s DE-604 Simon, Yoan C. (DE-588)1156569613 edt Craig, Stephen (DE-588)17101376X edt Erscheint auch als Online-Ausgabe, PDF 978-1-78262-388-5 Erscheint auch als Online-Ausgabe, ePub 978-1-78801-239-3 Polymer chemistry series 26 (DE-604)BV040344073 26 HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029820500&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Mechanochemistry in materials Polymer chemistry series Mechanical chemistry Mechanical chemistry fast Mechanochemie (DE-588)4295813-1 gnd Werkstoffkunde (DE-588)4079184-1 gnd |
| subject_GND | (DE-588)4295813-1 (DE-588)4079184-1 |
| title | Mechanochemistry in materials |
| title_auth | Mechanochemistry in materials |
| title_exact_search | Mechanochemistry in materials |
| title_full | Mechanochemistry in materials edited by Yoan C. Simon and Stephen L. Craig |
| title_fullStr | Mechanochemistry in materials edited by Yoan C. Simon and Stephen L. Craig |
| title_full_unstemmed | Mechanochemistry in materials edited by Yoan C. Simon and Stephen L. Craig |
| title_short | Mechanochemistry in materials |
| title_sort | mechanochemistry in materials |
| topic | Mechanical chemistry Mechanical chemistry fast Mechanochemie (DE-588)4295813-1 gnd Werkstoffkunde (DE-588)4079184-1 gnd |
| topic_facet | Mechanical chemistry Mechanochemie Werkstoffkunde |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029820500&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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