Main group metal coordination polymers: structures and nanostructures
Saved in:
| Main Authors: | , |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Beverly, MA
Scrivener
[2017]
Hoboken, NJ Wiley [2017] |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis Klappentext |
| Physical Description: | xvii, 240 pages Illustrationen, Diagramme |
| ISBN: | 9781119370239 |
Staff View
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| adam_text | Contents
Preface jj
Abbreviations xjü
1 Introduction to Coordination Polymers 1
1.1 Coordination Space 1
1.2 Coordination Polymer 2
1.3 Development of Coordination Polymer 5
1.4 Synthetic Methods 7
1.5 Design of Coordination Polymer 10
References 13
2 Application of Coordination Polymers 17
2.1 Introduction 17
2.2 Gas Storage 17
2.3 Catalysis 19
2.4 Luminescence 20
2.5 Redox Activity 21
2.6 Magnetism 21
2.6.1 Long-Range Magnetic Ordering 22
2.6.1.1 Molecule-Based Magnets 23
2.6.1.2 Single-Chain Magnets 24
2.6.2 Spin Crossover 24
2.7 Acentric and Chiral Networks 25
References 28
3 Zinc(II) Coordination Polymers 31
3.1 Introduction to Zinc(II) Coordination Polymers 31
3.1.1 Coordination Polymers Constructed from
Rigid Two-Connecting Ligands 33
3.1.1.1 Rod-Type Ligands 33
3.1.1.2 Angular, Rigid Two-Connectors 36
v
38
40
41
43
46
46
52
52
59
59
60
63
67
70
74
75
83
83
84
89
91
93
97
97
101
101
102
102
104
105
105
106
Contents
3.1.2 Coordination Polymers Constructed from
Rigid, Trigonal Three-Connectors
3.1.3 Coordination Polymers Constructed from
Carboxylates, Pyridine Carboxylates and
Pyrazine Carboxylates
3.1.4 Coordination Polymers Constructed from
Secondary Building Blocks (SBUs)
3.1.5 Coordination Polymers Constructed from
Conformational Flexible Ligands
3.1.6 Coordination Polymers Constructed from
Phosphate and Phosphonate Ligands
3.2 Nano Zinc(II) Coordination Polymers
3.3 Conclusion
References
Cadmium(II) Coordination Polymers
4.1 Introduction to Cadmium (II) Coordination Polymers
4.1.1 One-dimensional Coordination Polymers
4.1.2 Two-dimensional Coordination Polymers
4.1.3 Three-dimensional Coordination Polymers
4.2 Nano Cadmium(II) Coordination Polymers
4.3 Conclusion
References
Mercury(II) Coordination Polymers
5.1 Introduction Mercury(II) Coordination Polymers
5.1.1 One-dimensional Coordination Polymers
5.1.2 Two- dimensional Coordination Polymers
5.1.3 Three- dimensional Coordination Polymers
5.2 Nano Mercury(II) Coordination Polymers
5.3 Conclusion
References
Lead(II) Coordination Polymers
6.1 Introduction
6.2 Mono-donor Coordination Mode
6.2.1 Discrete Complexes
6.2.2 One-Dimensional Coordination Polymers
6.2.3 Two-Dimensional Coordination Polymers
6.2.4 Three-Dimensional Coordination Polymers
6.3 Bi-donor Coordination Polymers
Contents vii
6.3.1 Bridging (p^php1) Mode 106
6.3.1.1 Discrete Complexes 106
6.3.1.2 One-Dimensional Coordination
Polymers 106
6.3.1.3 Two-Dimensional Coordination
Polymers 107
6.3.1.4 Three-Dimensional Coordination
Polymers 108
6.4 Tri-donor Coordination Polymers 109
6.4.1 Bridging (p3-p3:p2) Mode 109
6.4.1.1 Two-Dimensional Coordination
Polymer 109
6.4.1.2 Three-Dimensional Coordination
Polymers 110
6.5 Tetra-donor Coordination 111
6.5.1 Chelating, Bridging (p3-p3: p2: p1) Mode 111
6.5.1.1 One-Dimensional Coordination
Polymers 111
6.5.1.2 Two-Dimensional Coordination
Polymers 112
6.5.1.3 Three-Dimensional Coordination
Polymers 113
6.6 Nano Lead(II) Coordination Polymers 113
6.7 Conclusion 122
References 123
7 Thallium(I) Coordination Polymers 131
7.1 Introduction to Thallium(I) Coordination Polymers 131
7.2 Thallium(I) Coordination Polymers 133
7.2.1 One-Dimensional Coordination Polymers
with Secondary Interactions in Tl1
Coordination Sphere 136
7.2.2 One-Dimensional Coordination Polymers
