Rheology and processing of polymer nanocomposites:
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| Other Authors: | , , |
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| Format: | Book |
| Language: | English |
| Published: |
Hoboken, New Jersey
Wiley
[2016]
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| Subjects: | |
| Online Access: | Inhaltsverzeichnis Klappentext |
| Physical Description: | xvi, 600 Seiten Illustrationen, Diagramme |
| ISBN: | 9781118969793 |
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| 245 | 1 | 0 | |a Rheology and processing of polymer nanocomposites |c edited by Sabu Thomas, Rene Muller, Jiji Abraham |
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CONTENTS
List of Contributors xiii
1 Materials for Polymer Nanoeomposites 1
Jiji Abraham, Soney C. George, Rene Muller, Nandakumar Kalarikkal,
and Sabu Thomas
1.1 Introduction, 1
1.2 Nanocomposite Framework, 3
1.2.1 Nanoscale Fillers, 3
1.2.2 Choice of Polymeric Matrices, 13
1.3 Recent Developments and Opportunities in the Area of Polymer
Nanocomposites, 16
1.4 Challenges in the Area of Polymer Nanocomposites, 17
1.5 Relationships of Macroscopic Rheological Properties to Nanoscale
Structural Variables, 18
1.6 Conclusion, 19
Acknowledgments, 20
References, 20
2 Manufacturing Polymer Nanocomposites 29
Yuvaraj Haldorai and Jae-Jin Shim
2.1 Introduction, 29
2.2 Nanofillers, 30
2.2.1 Structure and Properties of Clay, 31
2.2.2 Structure and Properties of Organically Modified Clay, 32
2.2.3 Structure and Properties of CNTs, 33
vi
CONTENTS
2.3 Polymer Matrices, 36
2.4 Preparation of Nanocomposites, 37
2.4.1 In Situ Polymerization, 37
2.4.2 Solution Blending, 39
2.4.3 Melt Compounding, 42
2.4.4 Other Methods, 54
2.4.5 Supercritical C02 Assisted Compounding, 55
2.5 Characterization, 58
2.6 Conclusions, 60
References, 61
3 Rheology and Processing of Polymer Nanocomposites: Theory, Practice,
and New Challenges 69
Jean-Charles Majesté
3.1 Introduction, 69
3.2 Viscoelasticity of Nanocomposites, 72
3.2.1 General Trends, 72
3.2.2 Percolation Treshold, 75
3.2.3 Equilibrium Shear Modulus, 78
3.2.4 Validity of TTS Principle, 81
3.2.5 Quantifying Dispersion via Melt Rheology, 83
3.2.6 Payne Effect, 87
3.3 Flow Properties of Nanocomposites, 92
3.3.1 Steady-State Flow Curves: Relative Viscosity and Normal
Stress Difference, 93
3.3.2 Flow-Induced Structure in Nanocomposites, 97
3.3.3 Elongational Flow, 99
3.4 Theory and Modeling of Nanocomposites Rheology, 103
3.4.1 Steady-State Viscosity, 104
3.4.2 Dynamic Rheology, 105
3.4.3 Elongational Rheology, 109
3.4.4 Payne Effect, 113
3.5 Processing of Nanocomposites, 119
3.5.1 Influence of Blending Procedure, 119
3.5.2 Usual Processing Methods, 121
3.5.3 New Processing Routes, 124
3.6 Conclusion and Futures Challenges, 125
Acknowledgments, 127
References, 127
4 Mixing of Polymers Using the Elongational Flow Mixer (RMX®) 135
Rigoberto Ibarra-Gômez and René Muller
4.1 Introduction, 135
4.2 Polymer Blends, 136
CONTENTS
vii
4.2.1 Capillary Number, Ca, 138
4.2.2 Rheology and Processing of Polymer Blends, 142
4.3 Polymer Nanocomposites, 147
4.3.1 Dispersion of Solid Additives, 148
4.4 Elongational Flow Mixer (RMX®), 151
4.4.1 RMX® Assembly and Operating Principles, 152
4.4.2 RMX® Flow Analysis by Numeric Simulation, 155
4.4.3 Estimation of Rheological Parameters in the RMX® via
Capillary Rheometry, 156
