Mode of Action of Adjuvants for Foliar Application: = Wirkmechanismen von Adjuvantien für die Blattflächenapplikation
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| Main Author: | |
|---|---|
| Format: | Thesis Book |
| Language: | English |
| Published: |
Würzburg
2016
|
| Subjects: | |
| Online Access: | Volltext Inhaltsverzeichnis |
| Physical Description: | xiv, 168 Seiten Illustrationen, Diagramme |
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| 245 | 1 | 0 | |a Mode of Action of Adjuvants for Foliar Application |b = Wirkmechanismen von Adjuvantien für die Blattflächenapplikation |c submitted by Elisabeth Asmus from Bad Salzungen |
| 246 | 1 | 1 | |a Wirkmechanismen von Adjuvantien für die Blattflächenapplikation |
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| 502 | |b Dissertation |c Julius-Maximilians-Universität Würzburg |d 2016 | ||
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Record in the Search Index
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| adam_text | MODE OF ACTION OF ADJUVANTS FOR FOLIAR APPLICATION
WIRKMECHANISMEN VON ADJUVANTIEN FUER DIE
BLATTFLAECHENAPPLIKATION
DOCTORAL THESIS FOR A DOCTORAL DEGREE
AT THE GRADUATE SCHOOL OF LIFE SCIENCES,
JULIUS-MAXIMILIANS-UNIVERSITAET WUERZBURG,
SECTION INTEGRATIVE BIOLOGY
SUBMITTED BY
ELISABETH ASMUS
FROM
BAD SALZUNGEN
WUERZBURG 2016
TABLE OF CONTENTS
TABLE OF CONTENTS
.........................................................................................
I
SUMMARY............................................................................................................
V
ZUSAMMENFASSUNG........................................................................................
IX
ABBREVIATIONS..............................................................................................XIII
1 INTRODUCTION
............................................................................................
1
1.1 CHALLENGES OF CROP PROTECTION
APPLICATION.................................................1
1.2 THE PLANT CUTICULAR
MEMBRANE..................................................................3
1.3 MODE OF ACTION OF
ADJUVANTS......................................................................9
1.4 SURFACTANTS AND THEIR PHYSICOCHEMICAL
PROPERTIES...................................12
1.4.1 SORBITAN FATTY ACID
ESTERS...................................................................14
1.4.2 POLYOXYETHYLENE SORBITAN FATTY ACID ESTERS
.......................................
15
1.4.3 OLEYL ALCOHOL POLYGLYCOL ETHER
...........................................................
20
1.4.4 LIST OF
CHEMICALS...............................................................................
21
1.5 MOTIVATIONS AND OBJECTIVES OF THIS
WORK...................................................22
2 CHARTER I: FROM THE NOZZLE TO THE LEAF SURFACE-SPRAY
DROPLET RETENTION AND
WETTING............................................................ 25
2.1 INTRODUCTION
..................................
25
2.2 MATERIALS AND
METHODS...........................................................................
32
2.2.1
CHEMICALS........................................................................................
32
2.2.2 EQUILIBRIUM SURFACE
TENSION..............................................................32
2.2.3 DYNAMIC SURFACE
TENSION..................................................................34
2.2.4 CONTACT ANGLE
MEASUREMENT............................................................35
2.2.5 DROPLET SPREAD
AREA..........................................................................36
2.2.6 VISUALISATION OF SURFACE STRUCTURES BY
SEM......................................37
2.2.7 T RACK SPRAYER
EXPERIMENTS...............................................................37
2.3
RESULTS....................................................................................................
40
2.3.1 EQUILIBRIUM SURFACE
TENSION...............................................................40
2.3.2 DYNAMIC SURFACE
TENSION..................................................................41
2.3.3 CONTACT ANGLE
MEASUREMENT.............................................................42
2.3.4 DROPLET SPREAD
AREA..........................................................................48
2.3.5 VISUALISATION OF SURFACE STRUCTURES BY SEM
......................................
50
2.3.6 T RACK SPRAYER
EXPERIMENTS...............................................................54
2.4
DISCUSSION...............................................................................................
56
2.4.1 SURFACE TENSION
MEASUREMENTS........................................................56
2.4.2 WETTING CHARACTERISTICS OF SELECTED SURFACTANTS
................................
60
2.4.3 SPRAY DROPLET RETENTION EXPERIMENTS
................................................
65
3 CHARTER II: THE HUMECTANT PROPERTIES OF ADJUVANTS
..........
71
3.1
INTRODUCTION.............................................................................................
72
3.2 MATERIALS AND
METHODS............................................................................75
3.2.1
CHEMICALS.........................................................................................
75
3.2.2 CALCULATION OF HYDROPHILIC-LIPOPHILIC BALANCE (HLB) VALUES
...............
76
3.2.3 WATER SORPTION
ISOTHERMS..................................................................76
3.3
RESULTS....................................................................................................
78
3.4
DISCUSSION...............................................................................................
