Water for energy and fuel production:
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| Main Author: | |
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| Format: | Book |
| Language: | English |
| Published: |
Boca Raton ; London ; New York
CRC Press
2017
|
| Edition: | First issued in paperback |
| Series: | Green chemistry and chemical engineering
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| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | xxi, 402 Seiten, 16 ungezählte Seiten Tafeln |
| ISBN: | 9781138076068 9781482216189 |
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MARC
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| 245 | 1 | 0 | |a Water for energy and fuel production |c Yatish T. Shah |
| 250 | |a First issued in paperback | ||
| 264 | 1 | |a Boca Raton ; London ; New York |b CRC Press |c 2017 | |
| 300 | |a xxi, 402 Seiten, 16 ungezählte Seiten Tafeln | ||
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| _version_ | 1804177674092937216 |
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| adam_text | Contents
Series Preface...........................................................xv
Preface................................................................xvii
Author..................................................................xxi
Chapter 1 Introduction....................................................1
1.1 Global Energy Landscape: Past, Present, and Future.......1
1.2 The Theme and Outline of the Book.......................5
1.2.1 Chapter 2: Water for Raw Fuel Production........6
1.2.2 Chapter 3: Water as Energy Carrier..............7
1.2.3 Chapter 4: Steam for Synthetic Gas Production...8
1.2.4 Chapter 5: Synthetic Fuel Production by Water
under Subcriticai Conditions....................9
1.2.5 Chapter 6: Production of Synthetic Fuels by
Aqueous-Phase Reforming........................11
1.2.6 Chapter 7: Production of Synthetic Fuels and
Chemicals by Hydrolysis Followed by Selective
Catalytic Conversions..........................11
1.2.7 Chapter 8: Production of Hydrogen and Methane
by Anaerobic Digestion of Aqueous Waste........12
1.2.8 Chapter 9: Production of Ethanol by
Aqueous-Phase Fermentation.....................12
1.2.9 Chapter 10: Production of Synthetic Fuels by
Supercritical Water............................13
1.2.10 Chapter 11 : Production of Hydrogen by Water
Dissociation...................................13
1.2.11 Chapter 12: Production of Methane from Gas
Hydrates.......................................14
1.2.12 Chapter 13: Water as a Direct Source of Energy.14
1.3 Water-Based Refinery and Water Management for the Future.... 15
References..................................................16
Chapter 2 Role of Water in Recovery and Production of Raw Fuels........17
2.1 Introduction...........................................17
2.2 Increased Water Usage for Recovery of Coal Bed
Methane and Gas from Geopressurized Zones.............19
2.3 Enhanced Oil Recovery (EOR) Process....................22
2.3.1 Chemical Processes.............................23
2.3.1.1 Surfactant-Polymer Solution
(Microemulsion Flooding)..............23
2.3.1.2 Polymer Solution.......................24
v
vi Contents
2.3.1.3 Caustic Alkaline Solution................24
2.3.2 Thermal Processes................................24
2.3.2.1 Steam Stimulation........................24
2.3.2.2 Hot Water Injection......................25
2.3.2.3 In Situ Combustion.......................25
2.4 Role of Water in the Fracking Process....................25
2.5 Water Requirement for Mining, Preparation, and
Extraction of Solid Fuels................................27
2.5.1 Oil Shale Industry...............................27
2.5.2 Tar Sand and Heavy Oil Industries.............. 27
2.5.3 Uranium Mining and Leaching......................28
2.5.4 Coal Mining and Preparation......................29
References.....................................................29
Chapter 3 Energy Recovery by Benign Hydrothermal Processes...............33