4.5 RMX® Mixing of Polymer Blends, 158
4.5.1 Influence of the RMX® Parameters on Mixing, 159
4.5.2 Influence of the Viscosity Ratio, p9 165
4.5.3 Energy of Mixing: Performance Comparison, 168
4.5.4 Viscous Heating, 170
4.5.5 Effect of a Compatibilizer, 170
4.5.6 Rheology/Morphology Relationship, 172
4.6 Mixing of Polymer Nanocomposites, 173
4.7 Concluding Remarks, 182
References, 182
5 Rheology and Processing of Polymer/Layered Silicate
Nanocomposites 187
Masami Окатої о
5.1 Introduction, 187
5.2 Nanostructure Development, 189
5.2.1 Melt Intercalation, 189
5.2.2 Interlayer Structure of OMLFs and Intercalation, 190
5.3 Novel Compounding Methods for Delamination of OMLFs, 199
5.3.1 Solid-State Shear Processing, 200
5.4 Nanostructure and Rheological Properties, 202
5.4.1 Flocculation Control and Modulus Enhancement, 202
5.4.2 Linear Viscoelastic Properties, 205
5.4.3 Relaxation Rate and Crystallization, 210
5.4.4 Nonlinear Shear Response, 213
5.4.5 Analogy to Soft Colloids, 214
5.4.6 Reversibility of Network Formation Process, 215
5.4.7 Alignment of Silicate Layers in Networks, 218
5.5 Nanocomposite Foams, 222
5.5.1 Foam Processing Using Supercritical C02, 222
5.5.2 PLA-Based Nanocomposite Foams, 224
5.5.3 Polyethylene Ionomer-Based Nanocomposite Foams by
MuCell® Injection Molding, 227
5.6 Future Prospects, 230
References, 230
CONTENTS
6 Processing and Rheological Behaviors of CNT/Polymer
Nanocomposites 235
Mohan Raja, Modigunta Jeevan Kumar Reddy\ Kwang Ho Won, Jae Ik Kim,
Sang Hun Cha, Han Na Bae, Dae Hyeon Song, Sung Hun Ryu,
and Andikkadu Masilamani Shanmugharaj
6.1 Introduction, 235
6.2 Processing Techniques of Polymer/CNT Nanocomposites, 237
6.2.1 Solution Processing, 238
6.2.2 Dry Powder, Wet, and Partial Solution Mixing, 241
6.2.3 In Situ Polymerization, 242
6.2.4 Melt Blending, 249
6.3 Rheological Properties of Polymer/Carbon Nanotube Composites, 254
6.3.1 Dilute Regime, 254
6.3.2 Semidilute Regime, 255
6.4 Summary, 274
Acknowledgment, 274
References, 274
7 Unusual Phase Separation in PS Rich Blends with PVME in Presence of
MWNTs 279
Priti Xavier and Suryasarathi Bose
7.1 Introduction, 279
7.2 Experimental Methods, 280
7.2.1 Materials and Sample Preparation, 280
7.2.2 Characterization, 281
7.3 Theory Background, 281
7.4 Results and Discussion, 284
7.4.1 Rheologically Determined Demixing Temperature, 284
7.4.2 Evolution of Morphology in the Blends in Presence of
MWNTs, 286
7.5 Conclusions, 291
Acknowledgements, 291
References, 291
8 Rheology and Processing of Polymer/POSS Nanocomposites 293
Krzysztof Pie lichowski, Tomasz M. Majka, and
Konstantinos N. Raftopoulos
8.1 Introduction, 293
8.2 Polyhedral Oligomeric Silsesquioxanes, 296
8.2.1 General Interactions between Polymer Matrices and POSS
Particles, 297
8.3 Processing of Polymer/POSS Nanocomposites, 299
8.3.1 Polyolefin/POSS Nanocomposites, 299
CONTENTS
ix
8.3.2 Polyamide/POSS Nanocomposites, 306
8.3.3 Polyurethane/POSS Nanocomposites, 309
8.3.4 Other Polymer/POSS Nanocomposites, 310
8.4 Rheological Behavior of POSS-Based Polymer Nanocomposites, 314
8.5 Conclusions, 318
Acknowledgments, 320
References, 320
9 Polymer and Composite Nanofiber: Electrospinning Parameters and
Rheology Properties 329
Palaniswamy Suresh Kumar, Sundaramurthy Jayaraman, and
Gurdev Singh
9.1 Introduction, 329
9.2 Electrospinning, 331
9.3 Electrospinning Process Parameters, 333
9.3.1 Solution Properties, 333
9.3.2 Operating Conditions, 335