without Secondary Interactions in Tl1
Coordination Sphere 138
7.2.3 Two-Dimensional Coordination Polymers
with Secondary Interactions in Tl1
Coordination Sphere 138
7.2.4 Two-Dimensional Coordination Polymers
without Secondary Interactions in Tl1
Coordination Sphere 140
viii Contents
7.2.5 Three-Dimensional Coordination Polymers
with Secondary Interactions in Tl1
Coordination Sphere 141
7.2.6 Three-Dimensional Coordination Polymers
without Secondary Interactions in Tl1
Coordination Sphere 142
7.3 Nano Thallium(I) Coordination Polymers 143
7.4 Conclusion 147
References 147
8 Bismuth(III) Coordination Polymers 153
8.1 Introduction to Bismuth Coordination Polymers 153
8.2 Bismuth(III) Complexes with Monoaminopoly
Carboxylate 156
8.2.1 Bi(III) Complexes with Iminodiacetate
Ligands 156
8.2.2 Bi(III) Complexes with Nitrilotriacetate 156
8.2.3 Bi(III) Complexes with
2-hydroxyethyliminodiacetate 157
8.2.4 Bi(III) complexes with Pyridinedicarboxylate
Ligands 159
8.3 Bismuth(III) Complexes with Diaminopolycarboxylate
Ligands 160
8.3.1 Bi(III) Complexes with
Ethylenediaminetetraacetate 160
8.3.1.1 Protonated Bi(III)
Ethylenediaminetetraacetate
Complexes 160
8.3.1.2 Bi(III) Ethylenediaminetetraacetate
Complexes with Alkali Metal and
Ammonium Cations 161
8.3.1.3 Bi(III) Ethylenediaminetetraacetate
Complexes with Divalent Metal
Cations 162
8.3.1.4 Bi(III) Ethylenediaminetetraacetate
Complexes with Protonated Organic
Base Cations 163
8.3.1.5 Bi(III) Ethylenediaminetetraacetates
with Metal Complex Cations 164
Contents ix
8.3.1.6 Mixed-Ligand Bi(III)
Ethylenediaminetetraacetate
Complexes 165
8.3.2 Bi(III) Complexes with other than edta4՜
diaminopolycarboxylate Ligands 166
8.4 Bismuth Complexes with Polyaminopolycarboxylate
Ligands 167
8.4.1 Bi(III) Complexes with
Diethylenetriaminepentaacetate Ligands and
its Analogues 167
8.4.2 Bi(III) Complexes with
Triethylenetetraaminehexaacetate Ligands 168
8.4.3 Bi(III) Complexes with Macrocyclic
Polyaminopolycarboxylate Ligands 169
8.5 Applications 170
8.6 Nano Bismuth(III) Coordination Polymers 170
8.7 Conclusion 175
References 176
Main Group Metal Coordination Chemistry 183
9.1 Introduction 183
9.2 Group 12 185
9.3 Group 13 185
9.3.1 Boron 185
9.3.2 Aluminium 186
9.3.3 Gallium 188
9.3.4 Indium 190
9.3.5 Thallium 191
9.4 Group 14 191
9.4.1 Silicon 191
9.4.2 Germanium 192
9.4.3 Tin 194
9.4.4 Lead 195
9.5 Group 15 195
9.5.1 Phosphorus 195
9.5.2 Arsenic 195
9.5.3 Antimony 196
9.5.4 Bismuth 197
9.6 Group 16 198
References 199
x Contents
10 S-block Coordination Polymers (Group 1) 205
10.1 Introduction 205
10.2 Group 1(Alkali) Metal Coordination Polymers 206
10.2.1 Neutral Oxygen Donor Ligands 206
10.2.2 Anionic Oxygen Donor Ligands 208
10.2.2.1 Alkoxides and Aryloxides 208
10.2.2.2 Carboxylates 208
10.2.2.3 Sulfonates and Nitro-derivatives 209
10.2.2.4 Amino Acids 210
10.2.2.5 Mixed O-and N-donors 210
10.2.3 N-donor Ligands 211
10.2.4 Carbon Donor Ligands 211
10.2.5 Sulfur Donor Ligands 213
10.3 Conclusion 214
References 214
11 S-block Coordination Polymers (Group2) 219
11.1 Introduction 219
11.2 Group 2(Alkaline Earth) Metal Coordination
Polymers 220
11.2.1 Neutral Oxygen Donor Ligands 221
11.2.2 Anionic Oxygen Donor Ligands 222
11.2.2.1 Beta-diketonates 222
11.2.2.2 Alkoxides 222
11.2.2.3 Carboxylates 223
11.2.2.4 Phosphonates 224
11.2.2.5 Sulfonates 225
11.2.3 Mixed N- and O-donors 225
11.2.4 N-donor Ligands 225
11.2.5 Carbon Donor Ligands 226
11.2.6 Sulfur Donor Ligands 227
11.3 Conclusion 228
References 229
Glossary 233
Index
239
This first-ever book to discuss metal coordination chemistry at
the nano scale informs researchers and graduate students how
to understand metal coordination polymers in bulk and nano
dimensions and their applications.