3.1 Introduction.............................................33
3.2 Role of Water in Production of Nuclear Power.............33
3.2.1 Light Water Reactor..............................33
3.2.2 Boiling Water Reactor.......................... 34
3.2.3 Pressurized Water Reactor........................35
3.2.4 Pressurized Heavy Water Reactor (CANDU)..........36
3.2.5 Graphite-Moderated, Direct Cycle
(Boiling Water) Pressure Tube Reactor............37
3.2.6 Supercritical Water-Cooled Reactor...............37
3.3 Hydrothermal Processes for Recovery of Geothermal
Energy...................................................37
3.3.1 Enhanced Geothermal Systems......................41
3.3.2 Coproduction of Geothermal Electricity in Oil
and Gas Wells....................................42
3.4 Role of Water in Storage of Solar Energy.................43
3.5 Steam Turbine............................................44
References.....................................................45
Chapter 4 Steam Gasification and Reforming Technologies.....................47
4.1 Introduction.............................................47
4.2 Mechanisms, Kinetics, and Catalysis of Steam
Gasification and Reforming...............................50
4.2.1 Mechanism of Steam Gasification..................50
4.2.2 Mechanism of Steam Reforming.....................52
4.2.3 Catalysts for Steam Gasification.................53
4.2.3.1 Dolomite, Olivine, and Alkali
Metal-Based Catalysts...................54
4.2.3.2 Nickel-Based Catalysts...................55
Contents
VII
4.2.4 Catalysts for Steam Reforming.....................55
4.3 Dry Reforming.............................................56
4.4 Tri-Reforming.............................................59
4.5 Effects of Feedstock and Operating Conditions on
Product Distributions.....................................60
4.5.1 Steam Gasification................................60
4.5.1.1 Coal......................................60
4.5.1.2 Biomass...................................62
4.5.1.3 Mixed Feedstock...........................67
4.5.1.4 Tar.......................................68
4.5.1.5 Black Liquor..............................69
4.5.1.6 Lignin....................................70
4.5.2 Steam Reforming...................................70
4.5.2.1 Ethanol...................................70
4.5.2.2 Methanol..................................72
4.5.2.3 Liquid Hydrocarbons.......................75
4.5.2.4 Glycerol..................................76
4.5.2.5 Biomass...................................77
4.5.2.6 Mixed Feedstock...........................78
4.5.2.7 Carbon and Carbon Monoxide................79
4.5.2.8 Bio-Oil...................................80
4.6 Steam Gasification and Reforming Reactors.................81
4.6.1 Steam Gasification Reactors.......................81
4.6.1.1 Fixed-Bed Gasifiers.......................81
4.6.1.2 Suspended Bed Reactor.....................82
4.6.1.3 Plasma and Free Radical Gasifiers.........84
4.6.1.4 Molten Salt Steam Gasification Reactors ... 84
4.6.2 Steam Reforming Reactors..........................87
4.7 Novel Steam Gasification and Reforming Processes..........89
4.7.1 Solar Gasification Technology.....................89
4.7.2 Solar Gasification Reactors and Processes.........90
4.7.3 Solar Reforming...................................92
4.7.3.1 ASTERIX: Solar Steam Reforming
of Methane...............................92
4.7.3.2 The Weizmann Institute Tubular
Reformer/Receiver........................93
4.7.3.3 Soltox Process............................93
4.7.3.4 Open-Loop Solar Syngas Production.........94
4.7.3.5 Other Solar Reforming Processes...........94
4.7.4 Microwave-Assisted Reforming......................95
4.7.5 Underground Coal Gasification.....................95
4.7.5.1 Underground Gasification Reactors.........96
4.7.6 Other Novel Processes.............................98
References.....................................................99
VII!