9.3.3 Process Conditions, 336
9.4 Polymer-Based Nanofiber and its Rheology, 337
9.5 Nanofiber and its Polymer Composites, 348
9.6 Conclusion, 351
References, 351
10 Rheology and Processing of Inorganic Nanomaterials and Quantum
Dots/Polymer Nanocomposites 355
Sneha Mohan, Jiji Abrahamt Oluwatobi S. Oluwafemi,
Nandakumar Kalarikkal, and Sabu Thomas
10.1 Inorganic Nanoparticle Filled Polymer Nanocomposites, 356
10.2 Fabrication of Inorganic Nanoparticle Filled Polymer
Nanocomposites, 356
10.3 Why Rheological Study is Important for Polymer
Nanocomposites, 357
10.3.1 Assessment of the Dispersion Quality, 358
10.3.2 Assessment of Processability, 358
10.3.3 Assessment of Correlation between Molecular Structure and
Dynamics of Polymers (Structure-Property Relationship), 359
10.4 Rheology of Quantum Dot Based Polymer
Nanocomposites, 359
10.5 Metal Oxide Nanoparticle-Based Polymer Nanocomposites, 366
10.5.1 Alumina, 366
10.5.2 Silica, 368
10.5.3 Titania, 372
10.5.4 Zinc Oxide, 376
x CONTENTS
10.5.5 Ferrite Nanoparticles, 376
10.5.6 Calcium Carbonate, 377
10.6 Conclusion, 379
References, 379
11 Rheology and Processing of Laponite/Polymer Nanocomposites 383
Huili Li, Wenchen Ren, Jiulong Zhu, Shimei Xu, and Jide Wang
11.1 Introduction, 383
11.2 Rheology, 384
11.2.1 Linear Viscoelastic Properties, 384
11.2.2 Nonlinear Viscoelastic Properties, 387
11.3 Processing, 388
11.3.1 Melt Blending, 389
11.3.2 Solution Blending, 390
11.3.3 In Situ Polymerization, 392
11.4 Conclusions and Outlook, 399
Acknowledgement, 400
References, 400
12 Graphene-Based Nanocomposites: Mechanical, Thermal, Electrical, and
Rheological Properties 405
Rachid Bouhfid, Hamid Essabir, and Abou el kacem Qaiss
12.1 Introduction, 405
12.2 Graphene, 407
12.3 The Use of Graphene in Nanocomposite Materials, 408
12.3.1 Problematic, 410
12.3.2 Manufacturing Technique of Graphene-Based
Nanocomposites, 411
12.4 Nanocomposite Characterization, 412
12.4.1 Structural Properties of Graphene Nanocomposites, 412
12.4.2 Thermal Stability, 414
12.4.3 Crystallization and Melting Properties, 416
12.4.4 Mechanical Properties, 418
12.4.5 Rheological Properties, 421
12.4.6 Electrical Properties, 423
12.5 Conclusion, 425
12.6 Future Perspective, 425
References, 426
13 Processing, Rheology, and Electrical Properties of Polymer/Nanocarbon
Black Composites 431
Luís C Costa and Manuel P Graça
13.1 Introduction, 431
CONTENTS
xi
13.2 Experimental, 435
13.2.1 Sample Preparation, 435
13.2.2 Characterization Techniques, 436
13.3 Electrical Properties of Carbon Black Composites and
Applications, 437
13.3.1 DC Conductivity, 437
13.3.2 AC Conductivity, 440
13.3.3 Positive Temperature Coefficient in Resistivity, 444
13.4 Conclusion, 447
References, 447
14 Rheology and Processing of Nanocellulose, Nanochi tin, and
Nanostarch/Polymer Bionanocomposites 453
Camen֊Alice Teacâ and Ruxanda Bodirlau
14.1 Introduction, 453
14.2 Biopolymers as Nanohllers for Polymer/Nanocomposites, 455
14.2.1 Nanocellulose, 455
14.2.2 Processing of Nanocellulose/Polymer Nanocomposites, 456
14.2.3 Nanochitin, 459
14.2.4 Processing of Nanochitin/Polymer Nanocomposites, 459
14.2.5 Nanostarch, 476
14.2.6 Processing of Nanostarch/Polymer Nanocomposites, 477
14.3 Potential Applications of Polysaccharide Nanofillers/Polymer
Nanocomposites, 478
14.4 Conclusions and Future Perspectives, 481
References, 482
15 Rheology and Processing of Nanoparticle Filled Polymer Blend