80
4 CHARTER III: EFFECTS OF ADJUVANTS ON PINOXADEN
PENETRATION THROUGH CUTICULAR MEMBRANES AND INTO INTACT
PLANTS...............................................................................................................89
4.1
INTRODUCTION.............................................................................................
89
4.2 MATERIALS AND
METHODS............................................................................97
4.2.1
CHEMICALS.........................................................................................
97
4.2.2 CUTICULAR MEMBRANES
......................................................
97
4.2.3 CUTICULAR PENETRATION EXPERIMENTS
...................................................
98
4.2.4 ANALYTICAL ANALYSIS OF
PINOXADEN......................................................99
4.2.5 ADJUVANT IMPACT ON IN VIVO ACTION OF PINOXADEN
..............................
99
4.3 RESULTS
..................................................................................................
102
4.3.1 CUTICULAR PENETRATION
EXPERIMENTS..................................................102
4.3.2 ADJUVANT IMPACT ON
IN VIVO ACTION OF PINOXADEN.............................109
4.4
DISCUSSION............................................................................................
114
4.4.1 CUTICULAR PENETRATION
EXPERIMENTS..................................................114
4.4.2 ADJUVANT IMPACT ON IN VIVO ACTION OF
PINOXADEN.............................124
5 SUMMARISING DISCUSSION AND
OUTLOOK......................................131
6 REFERENCES
...........................................................................................
141
APPENDIX.........................................................................................................157
ACKNOWLEDGEMENTS
.................................................................................
165
PUBLICATIONS AND
PRESENTATIONS........................................................
166
CURRICULUM
VITAE........................................................................................167
AFFIDAVIT.........................................................................................................168
EIDESSTATTLICHE ERKLAERUNG
..................................................................
168
IN
|
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| spelling | Asmus, Elisabeth 1989- Verfasser (DE-588)111628765X aut Mode of Action of Adjuvants for Foliar Application = Wirkmechanismen von Adjuvantien für die Blattflächenapplikation submitted by Elisabeth Asmus from Bad Salzungen Wirkmechanismen von Adjuvantien für die Blattflächenapplikation Würzburg 2016 xiv, 168 Seiten Illustrationen, Diagramme txt rdacontent n rdamedia nc rdacarrier Dissertation Julius-Maximilians-Universität Würzburg 2016 Zusammenfassung in deutscher und englischer Sprache Pflanzenschutzmittel (DE-588)4045587-7 gnd rswk-swf Adjuvans (DE-588)4141430-5 gnd rswk-swf Kutikula (DE-588)4166263-5 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Adjuvans (DE-588)4141430-5 s Pflanzenschutzmittel (DE-588)4045587-7 s Kutikula (DE-588)4166263-5 s DE-604 Erscheint auch als Online-Ausgabe urn:nbn:de:bvb:20-opus-138159 https://nbn-resolving.org/urn:nbn:de:bvb:20-opus-138159 Resolving-System kostenfrei Volltext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029238911&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Asmus, Elisabeth 1989- Mode of Action of Adjuvants for Foliar Application = Wirkmechanismen von Adjuvantien für die Blattflächenapplikation Pflanzenschutzmittel (DE-588)4045587-7 gnd Adjuvans (DE-588)4141430-5 gnd Kutikula (DE-588)4166263-5 gnd |
| subject_GND | (DE-588)4045587-7 (DE-588)4141430-5 (DE-588)4166263-5 (DE-588)4113937-9 |
| title | Mode of Action of Adjuvants for Foliar Application = Wirkmechanismen von Adjuvantien für die Blattflächenapplikation |
| title_alt | Wirkmechanismen von Adjuvantien für die Blattflächenapplikation |
| title_auth | Mode of Action of Adjuvants for Foliar Application = Wirkmechanismen von Adjuvantien für die Blattflächenapplikation |
| title_exact_search | Mode of Action of Adjuvants for Foliar Application = Wirkmechanismen von Adjuvantien für die Blattflächenapplikation |
| title_full | Mode of Action of Adjuvants for Foliar Application = Wirkmechanismen von Adjuvantien für die Blattflächenapplikation submitted by Elisabeth Asmus from Bad Salzungen |
| title_fullStr | Mode of Action of Adjuvants for Foliar Application = Wirkmechanismen von Adjuvantien für die Blattflächenapplikation submitted by Elisabeth Asmus from Bad Salzungen |
| title_full_unstemmed | Mode of Action of Adjuvants for Foliar Application = Wirkmechanismen von Adjuvantien für die Blattflächenapplikation submitted by Elisabeth Asmus from Bad Salzungen |
| title_short | Mode of Action of Adjuvants for Foliar Application |
| title_sort | mode of action of adjuvants for foliar application wirkmechanismen von adjuvantien fur die blattflachenapplikation |
| title_sub | = Wirkmechanismen von Adjuvantien für die Blattflächenapplikation |
| topic | Pflanzenschutzmittel (DE-588)4045587-7 gnd Adjuvans (DE-588)4141430-5 gnd Kutikula (DE-588)4166263-5 gnd |
| topic_facet | Pflanzenschutzmittel Adjuvans Kutikula Hochschulschrift |
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