Contents
Chapter 5 Hydrothermal Processes in Subcriticai Water................... 113
5.1 Introduction.........................................113
5.1.1 Properties of Water at High Temperature and
Pressure......................................114
5.2 Hydrothermal Carbonization (Wet Pyrolysis)........... 117
5.2.1 Reaction Mechanisms........................... 119
5.2.2 Effects of Operating Conditions................121
5.2.3 Comparison of HTC and Dry Pyrolysis Process...122
5.2.4 Product Characteristics and Usages.............123
5.2.5 Process Considerations.........................125
5.3 Hydrothermal Liquefaction............................125
5.3.1 Reaction Mechanisms............................126
5.3.2 Effects of Operating Conditions on HTL Process ... 128
5.3.2.1 Pressure, Temperature, and Residence
Time..................................128
5.3.2.2 Biomass Particle Size, Heating Rate,
and Concentration.....................130
5.3.2.3 Gas and Liquid Properties............. 131
5.3.3 Role of Feedstock..............................132
5.3.3.1 Biowastes..............................132
5.3.3.2 Lignocellulose.........................133
5.3.3.3 Algae..................................134
5.3.4 HTU Process....................................136
5.4 Hydrothermal Gasification.............................136
5.4.1 Catalysts for HTG..............................137
5.5 Coal-Water Chemistry..................................139
5.5.1 Effect of Water Pretreatment of Coal on Coal
Liquefaction...................................139
5.5.2 Coal Liquefaction in High-Pressure and
High-Temperature Water........................ 141
5.5.3 Coal—Water Mixture as Fuel.....................142
5.5.3.1 Production of CWF......................144
5.5.3.2 Fuel Preparation and Transportation....146
5.5.3.3 Combustion of CWF..................... 147
References.................................................148
Chapter 6 Aqueous-Phase Reforming and BioForming Process................157
6.1 Introduction..........................................157
6.2 Aqueous-Phase Reforming...............................158
6.3 APR versus Steam Reforming............................159
6.4 Thermodynamics of APR.................................160
Contents
ix
6.5 Kinetics and Catalysis of APR Process.................163
6.5.1 Effects of Temperature, Carbon Number,
and Pressure...................................163
6.5.2 Effects of Catalysts and Supports..............163
6.5.3 Effects of Promoters and Acidity of Liquid
and Solids.....................................165
6.5.4 Effects of Feedstock...........................166
6.5.4.1 APR of Ethylene Glycol, Alcohols,
and Glycerol (Primary Feedstock with
High Vapor Pressure)..................166
6.5.4.2 APR of Sugar and Glucose (Primary
Feedstock with Low Vapor Pressure)....167
6.5.4.3 APR of Biomass and Cellulose
(Secondary Feedstock).................168
6.5.5 Novel Reactor Designs..........................170
6.5.6 Summary........................................171
6.6 Production of Syngas and Monofunctional Groups
and Their Upgrading...................................172
6.6.1 Syngas....................................... 172
6.6.2 Monofunctional Groups........................ 172
6.7 Virent’s Bioforming Process...........................173
References.................................................. 178
Chapter 7 Bioiine Hydrolysis Process and Derivative Product Upgrading
Technologies............................................... 183
7.1 Introduction..........................................183
7.2 The Hydrolysis Process................................185
7.3 Upgrading of Intermediate Products from the Biofine
Process.............................................. 191
7.3.1 Transformation of Levulinic Acid...............192
7.3.2 Gamma-Valerolectone............................195
7.3.3 Furfuryl and Hydroxymethyl Furfuryl............196
7.3.4 Formic Acid....................................197
7.3.5 Biofine Char...................................197
7.4 Comparison of Biofine Process with Other Technologies.197
7.4.1 DIBANET Project................................197
7.4.2 Biofine Process versus Fermentation Process....199
7.4.3 Biofine Process versus Bioforming Process......199
7.5 Large-Scale Biofine Process...........................200
References.................................................200
x Contents
Chapter 8 Anaerobic Digestion of Aqueous Waste for Methane and
Hydrogen......................................................205
8.1 I ntroduc t ion.........................................205