Nanocomposites 491
Chongwen Huang and Wei Yu
15.1 Rheology of Polymer Blends, 491
15.1.1 Miscible Blends, 491
15.1.2 Immiscible Blends, 495
15.1.3 Partially Miscible Blends, 502
15.2 Effect of Nanoparticles on the Morphology of Polymer
Blend, 509
15.2.1 Selective Distribution, 510
15.2.2 Phase Separation, 523
15.3 Rheology of Nanoparticles Filled Polymer Blend, 531
15.3.1 Viscoelasticity of Partially Miscible Systems, 531
15.3.2 Viscoelasticity of Polymer Blend Nanocomposites, 535
15.4 Summary, 540
References, 541
xü
CONTENTS
16 Rheology as a Tool for Studying In Situ Polymerized Carbon
Nano tube Nanocomposites 551
Guo-Hua Hu, Philippe Marchal, Sandrine Hoppe, and Christian Penu
16.1 Introduction, 551
16.2 Basic Principles of Rheokinetics, 552
16.2.1 Systemic Rheology: Couette Analogy/Mixer-Type
Rheology, 552
16.2.2 A Couette-Type Rheoreactor for the Kinetics of In Situ
Polymerization, 558
16.3 Rheokinetics of In Situ Polymerization of Carbon Nanotube/Monomer
Systems, 560
16.3.1 Effects of the Presence of MWCNT on the Polymerization
Kinetics, 560
16.3.2 Effect of the State of Dispersion of Carbon Nanotubes on the
Polymerization Kinetics, 563
16.3.3 Inhibiting Effect of the MWCNT on the Polymerization
Kinetics, 564
16.4 Rheological Percolation Threshold of Carbon Nanotube-Based
Nanocomposites, 567
16.4.1 Experimental Procedures, 567
16.4.2 Percolation Threshold Observed by Mechanical
Spectroscopy, 568
16.4.3 Electrical Percolation Threshold, 576
16.4.4 Determination of the Percolation Threshold by Mechanical
Spectroscopy, 576
16.4.5 Electrical versus Rheological Percolations, 578
16.5 Concluding Remarks, 581
References, 581
Index
587
With increasing frequency, the utilization of polymer nanocomposites continues
to revolutionize the field of plastics processing for advanced technologies. Rheology
and Processing of Polymer Nanocomposites presents a comprehensive overview of
cutting-edge advances, current trends, and future challenges in the characterization
of nanofiller/polymer interactions, nanofiller dispersion, distribution, filler-filler
interactions, and interfaces in polymer nanocomposites. Special emphasis is placed on
nanoscale dispersion of fillers and filler/polymer interactions, recent developments in
the characterization of polymer nanocomposites by rheology, and various unresolved
issues and challenges in the processing of polymer nanocomposites. To ensure
relevance to all, readings are contributed by leading researchers carefully chosen
from industry, academy, government, and private research institutions around the
world. Topics addressed include advancements in the mixing of various nanofillers
with polymeric materials, rheological percolation, filler-filler interactions, and filler
network formation in the polymer matrix. Rheological results are compared with
microsopy, SAXS, dielectric spectroscopy, and other sensitive techniques. Other
topics include the rheo-optical characterization of polymer nanocomposites and
the characterization of polymer nanocomposites based on rheo-SAS analysis -
which allows for the investigation of flow-induced microscopic or nanoscopic scale
structure of complex polymer nanocomposite. Rheology and Processing of Polymer
Nanocomposites is an indispensable and invaluable resource for those seeking the
current state of knowledge in all areas of this increasingly important field.