Coordination polymer is a general term used to indicate an infinite array
composed of metal ions which are bridged by certain ligands among them.
This incorporates a wide range of architectures including simple one-
dimensional chains with small ligands to large mesoporous frameworks.
Generally, the formation process proceeds automatically and, therefore,
is called a self-assembly process. In general, the type and topology of the
product generated from the self-assembly of inorganic metal nodes and
organic spacers depend on the functionality of the ligand and valences
and the geometric needs of the metal ions used.
In this book the authors explain main group metal coordination polymer
in bulk and nano size with some of their application, synthesis method,
etc, The properties of these efficient materials are described at length
including magnetism (long-range ordering, spin crossover), porosity
(gas storage, ion and guest exchange), non-linear optical activity, chiral
networks, reactive networks, heterogeneous catalysis, luminescence,
multifunctional materials and other properties.
Audience
The core audience of this book is inorganic chemists working in the field
of coordination chemistry, coordination polymers and metal organic
frameworks, as well as nanotechnologists. PhD and master students will
find the book extremely valuable.
Ali Morsali is Master in Inorganic Chemistry in Tarbiat Modares
University, Tehran, Iran. He obtained his PhD in 2003 in Inorganic
Chemistry from the same university. He has published more than
400 articles in international journals as well as 5 patents. He has
received numerous national awards. Amongst his research interests are
coordination chemistry and metal-organic frameworks.
Lida Hashemi is a postdoctoral researcher at Tarbiat Modarers University,
Tehran, Iran. She obtained her PhD in inorganic chemistry from the same
university in 2014. She has published 30 articles in international journals
and has one patent to her name. Her research interests are coordination
chemistry, nanotechnology and metal-organic frameworks.
|
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| id | DE-604.BV044258602 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T07:48:00Z |
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| physical | xvii, 240 pages Illustrationen, Diagramme |
| publishDate | 2017 |
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| spelling | Morsali, Ali Verfasser (DE-588)1130278948 aut Main group metal coordination polymers structures and nanostructures Ali Morsali and Lida Hashemi, Department of Chemistry, Tarbiat Modares University, Tehran, Islamic Republic of Iran Beverly, MA Scrivener [2017] Hoboken, NJ Wiley [2017] © 2017 xvii, 240 pages Illustrationen, Diagramme txt rdacontent n rdamedia nc rdacarrier Coordination polymers Polymers Metal complexes Hauptgruppenmetall (DE-588)4588717-2 gnd rswk-swf Komplexe (DE-588)4133953-8 gnd rswk-swf Polymere (DE-588)4046699-1 gnd rswk-swf Polymere (DE-588)4046699-1 s Hauptgruppenmetall (DE-588)4588717-2 s Komplexe (DE-588)4133953-8 s DE-604 Hashemi, Lida Verfasser (DE-588)1130279030 aut Erscheint auch als Online-Ausgabe, ePub 978-1-449-37076-5 Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029663596&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029663596&sequence=000002&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
| spellingShingle | Morsali, Ali Hashemi, Lida Main group metal coordination polymers structures and nanostructures Coordination polymers Polymers Metal complexes Hauptgruppenmetall (DE-588)4588717-2 gnd Komplexe (DE-588)4133953-8 gnd Polymere (DE-588)4046699-1 gnd |
| subject_GND | (DE-588)4588717-2 (DE-588)4133953-8 (DE-588)4046699-1 |
| title | Main group metal coordination polymers structures and nanostructures |
| title_auth | Main group metal coordination polymers structures and nanostructures |
| title_exact_search | Main group metal coordination polymers structures and nanostructures |
| title_full | Main group metal coordination polymers structures and nanostructures Ali Morsali and Lida Hashemi, Department of Chemistry, Tarbiat Modares University, Tehran, Islamic Republic of Iran |
| title_fullStr | Main group metal coordination polymers structures and nanostructures Ali Morsali and Lida Hashemi, Department of Chemistry, Tarbiat Modares University, Tehran, Islamic Republic of Iran |
| title_full_unstemmed | Main group metal coordination polymers structures and nanostructures Ali Morsali and Lida Hashemi, Department of Chemistry, Tarbiat Modares University, Tehran, Islamic Republic of Iran |
| title_short | Main group metal coordination polymers |
| title_sort | main group metal coordination polymers structures and nanostructures |
| title_sub | structures and nanostructures |
| topic | Coordination polymers Polymers Metal complexes Hauptgruppenmetall (DE-588)4588717-2 gnd Komplexe (DE-588)4133953-8 gnd Polymere (DE-588)4046699-1 gnd |
| topic_facet | Coordination polymers Polymers Metal complexes Hauptgruppenmetall Komplexe Polymere |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029663596&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029663596&sequence=000002&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT morsaliali maingroupmetalcoordinationpolymersstructuresandnanostructures AT hashemilida maingroupmetalcoordinationpolymersstructuresandnanostructures |