8.2 Basic Principles of Anaerobic Digestion.................206
8.3 Microbes and the Effects of Operating Conditions........209
8.3.1 Effects of Temperature and Ammonia Inhibition ....209
8.3.2 pH Effect........................................209
8.3.3 Nutrients Effect.................................210
8.4 Feedstock Effects.......................................210
8.4.1 Coir Pith........................................212
8.4.2 Whey.............................................212
8.4.3 Distillery Spent Wash............................212
8.4.4 Swine Waste......................................214
8.4.5 Byproducts of Biodiesel Production...............214
8.4.6 Palm Oil Mill Effluent...........................215
8.4.7 LCFAs in Wastewater..............................215
8.4.8 Food and Kitchen Organic Waste...................216
8.4.9 Wastewater Treatment.............................217
8.4.10 Dairy Effluent...................................217
8.4.11 Tofu Wastewater..................................217
8.4.12 Fruit Waste......................................218
8.5 Co-Digestion............................................218
8.6 Effects of Harvesting, Storage, and Pretreatment........219
8.6.1 Effect of Harvesting.............................219
8.6.2 Storage..........................................219
8.6.3 Pretreatment.....................................220
8.7 Types of Fermentation and Associated Digester
Configurations..........................................220
8.7.1 Wet Fermentation.................................220
8.7.2 Dry Fermentation.................................221
8.7.3 Batch Fermentation...............................221
8.7.4 Two-Stage Fermentation...........................221
8.7.5 Novel Digester Technology........................222
8.8 Simulation, Modeling, Scale-Up, and Control
of Fermentation Process.................................222
8.9 Purification of Biogas..................................223
8.10 Utilization of Biogas and Digestate.....................224
References....................................................225
Chapter 9 Hydrolysis and Fermentation Technologies for Alcohols.......... 233
9.1 Introduction............................................233
9.2 Grain (Corn) Ethanol....................................235
9.2.1 Starch Hydrolysis................................236
9.2.2 Yeast Fermentation............................. 236
Contents
XI
9.2.3 Ethanol Purification and Product Separation......236
9.2.4 Byproducts and Coproducts........................237
9.2.5 Environmental Implications.......................237
9.3 Corn to Ethanol Process Technologies....................237
9.3.1 Wet Milling Technology for Conversion of
Corn to Ethanol..................................237
9.3.2 Dry Milling Corn֊to-Ethanol Process..............239
9.4 Cellulosic Ethanol......................................241
9.4.1 Pretreatment................................... 244
9.4.1.1 Rapid Steam Hydrolysis..................245
9.4.1.2 Dilute Acid Prehydrolysis...............245
9.4.1.3 Organosolv Pretreatment.................245
9.4.1.4 Combined RASH and Organosolv
Pretreatment............................246
9.4.1.5 Ionic Liquid Pretreatment...............247
9.4.2 Hydroly si s.....................................247
9.4.2.1 Acid or Chemical Hydrolysis.............247
9.4.2.2 Enzymatic Hydrolysis....................248
9.4.2.3 Mechanism of Cellulose Hydrolysis.......250
9.4.3 Fermentation.....................................251
9.4.3.1 Separate Hydrolysis and Fermentation...251
9.4.3.2 Simultaneous Saccharification and
Fermentation............................252
9.4.3.3 Comparison between SSF and SHF
Processes...............................253
9.4.3.4 Xylose Fermentation.....................253
9.4.4 Ethanol Extraction during Fermentation...........254
9.4.5 Lignin Conversion................................255
9.4.6 Coproducts of Cellulosic Ethanol Technology......255
9.4.7 Future Directions for Cellulosic Ethanol.........256
9.5 Fermentation of Sugar to Isobutanol.....................256
References...................................................257
Chapter 10 Fuel Production by Supercritical Water.........................261
10.1 Introduction............................................261
10.2 Properties of SCW.......................................262
10.3 Role of SCW in Chemical Synthesis.......................265
10.4 Oxidation in SCW........................................266
10.4.1 Catalysts for SCWO...............................268