• Represents the first resource dealing with recent advances in the interfaces of
polymer nanocomposites
♦ Offers invaluable benefits to academics, researchers, scientists, engineers, and
in the field of polymer nanocomposites
• Comprehensively summarizes the wealth of recent technical research
accomplishments in filler/polymer interactions of polymer nanocomposites
* Discusses and compares various important characterization techniques to aid
scientists in decision-making on a particular problem
students for solving problems |
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| discipline | Physik Werkstoffwissenschaften / Fertigungstechnik |
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| id | DE-604.BV043932381 |
| illustrated | Illustrated |
| indexdate | 2024-11-04T13:01:48Z |
| institution | BVB |
| isbn | 9781118969793 |
| language | English |
| lccn | 016007780 |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-029341403 |
| oclc_num | 981912145 |
| open_access_boolean | |
| owner | DE-703 DE-29T DE-83 |
| owner_facet | DE-703 DE-29T DE-83 |
| physical | xvi, 600 Seiten Illustrationen, Diagramme |
| publishDate | 2016 |
| publishDateSearch | 2016 |
| publishDateSort | 2016 |
| publisher | Wiley |
| record_format | marc |
| spelling | Rheology and processing of polymer nanocomposites edited by Sabu Thomas, Rene Muller, Jiji Abraham Hoboken, New Jersey Wiley [2016] xvi, 600 Seiten Illustrationen, Diagramme txt rdacontent n rdamedia nc rdacarrier Rheology Plasticity Polymers Nanocomposites (Materials) Nanokomposit (DE-588)4768127-5 gnd rswk-swf Kunststoff (DE-588)4033676-1 gnd rswk-swf Rheologie (DE-588)4049828-1 gnd rswk-swf Polymere (DE-588)4046699-1 gnd rswk-swf Polymergemisch (DE-588)4175243-0 gnd rswk-swf Verbundwerkstoff (DE-588)4062670-2 gnd rswk-swf Polymere (DE-588)4046699-1 s Verbundwerkstoff (DE-588)4062670-2 s Rheologie (DE-588)4049828-1 s DE-604 Kunststoff (DE-588)4033676-1 s Nanokomposit (DE-588)4768127-5 s Polymergemisch (DE-588)4175243-0 s Thomas, Sabu 1960- (DE-588)1021317551 edt Muller, René 1955- (DE-588)1126209325 edt Abraham, Jiji edt Erscheint auch als Online-Ausgabe, EPUB 978-1-118-96981-6 Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029341403&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029341403&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
| spellingShingle | Rheology and processing of polymer nanocomposites Rheology Plasticity Polymers Nanocomposites (Materials) Nanokomposit (DE-588)4768127-5 gnd Kunststoff (DE-588)4033676-1 gnd Rheologie (DE-588)4049828-1 gnd Polymere (DE-588)4046699-1 gnd Polymergemisch (DE-588)4175243-0 gnd Verbundwerkstoff (DE-588)4062670-2 gnd |
| subject_GND | (DE-588)4768127-5 (DE-588)4033676-1 (DE-588)4049828-1 (DE-588)4046699-1 (DE-588)4175243-0 (DE-588)4062670-2 |
| title | Rheology and processing of polymer nanocomposites |
| title_auth | Rheology and processing of polymer nanocomposites |
| title_exact_search | Rheology and processing of polymer nanocomposites |
| title_full | Rheology and processing of polymer nanocomposites edited by Sabu Thomas, Rene Muller, Jiji Abraham |
| title_fullStr | Rheology and processing of polymer nanocomposites edited by Sabu Thomas, Rene Muller, Jiji Abraham |
| title_full_unstemmed | Rheology and processing of polymer nanocomposites edited by Sabu Thomas, Rene Muller, Jiji Abraham |
| title_short | Rheology and processing of polymer nanocomposites |
| title_sort | rheology and processing of polymer nanocomposites |
| topic | Rheology Plasticity Polymers Nanocomposites (Materials) Nanokomposit (DE-588)4768127-5 gnd Kunststoff (DE-588)4033676-1 gnd Rheologie (DE-588)4049828-1 gnd Polymere (DE-588)4046699-1 gnd Polymergemisch (DE-588)4175243-0 gnd Verbundwerkstoff (DE-588)4062670-2 gnd |
| topic_facet | Rheology Plasticity Polymers Nanocomposites (Materials) Nanokomposit Kunststoff Rheologie Polymere Polymergemisch Verbundwerkstoff |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029341403&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029341403&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT thomassabu rheologyandprocessingofpolymernanocomposites AT mullerrene rheologyandprocessingofpolymernanocomposites AT abrahamjiji rheologyandprocessingofpolymernanocomposites |