10.5 Decomposition and Extraction of Materials by SCW........268
10.6 Gasification in SCW.....................................272
10.7 Reforming in SCW........................................277
10.7.1 Liquid Fuels.....................................277
10.7.2 Biomass..........................................279
XII Contents
10.7.3 Glycerol.......................................279
10.7.4 Ethylene Glycol................................280
10.7.5 Methanol.......................................280
10.7.6 Ethanol........................................281
10.8 Tri-Reforming in SCW....................................283
References.....................................................285
Chapter 11 Water Dissociation Technologies for Hydrogen...................295
11.1 Introduction............................................295
11.2 Electrolysis and Its Derivative Technologies............297
11.2.1 Alkaline Electrolysis..........................298
1 1.2.2 HTE Process....................................298
1 1.2.3 HPE Process....................................299
1 1.2.4 Photoelectrolysis..............................300
1 1.2.5 Photo-Aided Electrolysis.......................300
1 1.2.6 Photovoltaic Electrolysis......................301
1 1.2.7 Solar Electrolysis.............................301
11.3 Photochemical and Its Derivative Technologies......... 301
1 1.3.1 Water Splitting on Semiconductor Catalysts
(Photocatalysis)................................302
1 1.3.1.1 Titanium Oxide Photocatalysts.........302
11.3.1.2 Tantalates and Niobates...............303
1 1.3.1.3 Transition-Melal Oxides, Nitrides,
and Oxynitrides.......................303
1 1.3.1.4 Metal Sulfides........................304
11.3.2 Photobiological Production of Hydrogen from
Water...........................................304
1 1.3.3 Plasma-Induced Photolysis......................305
11.4 Thermal and Thermochemical Decomposition of Water ... 305
11.4.1 Thermochemical Decomposition of Water..........307
11.4.1.1 The UT-3 Cycle........................308
11.4.1.2 Zn/ZnO Cycle..........................310
11.4.1.3 SnO/Sn02 Cycle........................311
11.4.1.4 Mixed Iron Oxide Cycle................311
11.4.1.5 Carbothermal Reduction of
Metal Oxides..........................312
11.4.1.6 Sulfur Family Thermochemical
Water Splitting Cycles................312
11.4.1.7 S-I Cycle.............................314
11.4.1.8 The Westinghouse Process..............315
1 1.4.1.9 Copper-Chlorine Cycle.................315
11.4.1.10 Copper-Sulfate Cycle..................316
11.5 Other Miscellaneous Technologies........................319
11.5.1 Chemical Methods...............................319
11.5.2 Magmalysis.....................................320
Contents
XIII
11.5.3 Radiolysis......................................320
11.5.4 Shock Waves and Mechanical Pulses...............320
11.5.5 Catalytic Decomposition of Water................321
11.5.6 Plasmoiysis.....................................321
11.5.7 Magnetolysis....................................321
References...................................................322
Chapter 12 Methane from Gas Hydrates....................................329
12.1 Introduction: What Is Gas Hydrate and How Is It Formed?.329
12.2 Sources, Sizes, and Importance of Gas Hydrate Deposits .... 330
12.3 Importance of Gas Hydrates on Offshore Oil and Gas
Operations.............................................335
12.3.1 Drilling........................................335
12.3.2 Production by Enhanced Oil and Gas Recovery
Methods.........................................336
12.3.3 Natural Gas Hydrates versus Liquefied Natural
Gas in Transportation...........................337
12.4 Environmental Impacts of Gas Hydrates .................337
12.5 Production of Methane from Gas Hydrate Reservoirs......339
12.5.1 Thermal Stimulation.............................340
12.5.2 Depressurization................................340
12.5.3 Inhibitor Injection.............................341
12.5.4 Gas Exchange....................................342
12.5.5 EGHR Method.....................................343
12.5.6 Computer Simulation.............................345
12.5.7 Commercial Applications.........................346
References...................................................346
Chapter 13 Power and Energy Directly from Water.........................361
13.1 Introduction...........................................361
13.2 Hydroelectric Power by Water Dams......................361
13.2.1 Conventional Dams...............................363
13.2.2 Pumped Storage..................................363
13.2.3 Other Methods...................................364
13.2.4 Advantages and Disadvantages of Hydroelectric
Power...........................................364
13.2.4.1 Advantages.............................364
13.2.4.2 Disadvantages..........................365
13.2.5 Environmental Issues............................365
13.2.6 Size and Capacities of Hydroelectric Power
Facilities......................................366
13.2.6.1 Small Hydropower Plants................366
13.2.6.2 Microhydropower Plants.................366
13.2.6.3 Picohydropower Plants..................367
XIV
Contents
13.3 Hydrokinetic Energy and Power Generation...............367
13.3.1 Why Hydrokinetic Energy?........................367
13.3.2 Hydrokinetic versus Hydroelectric Energy:
Potentials and Issues...........................369
! 3.3.3 Hydrokinetic Power Devices......................371
13.3.3.1 Wave Energy Converters.................372
13.3.3.2 Commercial Applications of WEC.........372
13.3.3.3 Rotating Hydrokinetic Devices..........376
13.3.3.4 Devices to Harness Tidal Power.........379
13.3.3.5 Hydrokinetic Power Barges..............380
13.3.3.6 Criteria for Choice of a Device and Its
Location...............................381
13.3.4 Recent Commercialization Examples in the
United States...................................382
13.4 Ocean Thermal Energy Conversion (OTEC)..................384
13.4.1 Operating Principles............................385
13.4.2 Operating Sites.................................386
13.4.3 Other Usages of OTEC............................387
13.4.4 Barriers to Implementation......................387
13.5 Growth of Hydrokinetic Energy and OTEC Industries
and Cost of Hydrokinetic and OTEC Power.................389
References....................................................390
Index......................................................................395
|
| any_adam_object | 1 |
| author | Shah, Yatish T. |
| author_GND | (DE-588)1029975272 |
| author_facet | Shah, Yatish T. |
| author_role | aut |
| author_sort | Shah, Yatish T. |
| author_variant | y t s yt yts |
| building | Verbundindex |
| bvnumber | BV044396680 |
| classification_rvk | ZP 3200 |
| ctrlnum | (OCoLC)1024110224 (DE-599)BVBBV044396680 |
| discipline | Energietechnik |
| edition | First issued in paperback |
| format | Book |
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| id | DE-604.BV044396680 |
| illustrated | Not Illustrated |
| indexdate | 2024-07-10T07:51:49Z |
| institution | BVB |
| isbn | 9781138076068 9781482216189 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-029798815 |
| oclc_num | 1024110224 |
| open_access_boolean | |
| owner | DE-703 |
| owner_facet | DE-703 |
| physical | xxi, 402 Seiten, 16 ungezählte Seiten Tafeln |
| publishDate | 2017 |
| publishDateSearch | 2017 |
| publishDateSort | 2017 |
| publisher | CRC Press |
| record_format | marc |
| series2 | Green chemistry and chemical engineering |
| spelling | Shah, Yatish T. Verfasser (DE-588)1029975272 aut Water for energy and fuel production Yatish T. Shah First issued in paperback Boca Raton ; London ; New York CRC Press 2017 xxi, 402 Seiten, 16 ungezählte Seiten Tafeln txt rdacontent n rdamedia nc rdacarrier Green chemistry and chemical engineering Energieversorgung (DE-588)4014736-8 gnd rswk-swf Wasser (DE-588)4064689-0 gnd rswk-swf Wasser (DE-588)4064689-0 s Energieversorgung (DE-588)4014736-8 s DE-604 Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029798815&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Shah, Yatish T. Water for energy and fuel production Energieversorgung (DE-588)4014736-8 gnd Wasser (DE-588)4064689-0 gnd |
| subject_GND | (DE-588)4014736-8 (DE-588)4064689-0 |
| title | Water for energy and fuel production |
| title_auth | Water for energy and fuel production |
| title_exact_search | Water for energy and fuel production |
| title_full | Water for energy and fuel production Yatish T. Shah |
| title_fullStr | Water for energy and fuel production Yatish T. Shah |
| title_full_unstemmed | Water for energy and fuel production Yatish T. Shah |
| title_short | Water for energy and fuel production |
| title_sort | water for energy and fuel production |
| topic | Energieversorgung (DE-588)4014736-8 gnd Wasser (DE-588)4064689-0 gnd |
| topic_facet | Energieversorgung Wasser |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029798815&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT shahyatisht waterforenergyandfuelproduction |